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By W. I. Nissen

This Bureau of Mines report presents the design for a commercial-sized flue gas desulfurization (FGD) demonstration plant that uses the citrate process. The goal of the Bureau's citrate process is to minimize the undesirable environmental impacts of industrial plants emitting SO2-bearing gas. The FGD plant is located at the George F. Weaton powerplant, Monaca, Pa. Construction was completed in April 1979 and will be followed by preliminary testing and a 1-year testing and evaluation program. Design capacity of the FGD plant is 156,000 scfm of 0.2-volume-percent-SO2 flue gas yielding about 16 tons of sulfur per day. The plant is intended to (1) clean fly ash, SO2, and Cl- from the gas while cooling the gas in a venturi scrubber, (2) absorb SO2 from the gas using 1,200 gpm of a countercurrent-flowing citric acid-sodium citrate-sodium thiosulfate solution, (3) react the absorbed SO2 in two 13,000-gal stirred closed vessels with added H2S, thus precipitating elemental sulfur and regenerating the citrate solution for recycle, and (4) recover the sulfur from the slurry by air flotation, followed by melting in a heat exchanger and separation from the occluded citrate solution in a sulfur decanter at 35 psi and 135° C.

Jan 1, 1979

By Michael S. Miller

In 1987 and 1988, at the request of the U.S. Bureau of Land Management, the U.S. Bureau of Mines studied the 3,100-acre Borah Peak Wilderness Study Area (10-047-004) and a 708-acre parcel adjacent to the north in order to evaluate their identified mineral resources. The study area is located in Custer County, ID, about 18 mi northwest from MacKay. The study area lies along the western foothills of the Lost River Range and is underlain by quartzite, sandstone, shale, argillite, dolostone, and limestone. The Lost River fault, a major active fault, lies along the length of the study area. Large alluvial fans spread out from valleys originating east of the study area.

Jan 1, 1989

By Alla D. Mah

The heat of formation of scandium sesquioxide (Sc203) has not been measured previously, and existing values for gallium sesquioxide (Ga203) are subject to large uncertainties. As a consequence, thermodynamic calculations involving these oxides hare lacked scientific exactness. This paper reports newly determined values of the heats of formation of gallium and scandium sesquioxides at 298.15° K., by combustion calorimetry. The corresponding free energies of formation are derived from heat and entropy data.

Jan 1, 1962

By W. N. Patterson

The three major objectives of this contract were (1) to survey underground diesel-powered mining machinery to determine noise exposure problems, (2) to recommend noise control techniques, and (3) to develop a technique for predicting underground sound levels from surface sound power measurements. The objectives were achieved. The contractor developed information on the severity of the noise problem caused by diesel engines underground and pinpointed the equipment causing the problems. He recommended a number of corrective techniques that can provide relief until long-term solutions are found. A procedure for predicting underground noise levels from above-ground measurements of the machine noise was found valid for several cases tested.

Jan 1, 1975

By A. B. Campbell

The mines in the eastern part of the now active region of the Tri-State zinc district of Missouri, Kansas, and Oklahoma have unusually acid water, which during periods of moderate or no rainfall As used in the mills to replace losses from evaporation, seepage, and tailings disposal. Its use has caused difficulties by corrosion of equipment and by interference with flotation. The growing importance of flotation- Which requires good water, and the increasing troubles caused by the corrosion of the milling equipment have prompted the Mississippi Valley Experiment Station of the United States Bureau of Mines, in cooperation with the Missouri School of Mines and Metallurgy, Rolla, Mo., to investigate the action of the waters on flotation and to undertake to develop means of obviating their harmful effects.

Jan 1, 1932

By Rudolf E. Greuer

This study concerns itself with two topics of the mine ventilation - mine fire interface which, when the work for this study began, did not seem to receive sufficient attention. Section 1: Comments on Spontaneous Combustion of Coal in Mines It is attempted to describe heat generation, heat and oxygen transport, in such a way that existing experimental data for U.S. coals can be used to assess conditions inducive to spontaneous heatings quantitatively. Investigated are, in particular, critical air velocities, minimum sizes of coal accumulations, moisture contents and the influence of mining factors. An extensive, practice oriented literature survey is included. Section 2: The Early Detection of Mine Fires by Assessment. of Mine Gases The suitability of the major constituents of combustion products for an early detection of fires is discussed. The same is done for gas concentration ratios. Since it was felt (at least at the time when this report section was written) that the value of the carbon monoxide/oxygen deficiency ratio was overestimated, the usefulness of monitoring this ratio as compared to monitoring CO concentrations was critically investigated. The state of art concerning instrumentation and organization of fire detection systems is reviewed also.

Jan 1, 2011

Mining and the related extractive and processing industries are chiefly responsible for America's high standard of living. Enormous quantities of sand and gravel, limestone, copper, iron and a myriad of other mineral commodities are required to sustain our growing nation. However, the mineral deposits, both domestic and foreign, are becoming increasingly difficult to find. Adding substantially to the problem, is the fact that the conditions are worldwide. Foreign politics are increasingly affecting mineral commodity availability. Figure 1, taken from Bureau of Mines, "Status of the Mineral industries 1976" illustrates our dependency (in some cases total) on foreign sources for vital mineral commodities. While few nations are capable of exerting an OPEC-like influence on any one mineral commodity, the threat of cartel arrangements and related control strategies is evident. Nationalization of entire industries, once they become self-sufficient, is also exerting a disruptive influence on a large portion of the mineral industries.

Jan 1, 1977

By H. C. Fuller

Rhodonite, a manganese silicate, occurs as an important component of extensive veins in the San Juan district of Colorado. Recent work by the Bureau of Mines has demonstrated that typical ores of the area can be upgraded to about 30-percent manganese content. Because of their siliceous nature, such concentrates require further processing to convert the manganese into more usable forms. The investigation described in this report demonstrates the technical feasibility of producing silicomanganese from a rhodonitic concentrate by electric smelting methods. The rhodonitic concentrate used in the smelting research was prepared by dry high-intensity magnetic separation of ore from the Silver Queen vein. The concentrate contained 29 percent manganese, 2 percent iron, and 41 percent silica. The principal minerals in the concentrate were 35 percent rhodonite, 30 percent rhodochrosite, and 25 percent quartz and chalcedony. Limestone was used as the flux and coal was used as the reductant. These minerals were crushed and screened to minus 1/2-inch plus la-mesh size.

Jan 1, 1962

By G. L. Fitzpatrick

Preliminary results of an experiment in seismic holography indicate that the techniques of acoustical holography may be successfully used with seismic waves to determine the size and general shape of underground objects. This experiment was carried out under field conditions on a moderately large scale compared with the typical laboratory experiments in acoustical holography. The object to be mapped was a 100-foot-diameter, spherical, low-velocity zone of explosively fractured rock in oil shale at an average depth of 80 feet. The seismic wavelength of the Fourier component wave used in making the seismic holograms was 50 feet at a frequency of 140 cps. The hologram sampling aperture was 226 feet square and was sampled by 441 geophones in a 21 by 21 rectangular array. One novel aspect of the experiment was the use of a wide-band polychromatic explosive source of seismic waves rather than a narrow-band quasi-monochromatic vibrator source. A successful laser reconstruction of the object image from a lensless Fourier-transform hologram in the form of a 5/l6-inch-square photographic transparency is illustrated. The size of the underground object measured from the laser reconstruction of the object and the size inferred from a knowledge of the amount of explosives used to fracture the site and the tensile strength of the oil shale are found to agree.

Jan 1, 1972

By Harry Perry

One of the most notable achievements of the iron and steel industry in the United States in this century has been the general increase in productivity of individual blast furnaces and the reduction in coke rate. Most of the improvement in furnace operations has occurred within the past decade. During this time the output of the average furnace increased about one-third, while fuel rates decreased from 15 to 20 percent. For example, in 1949, the iron and steel industry produced 811.2 short tons of pig iron per blast-furnace day with a coke rate of 1,870.4 pounds per ton of pig iron, By 1960, the average production of pig iron per blast-furnace day had risen to 1,182.4 tons, while the coke rate had decreased to 1,497 pounds per ton of pig iron. These figures are averages for the entire industry; many furnaces produced over 2,000 tons per day and one furnace, operating on pellets, reached 2,700 tons of pig iron per day, Coke rates of individual furnaces varied, but some furnaces operated on less than 1,200 pounds per ton of pig iron. The significance of this decrease in coke rate is shown clearly when data on pig-iron production and coke consumption in 1959 are compared with 1948. In 1948, 57.3 million short tons of coke was charged into blast furnaces to produce 60.1 million tons of pig iron; in 1959 only 47.6 million tons of coke was needed to produce 60.2 million tons of pig iron. Thus, in 1959, nearly 10 million tons less coke was required to produce about the same amount of pig iron as was produced in 1948.

Jan 1, 1962

By Thomas O. Meyer

Laboratory test results are presented for the determination of elastic modulus made with the NX borehole jack. Determinations were made in massive pieces of aluminum so as to satisfy conditions of linear elasticity, homogeneity, and isotropy. Results indicate a large discrepancy (approximately 200 percent) betwen material modulus as determined by laboratory block-loading tests and that indicated by the jack under relatively ideal circumstances. Effects due to interface friction, finite block size, incomplete plate-bore contact, and other factors were examined and found not to be significant. Finite element results indicate that assumed loading conditions for the jack differ from those actually occurring, at least in materials of high elastic modulus (approximately 10 million psi), such as quartzite.

Jan 1, 1974

By E. L. Garton

Michigan is becoming one of the important oil-producing States of the country. The amount of crude oil produced within its boundaries has increased from only 4,000 barrels in 19253/ to nearly 16 million barrels in 19935.4/ The Bureau of Mines method of crude-oil analysis and classification-indicates that the oils from the several producing fields are predominantly paraffin-intermediate-base, wax-bearing crudes. In general, they will yield 25 to 35 percent of highly paraffinic gasoline and about the t- me amount of kerosene and gas-oil combined, 7.2 to 15 percent of lubricating oil stock, and 20 percent of residuum with a carbon residue or about 6 to 7 percent. In addition, there appears to be some correlation between certain properties of the crude oils and both the geographical location and geological structure of the oil-producing areas within the State. These general conclusions are based on the analytical data presented in this report, which is one of a series of papers that record the general characteristics of crude oil from the many producing fields of the United States. This report discusses briefly the oil fields of Michigan and the characteristics of the crude oils produced from them. The analyses of 15 samples are given. These samples were obtained from 13 fields in 9 counties in the lower peninsula and represent crude oils produced from the Berea sandstone, Upper Traverse and Traverse limestones, and the

Jan 1, 1937

By James C. Barker

The U. S. Bureau of Mines made a reconnaissance In the western Crazy Mountains for cobalt and associated metals as part of the Alaska-wide critical and strategic metals program. The area, located about 75 miles north of Fairbanks in central Alaska, is underlain by complexly faulted, predominantly clastic sedimentary rocks bordering the Tintina Fault system. Above background metal concentrations were found to occur in altered fault zones, tectonic breccias, soils, and ground water seeps and precipitates that either cut or are derived from the faulted clastic sedimentary rocks. Up to 0.115 pct cobalt and more than 2.0 pct zinc were detected in soil samples. Spring precipitates contained up to 1.3 pct zinc, 0.037 pct tungsten, and other metals. Some localities lacked cobalt but contained anomalous amounts of copper, lead, zinc, silver, and other metals. No outcropping of primary metallic minerals was located because of Colluvium and vegetation cover and extensive deep leaching. Therefore, whether the metal values encountered are due to primary deposits with economic development potential or are the results of concentration by ground water from low-grade sources is unknown. The presence of cobalt, nickel and zinc, and the identification of minor tin and tungsten indicate that further investigation is warranted.

Jan 1, 1983

By N. S. Shan

This report presents the results of a study to determine compaction criteria for coal waste embankments. The purpose of this study is to evaluate the costs and resulting effects on the engineering proper-ties of coal waste materials, utilizing different compaction methods, equipment passes, and lift thickness. Based on the results of the study, a cost efficient compaction method that will attain the desired results will be recommended to the coal mining industry. The report describes a comprehensive literature search into the compaction of coal waste materials, field compaction programs, laboratory investigations, analysis of test data as well as conclusions and recommendations for establishing the compaction criteria. The findings obtained in this investigation are intended to supply much needed information and to justify the guidelines that have been recommended.

Jan 1, 1981

By Howard M. Stainer

Published X-ray mass absorption coefficients were compiled and tabulated. These coefficients are required for various X-ray analytical techniques. Values obtained from 28 authors are listed for 87 elements with both experimental and calculated points included; the wavelengths range from 4.01 to 68 A. Representative graphs are presented for six elements (lithium, nitrogen, iron, silver, holmium, and uranium. A 37-item supplementary bibliography is also included.

Jan 1, 1963

By Howard M. Stainer

Published X-ray mass absorption coefficients were compiled and tabulated. These coefficients are required for various X-ray analytical techniques. Values obtained from 28 authors are listed for 87 elements with both experimental and calculated points included; the wavelengths range from ~0.01 to 68 A. Representative graphs are presented for six elements (lithium, nitrogen, iron, silver, holmium, and uranium. A 37-item supplementary bibliography is also included.

Jan 1, 1963

By Clark F. Grain

These investigations were undertaken as part of the Bureau of Mines program for the development and evaluation of high temperature nonmetallic materials. This report consists of thermal expansion and phase inversion measurements by high-temperature X-ray diffractometry on the principal oxides of beryllium (BeO), calcium (CaO), titanium (TiO2 ), zirconium (ZrO2 ), hafnium (HfO2), and thorium (ThO2); all were high-purity commercially available oxides. Thermal expansion values were calculated from unit cell dimensions measured at selected temperatures. Expansion was determined parallel to each major crystallographic axis for the anisotropic oxides: BeO, TOi2, ZrC2, and HfO2. Combined random and systematic errors in the thermal expansion values are considered to be less than 3 percent of the total expansion at 500° C. and approximately 2 percent at 1,000° C. No hysteresis in the expansion curves was noted between heating and cooling cycles. The Bureau's values were compared with published expansion measurements obtained by X-ray diffraction, dilatometric, interferometric, and telemicroscopic techniques. For anisotropic oxides, average linear expansion values were calculated from the volume expansion.

Jan 1, 1962

By Curtis H. Elder

In studies conducted by the Bureau of Mines, two test areas were hydraulically stimulated and exposed by mining: One in the Pittsburgh coalbed at the Vesta No. 5 mine, Washington County, Pa.; and one in the Illinois No. 6 coalbed at the Inland mine, Jefferson County, Ill. Induced fractures were contained totally within the coalbed with no adverse effect on the stability of associated rock strata. Induced fractures were vertical and were propagated normal to the direction of least residual tectonic stress. Gas production was increased fivefold to twentyfold by hydraulic stimulation.

Jan 1, 1977

By N. A. Eilertsen

Mining operations were in progress at the Shawangunk mine near Summitville, Sullivan County, N. Y. as early as 1843 and again as late as 1918. Difficulty in effecting mechanical separation of sphalerite and galena was the primary reason for abandonment by various operators. The Bureau of Mines investigated this mine by diamond drilling, sampling, and performing beneficiation tests. The investigation included the construction of 1.25 miles of access road and the completion of 6,526 feet of core drilling in 24 holes. In addition, 151 samples were taken in the mine. The investigation proved an extension of ore contiguous to the old mine workings and resulted in the discovery of another ore shoot at depth. The ore occurs as fissure filling in a fault zone and contains concentrations of zinc and lead sulfides with minor dissemination of chalcopyrite in a quartz gangue. Metallurgical tests indicate that the ore can be concentrated by selective flotation.

Jan 1, 1950

By M. B. Balachandra

A three-dimensional finite element analysis was performed of an instrumented section of a double-entry coal mine in order to provide a comparison between field measurements and existing analytic techniques. The BMINES computer code was used to perform the analysis. The sequence of excavation of the entries was considered, as well as the installation of rock bolts and cribbing during the mining cycle. The materials In the region under investigation were idealized into four rock types and coal. The rocks were assumed to be isotropically elastic, perfectly plastic. Coal was represented by an elastically anisotropic (transverse isotropy) and plastically isotropic model. A fracture yield criterion of the Coulomb form was used for all materials. The strength and stiffness of all materials were substantially reduced from available laboratory data to account for in-situ properties. Qualitative trends and stress distributions obtained from the calculation were found to be reasonable. However, computed displacements and closures were greatly exaggerated and an excessive degree of inelastic deformation was indicated in the coal, especially adjacent to the excavated faces. It was established that both these effects were the result of an excessive reduction in the strength and stiffness of the materials. The analysis underscores the need for three-dimensional calculations by identifying a number of important structural response parameters that would be either outside the scope of, or misrepresented by, two-dimensional analyses. The analysis also emphasizes the need for comprehensive and accurate measurement of material properties in order fully to exploit the power of the analytical techniques to generate reliable predictions.

Jan 1, 1976