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By M. Pelser, H. Gous, J. H. W. M. Brits, K. Voogt

The effect of impurities; iron and selenium, on current efficiency and deposit quality in copper electrowinning was investigated using an at-line cell at the Rustenburg Base Metals Refiners’ Copper Tankhouse. The tankhouse is a direct leach, starter sheet electrowinning operation with a unique electrolyte composition. The effect of iron on the current efficiency in the at-line cell was found to be less severe than reported in literature. However, the distinction between the chemical impact of iron on current efficiency and the physical impact of iron on a starter sheet operation needs to be realised. The effect of selenium on current efficiency and deposit quality is also reported. INTRODUCTION Anglo American Platinum’s Rustenburg Base Metals Refiners’ (RBMR) Copper Tankhouse serves a unique function in the refinery flowsheet in that its primary functions are the removal of copper and production of acid for the leach circuit. This function needs to be performed to specification in order to keep the leach circuit operating optimally. Current efficiency is seen as an indicator of tankhouse performance and efficient energy use. The tankhouse plates starter sheets onto titanium blanks which, after stripping and preparation, return into the production cells for further plating. Approximately 78% of tankhouses surveyed (Robinson et al., 2013) use permanent cathode technology whereas older, smaller operations still use starter sheet technology. Drawbacks of the starter sheet technology are that the starters are thin and bend easily leading to increased shorts, they need to be removed after two days of plating to be manually straightened and are then returned to the cells. In addition, the electrolyte levels in the cells need to be adjusted during the plating cycle to improve loop adhesion to the cathode and reduce loop corrosion. The starter sheet technology is therefore very labour intensive and the final quality of the product is dependent on the quality of the starter sheets produced. In comparison, permanent cathode or direct plating technology lends itself to automation, allows for higher current densities and better cathode quality due to more robust geometric stability in the cell. The present barrier to implementation of permanent cathode plating at the RBMR Copper Tankhouse is the capital cost required to convert the tankhouse, i.e. blanks and stripping machine. At present, alternatives to titanium blanks, such as LDX 2101, are being investigated for the unique electrolyte composition of this tankhouse.

Jan 1, 2019

By Robert B. Parsons

"On February 15, 1984 Finance Minister Lalonde presented to Parliament a budget heavily flavoured with the current consultative mood of the Government. Notably absent from the budget was the typically long list of tax changes of immediate effect. Instead, the bulk of the budget papers consisted of a wide variety of white papers on significant topics that would have a far reaching impact on the future of all Canadians.This month. Tax Notes examines the highlights of Mr. Lalonde's budget.IntroductionThe mining industry need not feel slighted in Finance Minister Lalonde's budget of February 15, 1984: the budget offered very little that would have an immediate impact of significance on any sector of the economy. Apart from some welcome announcements for the oil and gas industry to postpone the implementation of certain negative tax changes, the budget was surprisingly scant in terms of definitive tax proposals.While massive revisions in the rules relating to pensions, small businesses, commodity taxation and profit-sharing were brought forward, many of these proposals are set out in White Papers or other documents to be implemented into legislation only after further consultation. Canadians will accordingly have to wait for such promised benefits as increased RRSP and other pension contribution limits."

Jan 1, 1984

By J. W. Reynolds

"The use of approved fire-resistant hydraulic fluids in equipment operating underground was made mandatory in British Columbia by amendment to the Provincial Mines Regulation Act effective January 1, 1975. This paper covers the action taken to achieve this, in the largest underground metal mine in British Columbia. Some evaluation of costs and effects based on experience to date is included.BackgroundAn amendment to the Mines Regulation Act of the Province of British Columbia was passed in July 1974 as follow s: "" Rule 111 (b) Hydraulic Fluids. After the first day of January 1975, all hydraulic fluids used in equipment operating underground shall be of a fire-resistant type accept able to the chief inspector.""Unquestionably, its intent was justified as a safety improvement measure. The list of fires in mines involving machinery where hydraulic fluid was a factor in the fires is long and sobering. In British Columbia, in a 22-month period from 1972 to 1974, there were six fires in metal mines resulting in extensive equipment damage and injury to four workmen. Nevertheless, no provision was made for research or development of systems modifications compatible with conditions encountered in B.C. and, as late as June 1977, the Mining Association of British Columbia continued to argue that fire suppression systems should be considered sufficient until a universal suitable hydraulic fluid could be developed. The sole concession was to issue permits for continued use of mineral oil in equipment bought prior to 1975 in order to allow producing operations to continue. The burden of developing the necessary technology was laid on the industry.The Sullivan Mine at Kimberley, the largest and longest established underground mine in the province, and Cominco's most important source of ore s for its smelter at Trail, B.C., was at the outset of a conversion from conventional to trackless mechanized mining methods in pillar recovery operation s. Introduction of fire-resistant hydraulic fluid s had to be done in a period of change, in many instances on equipment for which no data existed, and called for research which had to be done while retraining the work force.The introductory phase is complete. All equipment is on FRF, the requirements of Rule 111(b) are being satisfied, and a number of research and development programs continue."

Jan 1, 1980

By J. G. Conaway, P. G. Killeen

"Gamma-ray spectral logging, a useful technique for uranium exploration and evaluation, has generally been underutilized by the Canadian mining industry. Provided that the technique is properly applied, it is capable of yielding reliable quantitative information regarding the distribution of uranium and other radioelements along the borehole under most conditions.In practice. there are numerous factors which potentially can degrade the quality of the log and thus any quantitative interpretation based on it. Fortunately, the appropriate choice of logging equipment and technique can avoid many such problems, and corrections can be applied to the data to compensate for most of the others."

Jan 1, 1980

By E. Kouame, M. D. Everell, D. Hodouin, T. Kasongo

"To properly operate a mineral beneficiation plant it is often necessary to have systematic evaluations of the performances of a piece of machinery, of one of the processes or of the plant as a whole. The state of a process can be described from a collection of data: flow-rate values, particle-size distributions and chemical compositions of the various streams of the circuit studied.However, the obtained raw data are generally redundant and inconsistent from a material balance viewpoint, due to natural disturbances, sampling errors, unreliable instrument readouts and laboratory analysis inaccuracies.BILMAT is a computer program which upgrades mineral processing data, adjusting them in a least-squares sense in order that they may verify material conservation constraints. As a consequence, the program is able to calculate the best values of unmeasured flow rates (such as. circulating load ratios). BILMAT is a very general program in the sense that it can accept various data from any type of mineral processing circuit, and its usefulness is demonstrated here for three processing circuits of a pyrochlore concentration plant: grinding, desliming and flotation.IntroductionComputation of the material balance around any metallurgical process, that is the determination of stream flow rates and composition. is a basic step in its evaluation. In spite of the simplicity of the physical laws of mass conservation. and of the very fundamental need to know the flow of components around a process. it appears, particularly in mineral processing. that material balancing is quite often a difficult task. The reasons for this involve the problems associated with collecting measurements in mineral dressing plants. They are generally poorly instrumented and invariably data must be collected through hand sampling. Due to the heterogeneous nature of the streams, segregation occurs and samples are often not adequately representative, a problem made worse by the lack of circuit sampling facilities, which are often completely ignored by plant designers. Furthermore, the nature of the measurements to be performed (for instance particle size distributions in the fine range) frequently gives inaccurate results."

Jan 1, 1981

By R. W. Lawrence, A. Bruynesteyn

"Pre-oxidation of refractory pyritic concentrates by biological leaching to enhance the recovery of gold and silver in cyan ideation has been investigated. The results of laboratory tests on three concentrates are presented. In all cases substantial increases in precious metal recoveries were obtained following the pre-treatment. For one concentrate, gold recovery of 81% was achieved following an 87% oxidation of pyrite, compared with 24% recovery by direct cyanidation of non-oxidized concentrate. Gold and silver recoveries from the other concentrates were increased from the range 60-78% to over 90% and from 80-86% to over 98% respectively. Operating parameters are discussed and methods of maintaining high oxidation rates are evaluated. Methods of employing this pre-oxidation technique in commercial practice are described.IntroductionMany of the gold and silver deposits now being developed contain precious metals finely disseminated in sulphide minerals such as pyrite. These ore s often present considerable resistance to metal recovery. The ease with which gold may be extracted is usually related to grain size and its manner of distribution within the host mineral. In many cases, a significant percentage of the gold may occur in submicroscopic form, or in solid solution with pyrite, so that even very fine grinding fail s to liberate the metal for recovery by cyanide leaching. Such ores are often termed refractory. Even in cases where liberation by fine grinding is practicable, high cyanide and lime consumption may be experienced due to the presence of specific sulphide minerals, and poor metal recovery may result.Pre-oxidation methods for refractory ore s and concentrates are commonly used to improve precious metal recoveries. Roasting, for example, as a pre-treatment to cyanidation, removes harmful constituents by oxidation or volatilization, and liberates gold from pyrite. In some cases, however, this method of pre-oxidation can result in poorer metal recovery, particularly of silver, due to fusion and the formation of clinker, and the formation of compounds which consume cyanide in the subsequent metal recovery stage. Difficulties in compliance with environmental pollution regulations may also be encountered."

Jan 1, 1983

By Robert B. Parsons

"Considering the traumatic events of Canadian mining taxation of the 1970s, one wonders at the sanity of anybody who tries to predict what the 1980s might hold for the tax structure of the mining industry. Yet, the author agreed to tackle this task when called upon to do so at the annual meeting of the Quebec Metal Mining Association in June. The text of this ""daring"" speech follows.IntroductionI have been asked to play the part of the oracle at Delphi, and to predict what the 1980s might hold for the Canadian mining industry in terms of taxation. To appreciate the challenge of this difficult assignment, try to imagine someone in my position back in 1972 attempting to forecast the balance of the 1970s. I daresay that ten years ago nobody could possibly have conceived of the devastating and casualty-ridden rollercoaster ride that mining taxation actually took in the 70s. Nevertheless, I shall examine the entrails and try to shed some light on what might happen during the balance of this decade as far as mineral taxation is concerned.If one were to retreat deep into history, one would find that taxation generally served one purpose-namely, to raise revenues for the government. More recently, an important second function has emerged: taxation is increasingly being used as a fiscal tool-a tool intended to mould and shape future events in order to accomplish certain economic, social and political objectives. It is these two main forces-the need (or desire) for revenues and the perceived convenience of using taxation as a fiscal tool-which will continue to shape the tax structure of the future.In our assessment of where taxation of the mining industry may be headed, we should be able to learn something by looking at where we have been."

Jan 1, 1982

By Ross Dimmock

The productivity of a mine has the same goals as the quest to complete a tunnel project both safely and within time. A key aspect to achieving this goal is to excavate and support the working face as quickly as possible, allowing early re-entry to start construction of the next advance in safety. As with tunnels, the use of high performance wet-mix sprayed concrete has increased in mines dramatically over the last few years, and year on year has seen a stepwise increase in shotcrete performance, particularly in the first few hours. Shotcrete early age strength development clearly offers mining teams enormous advantages by allowing early, safe re-entry to the face. This paper illustrates that in the hard rock tunnelling field, modern shotcrete approaches do not cause delays in re-entry, but allow a continuous construction cycle. Furthermore, the paper identifies the most suitable, up-to-date shotcrete admixture and equipment technology available to the mining community to permit early re-entry.

May 1, 2003

By M. B. McClenaghan

"The Matheson area of northeastern Ontario is of great interest for mineral exploration because of its geological similarities with the adjacent Timmins, Kirkland Lake and Larder Lake gold camps. Exploration in the area, however, is hampered by the presence of an extensive and thick cover of glacial sediments. For this reason, till geochemistry has become an important exploration method. The Ontario Geological Survey&apos;s Black River-Matheson (BRiM) reconnaissance till sampling project, carried out between 1984 and 1988, was designed to aid exploration in the Matheson area by documenting the Quaternary stratigraphy and providing a database of till geochemistry. Till samples were collected by backhoe trenching of surface pits in areas of thin drift (< 5 m) and by sonic overburden drilling in areas of thicker drift. This paper summarizes the results from the shallow till sampling component of the BRiM project.Two hundred and eighty-two surface samples were collected from Matheson Till, the youngest till sheet in the area, which was deposited during the Late Wisconsinan. For each sample, the non-magnetic heavy mineral (> 3.3 S.G.) and fine (- 250 mesh) till fractions were analyzed geochemically. In addition, visible gold grains were recovered by panning the heavy mineral fraction. Five areas that display multi-element anomalies in both till fractions warrant further investigation: (1) western Egan Township, overlying the Bradley Lake Syenite; (2) around and south of the Munro and Croesus mines, in Munro and Guibord townships; (3) central Garrison Township overlying the Garrison Stock; (4) south of Ore Car Lake in northern Thackeray Township; and (5) southeastern Harker Township. In these areas, Matheson Till has a local provenance and the bedrock sources for these anomalies are nearby in the up-ice (north northwest) direction. Due to the fine-grained nature of gold in bedrock deposits in the BRiM area, the small size of most gold grains recovered from till samples (< 50 um) and the variable distribution of gold in the heavy mineral concentrate and fine fractions, the fine fraction in addition to the more commonly used heavy mineral concentrate should be used for gold exploration.Surface till samples have been affected by weathering to a depth of = 3 m. Weathered till is characterized by a very low carbonate content in the matrix fraction, the absence of sulfide grains in the heavy mineral concentrate and higher concentrations of copper, nickel and zinc in the fine fraction than in the heavy mineral concentrate. As a result of the weathered/ oxidized nature of the surface till samples, the fine fraction is a better sampling medium for base metal exploration."

Jan 1, 1992

By R. H. McCorkell

Measurements of radon in air and aqueous solutions can be affected by leakage from vessels in which samples and standards are kept and by absorption and later release of radon by the materials of these vessels. The author had received various oral communications concerning the se processes : e.g ., that natural rubber and greases absorb large amounts of radon, whereas silicone rubber and grease do not; and that radon is readily lost from polyethylene bottles and that inverting glass bottles containing aqueous samples reduced radon loss from them . However, the results of actual tests and quantitative data showing these effects were not available. For this reason, it was necessary to make numerous measurements of the leakage and absorption of radon in the course of designing apparatus and methods for measuring radium and radon concentrations. It was thought that the data obtained might be of use to others, and consequently they are compiled in the present note .

Jan 1, 1980

By D. A. McIsaac

In these days, when mass production seems to be the watchword of all industrial companies, nothing is left undone to attain this end. Transportation, where necessary, becomes a question of very great importance. For this reason every mechanical contrivance known to man is employed, with its resultant advantages. So successful has man&apos;s ingenuity been that, offhand, we are inclined to say that practically all transportation on a large scale is done mechanically, that is, where speed and economy are desiderata. Granting this, one would think that to read a paper on the horse before your honourable and highly technical Society would surely be a waste of time, and that any Company employing old-fashioned &apos;horse&apos; power would certainly be very much behind the time, to say the least. However, the fact remains that the biggest industry in our country today-coal mining-must use horse power to a great extent, being compelled -both by considerations of economy and by necessity. For this reason,&apos; in the production of coal under present conditions, the pit horse is of great importance to this industry and is to be considered seriously as one of the units that help to make coal mining a success or a failure. Hence, in employing horses as a power for transportation, care must be exercised in selecting the animals, and the care of this power must be considered as seriously as any other department of such an organization. In selecting a pit horse, several things must be borne in mind, that is, one must get as much horse power as possible in as compact a form as is practicable. This determines the type of horse we must use, which is of very great importance under our present conditions of coal mining. With low roof, steep grades, and forced production, a distinct type of animal must be selected.

Jan 1, 1930

By D. A. McIsaac

In these days, when mass production seems to be the watchword of all industrial companies, nothing is left undone to attain this end. Transportation, where necessary, becomes a question of very great importance. For this reason every mechanical contrivance known to man is employed, with its resultant advantages. So successful has man&apos;s ingenuity been that, offhand, we are inclined to say that practically all transportation ?On a large scale is done mechanically, that is, where speed and economy are desiderata. Granting this, one would think that to read a paper on the horse before your honourable and highly technical Society would surely be a waste of time, and that any Company employing old-fashioned &apos;horse&apos; power would certainly be very much behind the time, to say the least. However, the fact remains that the biggest industry in our country today-coal mining-must use horse power to a great extent, being compelled both by considerations of economy and by necessity. For this reason,&apos; in the production of coal under present conditions, the pit horse is of great importance to this industry and is to be considered seriously as one of the units that help to make coal mining a success or a failure. Hence, in employing horses as a power for transportation, care must be exercised in selecting the animals, and the care of this power must be considered as seriously as any other department of such an organization. In selecting a pit horse, several things must be borne in mind, that is, one must get as much horse power as possible in as compact a form is practicable. This determines the type of horse we must use, which is of very great importance under our present conditions of coal mining. With low roof, steep grades, and forced production, a distinct type of animal must be selected.

Jan 1, 1930

By Robert B. Parsons

"A joint federal/provincial/industry subcommittee of the Intergovernmental Working Group on the Mineral Industry (IOWG) has published an informative and readable report on taxation matters concerning Canada&apos;s mining industry. The report, which was presented to the federal and provincial mines ministers in September 1986, identifies and discusses key tax issues relating to this industry. The report is mandatory reading for anybody with an interest in mineral exploration or production in Canada.IntroductionIn 1986, Canada&apos;s federal and provincial mines ministers were presented with an important report concerning the taxation of this country&apos;s mining industry. This document is important for a number of reasons, two of the reasons being: first, the report contains an objective analysis of the key mineral taxation issues of the day; and, second, the report is the product of a cooperative exercise involving representatives of various facets of the industry and government. The report should be regarded as compulsory reading for anybody who has an interest in fiscal matters affecting mineral exploration and production.The ""Report on Fiscal Proposals"" was prepared by a subcommittee of the Intergovernmental Working Group on the Mineral Industry (IOWO). IOWO is a group of senior federal, provincial, and territorial government officials concerned with the analysis of mineral policy issues in Canada."

Jan 1, 1986

By T. Kho, W. Zhang, M. E. Reed

The control of flash furnace heat balances is critical. Suspension smelting control and stability comes from stable operation of the heat balance, and this leads to a stable reaction shaft exit temperature. A number of flash furnace operations have been reviewed to determine if the application of this approach is beneficial for their operation. The cause and effect relationship between reaction shaft exit temperature with uptake and throat buildup is being enhanced with this work program. Our operating personnel are exposed to the operational hazards of cleaning this buildup from the throat and it is imperative that as an industry we continue to look for repeatable solutions. WorleyParsons has reviewed operational data from a number of flash furnaces and looked at the possible improvements that can be made to decrease variation in the reaction shaft exit temperature. The data assessed for each operation illustrate the need to fully understand the process inputs to the particular operation and to ensure that the control changes are correctly impacted. In the plant data that have been assessed for a number of operations combinations of feed changes and inappropriate process decisions have lead to changes in reaction shaft exit temperature which impact the overall furnace operation and the uptake shaft condition, and ultimately the boiler. INTRODUCTION In 2016 WorleyParsons jointly prepared a paper outlining the effects of heat balance control on the Olympic Dam flash furnace (Reed et al, 2016). That paper investigated the importance of heat balance control in flash furnaces and demonstrated the changes made at the Olympic Dam operation to control the heat balance in the furnace and the impact that change had. The operation is still using the tool to assist in trouble shooting performance and pinpointing problems that may lead to issues in the furnace throat and Waste Heat Boiler (WHB). As a result of the interest in the methodology and due to the issues surrounding safety and process performance caused by WHB throat buildup and damage, WorleyParsons approached a number of flash furnace operators to discuss the application of the approach at their operations.

Jan 1, 2019

By Noel G. Thomas

"This paper will identify where the industry is heading with iron· ore in the next ten years. From a customer&apos;s point of view, an indication of the changing, yet expanding, market will be made. This will progress further into the most likely changes in chemical and physical requirements of the ore products. No definite target can be set for 1990, but the logic from the direction of the changes will be established.IntroductionThe tonnage and quality of iron ore produced in the eighties will be heavily influenced by energy and investment considerations. That&apos;s not a great pronouncement, but this paper will explain how these two factors are :(I) influencing a disproportionate growth of electric furnace capacity and a greater use of scrap for iron units, in place of Iron ore;(2) influencing chemistry specifications; and(3) causing extensive examination of ore agglomerate form. Inflating investment costs are emphasizing the need for more productive blast furnaces, and the iron ore burden is under heavy examination as to how it affects productivity and coke rate."

Jan 1, 1981

By T. Yalcin

"This paper describes a study carried out to determine the behaviour of Cu-Ni mill tailings during natural and flocculated sedimentations. Settling rates were examined under various conditions through standard laboratory batch settling tests. Flocculation was found to improve the sedimentation process significantly, but its effectiveness depended on several factors such as the pulp density of feed, the type and dosage of flocculating reagent, the pH of pulp, the intensity of mixing flocculant with tailings sand the use of stirring during compaction.It is shown that. for a sedimentation process taking place under given conditions, underflow pulp density (P) and sedimentation time (t) are related by the expression P = k.tn, where k and n are constants. A procedure is described for the use of this expression in thickener size estimations. IntroductionOften a considerable proportion of the mill feed is disposed as tailing, because the valuable mineral recovered usually forms a small fraction of the ore. Moreover, wet concentration processes result in liquid wastes that are several times more voluminous than the ore itself. Thus the handling and disposal of these wastes become an important cost item in most milling operations. The principal unit process employed in tailing disposal is solid-liquid separation which is traditionally carried out by gravity sedimentation in thickeners or tailing dams. Direct disposal of tailings into tailing dams is common practice where sufficiently large areas of land are available but it frequently becomes more economical or practical to densify the tailings in a thickener beforehand.Successful thickener operation depends essentially on correct thickener size which is in turn governed by the sedimentation characteristics of the tailings handled. Flocculation can aid the sedimentation process and bring about significant savings in thickener size, but its effective use requires a detailed study to identify the optimum conditions of application."

Jan 1, 1988

By L. H. Thorleifson

Demand for both gem and industrial diamonds is very strong. Synthetic production supplies industrial uses, but synthetic gems remain inferior and expensive, so the large gem market is supplied by mining. Several major mines have been depleted, and the market is receptive to new sources of high quality gems. Canada&apos;s Precambrian terrane, extending across the Canadian Shield and under the Phanerozoic cover of the Plains and Hudson Bay, has excellent potential for diamonds, but exploration conditions are difficult due to recent glaciation. Early world exploration relying on recognition of diamond in alluvial sediments was adequate to launch pre-1900 production from India, Brazil, and Africa. Exploration success in Canada, as was the case in Russia and other more recently discovered sources, however, had to await large investments in effort supported by advanced science and technology. Canadian exploration in many ways is similar to that in other regions, relying on analysis of tectonics, indicator minerals, geophysical surveys, and multiple stages of drilling and sampling. Very different from other regions, however, is Canada&apos;s surficial environment, in which recent glaciation has caused fresh indicator minerals to be transported hundreds of km. Exploration accelerated in Canada after 1960, first in Ontario and the Arctic Islands, then in Saskatchewan in 1988, and most importantly after the Chuck Fipke - Stew Blusson discovery at Lac de Gras, Northwest Territories, in 1991 that led to the billion-dollar BHP - Dia Met Ekati Mine that opened in 1998. In 2003, production from Ekati is expected to be supplemented by that from the similar and nearby Diavik Mine of Rio Tinto and Aber, currently under construction. These mines will bring Canadian output to over 10% of world supply, and will position Canada with Botswana and Russia as world leaders in production of high quality gem diamonds. There could be other mines as well, as sites across the Arctic and in the south from Alberta to Québec are being explored by an array of companies, including De Beers, other majors, and several juniors.

May 1, 2001

By Ainul Akhtar, Steve Cockcroft, Daan Maijer, Carl Reilly, Lu Yao, Jun Ou

A coupled thermal-fluid flow-multicomponent model has been developed to aid in understanding the melting/dissolution behavior of solid Al-rich Material (TiAl) in a liquid titanium pool produced by an electron beam. The model is capable of accounting for the significant phenomena present affecting heat, mass and momentum transport including thermal and compositional buoyancy and Marangoni forces, Darcy attenuation, evaporation, melting and solidification, and the associated release or absorption of latent heat. The modeling results have indicated the compositional fluid flow driving forces (compositional buoyancy and Marangoni forces) contribute significantly to the melting/dissolution process. The model is waiting for validation against empirical data.

Jan 1, 2014

By R. Kong, X. W. Zhang

"High pressure (up to 50 MPa) isotropic compression tests were performed on marble, gneiss and sandstone specimens, of which represents the typical rocks, to investigate isotropic compression deformation characterization at room temperature. Experimental data with respect to volume change in loading and unloading are presented. An apparent volume change inflection point (sensitive stress) was observed at a lower pressure range for porous sandstone, indicating that the elastic-plastic behaviour arising in the isotropic compression stage, but for tight crystalline rock, the sensitive stress is much higher, not probed prior to 50 MPa. The irrecoverable volumetric strain in the unloading can be seen for sandstone as well. The anisotropic deformation was discussed in terms of the axial and radial strain measurement. It was found that essential features of mechanical anisotropy are the irreversible in deformation range. The deformation feature in the isotropic compression tests is a very complex issue due to the factors concerning the stress history, unloading in sampling and in-situ stress. INTRODUCTIONThe isotropic or hydrostatic compression condition that stress is compressive and has the same magnitude for all direction, which is expressed as s1=s2=s3 in principal stress space. A yield locus of soils subjected to the isotropic and anisotropic compression was widely known, for instance Cam Clay model, which forms a closure cap model. However, the similar isotropic compression yield curves for rocks, especially for hard rock, was not established due to the geo-stress in the rock mass is much less than the socalled isotropic yield stress. And hence, the previous experimental studies on the hard rock have been made tend to on the stress-strain-strength relationship (Handin & Hager, 1957; Edmond & Paterson, 1972; Menéndez et al., 1996). Perhaps the yield curves related to an increasing in the hydrostatic pressure is not forced to construct for hard rocks, undoubtedly, the deformation data in this processing is valuable to assess the bulk module (Fabre & Gustkiewicz, 1997), anisotropy (Niandou et al., 1997), field stress (Hakala et al., 2007). Furthermore, many rocks store much elastic volume strain energy link to the hydrostatic pressure exerted, following a deviator stress applying, to drive the unstable brittle fracture for hard rock. Latter was studied to interpret the incentive of rock burst. However, volume change characteristic in the isotropic compression behaviour have been scarcely studied experimentally to our knowledge, less application related to the fracture in hard rock as well. The mechanical behaviour in the isotropic compression of hard rock is notably affected by the original structure anisotropy, stress history and stress condition before sampling, all of which need reasonably assess. It is also a useful understanding to study isotropic compression that elastic and plastic volume change in the isotropic loading and unloading, and the micro crack evolution throughout it."

Jan 1, 2015

By F. Nava-Alonso, A. Uribe-Salas, C. Rodriguez-Rodriguez

Ozone has been proposed to pretreat refractory ores before the cyanidation process for precious metals extraction. As pyrargyrite is one of the silver species most common in Mexican refractory ores, the ozonization of this silver sulfide was studied. The effect of pH and ozone concentration on silver dissolution was evaluated by means of a factorial experimental design. Two levels of sulfuric acid concentration and ozone in gas concentration were evaluated: 0.18 and 0.72 mol/L of acid and 0.054 and 0.077 gO3/L, respectively. The highest silver dissolution was obtained when using the higher acid and ozone concentration.

Jan 1, 2011