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By Bruce Macdonald

Operational reservoir management activities such as cyclical steam, water or CO2 injections frequently cause surface micro-deformation. InSAR monitoring from space based sensors of this surface deformation has become a valuable approach to confirm and monitor extraction and injection activities. Sequestration of CO2 into deep saline aquifers is discussed as an important long term solution to slow future climate change. This method requires reliable continuous monitoring to assure that captured CO2 is sequestered in the substrate for ?all time? (typical minimum requirement by law is 20-30 years). We have shown that combining flow and deformation modeling with spaceborne synthetic aperture RADAR interferometry (InSAR) measurement of ground uplift caused by the underground release and spreading of the CO2 can be forged into a powerful tool to monitor sequestration. We used a novel InSAR approach to resolve the surface motion over the In Salah, Algeria CO2 sequestration site. Our approach exploits all information contained in an interferometric stack by exploiting both persistent distributed as well as persistent point scatterers. Displacement time series are obtained with a network inversion approach applied after topographic error and preliminary atmospheric correction of the network (dual-scale technique). After inverting the original network data to common master we then use an advanced spatio-temporal filtering scheme to remove the remaining atmospheric phase components down to scales of 1 km or less. By comparing final displacement series from multiple interleaving InSAR stacks we show that the accuracy of our refined solution to detect uplift outside of significant temporal data gaps in the InSAR stack is significantly better than 1 mm per year. We further show that accuracy and robustness to data gaps are both significantly improved by co-inverting multiple datasets with the same and different sensors. This co-inversion method also allows the seamless continuation of the monitoring from one sensor to another.

Jun 1, 2012

By Yusuke Yamamoto, Mineo Asano

"The present study investigated the texture transition during secondary recrystallization in the AA5182 sheet. During the initial stage of annealing, the texture showed a weak Cube orientation as the primary recrystallization texture. During the secondary recrystallization with abnormal grain growth, the area ratio of the {hkl} <011> orientations increased by consuming the other orientations. The texture transition was calculated by the 2-D Monte Carlo simulation with the misorientation dependency. When the higher grain boundary mobility was set in the specific range of the high angle misorientation, the orientation preferential growth of the RW {100} <011> orientation was reproduced. However, other {hkl} <110> orientations could not be well reproduced by the misorientation dependency.INTRODUCTION Crystal orientation and texture are important factors for aluminum sheet products from the standpoint of mechanical property, formability and isotropy. The recrystallization texture results from the orientation preferential growth from the rolling deformation microstructure and the texture (Alvi, Cheong, Suni, Weiland, & Rollett, 2008). Texture development has been a topic of intense research for decades with advances in analysis methods, e.g., orientation mapping (OIM) and computer simulations (Fjeldberg & Marthinsen, 2010; Ivasishin, Shevchenko, Vasiliev, & Semiatin, 2006). The grain boundary characteristic is considered to be a key for the orientation preferential growth. In the case of the recrystallization from the deformed microstructure, not only the grain boundary characteristic, but also the dislocation density and the subgrain size affect the nucleation and the grain growth (Engler, Löchte, & Hirsch, 2007). On the other hand, in the case of secondary recrystallization, the dislocation density and the subgrain size can be ignored and the effect of the grain boundary characteristic can play a significant role in the grain growth. There is intense research about the texture development during secondary recrystallization in aluminum alloys and it was reported that coarse {hkl} <011> grains were formed during the secondary recrystallization (Suk, Shin, & Huh, 2006; Rios, & Gottstein, 2001). However, the mechanism of forming the {hkl} <011> grains has not been fully clarified. In the present study, the effect of the grain boundary characteristic on the orientation preferential growth was investigated by EBSD analysis and Monte-Carlo (MC) simulation."

Jan 1, 2018

By W. J. Gibson

"This paper will provide a general assessment of the differences in construction and industrial labour relations. From this outline will come a detailed examination of labour relations in the construction industry and then specifically as related to the construction of mining projects, with emphasis on projects in isolated areas. Development of manpower forecasts, manpower availability, wage escalation formats, working rules, training and recruitment programs, and safety - as related to construction labour relations in the mining industry - are topics which will be dealt with."

Jan 1, 1972

By F. Czerwinski

Mechanically fragmented chips of an AZ91D magnesium alloy were transformed into a semisolid slurry within the Thixomolding® system. Microstructural analysis of a material at various processing stages revealed that the cold deformation of the alloy, experienced during chipping, led to the recrystallization and growth of equiaxed grains which were subsequently converted to the globular structures by melting the grain-boundary network.

Jan 1, 2004

By J. W. Griffith

"The mines in the Bancroft area of southeastern Ontario, a few kilometres west of the town of Bancroft, are in Faraday and Cardiff Townships. Three companies, known as Canadian Dyno Mines Limited, Macassa Gold Mines Limited (Bicroft Division) and Madawaska Mines Limited (formerly Faraday Uranium Mines Limited), with plants capable of handling a total of 4,()()() tons (3,629 tonnes) of ore a day, were at one time in production. A fourth company, Greyhawk Uranium Mines Limited, operated a small mine whose ore was shipped for custom treatment to the nearby Faraday mill. Canadian Dyno Mines Limited ceased operations in June 1960. In June 1963 the Bicroft Mine was closed and a year later Faraday closed because of contract completion. But in 1975, Faraday (now called Madawaska) was re-opened but closed again in 1982. During 1959, the peak year, these four mines produced an estimated 1,100 tons (998 tonnes) of uranium precipitates, which represented nearly 7 per cent of Canada's output for that year(Fig. 1).The deposits occur in pegmatitic granite dykes in a region of high-grade metamorphic and metasomatic rocks. Uranium distribution is usually controlled by the distribution of mafic minerals, particularly hematite and magnetite, and by late fractures. The best visual indicators for uranium concentration are hematite staining in the pegmatite, followed by the amount of mafic inclusions or crystals. The Bancroft area orebodies are the only known deposits of the general pegmatitic class in Canada that contained economic deposits of uranium. The principal radioactive minerals are uraninite and uranothorite. By comparison with many other pegmatitic occurrences, some of the ore bodies are unusually large, persistent in depth and relatively rich in uranium minerals. At the end of 1981, total ore reserves were estimated at 1,500,00 short tons (1,360, 000 tonnes) averaging 0.11 % U3O8."

Jan 1, 1986

By A. Vasenev

The quality and durability of asphalted roads strongly depends on the final step in the road construction process; the profiling and compaction of the fresh spread asphalt. During compaction machine operators continuously make decisions on how to proceed with the compaction accounting for project specific aspects as: ambient conditions, road geometry, roller type, asphalt mixture characteristics and behavior of other machines. In discussions over quality improvement in road construction it is often suggested to robotize rollers. To operate such robots would of course require operational strategies and routines. The reality of this moment is that these operational strategies and routines are not documented. To identify the existing best working practices and, ultimately, to proceed with developing automated robotized compactors, the knowledge of machine operators should at first be explored and described in a formalized way. Unfortunately operators have difficulty verbalizing their expertise. Observation of behavior, as machine movement patterns, could be helpful to extract the operational strategies, but such observations are time and labor consuming. To overcome this burden we developed a Virtual Reality (VR) environment. In this VR environment operators perform compaction virtually, and their operational choices are traced and analysed. This paper describes this VR development and explains how it helps in following machine operators and extracting their (tacit) professional knowledge. The road geometry and the working conditions are visually represented; the operators show - rather than explain - how they would proceed with the compaction process in the given conditions. Movements of virtual machines are documented, analysed, visualised and discussed. This VR approach is expected to contribute to learning, to more formal description of operational strategies; stepping stones towards compaction algorithms for roller robotisation.

Aug 1, 2013

By Jan Drzymala, Przemyslaw B. Kowalczuk

"Flotation is possible when the forces operating between a bubble and the attached particle are properly balanced. There are many forces operating in the bubble-particle aggregate. The magnitude, location and direction of the forces depend on the type of process. The simplest arrangement in flotation is when a spherical bubble is attached to a spherical particle and both are immersed in water. In such a system there are four essential forces which shape the stability of the bubble-particle aggregate. They are excess pressure and interfacial solid/liquid, solid/gas and liquid/gas forces. A proper analysis and balance of the size, location and direction of these four principal forces lead to a general equation delineating the stability of the spherical particle–attached bubble system. Specific cross sections of the system and solution of the general equation lead to different relationships including the Young formula as well as the well-known geometrical relation between contact angle, particle and bubble radiuses. The arrangement of forces in the proposed graphical representation of the Young law is different from that presently used in literature for a bubble attached to an unmovable solid particle. Many real solid/liquid/gas systems are more complex due to the presence of additional forces which change the regular curvature of the liquid/gas interface leading to advancing and receding contact angles.INTRODUCTIONThere are numerous papers (Athukorallage, Aulisa, Iyer & Zhang, 2015; Chau, Bruckard, Koh & Nguyen, 2009; Drzymala, 1994; Lubarda, 2012; Pellicer, Manzanares & Mafe, 1995; Wang, Cui, Zhou, Xu, Sun, & Zhu, 2014; Young, 1804) and books (Davies & Rideal, 1963; Defay & Prigogine, 1966; Lee, 2013; Lyklema, 2000) dealing with the solid/liquid/gas system. Many of them concern the three involved phases having the shape of a sphere or spherical cap and the formed contact angle. The contact angle is usually measured through the liquid phase and can be either smaller or greater than 90o. The essential part of these publications is a graphical representation of the system with the Young equation shown as a result of balance of only three forces that is the excess Gibbs (or Helmholz) free energy per unit area of the three involved interfaces (Davies & Rideal, 1963; Defay & Prigogine, 1966; Israelachvili, 1985) (Figs. 1a-c). The Young equation, when the gravity force/buoyancy is neglected, is:"

Jan 1, 2016

By Chandrakala Kari, Divyang Shah, Lakshmi Kanth Reddy, Kaushik Vakil, Sanjay Sarkar, Bhavin Desai

Gases rich in sulfur dioxide generated as a by-product of smelting and converting operations of copper concentrate contain selenium apart from zinc, lead, copper, cadmium, bismuth, antimony, and arsenic. The gaseous stream is heat exchanged in waste heat boiler, dust collected in electrostatic precipitator followed by cleaning in reverse jet scrubber to remove fumes, halogens and fine dust before passing to DCDA Monsanto catalytic converter to produce commercial grade sulfuric acid. The gas cleaning section of the acid plant uses water to scrub the smelting gases. During scrubbing, precipitated solids, known as sludge, settles at the bottom of the reverse jet scrubber containing 30 to 40 wt% copper and selenium up to 40 wt% selenium. In the existing process, the sludge collected during scrubber cleaning process is directly recycled to the smelter for copper recovery. However, the selenium is expected to again vaporize due to high oxidation potential during smelting and converting, causing accumulation of selenium in sludge. In present investigation, a roasting process has been developed to recover the selenium from acid plant sludge before charging it to smelter for copper recovery. Selenium is associated with copper in acid plant sludge as copper selenide, as determined by X-ray diffraction and electron microscopy. Thermodynamic and thermo-gravimetry study revealed that the copper selenide phase present in the sludge was amenable to oxidation at 600°C forming oxides of copper and selenium (Cu-Se-O). However, the dissociation of selenium from the copper oxide was made possible by sulfatation using sulfur dioxide between 450°C to 600°C, resulting into the formation of CuSO4(s) and SeO2(g). Lab scale experiments were carried out in vertical tubular furnace to determine the optimum roasting conditions with respect to roasting time, temperature and molar ratio of O2:SO2. Using these optimum conditions, selenium up to 90 wt. % in the form of SeO2 vapors could be recovered from the acid plant sludge in a large scale commercial roaster. Roasted sludge free from selenium and containing oxides and sulfates of copper could now be recycled in the smelter for copper recovery. INTRODUCTION There is an increasing demand for minor metals due to their use in innovative technologies. Similarly, the increase in demand for selenium is expected due to disruption in sectors related to renewable energy and photovoltaic battery. Selenium is a chalcogen and a non-metal with black or red crystalline appearance. Selenium is used in the glass industry to decolorize glass and to make red-colored glasses and enamels. It is also used in solar cells and as a photographic toner. Selenium is used as a brasses in stainless steel to improve its machinability. Selenium sulfide is used in anti-dandruff shampoos. In spite of the toxicity of its compounds, selenium is also an essential trace element for humans and animals. Selenium occasionally occurs free in nature, but more often occurs as selenides of iron, lead, silver and copper. There is an urgent need for the development of new methods for selenium recovery from the existing resources. Commercially, selenium is obtained only from anode mud produced during electrolytic refinery of copper.

Jan 1, 2019

By J. W. Reynolds

Use of crushed waste rock recovered by sink-float separation from normal ore production for backfill is an established procedure at Commco's Sulhvan mme, Kimberley, British Columbia. Need for a safe method of placement in voids which were difficult to reach by gravity methods led to a co-operative venture with Radmark Engineering Ltd. in the development of a workable pneumatic transportation system for rock material. This paper reviews work done to date in a current program, and includes comments on the nature of the fill so placed, options for cementing such fill, implications for other aspects of mining and references to other applications of the system by other organizations who exchanged experiences with the Sullivan mine staff during the five-year period reviewed.

Jan 1, 1972

By H. J. Meyer

"A hydrostatic elevation difference meter has been developed for use in measuring elevations along gravity traverses. Elevations of stations 100 feet apart can be obtained at a rate of 1/2 mile per hour and to an accuracy better than 1/3 foot. This can be done along traverses which have not been cut and chained. The instrument is durable, lightweight and constructed of materials which will withstand any temperature encountered in field work.It is believed that this device will more than double the rate at which gravity surveys over mining prospects can be carried out."

Jan 1, 1972

By Hans Lundberg

The magnetometer which was developed during the war for detecting submarines has proven exceedingly valuable in outlining deep-seated structures in oil exploration, and will be useful also to geologists in outlining regional structural features in the Precambrian. Our magnetometer has been developed to outline local and detail structures. 1 am quite sure that all geophysicists and geologists would agree with me that, in ore prospecting, it is important to obtain as much detailed information as possible. We know that, as we ascend from the ground and get away from the magnetic ore-bearing structures and orebodies, the magnetic intensity decreases rapidly, but, worse than that, we lose the details even faster. Figure l shows two strong, very sharp, magnetic &apos;highs&apos; over two orebodies which, as our distance increases, rapidly merge into one fairly broad, moderately strong anomaly. If we drilled on this maximum, we would not encounter any of the orebodies. Therefore, we should fly the airborne magnetometer as close to the ground as possible in order to duplicate the results of the magnetic ground surveys. The first chance to accomplish this came with the helicopter, which is an exceedingly maneuverable aircraft. It can be landed in a cleared space not much more than fifty feet square. With floats, it can be landed anywhere, even in a swamp, on thin ice, or on soft snow. It can stand still in the air, hovering over a given point. It can ascend and descend vertically, fly sideways and even backwards, at the will of the pilot. It flies forward at any speed up to l00 miles an hour. The helicopter can be taken to any desired position at a given time. It can fly at any useful altitude from a few feet to several thousand feet above the ground. It can fly very close to the ground with safety. In bare areas, the survey flight may be performed a few feet above the ground. In forested areas, however, the flights, to clear the trees, must be made at l00 to 150 feet. To mark out a certain point, a small parachute-like marker may be draped over a tree or laid on the ground. This can be done from the helicopter without touching the ground.

Jan 1, 1947

By G. Couture

In the introduction to this presentation, we will cover the market of motorized recreational products. We will introduce the public to what is produced and sold worldwide, what is the nature and general behaviour of the customers for such products. We will cover the evolution of this market and put in evidence how drastic must be the changes in the manufacturers organizations in order to, in one hand, constantly adjust to the customer demand, and in the other hand, react to the competitors&apos; offensives on the market.

Jan 1, 2006

By D. R. Schmitt, Q. Jia, R. Kofman

"Tests were carried out on clear glass blocks containing borehole aligned with and at an angle to applied principal stress states in order to study the growth of drilling induced tensile fractures. The samples were illuminated such that photoelastic fringes could be video recorded during the measurements; this was useful in assessing states of stress and in determining fracture initiation. Axial drilling induced fractures were observed at the azimuths of the applied uniaxial stress as would be expected from the concentrated stresses. En echelon fractures were observed from the borehole deviated at 45° to the direction of the compression. These preliminary and currently qualitative results show that glass blocks serve as a useful test medium for studies of stress concentration and drilling induced fracture creation. INTRODUCTIONWith the increasing exploitation of unconventional oil/gas reservoirs using deviated drilling in recent years, the effects of the in-situ stress on the success of energy production have become more critical than ever before. Knowledge of the state of stress in the earth enables us to determine well trajectories, well locations, hydraulic fracturing design and production rates, but knowing the crustal stress is always challenging. Strictly, it can only be obtained to varying quantitative degrees by accessing the earth through drilling. Failure of the rock at the borehole wall produces borehole breakouts (e.g., Bell & Gough, 1979; Haimson & Herrick, 1986; Zoback et al., 1985) and drilling-induced tensile fractures (DITF) (e.g., Aadnoy, 1990; Aadnoy & Bell, 1998; Barton et al., 1997; Brudy & Zoback, 1999; Davatzes & Hickman, 2010; Peska & Zoback, 1995). Thus, it is important to understand the failure mechanism of the rock in the vicinity of the borehole. A number of closed-form expressions have been developed that allow the stress concentrations to be calculated in the vicinity of a borehole including Kirsch’s (1898) 2-D plane strain solution and 3D formulae for elastically isotropic (Hiramatsu and Oka, 1962) and anisotropic (Lekhnitskii, 1981; Amadei, 1983) continua. These solutions have been applied in numerous studies (e.g., Ong, 1994; Ong & Roegiers, 1996; Vahid & Ghassemi, 2011; Jia & Schmitt, 2014; Ito et al., 2001) to analyze the failure mechanisms of drilling-induced tensile fractures (DITF) on the borehole wall."

Jan 1, 2015

By Forrest A. Kerr

The subject of the Coast Range batholith and its eastern contact zone needs no introduction to British Columbia mining men. Because of its reputed potentialities, this zone has aroused much interest. Because it has touched the pockets of the people by actually producing dividend-paying mines, it has been able, more particularly in certain isolated sections, to retain and accentuate that interest. However, the Stikine River section of the zone has never had the good fortune to have a mine developed, which, through profits or lack of profits, could create such interest. The Cassiar district, beyond the Stikine River area, has been a lure to the prospector for over half a century and was still strong enough in the last few years to attract close to a million dollars in capital and labour. All of this has passed through the Stikine river area, has looked at it, and ignored it. Sufficient interest has never been aroused in the area to bring forth an effort to see what is there, in spite of the fact that it belongs to the same zone in which some of our richest mining camps are located. Because the contact zone of the Coast Range batholith has long been recognized as an ore producer of considerable potentiality, the Geological Survey some years ago formulated a plan to map as much of this area as possible in order to assist in promoting its development. This plan has been furthered during the last fifteen years whenever opportunity presented itself, until today a fairly large part of the area has been covered. The work which has been done on the Stikine during the last two years is the beginning on what is the largest remaining gap in the general plan.

Jan 1, 1928

An optimized long-term mine planning determines the best order of material extraction, so that the Net Present Value (NPV) becomes maximum. In the case of oil sands surface mining, one of the key constraints in NPV maximization is the volume of tailings slurry that will be generated downstream. Specifications of tailings slurry are also important from environmental perspective. Moreover, most of the material that will be used for the reclamation of tailings ponds in later periods is generated in extraction and processing of oil sands. In this paper, an integrated optimization framework is proposed to maximize the NPV of the produced oil sands, with respect to tailings capacity constraints and reclamation material requirements. A mixed integer linear programming (MILP) model is developed to find the optimal solution for long-term mine planning problem. The proposed model is coded in Matlab and has been run using CPLEX for verification. The results for real-case oil sands dataset show that the optimal production schedule meets material requirements for reclamation, tailings volume is within tailings capacity range in all periods and the production schedule follows the predetermined horizontal direction.

Aug 1, 2013

The influence of joint orientation and joint persistence, on the mechanical behaviour of jointed rock masses under uniaxial compression, has been studied systematically. The joint inclination angle ß was varied from 0° to 90° with an increment of 15°. The joint continuity factor k was taken as 0.2, 0.4, 0.6 and 0.8. The peak strength, Young’s modulus, the complete axial stress-axial strain curves, the cracking process and the characteristic of the fragments, were investigated. It was found that the anisotropic response of the jointed specimens was governed by the micro-mechanism, such as crack initiation, propagation and coalescence, crack opening or closing, and frictional slip of cracks or joints. With the increase of joint continuity factor, the axial stress-axial strain curves change from single-peak to multipeak, the peak strength and Young’s modulus decrease. The specimens with medium joint inclination angle (30°,45° and 60°) has lower energy dissipation and strength due to stepped or shear failure, while specimens with small and large joint inclination angle (0°, 15°, 75° and 90°) has higher energy dissipation and strength due to axial cleavage or crushing failure.

Jan 1, 2015

By Suzie Poulin, N. Geoffroy, G. P. Demopoulos

Most metallurgical industries generate toxic waste that must be treated prior to being released to the environment. However, in a lot of cases, the waste materials are poorly characterized or the analytical results are not well interpreted. These shortcomings often result in the development of inefficient industrial procedures, thus causing economic waste and difficulty meeting environmental regulations. Fortunately, a wide range of analytical techniques are available to guide researchers and engineers into making sound process development decisions. In this work, an industrial selenium and mercury removal process is used as an example to illustrate the application of X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM) coupled with Energy-dispersive X-ray spectroscopy (EDX) and powder X-ray diffraction (PXRD) on solid waste. Furthermore, samples of analytical results are presented and interpreted and the modifications to the industrial process that resulted are explained. Finally, a brief description of the advantages and limitations of the aforementioned analytical techniques is given with an emphasis on industrial solid waste material.

Jan 1, 2011

By H. Hejny

Given the current status of political discussion in Europe about raw materials issues, the sustainable development of the extractive industry and the reduction of its environmental and societal footprint are among the key topics in this discussion. In this context, the European Commission approved the EO-MINERS project (Earth Observation for Monitoring and Observing Environmental and Societal Impacts of Mineral Resources Exploration and Exploitation). The overall aim of EO-MINERS is to bring into play EO-based methods and tools to facilitate and improve interaction between the mineral extractive industry, authorities, and the society in view of its sustainable development while improving its societal acceptability. Developing generic, standardised and reliable EO-based products to monitor the environmental and societal footprint of mining projects is the way chosen by EO-MINERS to improve this interaction, along with the organisation of tripartite meetings gathering all relevant stakeholders. The project uses existing EO knowledge and carries out new developments on three demonstration sites (Sokolov lignite mining area, Czech Republic, Witbank coal field, South Africa, Makmal gold mine, Kyrgyzstan) to further evaluate and demonstrate the capabilities of integrated EObased methods and tools in monitoring the environmental and societal footprints of the extractive industry during all phases of a mining project, from the exploration to the exploitation and closure stages. It contributes providing reliable and objective information about affected ecosystems, populations and societies, to serve as a basis for a sound ?trialogue? between corporate stakeholders, governmental organisations and societal stakeholders. The project already developed a set of consolidated indicators based upon previous knowledge about mining-related issues along with interviews of national, regional, and local stakeholders. These indicators reflect known environmental and societal issues at mining sites as well as the interest of various relevant stakeholder groups. The process described in the EO-MINERS project ? policy assessment > indicator identification > choice of suitable EO tools able to serve monitoring task > monitoring by EO tools > making available objective information for fair dialogue among stakeholders ? is generally applicable to all stages of a mining project. The key to success will be the right choice of indicators addressing the problem and subsequently the right choice of suitable EO tools and finally the willingness of all stakeholders to find a common solution. To this end, the EO-MINERS project organises site-specific ?trialogue? workshops at each demonstrations site, which aim to provide relevant information in adequate quality to the stakeholders as common ground for discussions. Local stakeholders, including mining companies, regulatory bodies, and community representatives are invited to participate in these workshops where the relevance of the developed EO-based products to environmental and societal impact assessment will be discussed. The presentation will discuss results obtained during these trialogue workshops, as well as the success and difficulties and reluctances encountered. The project will further indicate ways and means how the EO products and other project results may be used for monitoring purposes in all phases of a mine.

Aug 1, 2013

By J. Shibata, K. Manabe, A. Fuji, N. Matsunaga, D. Murakami, Yamaguchi University, T. Suzuki

"Spent hydrodesulphurization (HDS) catalyst contains rare metals such as cobalt, nickel (Ni), molybdenum (Mo), and vanadium (V). The overall objective of this project is to develop a hydrometallurgical process that provides a degree of high recovery and selectivity of these rare metals from spent HDS catalyst. As a part of this project, this study focused on (i) development of a solvent extraction-precipitation stripping process for separation of Mo and V from solutions and (ii) optimization of grinding conditions of alkaline leaching residue for selective Ni sulfuric acid leaching against aluminum (Al). Experimental results showed that effective separation between Mo and V can be achieved by the two-stage process; solvent extraction of Mo and V with TOA (tri-n-octylamine) and precipitation stripping of V with ammonium salt at pH above 8.0. Regarding grinding conditions of alkaline leaching residue for selective Ni leaching against Al, it was found that Ni leaching efficiencies increased by providing higher grinding intensity, while the Al leaching efficiency increased and then decreased with increasing grinding intensity.INTRODUCTIONHydrodesulphurisation (HDS) catalysts account for about one third of the total worldwide catalyst consumption and are extensively used for sulphur removal in petroleum refineries (Zeng & Cheng, 2009). Fresh HDS catalysts generally contain molybdenum (Mo) and nickel (Ni) on an alumina carrier, but various elements included in the crude oil such as sulphur, carbon, silica, arsenic, cobalt, and vanadium (V) deactivates HDS catalysts during HDS reactions. As a result, spent HDS catalysts contain high concentration of rare metals. For example, regarding to Mo and V, it has been reported in the literature that the concentrations of Mo and V in the general spend HDS catalysts are generally 10-30% and 1-12%, respectively (Zeng & Cheng, 2009), which makes it economically viable to recover these rare metals (Biswas et al., 1986).Among a number of processes proposed for the recycling of rare metals from spent HDS catalysts, alkaline leaching is often used for selective Mo and V leaching (Zeng & Cheng, 2009). However, the process which provides a high degree of separation between Mo and V from a leaching solution had not been developed. Therefore, the first objective of this study was set to develop a solvent extraction-precipitation stripping process for the separation of Mo and V from solutions. More specifically, using artificial aqueous solutions of Mo and V, a series of experiments was performed to optimize the extraction pH, stripping agent, and the stripping pH."

Jan 1, 2016

By Cristina Echavarría

MAIN POINTS ? The region: opportunities and limitations ? Overview of main issues emerging from MMSD in South America ? Who comprises the local community? ? What are the main challenges? ? Some suggestions for companies to improve their contribution to local sustainable development of mineral rich localities THE REGIONAL CONTEXT 1. The region is a producer of minerals contributing over 20% to world metal production. It consumes only 8% 2. Significant diversity of national contexts-both between countries and within countries 3. Variable but predominant need for strengthening of government and community institutions and governance, especially at the local level 4. Dearth of baseline information for decision making 5. Sustained social spending during early 90?s as a consequence of economic recovery and fiscal policy, produced important advances in education and health 6. Despite government efforts in most countries poverty continues growing 7. Highly inequitable distribution of wealth persists

May 1, 2002