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By R. L. Hopkins

Some typical thiacyclopentanes and thiacyclohexanes were synthesized to provide reference compounds needed for the identification of sulfur compounds in crude oils. Two general methods of synthesis were employed: (1) cleavage of 2-alkyltetrahydropyrans with hydrogen bromide followed by the reaction of the resulting dibromoalkanes with sodium sulfide and (2) the catlyzed reaction of cyclic ethers or 1)4-or 1)5-alkanediols with hydrogen sulfide. Both methods produced mixtures of 2-alkylthiacyclopentanes and 2-alkylthiacyclohexanes with 2-alkyltetrahydropyran as the starting material. The structures of the reaction products were established by analysis for sulfur; desulfurization; gas-liquid chromatography (GLC); mass, infrared, and nuclear magnetic resonance (NMR) spectra; and an alternate synthesis. The synthesis of the cyclic sulfides contributed substantially to the identification of 10 members of this class of sulfur compounds in crude oil.

Jan 1, 1967

By David R. Hanson

Transient electrical noise events pose serious problems for data acquisition systems used in monitoring acoustic emissions in laboratory and field environments. The U.S. Bureau of Mines has designed and constructed a trigger discriminator circuit for use in ultrasonic acoustic emission studies. Designed for use with signals in the frequency range of 50 to 400 kHz, the instrument examines .incoming signals for frequency content, amplitude, simultaneity, threshold crossings, and number of channels above threshold. If preselected criteria on these properties are met, a plus 5-V pulse is output that may be used to trigger a data acquisition system, allowing rejection of noise events that do not possess useful information. The system was designed for four input channels, but may be expanded to more channels with minimal design changes.

Jan 1, 1995

By Ivette E. Torres

Many significant events that began in 1990-91 continued to have a profound impact in the world minerals economy in 1992. The dissolution of the U.S.S.R. and the formal breakup of the Council for Mutual Economic Assistance (CMEA) had significant effects far beyond the geographic boundaries of Europe and Central Eurasia. CMEA's network of economic interdependence had relied on central planning, a variety of subsidies, and barter agreements that allowed its members to function without the pressures of productivity and efficiency. In the mineral sector, many decisions had been made based on the need for military planning and technology competition with the market economy world. Because of inexpensive oil available through subsidies and technology assistance from the former U.S.S.R., industries III CMEA member countries had been able to function and maintain production to supply minerals and materials required to support the policies of the central plan. In 1992, most of the former CMEA countries decreased their output of many minerals. In some cases, the network of production that had been in place was severed. Political and economic instability, destruction of infrastructure, and new priorities were affecting other mineral industries in the area. In late 1991, 15 independent countries replaced the U.S.S.R. and in early 1991 the former CMEA countries found themselves trying to adjust to the realities of economic independence and the need to compete with former allies for survival. Although 11 of the 15 former Soviet republics joined in the Commonwealth of Independent States (CIS) in December 1991, in 1992, individual economic needs exceeded the needs of the Commonwealth III importance. As a result, new mineral trade patterns emerged as minerals were used as a source of much needed capital.

Jan 1, 1994

By William R. Sharp

This Bureau of Mines report details a technique for aiding the engineer with the long-range design of an underground mine. The method is based upon the assumption that sufficient data are available to assign numeric values to some finite number of mineralized blocks; assignment of numerical values is problem dependent. By assigning appropriate weighting schemes, the algorithm developed in this report may be used to solve the optimal end-of-life underground mine layout, design least-cost electrical layout networks and efficient material handling networks, find least risk escape routes in the event of an accident, etc. The method is based upon the assumption that sufficient cost and geologic data is available to build a detailed mineral block inventory of the mineral deposit. It is further assumed that the cost assigned to any minable unit is independent of the neighboring blocks. The basic approach relies upon concepts and ideas from the theory of networks. To make the approach user oriented, a computer program is included and discussed. The computer code is written for an orthogonal, three-dimensional set of blocks. Computational costs and experience indicate that the program could be of great benefit in evaluating large complex mineral properties from the viewpoint of predesigning an underground mine layout.

Jan 1, 1974

By Van E. Shaw

Bastnaesite is a natural rare-earth fluorcarbonate of the cerium group that affords an abundant and high-grade source of the lighter rare-earth elements. A simple and efficient method has been developed by the Bureau of Mines for extracting rare-earth compounds from this mineral. Digesting of a flotation concentrate with sulfuric acid converts the rare-earth compounds from fluorcarbonates to sulfates. Action of the acid releases gaseous com-pounds of fluorine and silicon, leaving the sulfated material free of these elements; carbon dioxide from carbonate decomposition is eliminated at the same time. Calcining the sulfated material at 1,200° F. renders the gangue constituents insoluble, whereas the rare-earth sulfates are left in water-soluble form. Leaching with water yields a solution of pure rare-earth sulfates. Bastnaesite could become prominent as a source of cerium-group rare-earth elements. It is rich in the light rare-earth elements and comparatively easy to process; reserves of the mineral are extensive enough to supply a greatly expanded market for many years.

Jan 1, 1959

By A. B. Hooker

Investigations at the Pittsburgh Experiment Station of the Bureau of Mines have shown that satisfactory operation of a flame safety lamp depends not only upon proper design and assembly of the lamp but also upon the kind

Jan 1, 1945

By M. J. Ankeny, J. J. Forbes

Several sets of questions and answers on the fundamentals of first aid to the injured, based on the Manual of First-Aid Instruction of the United States Bureau of Mines, are now in use in various parts of the United States. Persons experienced in first-aid instruction believe that a standardized set of questions and answers will assist materially in preparing men for examin- ations conducted by the Bureau for first-aid certificates. Inquiries as to whether a set of standardized questions and answers is available have been made frequently by those training men for the Bureau of Mines examination for certificates. It is believed that the following list of 171 questions and answers com- piled directly from the manual will be useful to company officials and em- ployees who are engaged in cooperative first-aid training to qualify for Bureau of Mines certificates. The list may also be used by field men of the Bureau in training instructors preparatory to a cooperative training campaign and in examining classes or individuals for first-aid certificates. The page references in parentheses refer to pages in the Manual of First-Aid Instruction.

Oct 1, 1935

By S. R. B. Cooke, F. D. DeVaney

"INTRODUCTION The potash mineral receiving the most attention in the newly discovered. New Mexico-Texas potash district near Carlsbad, N. M. is sylvite (potassium chloride). Sylvite contains more potassium than any other mineral. Merchantable high-grade deposits have been found, and those of lower grade may be enriched to a high degree of purity by refining methods. Deposits containing sylvite were the first to be developed and axe the only ones being mined.However, many other minerals that contain potash occur in the salt beds of the Carlsbad District. Of these the more important are polyhalite, carnallite, langbeinite, leonite, and kainite. The nature of the deposits and their mineralogy have been described in detail by members of the United States Geological Survey. 4/Langbeinite, although not so abundant in these deposits as carnallite and has particular interest because the potash is in the form of the sulphate and as such commands a premium in terms of K20 unit. This is explained by Fox and Turrentine 5/, who state:"

Feb 1, 1936

In laboratory tests using reconstructed soil columns, rubber latex showed good sealing efficiency when applied at a rate equivalent to 4000-5000 pounds per acre. Results of field testing, however, were inconclusive. The ideal situation in which latex would coagulate in a narrow zone two to three feet below the surface by reacting with acidic or metallic constituents of the soil was not attained. Rather, the latex was deposited progressively as it passed through the soil (most of it remained in the top foot), the rate of deposition being dependent on soil structure and composition as well as on properties of the latex such as particle size and emulsion stability. Latex stability appears to be a more critical property than latex particle size in controlling penetration. Addition of excess anionic or nonionic surfactants to latex improved its penetration into the soil. A styrene-butadiene (SBR) rubber latex of 2400 Å average particle size with high mechanical stability gave the best balance of penetrating ability and sealing capacity in laboratory tests and this was confirmed in tests on a 5 x 5 foot test plot at Lanse, Pennsylvania. This latex was subsequently applied to three one-quarter-acre plots at Lanse by sprinkler irrigation, and compared to adjacent areas that were sprinkled with water only. Soil moisture measurements did not enable us to judge the effectiveness of the seal because differences between sampling positions were greater than differences between treated and untreated sections, but permeability tests showed that water flow was much slower (90-99% reduction) within the top ten inches of soil in the latex- treated sections. This sealing effectiveness was reduced after wintering. There was no deleterious effect on the vegetation as a result of sprinkling the areas with latex. A laboratory study conducted in a 5 x 5 x 5 foot box containing uniform reconstructed soil from a New Jersey source suggests that latex penetration into the soil in the field occurs mainly through natural macro openings and not through the capillaries of the soil structure. Dilute solutions of ammonium hydroxide or sodium carbonate (with no latex present) were found to seal effectively in laboratory soil columns as well as in field applications. However, since these chemicals are water soluble, the seal is temporary. Raw material costs of latex at the application rates used in the field testing are in the order of $1000 per acre. Equipment and operating

Jan 1, 1972

By F. N. Kissell, C. D. Litton

This study ranks the factors impacting survival during a coal mine fire. It bas already been established that reducing time delays is the most important factor in saving lives. Consequently every event during afire is measured in terms d its duration, and the effectiveness d any action taken to improve survival is measured in terms d the time it saves. By ranking actions according to time saved these authors found that a comhination d actions was most effective. This combination was: • installing lifelines. • moderately decreasing air leakage and • decreasing the fire growth rate. Changing ventilation leakage alone was much less effective, as was altering the CO (carbon monoxide), sensor alarm threshold. These results confirm an earlier fault-tree study on escape from mine fires. The fault-tree study bad shown that, with the exception d delays, single factor changes have minimal impact. Significant reductions in fire fatalities only take place with multiple factor changes.

By C. M. McCulloch

As part of the Bureau of Mines methane control program, the Pittsburgh coalbed was studied in Washington and Green Counties, Pa., and in Marion and Monongalia Counties, W. Va., where this coalbed is now being mined at its greatest depth. The coalbed thickness appeared to be structurally controlled; the bed was generally thinner near the axes of anticlines and thicker near the axes of synclines. The overburden isopach shows a similar relationship. Most of the clay veins in coal occur in the synclinal troughs, generally under sandstone roof. Cleat orientations measured in 18 underground mines showed that face cleats are perpendicular to the axial trends of the folds, and the butt cleats are parallel to the axial trends, indicating structural control of the cleat. Measurement and analysis of surface joint orientations provide a method for predicting the cleat orientations of the coalbed, but linears measured from infrared photographs and photoindex sheets helped only to determine regional trends. The results of these investigations provide a geologic framework for rational planning for underground mine development to use the best available technology to cope with methane emissions, coalbed discontinuities, and related ground support problems.

Jan 1, 1975

By J. M. Oestreich

Supercritical water (sew) Is being tested for commercial use 1n several organic extraction systems but little work has been done on the extraction of metals from minerals. This lack of information prompted Bureau of Hines (BOM) research into the sew treatment of minerals. As a result, this research project is intended to serve mainly as a starting point for further experimentation. A simple flow-through reactor was built out of high pressure tubing and used to treat minerals with SCU at 400? C and 3500 to 7000 psi. The research produced four main conclusions: (1) carbonates of copper, iron, and lead convert to oxides; (2) most iron minerals showed alteration to oxides with some iron dissolution; (3) valuable trace elements including nickel, chromium, and others leached to some extent from sea minerals along with some calcium, iron, silicon, and sulfur; and (4) treatment of sulfides extracted elemental sulfur and resulted in several alteration reactions, though with the exception of cinnabar and the iron bearing minerals, the metals in sulfides were mainly insoluble. Surface alterations on many of the minerals show significant changes have occurred in the minerals even when only minor extractions were detected. These surface effects may be very important when used in conjunction with flotation processes since the sew treatment may selectively enhance or suppress a mineral's floatability.

Jan 1, 1989

By D. G. Kesterke

Research was conducted to determine the feasibility of extracting elemental oxygen from silicate-bearing melts by high-temperature electrolysis. The method was based on a modification of existing processes for electrowinning metals from their oxides dissolved in molten halide systems. Electrolyses were performed at temperatures ranging from 1,050° to 1,250° C in boron nitride cells that incorporated a silicon carbide cathode and an iridium anode. The electrolytes contained volcanic scoria as the oxygen source, plus mixtures of BaF2 and LiF as fluxing agents. Cell gases containing almost 14 volume-percent oxygen were obtained. The average anode current efficiency for several experiments of extended duration was calculated to be 55 percent. Cell design and operating conditions are described, and some of the problems associated with the process are discussed.

Jan 1, 1971

By Joan T. May

Anhydrous methods were tested for the extraction of beryllium from low-grade source materials. The purpose of the investigations was to find new extraction processes that are applicable to domestic ores. Beryl, helvite, and phenacite materials containing from 0.1 to 2.8 percent BeO were used as starting materials for direct halogenation tests and pretreatment followed by halogenation. The results of the investigations showed that direct fluorination and carbide-chlorination are two practicable methods that can be applied to low-grade concentrates. Treatment of concentrate-carbon mixtures with anhydrous hydrogen fluoride extracted 99 percent of the beryllium in the concentrate; the soluble fluoride product, converted to an oxide, contained 70 percent BeO. Chlorination of beryllium-silicon carbide, prepared from low-grade concentrates, extracted beryllium into the volatile chloride product.

Jan 1, 1962

By Marvin L. Whisman

A radiotracer technique developed by the Bureau of Mines extends to the parts-per-billion range the sensitivity for determining contributors of deposits formed in stored and thermally stressed jet fuels. The method depends upon measuring radioactivity associated with thermally induced deposits from fuels containing one labeled compound. The technique was applied to 88 test blends, representing 12 fuels and nine carbon-l4 labeled fuel constituents or fuel additives, or both. Data from results of these tests are included in this report. With this radiotracer technique, the contribution of fuel components and additives to thermally induced deposits in a variety of fuel environments was estimated before and after storage.

Jan 1, 1969

Reduce or prevent acid mine drainage from coal refuse piles and surface mines by inhibiting the growth of acid-causing bacteria. Approach A dilute surfactant or deter? gent solution is applied directly to coal refuse piles or overburden using a hydro-seeder or road watering truck. The surfactant treatment can be used either as a preventive measure to avoid a potential acid drainage problem or to reduce water treatment costs by controlling acid drainage at its source. How It Works Acid drainage is prevented or reduced by inhibiting the growth of Thiobacillus ferrooxidans, a type of bacteria which obtains most of the energy it needs to survive by oxidizing ferrous iron in water. The oxidized iron in turn attacks pyrite, which forms an acid and additional ferrous iron for the bacteria to oxidize. T. ferrooxidans is protected by an outer membrane which enables it to survive in its acid environment. Anionic surfactants, or surfactants containing negatively charged ions, can be used to destroy this membrane, thus killing the bacteria and slowing down the oxidation of acid-forming pyrite. Of the anionic surfactants tested to date, sodium lauryl sulfate (SLS) appears to be the most effective as a bactericide. Alpha olefin sulfonate and alkyl benzene sulfonate are acceptable alternatives. These surfactants are major components of common household products, such as laundry detergent, shampoo and toothpaste. They are, therefore, readily available, inexpensive, biodegradable and present no environmental problems at low concentrations.

Jan 1, 1983

By Kenneth J. Miner

Pittsburgh bed and Lower Freeport bed coals were tested in the U.S. Bureau of Mines two-stage froth flotation pilot plant, which utilizes a new flotation process to remove pyritic sulfur. The process consists of a first-stage coal flotation step to remove coarse, free pyrite and other refuse in the tailings. The clean coal froth concentrate is then repulped and treated with a coal depressant, a pyrite collector, and a frother to selectively float the remaining pyrite in a second stage. Results in the pilot plant were excellent, comparing well with those obtained in laboratory batch tests. That is, about 70 percent of the pyrite present in the Pittsburgh bed coal and about 90 percent of the pyrite present in the Lower Freeport bed coal were removed with excellent final clean coal recoveries.

Jan 1, 1973

By J. W. Thompson

"The ordinance of March 27, 1919, contains provisions relative to the exploration for, Ind the exploitations of bauxite in the Colony of Surinam in Dutch Guiana.Permission to explore is limited to: Netherlanders; inhabitants of the Netherlands; inhabitants of Surinam; companies established in Netherlands, and companies established in Surinam.Holders of concessions for the exploitation of bauxite are limited to companies established in the Netherlands, or in Surinam, and these must reside in the Colony or must be represented the constantly.A permission or concession lapses: (a) when the holder ceases to have the required qualifications; (b) on the death of the holder where the assigns fail within one year to prove the required qualifications.Any dispute concerning the required qualifications must be decided by the Judge in the manner to be regulated by colonial ordinance.The Governor may, after consultation with the Privy-Council reserve tracts of land for the exploration and exploitation of Bauxite, either for the Government directly, or for concession under special provisions. These provisions shall be fixed by virtue of the colonial ordinances.Application for permission to explore shall be made in accordance with existing laws. Simultaneous applications, those made on the same day, must be decided by drawing lots; but an application for the concession for exploitation has preference ovor that for permission for exploration. On notice of objection to the drawing of lots, the Governor may in his discretion, declare the drawing null and void and order a re-drawing."

May 1, 1920

By Arnulf P. Hagen

This project was designed to explore the suitability of using fluorinated inorganic materials as solvents for the in situ mining of thin seamed, heavily overburdened coal; to build a data base for the selection of an inorganic solvent for use for coal cleaning; to determine if fluorinated solvents will reduce the organic and inorganic sulfur contents of the coal, as well as to lower the ash content. The coal samples have been combined with pure solvent, as well as with aqueous solutions at atmospheric pressure and at increased pressure. The increased pressure experiments are important since they duplicate the conditions anticipated for an in situ cleaning and mining operation. Trifluoroacetic, difluorphosphoric (phosphorodifluoroidic), and trifluoromethanesulfonic acids have been found to be effective for the cleaning of high sulfur, high ash coal at 300°C and at atmospheric pressure. At pressures up to 20,000 psi the effectiveness of these reagents is not decreased.

Jan 1, 1983

By G. Dale Cor, Will H. Coghill, M. F. Williams, I. L. Feld

"INTRODUCTION During the past several years the Southern Experiment Station of the Bureau of Mines, with the cooperation of the University of Alabama, has given attention to hydraulic classification. One of the things this work has revealed is a variability not generally recognized in the conditions of teeter at different depths. This report depicts the passage of material through a teeter column and its emergence as a classified product.The work was made possible through the development of a classifier for several hundred pounds per hour permitting a small quantity of coarse spigot material to be discharged without the usual interruptions caused by stop-pages. Previous designs of small classifiers have been unsatisfactory because the,orifice used to control the quantity of spigot product as subjectto stoppages, particularly when attempting to discharge a small quantity of although the classifier used in this work has been described in detail in a previous publication 6/ its principal features will be discussed briefly herein. The main subject matter of the paper is based upon the three figures that illustrate in panorama the conditions that exist in a classifier during the continuous classification of bituminous coal, anthracite coal, and an iron ore trailing."

Jan 1, 1946