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By P. S. Daly

"The purpose of this paper is to describe the types of instrumentation used at Sherritt Gordon's Ruttan Mine to monitor the"" effects of mining. The aim of the monitoring program is to establish parameters to achieve a maximum ore recovery with minimum dilut ion in a safe environment.The copper-zinc Ruttan Mine is in northwestern Manitoba, approximately 760 km from Winnipeg (Fig . I) . Production commenced in 1973 from the open pit at the rate of 10,000 tons per day. Pit bottom lies 58 metres above the first mine level. Underground development has overlapped with open-pit mining throughout. The open pit was phased out in the latter part of 1980.Underground production began in early 1979. The mining method employed in the first lift is sub-level blasthole open stoping with delayed hydraulic filling. Large-diameter (6.5-in.) holes are being drilled in the crop stope area and are also planned for some other areas for vertical retreat mining into a slot. GeologyThe orebody consists of numerous sulphide lenses of variable size, geometry and geology . The lenses occur within volcanoclastic host rocks which exhibit a strong variability in intensity and type of alteration and structural characteristics. Stope design and sequencing were based on these complex geological factors."

Jan 1, 1981

By ByongPil Lee, Changkyu Lee, Jin Gyun Park, Hyung Sub Eom, Sung-Koo Jo, Jae-Young Lee, Gilsoo Han

"A new hydrometallurgical process for nickel extraction from a low grade laterite ore such as limonite has been developed by RIST and POSCO. This POSCO Nickel Extraction Process (PosNEP) consists of five main processes: ore reduction using hydrogen as a reductant; acid leaching at atmospheric pressure and temperature; cementation by the use of reduced-ore seed; production of the main product such as ferronickel or a high purity nickel compound; and production of by-products such as cobalt and iron in the forms of cobalt sulfate and iron oxide. In addition, hydrogen produced in acid leaching and hydrochloric acid regenerated in pyrohydrolysis for iron oxide production can be reused in the process, which makes PosNEP more cost-effective. The performance of PosNEP has been proven through pilot tests, showing that this process is economically and technically viable. In this paper, basic concepts and detailed test results of PosNEP are shown.INTRODUCTIONNickel has been extracted from two types of ore, sulfide and oxide ore. Nickel and cobalt usually occur together in the ores. The principal ore mineral of the sulfide is pentlandite, (Ni,Fe)9S8, which is easily beneficiated to produce sulfide concentrates(Moats & Davenport, 2014). These concentrates are usually treated by smelting and converting to make a matte. The produced matte is then purified through either hydrometallurgical or pyrometallurgical processes to produce high-purity nickel. In general, this process for sulfide ore has been known as a more cost-effective process than that for oxide ore.The oxide ore is laterite comprised of two different ore types, saprolite and limonite. The main nickel-bearing mineral of saprolite is nickeliferrous garnierite,(Mg,Ni)6Si4O10(OH)8, and that of limonite is nickeliferrous goethite (Fe,Ni)O·OH ore (Moats & Davenport, 2014). Since the saprolite has high contents of nickel and slag formers (MgO and SiO2) and a low content of iron, it tends to be treated by a pyrometallurgical smelting process such as calcination and electric furnace techniques to produce ferronickel for use in stainless steel. In this process, the cobalt in the ferronickel does not have any economic value."

Jan 1, 2017

By B. R. Casement

"Managing safety on the basis of after-the-fact reaction to accidents, can never be more than partially successful. Injuries will occur as long as the underlying potential for them still exists. Unless unsafe actions and conditions are systematically decreased, no program can have more than a short-term success.The pro-active Bullmoose loss control process, instead, focusses on heightening awareness of work habits, to prevent incidents by reducing their potential.Any safety program will be doomed to failure if the development of safe work habits depends on the safety supervisor or a safety committee. At Bullmoose the focus is on the critical actions out of which losses emerge. The successful application of performance-related feedback is achieved by taking safety, health, and environmental concerns into consideration on every level, and, by doing the right thing in every job done.What is an Exceptional Loss Control Program?If an accident in an organization creates a flurry of interest, resulting in ""cracking down"" on violations for a short period of time then an ""exceptional"" loss control program exists. Unfortunately, exceptional here does not refer to the effectiveness of quality of the program but to the fact that the organization is managing loss control by exception. The degree of management attention in an ""exceptional"" safety program varies over a period of time, remaining low as long as the rate of losses stays within management's acceptable control limit (Fig. I). When the losses rise above this, management becomes motivated to begin ""exceptional"" efforts to manage losses. When the rate falls again to within the accepted limit, efforts to control losses take a back seat.Such a strategy guarantees that losses will be tolerated or ignored as long as the actual rate is below the acceptable limit. Simply to lower the limit would not reduce losses, but would result in an increased number of flurries of management attention to loss control. This ""on-again, off-again"" style of management teaches supervisors and others that basic loss control is not as important as are statistics."

Jan 1, 1993

By T. R. Yu, D. B. Counter

"In an effort to increase productivity, the use of fly ash as a binder for consolidated backfill was studied. From laboratory and underground tests f or its cementitious properties and environmental effects, it was found that a portion of Portland cement could be replaced by the same amount of type ""C"" fly ash to produce an acceptable consolidated rockfill product for use at Kidd Creek.The environmental concerns in terms of dust control and emanation of radon gas were unfounded from measurements. The dust count was comparable to the use of Portland cement only, or with ground blast furnace slag, and the radiation readings were low, averaging one-seventh the regulation level.Since May 1984, a total of over 100 000tonnes of fly ash has been consumed as a binder blended with Portland cement, producing over four million tonnes of consolidated rockfill. To date, the fill in the stopes has performed very satisfactorily, while yielding considerable cost savings.IntroductionThe Kidd Creek minesite, located 27 km north of the city centre of Timmins, Ontario, produces 4.5 million tonnes of base metal sulphide ore annually. The mining method for both No. I and No .2 mines is mainly sub-level blasthole stoping with delayed backfilling.No. 1 mine was developed with a shaft to a depth of 930 m in 1973 to recover the ore between the floor of the open pit at the 216 m horizon, and the 792 m horizon. Stopes are normally 18 m wide, 22 m to 65 m long, with heights varying from 90 m to 135 m. Vertical rib pillars between stopes are typically 24 m wide and sill pillars are 30 m thick.Pillar recovery is implemented after the consolidated rockfill placed in the mined stopes has cured for a period of at least three months. This allows a maximum recovery of the ore with a minimum of dilution, while also maintaining safe working conditions.No. 2 mine was developed from a second shaft, sunk to a depth of 1530 m in 1978, for the recovery of ore beneath the No. I mine. Sub-level stoping in No .2 mine is similar to No.1 mine in methodology, yet differs in sequencing, as no rib pillars are left."

Jan 1, 1988

By K. E. Waters, J. E. Nesset, F. Rosenblum, J. A. Finch, S. Moon

"Some materials when exposed to various conditions can exhibit a rise in temperature without requiring an external heat source. Generally referred to as pyrophoric or self-heating substances, they challenge the safety of materials handling, storage and transportation. Reliably assessing the self-heating potential of materials is thus essential. Over the years a number of test protocols have been developed. A widely accepted method is that recommended by the United Nations to certify the safety of shipping pyrophoric goods. Our test work on sulphide materials has shown that the U.N. test can give false negatives if the sample oxidation history is not considered. Depending on the degree of oxidation (“weathering”), the same sulphide material can exhibit self-heating ranging from safe to hazardous. For concentrates, oxidation can occur during storage and transport making the sample weathering history an important consideration in the test work. To make the U.N. test, and other single-stage self-heating procedures, more reliable in assessing self-heating potential when testing sulphide materials, it is suggested that a weathering step be incorporated in the test protocol. This test work for two sulphide samples, an ore and a concentrate, demonstrates the impact of incorporating a weathering stage in the test protocol. INTRODUCTIONSelf-heating occurs when exothermic reactions produce heat faster than can be dissipated to the surroundings. Numerous substances self-heat, ranging from wood chips and powdered milk to coal and sulphide minerals (Beever & Crowhurst, 1989; Hudak, 2002). Mixtures of sulphide minerals, most notably those containing the iron sulphide pyrrhotite (Fe(1-x)S), commonly encountered in the extraction of base metals (e.g., copper, zinc, lead, and nickel), are particularly prone to self-heating (Rosenblum, Nesset, & Spira, 2001; Payant, Rosenblum, Nesset, & Finch, 2012). In the mining and subsequent processing stages, the minerals are progressively liberated and finely ground, then separated, usually by flotation, with the resulting concentrates stored and transported to smelters for metal extraction. At most of these stages the sulphides are exposed to both moisture and oxygen, conditions that promote partial sulphide oxidation and the formation of elemental sulphur. Studies have shown that pyrrhotite, in particular, readily oxidizes to form elemental sulphur (Bernier & Li, 2003; Belzile, Chen, Cai, & Li, 2004; Somot & Finch, 2010). The elemental sulphur becomes fuel for further self-heating as the temperature of the mineral mixture increases above 100 oC (Rosenblum & Spira, 1995; Somot & Finch, 2010). It is believed the propensity of pyrrhotite to self-heat is a result of its iron-deficient, and hence somewhat unstable structure. It is worth noting that pure metal sulphides (with the exception of pyrrhotite) do not exhibit appreciable self-heating. A mixture of minerals sufficiently different in their electrochemical rest potential is required to initiate self-heating at ambient temperatures (Payant et al., 2012)."

Jan 1, 2016

By Dirk van Zyl

The world is consuming more and more electronic products every year. This has caused a dangerous explosion in electronic scrap (e-waste) containing toxic chemicals and heavy metals that cannot be disposed of or recycled safely. But this problem can be avoided. We are pressing leading electronic companies to change; to turn back the toxic tide of e-waste. Every year, hundreds of thousands of old computers and mobile phones are dumped in landfills or burned in smelters. Thousands more are exported, often illegally, from the Europe, US, Japan and other industrialized countries, to Asia. There, workers at scrap yards, some of whom are children, are exposed to a cocktail of toxic chemicals and poisons.

May 1, 2008

By Edmond Chow

Shovel bucket blast fragmentation analysis is an alternate way to assess blast performance and its effects on downstream mining processes. A camera is installed on the boom of cable shovels, and the stick of hydraulic shovels. Images are captured automatically as the shovel digs, and are processed to acquire rock size information. The automatic data acquisition makes this method safe to use with minimal manual labour. It also allows for a large set of sample data to be captured from both the surface and the interior of a bench face. The system has been deployed in several mines to provide an objective assessment of blasting performance. Images are captured from their cable or hydraulic shovels. The images are grouped into sets based on the shovel location and time to match the fragmentation to specific blasts. Blast fragmentation reports are created for each blast after reviewing the results. Measuring blast fragmentation from the shovel bucket proves to be an effective alternative for blast performance assessment with unique advantages. The blast fragmentation information has been valuable to the mines, and the mines have begun adopting it into their operations.

May 1, 2011

"SART technology is a useful tool for improving the economics of gold recovery from certain types of complex gold ores. SART liberates cyanide consumed by base metals such as copper, zinc and nickel, and enables the newly freed cyanide to be recycled to precious metals leaching while producing high-grade base metal sulphide concentrates for sale. The benefits of SART include the reduction in cyanide consumption, avoidance of cyanide destruction costs, minimization of risks of environmental non-compliance due to residues of cyanide destruction reporting to mine effluents, and generation of extra revenue from the sale of base metal concentrates. Concerns with SART typically include uncertainties around capital and operating costs and proper integration of SART into the overall metallurgical flowsheet. This paper presents two case studies addressing these concerns. The first involves actual costs of the full scale SART integrated into a gold heap leach operation and treating up to 500 m3/hr of leach solution at a mine in Mexico. The second involves field pilot testing and a preliminary cost estimate for integrating SART into a silver mine in Peru using Merrill Crowe.INTRODUCTION One of the current trends in the gold industry globally is the increasing importance of complex polymetallic gold deposits as discoveries of large Carlin type gold deposits become increasingly rare (Sceresini, 2005). The presence of cyanide soluble copper and zinc in complex gold deposits necessitates changes in traditional gold extraction metallurgical flowsheets. One of the tools available to the industry to help deal with interferences of cyanide-soluble base metals in gold extraction is the SART (sulphidization-acidification-recycling-thickening) process. SART breaks the weak acid dissociable (WAD) base metal-cyanide complexes, precipitates the metals as high-grade sulphide concentrates and makes the freed cyanide available for recycle. Although SART is a commercially available technology, it is still relatively new to the industry. Fewer than ten (10) full scale plants have been constructed in the past couple of decades. Some of these SART plants are small, most are located at remote sites, and the majority have not operated on a continuous basis. This has resulted in a general lack of information in the industry about the true costs, operability and metallurgical performance of SART. BQE Water has been involved in the design, construction, commissioning and operation of large scale SART plants in Mexico, Turkey and Chile and has conducted field testing programs as part of the technical assessment of SART integration into various metallurgical circuits. Having built and operated numerous plants utilizing selective sulphide precipitation of heavy metals, BQE Water has gained unique insight into the design and control of the sulphidization stage of SART to minimize costs and ensure high efficiency in cyanide recovery."

Jan 1, 2017

By C. S. Ha, H. S. Choi, D. Y. Shin

POSCO installed a new 100 ton oxygen bottom-blown converter in 2013 for the development of new steelmaking process named as PS-BOP which is reading POSCO-Saarstahl Basic Oxygen Process. This process was developed by the collaboration research between POSCO and Saarstahl AG in Germany that is based on substantial increase of CO post combustion in a converter by blowing hot air from the top of converter. The collaboration research has been finished successfully in November 2013 with 17% decrease in hot metal ratio (HMR) when hot air was blown from the top of the oxygen bottom-blown converter. After the collaboration research the converter has been tried to be operated as oxygen top and bottom-blown converter to reduce bottom wear and to decrease production cost with increased use of low cost Fe source by the help of increased CO post combustion. The presentation includes experience on the start up of oxygen bottom-blown converter, HMR reduction trials with hot air top blowing and transition from oxygen bottom-blown to top and bottom-blown converter operation.

Jan 1, 2015

By S. Khallouk, J. Zollinger, J. R. Kennedy, E. Bouzy, B. Rouat, D. Daloz

Titanium aluminides recently replaced Ni-based superalloys as turbine blades in the last LP stage of aircraft engines. To extend their range of use at higher temperature their properties need to be improved, either by alloying or processing. An efficient solution is to reduce the grain size during the solidification process. In the first part of the paper, an overview is given on the possibilities for grain refinement of such alloys, based on literature data and new results. The most efficient grain refinement is obtained with boron addition which leads to boride formations that are detrimental for in-use properties of turbine blades. In this work, the use of the high grain refinement potency of inoculation with non-brittle particles has been used by developing new refractory-based inoculants. The effect of one of these inoculants on grain refinement of an as-cast structure in a Ti-46Al is presented; resulting in a reduction of the grain size by a factor of 3.While less efficient compared to the potency of boron containing alloys, the grain refinement is effective and does not introduce any embrittling particles.

Jan 1, 2015

By Leopoldo Gutierrez, Sergio Castro, Lina M. Uribe, Janusz S. Laskowski

"The effect of sulfite and metabisulfite ions on the amyl xanthate flotation of copper-activated pyrite, in distilled water and seawater, has been studied by micro-flotation tests and redox potential measurements. The activation of pyrite was carried out varying copper ions concentration. It was found that in the presence of copper ions in solution, sulfite and metabisulfite are able to depress copper-activated pyrite at neutral or slightly acid pH. After the addition of sulfite or metabisulfite ions the resulting pH is more acidic with metabisulfite ions. A significant increase of the redox potential of the solution was observed as copper ions concentration increased. Then, the initial reducing conditions brought about by sulfite and metabisulfite ions, change abruptly to oxidizing conditions in the presence of copper ions. Under these oxidizing conditions, the metabisulfite showed to be an effective depressant for pyrite mainly in seawater. However, sulfite was a pyrite depressant in both distilled water and seawater. Based on these results, the pyrite depression by sulfoxy-depressants during the flotation of Cu/Mo ores in distilled water and seawater is discussed.INTRODUCTIONDepression of pyrite by sulfoxy-depressants (sulfite and metabisulfite) in the presence of copper ions is an important issue. This is particularly true when pyrite depression in the flotation of Cu/Mo sulfide ores is carried out in seawater. The use of lime in seawater must be avoided because the formation of magnesium hydroxy-complexes and precipitating magnesium hydroxide strongly depresses molybdenite flotation (Castro et al., 2014). In order to solve this problem, one large plant in Chile uses sodium metabisulfite (MBS) instead of lime to depress pyrite in seawater. In plant practice, this also improves molybdenite flotation since with the use of MBS the pyrite depression is carried out at pH 6-7, instead the pH 11-12 usually employed with lime.From a general point of view, pyrite exhibits some natural floatability over acidic pH ranges and may be partially floated without thiol collectors (a coating of sulfur/polysulfides has been claimed). Therefore, pyrite flotation with xanthates is usually high in the acidic pH region, but decreases greatly at alkaline pH (Leppinen, 1990; Fornasiero and Ralston, 1992; Zhang et al., 1997)."

Jan 1, 2016

By Robert B. Parsons

"It is easy to throw darts at government - and government often deserves to be a target. This month, Tax Notes examines tax legislation from a different angle, and sees some bright spots.The following article is based on a paper presented by the author at the International Gold Symposium in Rio de Janeiro in August 1989Introduction""No man's life, liberty, or property are safe while the Legislature is in session.”With one federal government, ten provincial governments, and two territorial governments all claiming to have constitutional rights to tax and otherwise regulate Canada's mining industry, and with each of these thirteen governments pursuing their respective rights with some vigor, government involvement in one way or another is an accepted way of life in the industry. While one's initial reaction to government involvement in an industry might be one of scepticism or fear, generally speaking the federal, provincial, and territorial governments in Canada tend to be pro-mining. They recognize the importance of the mining industry to Canada, especially in terms of job creation and exports. It is not surprising, then, to find that an array of valuable fiscal incentives are available to the industry through federal and provincial legislation.This paper summarizes the principal incentives that are inherent in Canada's tax legislation, as well as the Canadian Exploration Incentive Program. Although it is beyond the scope of this paper to deal with all of the incentives that are available, it is noted that various forms of federal or provincial assistance are also available outside of specific legislation, through negotiation with government departments. This latter type of assistance is generally directed toward helping with the cost of infrastructure such as roads or hydro lines, or Jess often toward loan guarantees or similar financing assistance."

Jan 1, 1990

By Terry J. Briggs, Ian J. Kelso

"Abstract- The Century mine in northwest Queensland,Australia, is a major sediment-hosted zinclead- silver orebody, located within the western Mount Isa Basin. Stratiform, carbonaceous shalehosted mineralization is developed within Proterozoic shale and siltstone sequences of the Lawn Hill Formation. CRA Exploration Pty Ltd (CRAE) discovered the Century deposit in 1990 and open pit mine development commenced in 1998 under the ownership of Pasminco Century Mine Limited (PCML). The deposit contains an identified mineral resource of 105 Mt @ 12.1% Zn + 1.7% Pb + 46 g/t Ag (Broadbent and Waltho, 1998) which is currently being mined at a rate of 5 Mt/y.In December 1998, an exothermic reaction was observed between explosives spilt onto shale drill cuttings from a blasthole. This reaction is referred to as ‘reactive ground’ and has the potential to cause premature detonation of explosives in a charged blasthole with catastrophic consequences. The incident led to a subsequent geological and geochemical assessment of the different rock types at the Century deposit and their potential reactivity with ammonium nitrate-based (AN) explosive products. This assessment was conducted in an attempt to characterize zones safe for blasting with uninhibited AN-based explosive products. A direct result of this study is a set of procedures outlining the use of different AN-based explosives in areas defined as potentially reactive or non-reactive for the different lithologies present. Black shales contained in both the waste and mineralized sequences contain the sulfide mineral pyrite (FeS2), which is thermodynamically unstable with AN contained in commonly used explosives. The potential reactivity of partially weathered pyrite can ultimately result in the decomposition of an AN-based explosive. It was determined that only pyritic black shales showed any potential to react with AN, irrespective of their position in the stratigraphic sequence. Other lithologies present at Century, including Proterozoic sandstone and Cambrian limestone, are classified as non-reactive with AN. This is a geological risk management situation present at the Century mine."

Jan 1, 2001

By T. Johnson, K. Lambrych, D. Kelley

Materials for construction of equipment used in hydrometallurgical plants are selected based on a combination of their ability to perform as required in aggressive process environments as well as their cost. As a material of construction, fiber reinforced plastic (FRP) has been shown to provide equal if not improved durability relative to alternative materials such as corrosion resistant alloys at a considerably lower cost. This is particularly true in the case of equipment used in acid leaching processes for copper, cobalt, nickel and rare earth elements. The selection and extensive use of FRP over alloys in new hydromet plant construction in North and South America illustrates this advantage of FRP effectively. This paper will compare corrosion performance and cost of plant equipment fabricated with stainless steel alloys and FRP made with Epoxy Vinyl Ester thermoset resins. Real world case histories for FRP piping, storage tanks, extraction vessels, and electrowinning cells combined with laboratory based corrosion studies will be reviewed to demonstrate how FRP materials are selected for hydrometallurgical equipment.

Jan 1, 2015

By Steve Forgeron, Brendan MacKenzie, Kevin MacPherson

"The geological composition of strata immediately adjacent to coal seams has a significant effect on the safe and efficient extraction of coal from underground mines of the Sydney coalfield. Geological features such as paleo-sandstone river channels, seam splits, floor rolls, paleo-soils and stone-filled rupture features can rapidly alter the competency of immediate roof and floor strata, significantly reduce the height of the coal seam, cause rapid variations in seam gradient and influence the in situ and run-of-mine quality of the coal.The impact of these features on the over-all mining operation can be significantly reduced if mine management can be for-warned of their impending occurrence. Using the information acquired from boreholes, geological mapping, x-ray diffraction analyses, microscopic studies, geophysical logs and seismic surveys, sedimentary models have been constructed which enable the mine geologist to predict, with increasing accuracy, the future occurrence of deleterious geological features ahead of the working face."

Jan 1, 1986

By Nural Kuyucak, Bohumil Volesky

"Extensive screening revealed a seaweed (alga) biomass type which in its non-living state possesses a very high cobalt sequestering capacity comparable to that of activated carbon and the ion-exchange resin currently used in the cobalt production process. Performance of the new bio-sorbent material was studied by examining its equilibrium metal uptake isotherms generated under different solution conditions such as initial cobalt concentration pH, temperature, and the presence of selected cations and anions. The rate of cobalt uptake was determined, which is a crucial parameter for recovery process design. Almost all cobalt sorbed can also be desorbed with a solution of CaCI2. The bio-sorbent material can be used repeatedly in the sorption-desorption cobalt concentration process. IntroductionIt has been well documented that certain types of microbial biomass, living or non-living, possess a high potential to sequester and accumulate inorganic ions present in aqueous solutions. Metal concentration by microbial biomass from a solution is termed bio-sorption. This phenomenon is quite complex and includes adsorption of metals onto the surface of a microorganism and/or into the cellular structure in combination with ion-exchange, complexation, and/or micro-precipitation. Bio-sorption is generally considered to be a rapid physical/chemical process. The cell wall structure is porous and allows metal ions, as well as large organic nutrient molecules, to pass freely through. Polysaccharides of the cell wall could provide binding amino, carboxyl, phosphate and sulphate groups. In addition to these functional binding groups, polysaccharides often have ion-exchange properties. Sometimes, bivalent cations, such as Ca2+ or Mg2+, help the formation of ionic bond bridges between the negatively charged cell surfaces and positively charged cations in the solution, Proteins in the cell wall could offer functional groups and also offer peptide bonds to bind ions. Interactions between metal and the cell wall components are responsible for the sequestering of metals by way of bio-sorption. Many metals feature a complex solution chemistry and it is not always possible to determine what ionic species are actually present in the solution. The equilibria involved are dependent on pH, concentration, the anions present and other factors. The transport system for the ions are sometimes dependent on both temperature and energy. Biosorbent material could also be regenerated for multiple reuse."

Jan 1, 1988

By Abhilash

Uranium is conventionally extracted using a process that employs strong acid (H2SO4) and an oxidant (MnO2) as leaching agents. This method often creates environmental problems, requires large amounts of energy, and involves a complex operational plant. It is not, however, economically attractive to extract uranium from low-grade ores by chemical leaching. Because the content of U3O8 in the Indian ore is usually below 0.1% by weight, it is necessary to develop an alternative process to enable the efficient and economic recovery of uranium. Uranium ore from the Narwapahar mines, UCIL is a type of vein deposit found in India, which accounts for ~54% in India. The ore (0.047% U3O8), though of Singhbhum area, possess exceptionally different mineralogy due to presence of some refractory minerals and richness of apatite (5%) resulting in a maximum 78% recovery through conventional processing at UCIL, with a very high consumption of sulfuric acid and pyrolusite, besides possible loss of uranium as uranium phosphate. To avoid usage of environmentally non-benign oxidants, remediation of influence of phosphates, and improve the overall process output of uranium; an alternate extraction technology using microbial isolate(s) is worthwhile exploring and the same is presented in the paper. The microbial isolate enriched with Acidithiobacillus ferrooxidans grown from source mine water was employed for bio-leaching of uranium while varying pH, pulp density (PD), particle size, etc. On varying pH at 35oC using 20%(w/v) PD and <75µm particle size, 83.5% and 78% uranium bio-recovery were observed at 1.7 and 2.0 pH in 40 days against maximum recovery of 46% and 41% metal in control experiments respectively. Whereas, it was observed that grinding of ore to finer size actually helped dissolution of uranium. Finer size particles (<45µm) gave a maximum biorecovery of 93% in 40days at 10%(w/v) PD, 1.7 pH and 35oC. The bio-recovery of uranium fell down from 93% to 82.73% and 60% on increasing the pulp density from 10% to 20% and 30% respectively for particles of <45µm size. The higher uranium dissolution during bioleaching at 1.7pH can be correlated with increase in redox potential from 433 mV to 664mV in 40 days.

Aug 1, 2010

By F. Rosenblum, P. Spira

"Self-heating of broken sulphide ore or waste rock underground can lead to ignition and cause serious problems in a mine operation. An extensive study has demonstrated that it is caused by oxidation of certain species of pyrrhotite. Self-heating was found to take place in two stages, first progressing from ambient temperature to 1000C with exothermic formation of elemental sulphur in the presence of moisture and oxygen, and proceeding to a second stage in which the sulphur oxidizes to SO2. Ignition may eventually follow. An apparatus was developed to assess the propensity of sulphide rock to self-heating and the potential for hazardous behaviour. The effect of temperature, time, rock size, and surface treatment with chemicals is presented. On the basis of these results, possible approaches for preventing a runaway reaction are suggested for further investigation.IntroductionThe oxidation of sulphide ore, waste rock or tailings backfill, which may cause hazardous conditions underground through heating, oxygen depletion and, in some cases, fire, is well documented (Farnsworth, 1977; Ninteman, 1978; Rosenblum et al., 1982; Reimers, 1987). The self-heating mechanism, nevertheless, has not been satisfactorily explained. The onset of heating from ambient temperature, in particular, has not drawn the attention of researchers. In the course of a previous study (Rosenblum et al., 1982) aimed at finding a method to assess the hazard from using sulphide tailings as backfill, the authors developed an apparatus to measure self-heating rate under controlled, near ambient conditions. This has since provided decisive information in backfill investigations in the Noranda Group.The test methodology devised for tailings failed to predict self-heating in a broken waste rock known to be active. Upon repeated testing, however, a freshly crushed sample began to exhibit appreciable heating and oxygen uptake (Fig. I). After 14 tests, the self-heating rate reached a plateau of about 4O°C/h and then fell progressively to < 5°C/h after 30 tests. It was hypothesized that weathering in the presence of moisture and oxygen during testing had caused the onset of self-heating. Active tailings, on the other hand, are exposed to natural surface oxidation and need not be weathered to show heating. Based on this finding, a new apparatus was developed capable of simultaneously weathering a sample of rock and monitoring its self-heating behaviour."

Jan 1, 1995

By Alessandro Navarra, Amir Arash Rafiei, Kristian Waters

Mathematical programming (MP) is fundamental to systems engineering and operations management, but has not been widely adopted by mineral processors. The current paper presents an interdisciplinary approach, using MP to incorporate basic notions of mass balancing into an optimization framework. The optimization is typically related to economic profitability. Two- and three-product formulas are extended to give formal descriptions of alternate modes of operation, and a global representation of the concentrator. At this global level, the framework may assist plant managers to make tactical decisions based on incoming feed data. The MP framework is demonstrated through sample calculations describing a lead-zinc concentrator.

Jan 1, 2015

By Vicken Aprahamian

"The Royal Canadian Mint (RCM) operates a gold and silver refining toll operation in Ottawa, Ontario, Canada. The silver refining line is a recent addition and was commissioned in 2005. One source of silver in the refinery is from gold doré which undergoes Miller chlorination before electrorefining to 99.99% cathode gold. Treatment of the Miller salt or silver-copper chloride produced consisted of a 2-stage high temperature reduction process step using soda ash prior to 2005. Copper-rich silver bars were produced and shipped offsite for further refining.The copper-rich bars could not be blended into sufficient high grade silver doré to dilute the copper and allow electrorefining in a silver nitrate medium. A new wet process was developed and commissioned to replace the high temperature reduction and allow removal of bulk copper. Thus upgraded impure silver produced was cast into anode for electrorefining to 99.9% purity silver flake. The 2005 RCM Hydromet Slag process is presented as well as its more current version. In addition, mention is made of a novel processing scenario for the introduction of Miller chlorination silver into the electrorefining circuit."

Jan 1, 2015