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By J. Petersen, T. Moyo

Waste Printed Circuit Boards (PCBs) are a metals-rich fraction of electronic waste (e-waste) streams, and globally it has been demonstrated that they can be recycled gainfully to recover the metals. Reported successful cases of PCB recycling are carried out in large volumes, using high-level technology and high capital investment smelter house operations. This presents entry barriers for recyclers in developing economies where capital may not be accessible, and the waste volumes are not sufficient to warrant large scale operations. Hydrometallurgical processes have the potential to provide an option for the scalable processing of smaller volumes of PCBs and can be set up at relatively lower capital costs. However, to date, the hydrometallurgical treatment options available rely on precursor communition and classification processes that also require high capital and energy costs. This paper presents an overview of the work done under the Minerals to Metals signature theme towards understanding e-waste recycling processes and developing pre-processing and characterisation of PCBs in order to unlock potential for local end processing in developing economies, using South Africa as a case study. The structure of PCBs is reviewed, and the current size reduction techniques and the subsequent leaching processes are discussed. Keywords: Printed circuit boards (PCBs), PCB structure, pre-treatment, liberation, ammoniacal leaching

Jan 1, 2020

By D. W. de Vos

A school on the principles and practices of ladle metallurgy, organized by the Technical Committee: Metals Technology of The South African Institute of Mining and Metallurgy, was held at the University of Pretoria from 13th to 16th November, 1989. The course leader, Professor R.J. Fruehan from the Carnegie Melon University, Pittsburgh, Pennsylvania, presented the main part of the course. Three papers were read by local steelmakers on the experience gained in the field of ladle metallurgy in South Africa. The School also included a special half day seminar on new and innovative steelmaking and casting processes presented by Professor Fruehan.

Jan 1, 1990

By D. vas As, Constance M. Vleggaar, P. D. Toens

A facility at the National Nuclear Research Centre, Pelindaba, for the calibration of gamma survey meters used in uranium-prospecting operations by P. D. TOENS, D.Sc. (Fellow), D. van ASt, M.Sc. (Visitor), and CONSTANCE M. VLEGGAAR, B.Se. (Visitor) Ground radiometric surveys in uranium prospecting have in the past suffered from two serious shortcomings. Owing to varying instrument sensitivity and the often arbitrary height at which readings are taken, it has been impossible to compare results obtained in different surveys and, moreover, to relate such readings to actual U30s concentrations. A set of calibration sources designed to overcome these problems has recently been constructed on the site of the National Nuclear Research Centre, Pelindaba. A discussion of the standards applied and the instrument calibration procedure is presented.

By M. J. U. T. Van Wijngaarden, R. J. Dippenaar

An electrochemical technique based on the solid oxide galvanic cel Mo / Mo + MoO2/ ZrO2-MgO / Fe + (FexO)slag + Ag / Fe was used in a determination of FexO activities in liquid slag systems. The emf measurements, scanning electron microscopy, and microprobe analysis of the cross-sections of the electrolyte tubes used in direct contact with the slag melts indicated that slag attack did not affect the open-circuit emf values during normal cell operation, The reliability of the cell was confirmed by the good agreement between the standard free energy of formation of liquid Fep obtained in the present study and those reported in the literature, The FexO activities were determined in FexO -CaO and FexO-SiO2 slags at 1673 K, and are in good agreement with those measured by the conventional gas-equilibrium technique. The experimental technique was successfully extended to the measurement of Fe2O activities in the complex slags that are used for the external desilliconization of the hot metal product of the blast furnace.

Jan 1, 1986

By W. P. Nel

A fuel cell is an electrochemical engine that converts the chemical energy of a fuel, such as hydrogen, and an oxidant, such as oxygen, directly into electricity. The emerging fuel cell industry may represent a major opportunity for the global platinum mining industry. This is because low temperature fuel cell systems use platinum group metals as catalysts. Fuel cell vehicles may become the most important driver of future platinum demand within years of their commercialization. A great number of factors impact on and drive the diffusion of fuel cell vehicle innovation. Such drivers range from energy security to environmental concerns and the technological development of fuel cells and systems. Such factors and drivers of fuel cell vehicle diffusion are combined with the generic ?body of knowledge? on ?technology forecasting? and ?diffusion of innovation? to design a framework that provides a holistic approach to the analysis of this complex enterprise. An attempt is made in this paper to address the following questions: Which types of fuel cells require platinum group metals? Which types of fuel cells will achieve dominant design status? Will fuel cell vehicles diffuse successfully? How big will the impact of successful fuel cell vehicle diffusion be on future platinum demand? How well do fuel cell vehicles compete with incumbent technologies such as spark-ignited and compression-ignited internal combustion engine-driven vehicles? How soon will oil depletion start to drive the diffusion of fuel cell vehicles? How important is hydrogen as a fuel? What impact does the inadequate hydrogen fuelling infrastructure have on fuel cell vehicle diffusion? The paper contains some initial results of a research project that has the aim of producing a schedule of future platinum demand generated from fuel cell vehicles. Keywords: diffusion of fuel cell vehicles, technology forecasting, platinum demand forecasting.

Jan 1, 2004

By M. J. King, W. K. B. Loftus, H. S. Simpson

SYNOPSIS The history of the early diamond fields and primitive methods of diamond recovery are traced, giving a brief description of the improvements made in final diamond recovery processes and techniques up to the present day. In particular the emphasis is on the effect of improved equipment in reducing final hand sorting time and labour, better security and greater recovery of fine diamonds.

By M. L. Young, J. B. See

Effective thermal conductivities of packed beds of chromite ores by M. L. YOUNG, B.Se. (Rand), M.Sc. (Rand) (Visitor) and J. B. SEE, B.Sc. (Hons), Ph.D. (New South Wales), M.I.M., M.I.M.M. (Member) The effective thermal conductivities in stagnant air of packed beds of fines, lumps, and indurated and pre-reduced pellets of two chromite ores with different chromium-to-iron ratios were determined in the temperature range 300 to I 100°C by the heat-sink technique. Packed beds of fines, whether of the size fraction between 20 and 65 mesh, between 65 and 100 mesh, or between 100 and 150 mesh, were found to have the same values of effective thermal conductivity. For one ore, the effective thermal conductivities of packed beds of fines between 20 and 48 mesh at tem peratures above 600"C were higher than those for finer particles. This difference is explained as being due to the increase in importance of radiation heat transfer, but no definite conclusions are reached about the relative contributions of conduction and radiation heat transfer to the effective thermal conductivities of packed beds of fines between 20 and 48 mesh. Two published models were used for the theoretical prediction of values for thermal conductivities of the indurated and pre-reduced pellets as well as of lump ore. The experimental and theoretical results were in good agreement in view of the uncertainties in the assumed values of emissivity and thermal conductivity of the chromite ore.

Jan 12, 1976

By T. Ellis, J. Gagnon, L. Webb, M. Burr, D. Kakengela, D. Evans, A. Mirza

Lead-based alloys are used as the primary anodes for electrowinning from sulphate-based aqueous systems. Lead anode technology has evolved over the years, migrating from pure lead and lead-antimonial alloys to the present-day lead-calcium-tin alloys for copper electrowinning and leadsilver alloys for zinc electrowinning. Anode technology has also migrated from cast to rolled microstructures in search of improved mechanical properties and higher corrosion resistance. Although great strides have been made in the development of new alloys and production processes, the industry still has unresolved issues related to untimely corrosion, which limits anode life and may lead to higher contaminant levels in the metal being produced. Lead anodes corrode because of the difference in the chemical/electrochemical potential across the microstructural features of an anode. Given a very high purity material, we find that the grain boundary areas corrode significantly faster than the rest of the grain. A balance of alloying element selection and microstructural design allows the grain boundary area to be engineered, thus minimizing grain boundary corrosion. However, operational issues can lead to unexpected corrosion behaviours that we will discuss moving forward. The comments in this work, although directed toward copper electrowinning, can be extended to similar phenomena in other metals electrowon from sulphate media (i.e., zinc, nickel, cobalt, manganese). The life cycle of electrowinning anodes depends on tankhouse operating conditions and maintenance of the anodes, including cleaning and straightening. This paper will focus on the operational aspects of maximizing the utilization of lead anodes for base metals electrowinning.

Jan 1, 2016

By J. Ojeda, R. Kuyvenhoven, M. Ziemski M

This paper focusses on the identification of operational opportunities in a 1100 tph pellet plant to reduce the specific energy consumption in its comminution circuit, which is designed to process magnetite ore and produce pellets to be used as raw material in the iron and steel industry. The assessment is carried out through a frequency analysis for three of the four processing lines of the plant, consisting of one ball mill each with an installed power of 4.5 MW and 280 tph of mill throughput design capacity. The methodology, as described in this paper, facilitates the visualisation and quantification of plant performance and provides a good first approach to prioritise alternatives for optimisation. In a pellet plant, grinding is a critical stage due to its high energy consumption and its major impact on the physical properties of the iron pellets, which quality depends to a large extent on grind size and Blaine index. From the evaluation that was performed it can be concluded that production line 2 has the lowest specific energy consumption of 15.1 kWh/t, while line 1 has the highest with an average of 16.6 kWh/t for the same type of ore. On the basis of the results and current operational practices, it is recommended to increase the average mill throughput from 240 tph to 265 tph, translating into specific energy reduction of 10%, without affecting the chemical and physical properties of the final product. The implementation of an HPGR for regrinding the magnetic concentrate is proposed to assure adequate specific surface area in case grinding coarser becomes an alternative, which would also be beneficial for the subsequent water recovery stages. Keywords: Iron ore pelletisation, grinding circuit, energy efficiency, particle size, frequency analysis

Jan 1, 2020

By C. H. Wyndham, N. B. Strydom

Discussion C. G. Hinds (Member): The climatic chamber at Kloof Gold Mine was built to the design referred to in the paper presented by Professor Wyndham and Dr Strydom. As no suitable underground facilities existed for the acclimatization of labourers at the rate required, mining operations would have been severely restricted had there not been a climatic room timeously built on surface. The climatic room can accommodate 120 labourers per 4-!-hour shift. The standards laid down by the Human Sciences Laboratory were and still are being adhered to as strictly as possible. Through a shortage of European personnel the recommended degree of white supervision could not be adhered to and the use of Bantu assistants with a minimum education of Standard 8 was introduced. This is considered to have met with sufficient success to warrant acceptance as policy. The climatic room was brought into operation on the 1st September, 1967, i.e. two months after stoping at Kloof was commenced. The figures quoted herein therefore pertain to the period between that date and the 31st March, 1969, when the main shaft and the main surface fans were commissioned. The areas worked were sited between 5016 ft and 6 365 ft below surface. Virgin rock temperatures ranged between 92°F and 99°F. Stopes are cleaned by hand lashing. During the 20 months of stoping prior to the commissioning of the main shaft, mining operations at Kloof were effected through the Harvie Watt shaft of the Libanon Gold Mining Company Limited. In this period 10 452 Bantu labourers were acclimatized in the following categories: Experienced workers 7 326 New to the industry 2 086 Re-acclimatized 1 040 It will be noted that during the period, labourers 'new to the industry' averaged 22 per cent of the intake. This percentage fluctuated from time to time and reached 42 per cent. (The present percentage is 60.) The greatest number acclimatized during anyone month occurred in February, 1969 when 1234 Bantu were treated. The greatest number of Bantu acclimatized during any 8-day period was 411. As many as four X 41/2 hour shifts were run in 24 hours. The number of men found to be heat intolerant over the period of 20 months was 33 out of a total 9 412 Bantu. The following tabulation illustrates the history of the build-up of manpower and the climatic conditions under which they worked: The average dip of the reef is 35°. The number of heat stroke and heat exhaustion cases during the period of 20 months under most difficult ventilation conditions was Nil.

Jan 10, 1969

By T. N. Matveev, V. V. Getman, A. Yu. Karkeshkina, L. B. Lantsova, N. K. Gromova

Sulfide-type tin deposits in Russia are characterised by the complex mineral composition of ores and dump products of their processing. Tin-sulfide ores contain industrial quantities of copper, lead, zinc, tungsten, silver, rare and trace elements (indium, scandium, etc.). In addition, the ores are characterised by uneven dissemination of sulfide minerals (chalcopyrite, galena, arsenopyrite, etc.) and tin minerals (cassiterite, stannine, etc.). X-ray phase and spectral analysis, scanning electronic microscopy (SEAM), laser SIM and AFM microscopy helped to identify the selective fixing of sodium dibutyl dithiocarbamate (DBDTC) on chalcopyrite and galena, as well as the tall oil fatty acids (TOFA) and IM-50 on cassiterite. For the first time, collectors and flocculants of slurry fractions of silver and tin, thermomorphic polymers TMPF were used to isolate more than 80% silver from the tin tailings of the Solnechny mine into a copper-silver rough concentrate. It has been established that preliminary ultrasonic treatment and desliming according to the 0.02 mm class removes up to 20% of sludge material, which impairs the process of gravity separation. The combined flotation-gravity scheme using new reagent compositions helped to obtain tin concentrate with a tin content of 5.42%, which meets the requirements for further metallurgical processing (at least 5%). This work was supported by the RSF according to the research project No. 17-17-01292. Keywords: Flotation, flotation reagents, tin-sulfide ores, casiterite, adsorption, flocculation

Jan 1, 2020

By Colin M. Spence

If one is to discuss sensibly and beneficially the whole spectrum of education, training, and employment of engineers, it is not possible to confine oneself to Professional Engineers because the profession of engineering embraces also technologists, technicians, and those people known in South Africa as certificated engineers. It would therefore be imprudent if this seminar were to be limited to certain sectors of the profession and industry. I hope that it will review the full situation from top to bottom and from side to side. New President of FAPA Mr Douglas H. Mills took office as President of the Federation of Societies of Professional Engineers on 1st July, 1985.

Jan 1, 1985

By A. Smith

After the introduction of mechanized bord-and-pillar development at Dumacol in 1958, pillars were being developed at a much faster rate than they could be extracted by hand loading methods. Efforts were therefore made to increase the rate of pillar extraction by mechanization. Following two partially successful mechanized stooping trials in 1964 and 1971, it was decided that mechanized pillar extraction with 1 m3 cable-reel front-end loaders should be introduced. The first section to employ the new equipment started production in May 1979, and the mine now has four mechanized pillarextraction sections in operation. Considerable improvements in production, productivity, safety, and percentage extraction have been achieved.

Jan 1, 1985

By Page-Shipp. R. J., Elizabeth Harris

A study of the response of South African white gold miners to exposure to dust in their working environment yielded large quantities of dust data. Analysis of this data (presented in summarized form) reveals a variety of interesting relationships, including the shift-long exposure of different occupational groups, the dust levels due to various mining operations, relationships between different dust-measuring procedures and time trends in dust levels during the shift. The statistical probability of contracting silicosis at various levels of exposure to this dust is reported briefly. A new method of using microscope counts to estimate the respirable mass of dust samples is given in an appendix.

It is well understood that to develop wagon wheels with higher abrasion resistance, fracture toughness, and fatigue resistance, steels with lower amounts of inclusions need to be used. Clean steels are produced with technologies that minimize the amount of inclusions in the microstructure. The demand for cleaner steels is high, and lowering of non-metallic oxide inclusions and controlling their morphology, composition, and size distribution is vital. Reduction of residual impurity elements such as sulphur, phosphorus, hydrogen, nitrogen, and trace elements is essential in the production of cleaner steel. Material cleanliness is vital for fatigue endurance, since oxide inclusions may act as stress concentrators and initiation points for fatigue cracks. To better understand the relationship between the cleanliness and toughness of the 34-inch cast wagon wheels, two samples of different levels of cleanliness were supplied for investigation. This paper presents the results of metallurgical analysis using scanning electron microscopy(SEM), energy-dispersive spectrometry (EDS), and mechanical tests for the pearlitic high-performance cast rail wagon wheel (identified as Class B) that are currently being used. The Charpy V-notch impact test results for the three samples from wagon wheels were compared. With the aid of SEM/EDS analysis system, non-metallic inclusions in these steels were detected, and it was possible to determine the position, size, shape, and composition of each particle. Alumina and manganese sulphide inclusions could be identified as the dominant inclusion types in the investigated samples. Fracture surface analysis of the Charpy specimen with high inclusions indicated that transgranular cleavage was the predominant fracture mode. Fractography of fracture surfaces of Charpy impact test samples also showed improvement of toughness properties on the clean sample.

Jan 1, 2013

By P. Maais

This paper gives an account of the development of a plant for the differential flotation of mixed sulphide ore, special reference being made to the separation of copper and zinc sulphides. The uniqueness of the geology, mineralogy, and metallurgy of each complex ore-body is stressed. Consideration is given to the scale-up of laboratory data, and to some of the factors involved in the design of milling and flotation plants for this type of ore. Process control and development are discussed, as are the human requirements for the optimum operation of a concentrator.

Jan 1, 1980

By H. L. Zimba

Flotation involves the selective levitation of mineral and its transfer from cell to launder. The flotation rate is the rate of this transfer. It may be defined by the slope of a recovery-time curve for any cell in a bank or at any time in a batch operation. The objective in flotation rate study is an equation expressing the rate in terms of some measurable property of the pulp. This can be either the concentration of floatable mineral in weight per unit volume or a relative concentration, which will be a function of the recovery. A rate equation for an actual flotation pulp will contain at least two constants, both to be determined from the collected data. The data used in this paper were collected from bench-scale flotation tests on Konkola primary mill cyclone overflow at various pulp densities and pre-flotation thickener underflow at a pulp density of 35% solids by weight.

Jan 1, 2009

By R. M. Lamya

A semi-empirical kinetic model was developed for the atmospheric leaching of a Ni-Cu matte in copper sulphate-sulphuric acid solution. Kinetics of the leaching process was studied as a function of initial copper ion concentration, initial acid concentration, temperature, stirring rate and particle size distribution. The kinetic model was developed on the basis of the leaching mechanism and chemical reactions of the leaching system investigated, and was evaluated by comparing the model predictions to experimental data. The model was found to satisfactorily fit the trends in the leaching of the metals, namely copper, nickel, cobalt and iron.

Jan 1, 2009

By S. Mohanty, K. Sarangi, S. Dash, P. P. Patra

Industrial effluent from various industries contains heavy metals that are a serious threat to humans, flora and fauna in water bodies, and the environment. The heavy metals are dumped after precipitation, which has serious environmental consequences. In this paper, a 2D axi-symmetry CFD model has been developed to study the extraction of chromium ion from industrial effluent, in a hollow fibre membrane, using Alamine 336 as the carrier and kerosene as the diluent. The Navier Stokes equation was used to predict the velocity profile of the aqueous and organic phases, and species transport equation, which considers both convective and diffusive mass transfer, was used to predict the concentration profile of the chromium ion in the computational domain. The distribution coefficient was experimentally determined at a pH 4, which was found to be the optimum pH. Numerical simulations were performed considering 11.11 mol/m3 of initial feed concentration for chromium ions and extractant concentration of 0.2 M. Simulations were carried out with various aqueous and organic flow rates, and validated with experimental data. Keywords: CFD, metal extraction, hollow fibre membrane, heavy metals

Jan 1, 2020

By M. Bester, R. Carey, T. Russell, J. van Heerden

"In order to reach the goal of optimal and safe extraction of the mineral reserve, the mining industry is increasingly focusing on reconciliation across the mining value chain to ensure that the mining process occurs in a progressively more predictable manner. This will consequently improve the understanding of mine plans and their associated implementation risks, ultimately leading to increased investor confidence. In terms of geotechnical engineering, mine to design performance assessment is a critical aspect of mine to plan adherence focusing on the complex aspects influencing slope performance. A mine to design reconciliation process therefore needs to systematically track implementation and geotechnical aspects in order to review or update slope design criteria and pit layouts according to the mine planning cycle as the mine is developed. This paper describes the development and implementation of a standardized mine to design reconciliation system for operations utilizing laser scanning technology, analysis tools, as well as associated key performance indicators. Performance is evaluated on final pit boundaries in terms of geometry achieved as well as blast performance evaluation of face conditions. These aspects as well as the resulting catch berm capacity should be captured in an information system, enabling longer term trend analysis and detailed root cause analysis where unsatisfactory outcomes occur. Adverse outcomes should subsequently be incorporated into the mine’s risk management process informing risk mitigation measures including blast design adjustments, slope design changes, or rockfall protection measures. IntroductionIn order to reach the goal of optimal and safe extraction of the mineral reserve, the mining industry is increasingly focusing on reconciliation across the mining value chain to ensure that the mining process occurs in a progressively more predictable manner. This will consequently improve the understanding of mine plans and their associated implementation risks, ultimately leading to increased investor confidence. In terms of geotechnical engineering, mine to design performance assessment is a critical aspect of mine to plan adherence focusing on the complex aspects influencing slope performance. A mine to design reconciliation process therefore needs to systematically track implementation and geotechnical aspects in order to review or update slope design criteria and pit layouts according to the mine planning cycle as the mine is developed."

Jan 1, 2016