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By J. B. Gayle

A 1/2-ton experimental coke oven was installed ac the Bureau of Mines Southern Experiment Station, Tuscaloosa, Ala., in 1948. Designated as the Tuscaloosa oven, this unit features a 17-inch carbonizing chamber, globar heating elements, and silica-brick walls designed to simulate as closely as possible the carbonizing conditions for commercial slot-type ovens. Because of the small force exerted on the oven walls in most tests conducted to date (probably owing to the practice of charging coals and blends at a moisture content approximating that normal to commercial plants operating in this district), little information has been obtained about expansion properties. Two sole-heated ovens have therefore been constructed and used as supplementary equipment for determining the expansion properties of coals tested in the Tuscaloosa oven. The reasons for constructing the Tuscaloosa oven, the details of design, the operating, characteristics of the oven and the reproducibility of results have been discussed in previous publications. 3 4 5/ The present report deals with the effects of substituting various high- and low-volatile coals for components of a selected base blend carbonized under conditions similar to those normally used for producing foundry coke. Results of tests of 11 coals and 14 blends indicate that several blends tested rave cokes having physical properties very similar to those produced from the reference blend.

Jan 1, 1957

By R. L. Grayson, W. E. Wallace, T. Simonyi, J. C. Harrison

"Application of an SEM-based methodology suggests a reason for past contradictory results on the relationship between quartz and coal workers' pneumoconiosis (CWP). Results indicate that coal seams with the same bulk analysis of quartz may have different amounts of surface-availablequartz. Our research shows that the amounts of pure and surface-available quartz in a respirable dust vary directly with the rank of a coal seam, except in the case where rock materials are mined. The estimated amount of surface-available quartz therefore provides a measure of the quartz-related fibrogenic potential of a respirable dust.INTRODUCTIONFrom our previous work (Grayson, 1991), we have shown that the amount of pure quartz in a respirable coal mine dust sample appears to vary directly with the rank of the seam (using fixed carbon as the basis for comparison), except when a substantial rock parting, roof or floor are mined. Our other work (Wallace et al., 1989) showed that high-silica particles in a clay mine may generally be coated with clay, rendering the quartz core non-available for surface reaction in the lung. The combination of these findings led us to hypothesize that the coating phenomenon may indeed be present in coal mines as well, and that a rank relationship may be present regarding this phenomenon. Thus higher rank coal seams may have more surface-available quartz as well as more pure quartz particles in their respirable dusts. The scientific protocol for testing this hypothesis and the results obtained to date are discussed in this paper. Thus far, there is no reason to doubt that the relationship holds."

Mar 1, 1992

By James A. Morgan

FIELD MEASUREMENTS OF NOISE WERE MADE ON THE PERIPHERY OF ENCLOSURES DESIGNED, MANUFACTURED AND INSTALLED BY INDUSTRIAL ACOUSTICS COMPANY, INC. ON THE SECONDARY TACONITE CRUSHER AT THE JACKSON COUNTY IRON COMPANY PLANT IN BLACK RIVER FALLS, WISCONSIN. NOISE REDUCTION ACHIEVED BY THE ENCLOSURES WAS SUFPICIENT TO PERMIT REDUCTION OF CRUSHER ROOM NOISE TO 90 DBA, PROVIDED THAT OTHER SOURCES ARE APPROPRIATELY TREATED AND ACOUSTICAL ABSORPTION IS PROVIDED IN THE CRUSHER ROOM. SECONDARY CRUSHER NOISE WAS REDUCED 10 TO 15 DBA BY THE ENCLOSURES.

Jan 1, 1980

By Arcy R., D&apos George

The Bureau of Mines has developed, on a laboratory scale, a superior Eluex-type circuit for eluting and recovering uranium from ion exchange resins. The improved circuit differs from conventional Eluex practice in that a stage of uranium solvent extraction is coupled with each stage of resin elution rather than the elution and solvent extraction operations being conducted separately. The new system reduces the number of stages, retention time, and resin inventory in the elution circuit to one-fourth or one-fifth that in existing circuits. The system is applicable to both resin-in-pulp and moving-bed-type ion exchange uranium recovery circuits.

Jan 1, 1969

By B. J. Dalton

The Helium Research Center, Helium Activity, Bureau of Mines, is presently engaged in a critical examination of all of the PVT data on helium that appear in the literature. The long-range objective is the development of a single equation of state for helium that will allow all of the thermodynamic properties to be calculated and will reproduce all of the data within the accuracy with which the data are known. A preliminary objective is to obtain the best values of the second virial coefficients and to develop an equation that will reproduce the best values as a function of temperature. The method of treatment consists in expressing the PV product of a gas, for a given isotherm, in terms of a power series in either the pressure or the density and evaluating the constants by least squares solution. Associated with these functions whose coefficients have been evaluated by least squares, the following errors, or deviations, are of interest; the standard error of a single measurement; the standard error in each coefficient; and the standard error of the resulting function.

Jan 1, 1964

By B. J. Dalton

The Helium Research Center, Helium Activity, Bureau of Mines, is presently engaged in a critical examination of all of the PVT data on helium that appear in the literature. The long-range objective is the development of a single equation of state for helium that will allow all of the thermodynamic properties to be calculated and will reproduce all of the data within the accuracy with which the data arc known. A preliminary objective is to obtain the best val¬ues of the second virial coefficients and to develop an equation that will reproduce the best values as a function of temperature. The method of treatment consists in expressing the PV product of a gas, for a given isotherm, in terms of a power series in either the pressure or the density and evaluating the constants by least squares solution. Associated with these functions whose coefficients have been evaluated by least squares, the following errors, or deviations, are of interest; the standard error of a single measurement; the standard error in each coefficient; and the standard error of the resulting function.

Jan 1, 1964

By J. Dean Warner

In 1984, as part of a project to evaluate Alaskan occurrences of certain critical and strategic minerals, the Bureau of Mines investigated a columbium-bearing regolith on upper Idaho Gulch, near Tofty, AK. The regolith is derived from weathering of a dolomitic marble and consists mostly of iron oxide minerals with accessory apatite, zircon, xenotime, rutile, monazite, and the columbium minerals aeschynite, columbite, and ilmenorutile. Two regolith lenses contain 340,000 lb of columbium resources at an average grade of 0.07 pct. Calculated composite concentrates from two regolith samples (approximately 200 lb each) contained 53 and 57 pct of the columbium at grades of 0.97 and 0.86 pct, respectively. In each case the grade could be improved to 1.1 pct Cb with a sacrifice of 9-pct recovery. The regolith's mineralogy, trace-element geochemistry, and similarity to descriptions of other columbium-enriched regoliths suggest that the underlying marble may be a carbonatite. The lack of associated alkalic igneous rocks and the stratiform nature of the regolith, however, may be interpreted as evidence for sedimentary origin of the marble. The marble and regolith are a lode source for some of the minerals in the Idaho Gulch placer deposit.

Jan 1, 1986

By I. AITKENS

The precious stones rubies and sapphires are transparent varieties of the mineral corundum . Essentially they are aluminum oxide , but the aluminum is often replaced. by small amounts of chromium , titanium , or iron . The chromium is said to give a red color , titanium a blue , and iron a yellow . True rubies range from rose to a somewhat purplish red and are sometimes termed " oriental rubies " to distinguish them from spinel rubies , stones of inferior hardness , density , and value . " Oriental rubies " are very rare , and the so-called " pigeon's blood" variety is the most valuable . Sapphires normally range in color from palest blue to deepest indigo , but actually all precious varieties of corundum of any other color than red are called sapphires . The most esteemed tint is like that of the blue cornflower . Colorless corundum of gem quality is called white sapphire ; the yellow variety is described either as yellow or as golden sapphire ; and the pale pink is classed as pink sapphire . The word " oriental " is also used as a prefix in naming varieties of corumdum of less popular colors . For instance , oriental emerald is used for green corundum, oriental topaz for yellow , and oriental amethyst for violet to purple varieties . The chief physical characteristics of rubies and sapphires are hardness , adamantine luster , and moderately high specific gravity ( 3.9 to 4.1) . Next to the diamond, corundum is the hardest of all minerals ; in fact , the sapphire is number 9 on Moh's scale , ranking between the topaz and the diamond. Rubies crystallize in 6-sided prisms terminated by flat faces and other varieties of corundum with twelve inclined faces , six above and six below , meeting in a girdle . Corundum is doubly refractive , with a direction of single refraction running parallel to the edge of the prism . The refractive indexes are very constant, the ordinary index ranging from 1.766 to 1.774 and the extraordinary index from 1.757 to 1.765. The double refraction always remains the same.

Aug 1, 1931

By George H. Holmes

This paper , which describes mining methods and milling and manufacturing operations at the gypsum property of the Blue Diamond Corp. , is one of a series on mining methods and practices being prepared by the Mining Division of the Bureau of Mines . The property comprises about 4,000 acres and is in secs . 30 , 31 , 32 , and 33 , T. 21 S. , R. 59 E. , and secs . 5 , 6, 7 , 8 , and 9 , T. 22 S. , R. 59 E. , M. D. B. and M. , Clark County , Nev . , approximately 23 miles by paved highway southwest of Las Vegas , Nev . ( fig . 1 ) . This circular summarizes the history of company operations , describes physical features , labor and living conditions , and the geology . The method of exploration is outlined , and the section on mining methods contains descriptions of open - pit and underground systems , including loading and transportation methods . The crushing plant and tramway are described , as well as plaster-mill and board -plant practices . The boiler plant and organization are described , and wage scales are contained in the concluding section of the circular .

Mar 1, 1950

By G. W. Grove, H. R. Burdelsky, F. E. Griffith

"INTRODUCTION The work of using a system of air locks in unsealing a mine in Ohio following a fire probably was one of the outstanding jobs of its kind in a medium-thick coal bed.The fire in this mine, thought to have been of electrical origin, was discovered at about 1:30 a.m. on December 11, 1941. Forty-four men were working in the affected section at the time; 5 escaped unassisted, and 37, who had barricaded themselves, were rescued. The bodies of two men, who had succumbed after breathing fumes given off by the fire, were brought part way out of the mine before it became necessary to seal the mine.Direct attempts to extinguish the fire with water were abandoned when hazardous amounts of 'carbon monoxide, methane, and other inflammable gases were detected in return air passing through the main haulageway and escape-way of the mine.The mine was completely sealed on the surface at about 8 p.m. on December 12, 1941, with the two bodies remaining in the mine. Sixteen days after the mine had been sealed, the two bodies were recovered. This was accomplished by air-locking through a partitioned-off stairs compartment of a ventilation shaft. This work was done under adverse barometric and atmospheric conditions.A method for collecting representative air samples from the immediate fire area was used successfully by utilizing a vacuum pump on about 10,000 feet of existing water line that had been broken near the fire area.The immediate fire region was sealed, and confined to a relatively small area; the remainder of the mine was recovered, and operations were resumed February 9, 1942, or 59, days from the time of sealing the mine on the surface. This recovery was made by air-locking the main entries inby from the shaft and No. 2 right-face entries.The distance between air locks averaged about 500 feet, and as each new set of seal stoppings and air locks was completed, the old or outby seals were taken out and the area between was ventilated. In ventilating this area, it was often necessary to use line curtains to direct the air into dead-end places."

Oct 1, 1947

By Ronald A. Vary

This paper is one of a series prepared by the United States Bureau of Mines dealing with milling methods and costs. In view of the current revival of interest in gold mining, information dealing with practices and costs in the development of gold properties is apropos. Milling practice at a small gold property in the prospect stage is described where, with a small outlay for plant and equipment, development has been carried on for about 20 months on the proceeds of the mill operation with little additional expenditure. The paper shows about what may be expected as to costs at a small property operated under northern climatic conditions and with rigid economy throughout the plant.

Jan 1, 1931

By D. E. Shanks

As part of its program to lessen dependence on foreign bauxite as the Nation's primary source of cell-grade alumina, the Bureau of Mines is investigating sulfuric acid (H2S04) leaching procedures for the recovery of alumina from domestic aluminous materials. The successful application of a H2S04 leaching process depends on the recovery of the aluminum values in an easily washed and filtered form, containing a minimum of water to be driven off in the subsequent calcination step. This goal was met by the high-temperature hydrolysis of simulated aluminum sulfate [A12(S04)3] leach liquor. Crystalline, insoluble aluminum hydroxy sulfate [A1(OH)S04], which had a water-to-alumina mole ratio of 1:1, was produced. Eighty-six percent of a solution containing 127 g of A12(S04)3 per liter and 76 pct of a solution containing 336 g of A12(S04)3 per liter were hydrolyzed to insoluble aluminum hydroxy sulfate by autoclaving for 1 hr at 320° C and rapidly quenching to room temperature. Higher operating temperatures were precluded by corrosion of the autoclave. The yield of aluminum in the hydrolysis product increased with increasing hydrolysis temperature and decreasing A12(S04)3 concentration.

Jan 1, 1981

By A. W. Fahrenwald

[In studying coarse sand flotation3/ the question of the relation between fineness of grinding and mill capacity logically arose. Everyone familiar with present fine-grinding practice knows that the capacity of a ball mill or similar mill is determined, among other things, by the fineness of the finished product. Undoubtedly a great many mining companies must have a good deal of data directly bearing on this point, yet no quantitative relationship between ball-will capacity and fineness of finished product has been established. The experimental study presented here is an effort to establish this relationship in a semiquantitative way. The subject is a tremendously large one and grows in complexity as the study becomes more searching. In this work the power consumed by the mill in the various experiments was not determined end neither vas the steel consumption measured; mill capacity only was considered.]

Jan 1, 1930

By R. Agarwal

The in-situ stress field was determined, using the overcoring technique, at two underground sites at the Pea Ridge Mine, Sullivan, Missouri. At one of the sites in magnetite, the three dimensional stress field showed the largest principal stress to be compressive (-4564 psi), nearly horizontal and closely parallel to the strike of the orebody. The smallest principal stress was also compressive (-2047 psi) and nearly vertical. Considerable difficulty was experienced in drilling porphyry rock at the second test site in the host rock. Only one hole was drilled at this site. The secondary principal stresses obtained in the porphyry are -9464 and -4945 psi, respectively. The-test site in magnetite is located at a depth of 2505 feet whereas the site in porphyry rock is at 2475 feet. The vertical stresses: due to overburden loading at these sites are -3590 and -2782 psi, respectively. Field determined values of the vertical stress are -2207 and -5098 psi, respectively. The variance; between the two sets of values is most likely attributable to the orebody formation and the differences in the modulii of the host rock and the orebody.

Jan 1, 1977

By A. L. Engel

This report is a compilation of preliminary and, in some cases, more extensive concentration experiments by the Federal Bureau of Mines on low-and medium-grade fluorspar ores from three localities in Nevada and one in California. The work was done on samples obtained from Shoshone mine, Nye County, Valery mine, Pershing County, and the Broken Hills mine, Mineral County, all in Nevada, and Dirty Weather mine, Inyo County, Calif. These investigations were made to aid in the development of domestic fluorspar resources, in line with the Bureau's long-established program of conservation of mineral resources. The treatment methods employed in the experimental work described included simulated or "heavy-liquid" gravity concentration of coarse minerals and comparatively fine-grained minerals, and flotation concentration of finely-ground minerals. These methods were attempted in order to beneficiate the ores and produce concentrates which could be marketed readily, with as high a recovery rate as possible, while using simple treatment methods suitable for small-scale operation.

Jan 1, 1961

By M. R. Yenchek

The U.S. Bureau of Mines has determined a method for calculating coal mine portable power cable thermal life for a specified temperature loading. This work was the culmination of a multifaceted research project involving (1) accelerated life tests of insulation and jacket materials and (2) steady-state and cyclical loading of cables. Composite Arrhenius curves were derived for common insulation and jacket materials to identify the key cable quality that precipitates thermal failure. Plots of temperature rise versus current for popular cable sizes were then referenced to develop a correspondence between cable life, based upon thermal degradation and current loading. Predictions of cable thermal life were made through integration over variable load cycles and, consequently variable operating temperatures. This procedure may have utility for both the U.S. Mine Safety and Health Administration and mining machine designers in determining the appropriate cable size for new equipment.

Jan 1, 1991

By D. H. Baker

THIS REPORT presents the technique and equipment used in determining the hardness of titanium sponge. Detailed descriptions are given of the methods used in preparing test samples for chemical analysis and hardness testing, the method of melting and surfacing test ingots, and the technique of reading Brinell-hardness impressions. The arc-melting furnace described, for which engineering drawings are included, will produce from 70 to 90 double-melted buttons each 8 hours of operation. Experimental data are also presented depicting the effect on hardness of the methods of surfacing specimens, temperature of test specimens, and the effect of time at test load. These data show that surfacing of the specimen involves no critical machining operations but that the test surface must be paralleled by a relatively flat surface for contact with the anvil of the Brinell tester. The heating of a specimen to 150° C. during surfacing does not materially affect the results if the ingot is cooled to room temperature before the hardness impressions are made. The optimum time at load appears to be approximately 30 seconds, but load times of as much as 1/ ½ minutes will not cause major errors.

Jan 1, 1959

By N. S. Dalal, X. Shi, V. Vallyathan

"Correlated spectroscopic and cytotoxicity measurements were made on newly crushed silica to find whether the fracture-induced, silicon related (Si-0· or Si· type) free radicals play a direct role in the mechanism of hemolysis by silica particles. The free radical content of the silica particles was controlled through the radical decay, thermal annealing, and boiling processes, and was followed with electron spin resonance spectroscopy. Portions of the same sample were evaluated for their hemolytic potential, employing sheep erthyrocyte and optical absorption techniques. The results indicate little, if any, correlation between the amount of the silicon-based radicals and the hemolytic potential of the fresh dusts, but these or related radical sites might be contributors to silica cytoxicity and fibrogenicity via peroxidative pathways .INTRODUCTIONIn an earlier convnunication (1.) from our laboratory it was reported that mechanical crushing of coal and quartz under normal air atmosphere generates free rad;cals on the particle surfaces, and that these radicals decay with time, hence pointing to a higher toxicity of fresh dusts in relationship to pneumoconiosis and silicosis. More recently Fubin; et al.(2) have also reported the detection by electron spin resonance (ESR) of the formation of SiO· and Si·-type of radicals from quartz particles crushed under atmospheric conditions. In agreement with earlier ESR studies on single crystals of quartz crushed under high vacuum (10-10 torr) (3) and subsequent exposure to air (3), and to other gases (4), these radicals were identified (2) as being formed by the hemolytic cleavage of the Si-0-Si bonds and the reactions of the Si· and SiO· ,radical with atmosphere. Fubin; et al. (2) also suggested that these radicals might be involved in the mechanism of the fibrotic action by silica, either by transforming the particle surface into a selective oxidating agent or as an initiator of a sequence of reactions leading to fibrosis. Earlier Gabor and Anea (5) had reported that lipid peroxidation caused by free radicals on the silica surface might be involved in the red blood cell membrane damage. Thus far, however, no parallel cytotoxicity, fibrogenicity, and free radical studies on a given Quartz dust sample have been reported, except for some earlier work from our laboratory (1,6,7). We now present more recent results obtained from parallel cytotoxicity, fibrogenicity, and free radical measurements on a freshly made quartz dust. The dust’s free radical content was measured using ESR spectroscopy while its cytotoxicity poteni1al was estimated via hemolysis. Hemolysis was employed as the tox1c1ty test because it 1s a widely used method for estimating the potential of a dust for disrupting the cell membrane (8). The f1brotic potential was followed.by measuring the dust-induced lipid perox1dat1on. us1ng linole1c ac1d as a model lipid. As discussed below, the results obtained suggest new clues.to the mechanism of the Quartz-related cytotoxicity and fibrogenicity."

Jan 1, 1988

By Roy L. Wilfong, LeRoy R. Furlong, Louis P. Domingues

The bulk and apparent densities , particle size , and surface area of ceria powders derived from the ammonium sulfate , carbonate , nitrate , oxalate , and sulfate salts and heated at 950 ° to 1,500 ° C for 1 to 24 hours were studied . The bulk and apparent densities and particle size generally increased , and surface area decreased with increase in temperature and time of heating ; surface area was more sensitive to changes in temperature and time than the other properties studied . These properties of the ceria powders had a marked dependence on temperature and a lesser dependence on duration of heating at a given temperature ; and the source of oxide and thermal treatment cannot be considered optional in the preparation of refractory powders by thermal decomposition . The ammonium sulfate and sulfate salts heated at 950 ° and 1,200 ° C produced oxide powders with the lowest bulk density , the smallest particle size , and the highest surface area . The highest apparent densities were achieved for oxides resulting from the carbonate and the sulfate but the carbonate - derived material was considerably coarser . The surface areas of ceria powders derived from cerium salts decrease in the order of sulfate , ammonium sulfate , nitrate , oxalate , and carbonate . The observation of these physical properties are useful in predicting the sintering behavior of various oxide powders .

Jan 1, 1964

By J. D. Marchant

The Bureau of Mines studied solid-state electromigration to determine the value of the technique as a method of purifying cerium metal. Cerium metal in bars 6 inches long and 1/2 inch in diameter was refined at 600° C by solid-state electrolysis to remove iron, copper, and manganese. Iron and manganese were electrotransported to the anode and copper was electrotransported to the cathode. The concentration of iron at the anode of a cerium bar was 800 times greater than the concentration at the cathode. The concentration of manganese at the anode was twice the value at the cathode. The concentration of copper was 170 times greater at the cathode than at the anode. A radiotracer technique was used to follow the iron migration in the cerium metal. Molybdenum, silicon, and aluminum impurities were not electrotransported.

Jan 1, 1967