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By Isaac A. Zlochower

This paper presents data on the limiting (minimum) oxygen concentration (LOC), in the presence of added N2, of methane (CH4), propane (C3H8), ethylene (C2H4), carbon monoxide (CO), and hydrogen (H2), and some of their binary mixtures. It also addresses the issue of the flammable concentration (flammability) limits of these pure gases in air. The study is based on spark ignited explosions in large, spherical laboratory vessels (120-L and 20-L) using a 7% pressure-rise criterion for explosion propagation. The results of the study are compared with the older values which used long flammability tubes with a diameter >5 cm together with visual evidence of substantial upward propagation. They are also compared to results reported recently using a 12-L spherical flask with a visual flame propagation criterion. Finally, they are compared to results reported in Europe using more modest flammability criteria and smaller chambers. The findings reported here show excellent agreement between the 120-L and 12-L results, good agreement with the 20-L results, and reasonable agreement with the earlier flammability tube values for the lower flammability limits. They disagree, however, with the more conservative European values. These results and those from the 12-L experiments also feature lower LOCs than are given by traditional flammability tubes. A model for the LOCs of such fuel mixtures based on the Le Chatelier mixture rule for lower flammable limits is seen to reasonably fit the observed results on binary mixtures and can accommodate more complex mixtures as well. One such set of ternary mixtures containing CH4 and 1:1 CO:H2 is well fitted by the model.

Jan 1, 2009

By P. Kovalchik, S. Peng, G. Cole, R. Matetic

Previous studies conducted by the National Institute for Occupational Safety and Health (NIOSH) have shown that approximately 90 percent of coal miners and 49 percent of metal/nonmetal miners had a hearing impairment by age 50 (Franks, 1997). Mine workers are exposed to additional noise levels underground due to the reflection of machine-generated noise that would otherwise dissipate in an aboveground setting. Determining the sound-absorption coefficients is essential in modeling the sound field in an underground mining environment. Sound absorption is a measure of the amount of acoustic energy that strikes a surface and is absorbed rather than being reflected. The acoustic environment that mining machines operate in is a critical factor affecting the sound pressure level exposure for mining machine operators. Impedance tube testing is an inappropriate method for determining underground absorption coefficients due to the brittle composition of materials such as coal and slate. Classic absorption coefficient estimation using T60 measurements will not work well in an underground environment because the theory assumes a finite room, a diffuse field and a relatively uniform absorption. None of these assumptions are true in an open-ended mine entry. This paper presents a method using a ray-tracing technique to determine absorption coefficients for underground mines. Absorption coefficients are determined and presented for octave bands from 63 Hz to 8 kHz. The absorption coefficients are essential for determining and predicting potential overexposure to machine operators in different mine environments.1

By Roy L. Wilfong

Infrared reference spectra are presented of compounds of importance in lead sulfide flotation research. Included are the spectra of several short chain alkyl xanthates of lead and zinc, the corresponding dixanthogen compounds, and the common oxidation products of lead sulfide and their sodium analogs. The spectra of several frequently used industrial flotation reagent xanthates are also presented. A thorough, well-documented discussion is given of the various corrections made to correct the as recorded absorption band data to near absolute values.

Jan 1, 1974

By Noel N. Moebs

The Bureau of Mines conducted five reconnaissance magnetometer traverses across a small abandoned chromite mine in the State Line district of Pennsylvania and Maryland to determine the geophysical response of the area. The results indicate that more extensive geophysical surveys of the region might establish some worthwhile guidelines for chromite exploration. While chromite only rarely can be detected directly by magnetic methods, there is a possibility that geophysical signatures in the adjacent host rock could provide some guidelines for further exploration. Prior to 1875, all the chromite produced in the United States came from the State Line district, and the potential for discovering additional podiform deposits could be significant. Virtually no state-of-the-art geuphysical or geochemical studies have been conducted in this district since World War II and sizable areas remain undeveloped and suitable for exploration. While the results reported in this paper are not supported by drilling, it may encourage others to investigate the area more fully for improved methods of detecting subsurface podiform chromite deposits. New theories on the emplacement of ophiolites also could contribute to an assessment of the chromite potential of the serpentinite belt.

Jan 1, 1991

By Walter K. Utt

The U.S. Bureau of Mines conducted research to develop an accurate, real-time, position monitoring and warning system for the vehicles used in surface mining. The product of this research will be technology to reduce accidents and injuries associated with the operation of surface mining haulage equipment. The position monitoring system should reduce accidents related to vehicle position and also increase the efficiency of haulage operations. This research was conducted in preparation for development of an accurate, real-time position monitoring and warning system, which notifies equipment operators when they deviate from a known safe course and are approaching a fixed hazard. A radar positioning system designed for marine applications was evaluated and a series of tests was run to determine the accuracy of the radar positioning system when used in a land vehicle. The radar position determination was compared to surveyed values. Both static and dynamic (moving vehicle) tests were conducted. The static test results were marginal and the dynamic test results were not accurate enough for the position monitoring and warning system. Although a promising technology, the system tested needs to be modified to meet the accuracy requirements of mobile mine equipment.

Jan 1, 2010

By J. Nielen van der Merwe

For the last 3 decades, coal pillars in the Republic of South Africa have been designed using the well-known strength formula of Salamon and Munro that was empirically derived after the Coalbrook disaster. The database was recently updated with the addition of failures that occurred after the initial analysis and the omission of failures that occurred in a known anomalous area. An alternative method of analysis was used to refine the constants in the formula. The outcome was a new formula that shows that the larger width-to-height ratio coal pillars are significantly stronger than previously believed, even though the material itself is represented by a reduced constant in the new formula. The formula predicts lower strength for the smaller pillars, explaining the failure of small pillars that were previously believed to have had high safety factors. Application of the new formula will result in improved coal reserve utilization for deeper workings and enhanced stability of shallow workings.

Jan 5, 1999

By H. Billmayer

This report covers the period from June 17, 1974 to February 20, 1975, and describes the work performed in compliance with the requirements of Contract No. H0346102 and Modification No. 1 thereto. The purpose of the contract was to design protective canopies for an Elkhorn Scoop, a Lee Norse Miner, a Wilcox Miner and a Wilcox Bolter; to construct mockups of the canopies; and to obtain machine operator evaluations of the canopy designs by assessing the mockups while installed on their machines in the mines. The overall program objective was to achieve protective canopy designs for the four machines which would be acceptable to the operators.

Jan 1, 1975

By Jerry W. Ramsey

The Bureau of Mines studied two Pennsylvania anthracites using low-temperature carbon dioxide adsorption. A modified form of the Brunauer-Emmett-Teller equation was used to calculate specific surface areas. Two mesh sizes of each anthracite were used to determine how gamma irradiation at 106 and 108 rads, both in vacuum and in the presence of air, affected the carbon dioxide surface areas. Results show that anthracites have a system of pores that are essentially all interconnected rather than isolated; that anthracites differ from one another in specific surface, which may correlate with density; and that irradiation in vacuum has no discernible effect on specific surface of anthracite, but irradiation in air does produce changes in specific surface.

Jan 1, 1966

By Walter R. Storms, Allan B. Bowman

This paper , which describes mining methods and practices at the Mineral Hill copper mine , is one of a series being prepared by the Division of Minerals of the Bureau of Mines on mining methods , practices , and costs in various mining districts. of the United States . The Mineral Hill mine is situated on the northeastern piedmont of the Sierrita Mountains at an altitude of 3,650 feet in sec . 35 , T. 16 S. , R. 12 E. , and sec . 2 , T. 17 S. , R. 12 E. , Pima mining district , Pima County , Ariz . ( fig . 1 ) . The claims (figs . 2 and 3) are in a gently rolling area with only scant desert vegetation . The average annual precipitation is about 11 inches . The nearest surface water is the Santa Cruz River , an intermittent stream 8 miles east of the mine . The property is owned by the Banner Mining Co. , a Nevada corporation . This report presents a brief history of the mine , describes the geology of the area and the ore deposits , outlines methods of prospecting and exploration , and gives methods of sampling and the estimation of ore reserves and values . Development and stoping methods are explained , and methods of underground transportation , ventilation , mine drainage , and safety measures are described . The concluding section of the paper is a section on milling . The Mineral Hill mine is an old mine that was reopened in 1951 after having been closed for 30 years .

May 1, 1957

By F. E. Armstrong

Tritiated water has been used as a tracer to follow the path of leach liquids as they flow through a copper-mine dump. Semipermeable layers, produced within the dump by compaction and "stratification" of deposized dump material, restrict the vertical movement of water. Knowledge of this restriction would aid in the optimization of the leaching process. The portion of the dump of particular interest was approximately 2,000 feet long, 800 feet wide, and 200 feet high. A total of 94 curies of tritiated water was injected into the dump at the rate of 650 gpm over a period of 39 hours. The leach liquid was sampled at natural surface outflows and through a series of wells, some drilled to the bottom of the dump and others to intermediate levels. More than 3,300 samples were analyzed, most by liquid scintillation counting, but a few hundred by gas counting. Data obtained permitted calculation of flow paths, recycle times, total fluid volume, and estimates of retention times in various portions of the dump.

Jan 1, 1971

By Erica E. Hall, Robert H. Peters, Charles Vaught, Jon C. Volkwein

Coal workers’ pneumoconiosis is the leading cause of death due to occupational illness among U.S. coal miners. This disease is caused by miners’ exposure to excessive levels of respirable coal mine dust. A personal dust monitor (PDM) has recently been developed to provide near real-time feedback to miners regarding the level of respirable coal dust in the air they breathe. The main objective of this report is to document coal miners’ reactions to this device and how they make use of the information it provides. It summarizes a field study by the National Institute for Occupational Safety and Health that documented the opinions of 30 miners at 4 underground coal mines concerning the use of PDMs.

Jan 2, 2008

By Joseph Grumer

In addition to nine powder and gaseous extinguishants of propagating Pittsburgh seam coal dust-air explosions earlier evaluated,6 10 other powders have similarly been evaluated under like conditions such that wall quenching of the coal dust-air flames was virtually absent and the dust concentration was temporally and spatially uniform to within about ±5 percent. None of the newly examined extinguishants was better than Purple-K (potassium bicarbonate); the 10 of this report are anhydrite (calcium sulfate), monobasic (4 types) and dibasic ammonium phosphate, natural and synthetic cryolite (sodium fluoalumi-nate), sodium sulfate, and tricalcium phosphate. Except for anhydrite, sodium sulfate, tricalcium phosphate, and the cryolites, these materials were about equally effective, when present in relatively low concentrations (weight-percent of the coal dust-extinguishant mixture). The maximum oxygen concentration for the extinguishment of otherwise uninhibited coal dust explosions and the influence of coal dust particle size and the volatile content of the coal were also explored. For the present, the choice of the inhibitor among the good ones evaluated is not as critical as the system to be used to deploy the extinguishant against a coal dust explosion.

Jan 1, 1973

Track and control the tram maneuvers of continuous mining machines by developing and evaluating a laser sensor system. Background Progressive technology has the potential to greatly improve mine-worker safety, helping to create a safer, better working environment for mine workers by keeping them away from the dangerous face area. To benefit from such technology, the Bureau is investigating remote, computer-assisted operation of mining systems for underground, highwall, and surface mining applications. A cornerstone for computer-assisted operation is an effective guidance system. Since there are no guidance systems on any commercial continuous miners (CM's), the Bureau it-self developed and tested a laser-based sensor system, based on a commercial sensor called Lasernet. The laser-based guidance system employs four laser scanning sensors at fixed locations in a mine entryway to report the angular coordinates of two cylindrical retro-reflective targets mounted on a CM. Using triangulation, a real-time microcomputer system processes the sensor data and updates the xy position and heading (h) of the CM five times per second. Using a simple control algorithm and communications interface to the CM control computer, the system also controls rotational and translational tram maneuvers.

Jan 1, 1992

By Robert H. Merrill

A method of determining the strength of a mine roof layer in place is described in this report. The method was tested on a limestone roof layer 50 feet wide, 100 feet long, and 20 inches thick. In place measurements were accomplished by introducing air under pressure into a separation between the layer and the overlying roof, and as pressure was increased, the corresponding strain and deflection of the roof layer were measured until the roof failed. The ultimate strength of the roof agreed with the tensile strength of the roof rock (modulus of rupture) as determined in the laboratory; the modulus of elasticity as measured in place did not agree with the laboratory-determined values; the deflection and tensile strain in the layer in place showed good agreement with the theory of a body-loaded beam clamped at both ends. This procedure for determining the strength of a mine-roof layer is safer and less costly than successively widening a roof to failure. For example, it would have been necessary to mine the room to a width of 114 feet and a length of 228 feet to produce failure in this roof layer. The method is not necessarily limited to limestone; any thinly bedded rock type can be tested by this procedure when there is an open parting over the mined area.

Jan 1, 1958

By Thomas C. Ruhe

The Bureau of Mines conducted research to determine the safe operating conditions for using recycled (used) lubricating oil from mining equipment as a partial replacement for diesel fuel to make ANFO-type blasting agents. The use of recycled oil (RO) saves energy, reduces oil imports, and reduces mining costs. Low ambient temperatures may cause these recycled oils to become too viscous for proper absorption by ammonium nitrate (AN) prills and result in poor blast performance, safety hazards, and environmental problems. To help quantify and resolve these issues, viscosity, mixing, and performance tests were conducted at various temperatures. Diesel fuels No. 1 and No. 2 were studied separately and in blends with 25,50, and 75% RO. Good quality ANFO mixes (94-6) were produced with dry absorbent prills and blended fuel (No. 1 diesel plus RO) at temperatures as low as -40°F (-40°C) with 75% No. 1/25% RO, and at -20°F (-29°C) with 50/50. Diesel fuel No. 2 also made good mixes as low as -30" F (-34°C) with 75% No. 2/25% RO, and at 0°F (-18°C) with 50/50.

Jan 1, 2008

By C. M. Bouton

Although much valuable work has been done in the study of dust explosions, the laboratory technique has not been developed to the point where the many factors involved can be properly controlled, and thus where really fundamental information can be obtained. This paper presents a brief discussion of the difficulties encountered in fundamental work on dust explosions, a description of apparatus intended, to overcome some of them, and an account of some results obtained. FACTORS INVOLVED IN DUST EXPLOSIONS The more important factors pertaining to the dust cloud itself which are known to determine the phenomena of explosions are (1) the kind of dust; (2) its fineness; (3) its concentration in the exploding cloud; and (4) the nature of the interior motions, or turbulence, of the cloud before and during the explosion. These factors are arranged in what seems to be an ascending order of complexity. The kind of dust is the factor most easily subject to control. The fineness of the dust at first sight seems to be a controllable factor, but when it is recalled [that] most explosible dusts are mixtures of particles of continuously varying sizes so small as to pass through the finest woven sieves, and therefore difficult to separate either for purposes of analysis or experiment, the fineness is seen to be a factor difficult to control accurately.

Jan 1, 1929

By Stephen Krickovic

A methane emission rate study was conducted in 1969 on a longwall section of a Lower Kittanning coalbed mine in central Pennsylvania. The longwall face was mined with a drum shearer between developed headings on the head end and headings on the tail end that were driven with a ripper-type continuous miner as needed. The study was conducted over 22 consecutive shifts (7-1/3 days). The average methane emission rate from the Lower Kittanning coalbed during mining at the face and developing the headings at the tail end of the face was 34 Am. Caving of the gassy overlying strata as the result of mining at the face increased the methane emission to rates ranging from 702 to 1,049 cfm.

Jan 1, 1971

By John C. Holtz

The Bureau of Mines studied air contamination caused by diesel exhaust in a 10,000-ft ventilated tunnel. Sequential air samples were taken at the ends and middle of the tunnel during an operating cycle. Observed and calculated results for carbon dioxide, carbon monoxide, and nitrogen oxides were essentially in agreement. Nitrogen dioxide was present only in trace amounts. It was found that contamination was related to the volume of ventilating air, the number of haulage trips, train speed, and engine load.

Jan 1, 1968

By Edward D. Thimons

Several types of inflatable stoppings, developed under Bureau of Mines contract for use as mine air barriers during underground production, have been tested by the Bureau. All of the stoppings tested showed significant internal leakage initially but, in all but one stopping, the leaks were sealed with limited effort The stoppings were tested underground in two western noncoal mines under production conditions. The results from the Colorado molybdenum mine showed the stoppings to be generally unsatisfactory for daily mine usage if they are deployed near blasting areas or in locations where near-perfect air seals are required. They were very susceptible to blast damage and seldom were better than 90 percent efficient as air barriers. However, stoppings tested in the New Mexico uranium mine were located substantially distant from any blasting. Because slight leakage past the stoppings was acceptable, they proved very satisfactory in that application.

Jan 1, 1976

By E. D. Gardner

Humphreys Gold Corporation of Denver, Colo., was conducting a successful placer operation in 1936 on North Clear Creek about 6 miles below Blackhawk in Gilpin County, Colo. About 3,000 cubic yards of gold-bearing gravel are dug daily (September. 1936) by two draglines and a power shovel. The gravel is screened in a portable washing plant; the trommel oversize is discarded, and the undersize is pumped to a gold-saving plant. The gold is caught in riffles in sluice boxes. The total cost of mining is about 20 cents per cubic yard. The mine is in a narrow canyon at an altitude of 7,200 feet. The Blackhawk-Central City branch of the Colorado & Southern RR. runs over the property. Freight platforms for receiving supplies were moved as the workings advanced. The workmen reached the mine on a speeder that ran on the railroad tracks from a point on the automobile highway (U. S. 40) on Clear Creek near the bottom of Floyd Hill, about 5 miles distant. The mine is 36 miles by road and speeder, or 30 miles by rail, from Denver.

Jan 1, 1937