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By S. Itoh, T. Nagasaka, J. Ono

With respect to the recycling of used lead-batteries, a pure lead is required to prepare a lead-calcium alloy electrode for a new maintenance-free battery. The pure lead can be obtained by means of electrolytic and/or pyrometallurgical refining. In the lead electrorefming, antimony is concentrated in anode slime. From the viewpoint of the recycling and recovery of metal values from used lead-batteries, especially from anode slime, oxidation experiments were conducted for pure liquid antimony in the temperature range between 973 and 1373 K to elucidate the oxidation kinetics and mechanism. Furthermore, since lead anode slime generally consists of antimony, lead and bismuth, experiments have been also carried out using antimony-lead-bismuth alloy. The equation relating to the mass transfer characteristics in the gas phase was then applied to analyze the oxidation kinetics. As a result, it was found that the anode slime treatment, that is, an oxidation of antimony concentrated in anode slime followed by vaporization as antimony oxide Sb406, should be operated with higher oxygen partial pressure and sufficient amount of gas flow rate at lower temperature around 1073 K. The feasibility of the oxidation treatment for anode slime has been also discussed.

Jan 1, 2004

By G. L. Palmer

"In 1986, anomalous sampling results for heavy minerals were obtained at various sites in Namaqualand on the west coast of the Cape Province. Drilling in 1987 at Graauwduinen penetrated up to 35 meters of heavy mineral-bearing Tertiary sands which extend several kilometers inland from the coast. The heavy mineral suite includes ilmenite, rutile, leucoxene, zircon and monazite, along with gamet, pyroxene and amphibole. Three deposits are recognized, two of which comprise the resource to be mined by Namakwa Sands Limited, a recently formed Anglo American Corporation subsidiary company.Mineable reserves in excess of 500 million tonnes have been delineated, sufficient to sustain mining for over 35 years at projected production rates. During the feasibility study, on-site investigations included test mining at various sites to assess rnineability and to provide material for metallurgical testing in a pilot plant located at the site. llmenite produced at the mine will be smelted at a new facility to be built at Saldanha Bay. Saleable products comprise titania-rich slag, pig iron, zircon and rutile.During the exploration phase, company environmental guidelines were established and monitored. The feasibility study incorporated a Class 1 Environmental Impact Report, the contents of which were made public following the principles of the Integrated Environmental Management legislation."

Jan 1, 1994

By Kristie D. Tarr

Ideally, in situ monitoring would supply the input data for numerical modeling of backfill material property requirements. However, clue to production requirements and costs of conducting field tests, input data are often based on small-scale laboratory tests. The size of test samples is known to play an important role in the laboratory assessment of the behaviour of geotechnical materials, including backfill. There are observed differences between the mechanical properties of laboratory-scale samples and those of in situ materials, and these are generally attributed to the differences in scale. Various scaling factors have been proposed for converting laboratory observations to anticipated in situ conditions for soil and rock materials. With regard to mine backfill, very limited studies exist which have involved the effects of sample size on material properties. The literature indicates that reported backfill strength data are based on a variety of test sample sizes and in some cases, specimen geometries. Carefully determined laboratory scale effects could play an important role in estimating the potential backfill behaviour in the field, especially when developing new backfill systems. Laboratory studies were conducted with sample diameters ranging from 50 to 300 mm. Scale factors relating specimen size to strength were developed wherever possible, and are presented in this paper

May 1, 2008

By John O. Marsden

Technology development and innovation has played a crucial role in the copper industry throughout history. The effective development and implementation of new technologies allows mankind to produce copper at progressively lower cost of production at a given feed grade and mineral type. This progress serves to counteract cost escalation over time and, depending on the magnitude of the cost benefit, allows ore cut off grades to be reduced thereby improving the availability, accessibility and utilization of mineral resources. The development of step change technologies that can offer >$0.15/lb total cost benefits provides a significant opportunity for producers to achieve competitive advantage, but it has been argued that rapid dissemination of technology makes such competitive advantage unsustainable over time. This paper presents the results of a recent study that evaluates a number of historical and emerging step change technology case studies in the copper industry and quantifies the associated cost benefits for users, the impact on the production cost curve, and the duration of such cost benefits for various categories of implementers: first mover, fast follower, conservative followers and laggards. The results provide a compelling case for major, mid-tier and emerging copper producers to invest in technology development initiatives if they wish to achieve and sustain competitive advantage over the long term. INTRODUCTION AND BACKGROUND A key issue for mining companies is how much time, effort and cost to spend on research and technology development (R&TD). The economic drivers for technology development and implementation are poorly understood in our industry and the business case is clouded by some notable and well-publicized failures (McNulty, 1998). Mining companies are in business to deliver financial returns to investors. This means delivering short term results on a quarter-by-quarter reporting basis as well as sustaining and growing the company to retain and reward a sustainable longer term investor base. The cyclical nature of the commodity metal markets makes it challenging to maintain investment in research and step change technology development: Mining companies must manage through the highs and the lows of price cycles, typically ranging from 5-15 years in length. The discounted cash flow approach to investment evaluation results in weak financial justification for R&TD expenditures. A clear and compelling rationale to support longer term investment in research and step change technology implementation is required.

Jan 1, 2019

By M. R. Babcock

"The Rabbit Lake story began in the late sixties and will continue well into the twenty-first century. It is a story of success, of multiple ore body discoveries, of unique systems, and new methods made possible through innovative and state-of-the-art design. Two quite different geological systems host the five ore bodies mined, or slated to be mined. These two systems have yielded two distinct ore types, each with characteristic mineralogical properties and each requiring its own specific mill circuit.Emphasis on communications and our unique systems have led to a satisfactory and fulfilling work environment resulting in the historically low employee turnover which has contributed to the operation success.A comprehensive environmental study after twelve years of operation has given the Rabbit Lake Operation a completely clean bill of health. INTRODUCTIONRabbit Lake can be described as Saskatchewan's first highgrade uranium mining operation, which set the stage for the province's current role as the leader in uranium mining throughout the western world. The importance of the Rabbit Lake operations - past, present and future.LocationThe Rabbit Lake operation is located in northeastern Saskatchewan (Fig. 1)- 805 km north of Saskatoon, Saskatchewan, and 814 km northeast of Edmonton, Alberta. OwnershipGulf Minerals Canada Limited discovered the Rabbit Lake deposit in 1968. Mining operations began in 1975and were operated by Gulf until purchased by Eldorado Nuclear Limited in 1982. In 1988, Eldorado merged with Saskatchewan Mining Development Corporation (SMDC) to form Cameco-A Canadian Mining &. Energy Corporation. The new corporation is one of the world 's largest uranium companies.Cameco's $1.5 billion in assets include the Rabbit Lake uranium mine (Cameco 100010); the Key Lake uranium mine (Cameco 66.67%; Uranerz Exploration and Mining Limited 33.33%); the Cluff Lake uranium mine (Cameco 20%; Amok Ltd. 80%); the Fuel Services Division at Blind River and Port Hope, Ontario (Cameco 100%); and a 100%); and a 48.75% interest in the Cigar Lake uranium deposit which is now at the test mining stage (Cogema Canada Ltd . 32.625% ; Idemitsu Uranium Exploration Canada Limited 12.875%; Corono Grande 3.75%; Korea Electric Power Corporation 2%). In addition, Cameco is involved in a number of base and precious metal explor ation projects."

Jan 1, 1989

By T. Boiselle, C. Gielen, P. Henry, J. M. Bier

"Hydrometal is specialized in the production of zinc sulphate from complex secondary raw materials. Electric Arc Furnace (EAF) dust is one of the more interesting potential sources to produce zinc sulphate. In order to minimize waste quantities generated from EAF dust treatment, our R&D team has developed and patented a new process to recover the Fe contained in the dust as iron oxide product to be used and sold into the pigment market. The process is based on a specific reductive leaching step of the zinc ferrite contained in EAF dust, followed by a purification step to remove impurities (Ni, Cr, Cu...) and finally the controlled precipitation of the iron oxide. The aim of the iron precipitation step is to obtain the right shape and length of crystals in order to guarantee the right color and tinting strength of the pigment. The innovative aspects of the process results in the controlled oxidation of the iron to get the right crystal size and good purity material. The iron product can be valorized as red or yellow pigment often produced by the Penniman-Zoph process.INTRODUCTION A Few Words about HYDROMETAL Hydrometal SA (Engis, Belgium) is a subsidiary of Jean Goldschmidt International SA (JGI) in Brussels. JGI is mainly involved in metal trading activities (Goldschmidt, 1995). In 1985, JGI acquired the leaching circuit of a Belgian electrolytic zinc producer located in Engis, a few kilometers south of Liège, near the river Meuse and it was decided to name this plant: SA HYDROMETAL. Hydrometal is well connected by water, rail and road from its central location in the industrial region of Liege, in the heart of Europe. The company received in 1997 an additional license to process and recycle toxic and hazardous waste. Figure 1 shows a picture of the plant."

Jan 1, 2016

By Fathi Habashi

New technology first introduced by Nippon Steel Corporation at Kitakyushu in Japan in 1976 now used at a number of plants in other countries, known as dry quenching of coke, uses nitrogen in a closed circuit to avoid environmental emissions. In addition, heat is recovered in the form of steam, from the red-hot coke. In steel plants oxygen is used extensively and therefore by-product nitrogen from air liquefaction can be effectively utilized in this way.

Jan 1, 2014

By R. A. Elliott

This paper describes the development of an infra-red ore dryer at the Mines Branch. The dryer utilizes an infra-red heat source mounted over a stainless-steel belt to dry ores and concentrates of varying particle size and moisture content. It has been found to ?be successful in meeting Mines Branch requirements of minimum dusting loss and ease of cleaning to decrease ,contamination between various batches of dried products. It is described with the hope that it might .prove useful in other laboratories where there are similar problems. It might have an application in the drying of concentrates containing high values where dust losses would result in a considerable loss of revenue; also for small batches of material or an intermittent drying problem.

Jan 1, 1958

By Gerhard Melcher, Hermann Hilbrans, Michael Gamroth

"IntroductionSeveral new smelting processes have been proposed and developed during the last 20 years. This has been true, in particular, for copper smelting technology. The important impulses for the advances in this field have been the recent demands regarding the environmental protection, energy saving and improved utilization of the metals contents of deposits, in particular that of complex raw materials.The methods developed more recently for pursuing these objectives have been outlined in several papers. In some of them the advantages and drawbacks of certain developments have been stressed. These documents are of great importance for assessing the different processes. The following paper tries to explain some details of the cyclone smelting process taking into consideration a few of these well-known presentations. The effectiveness of operation of the cyclone smelting process indicates that this process presents a significant achievement when compared with other conventional methods.The application of the CONTOP smelting cyclone range s beyond the field of copper metallurgy or the smelting of sulphide concentrates with the aid of oxygen. The research work carried out in the pilot plant of KHD Humboldt Wedag AG in Cologne-Porz also includes the recovery of the metal contents of intermediate products and processing of smelter residues which have to be converted in a disposable stat e, free of environmental pollution. This paper explains a few examples in this regard."

Jan 1, 1987

By A. E. Wraith, J. Protheroe Jones, P. J. Mackey

INTRODUCTION When Victoria became queen in 1837, that technical wonder of the 19th century—electricity— had progressed from being an exciting physical curiosity and was now a field of intense scientific investigation, invention and application. Its role in electrochemistry had been brilliantly quantified by Faraday in 1833–1834, and his earlier discoveries in electro-magnetism were to lay the foundations of electricity generation and the electric motor. In this age of electrical experiment, silver electro-plating emerged as a popular decorative art, at first using batteries to provide the deposition current, superseded by dynamos in the early 1840s. The decorative chemical and electroplating of precious metals was largely pioneered in England by the firm of G.R. Elkington and Co., founded in Birmingham by George Richards Elkington (1801–1865) in 1832, and protected by a series of patents which helped the company establish a leading position in the new field of ‘electrometallurgy’. In the same decade, the technique of electrotyping emerged, the first application of electro- forming by electrolytic deposition. Simultaneously invented by Spenser in England and Jakobi in Russia, but generally claimed for Jakobi, electrotyping involved plating a thick copper layer on to an electrically conducting mould wall embossed or incised with a pattern or profile which would consequently be replicated on the copper deposit—essentially a method of casting by electro-deposition with the mould wall as cathode. Woolrich’s invention of the low voltage magneto-dynamo in 1842 eliminated the need for batteries as a continuous source of deposition power, opening up the possibility of making more massive electroplated deposits, and by the mid-point of Victoria’s reign in 1869, the work of Wilde, Wheatstone and Siemens had produced the self-excited electro-dynamo, capable of higher voltages and yet greater deposition power. In this early Victorian period copper was extracted and refined by methods which had developed step-by-step over many decades. Only relatively rich copper ores containing more than, say, 6% Cu were economically useful, and the final copper product was far from pure. Copper production in Britain was located principally in the Swansea area of South Wales, based upon the ‘Welsh process’ of reverberatory batch smelting and refining, using locally mined coal and ore imported from Cornwall and elsewhere. Silver was an important by-product. Much of the output was exported and South Wales remained a principal supplier to the world copper market until the 1890s. It was here at Pembrey, a few miles west of Llanelli, that a new primary copper smelter was stablished in 1849 under the name Mason and Elkington, arguably to supply the Elkington company’s market for electrotype products.

Jan 1, 2019

By E. H. Hall

"Perhaps .I should start this talk on Arsine poisoning, by giving a brief background and history of the Bralorne Mill.The present Bralorne company started milling operations in 1932, with amalgamation and flotation, and operated continuously until 19 61 . In 19 59, it was decided to change over to cyanidation, and to use double filtration rather than counter current. The cyanide portion of this new plant was completed and went on stream in August 1961 utilizing the grinding circuit of the old flotation plant. The new grinding circuit was completed and started operating December 15, 1961.The grinding circuit consists of a 7 1 x 101 Hardinge Rod Mill, and a 7 1 x 101 Hardinge Ball Mill. In series with the rod mill is a 16"" x 24"" Denver Duplex Jig, and two of these jigs are also in parallel with the ball mill. The rod mill product is classified by a Kreb cyclone, the oversize going to the ball mill. The ball mill is in closed circuit with this same cyclone. The jig products are amalgamated daily, and the amalgam barrel tails are returned to the ball mill for regrind. Arsenious oxide (As203) is one of the reagents used in amalgamation. Approximately 39 ozs. per day is used.The cyanide circuit consists of a 481 x 121 thickener, three 24' x 24' agitators, two 141 x 161 drum filters and a Merrill Crowe precipitation unit.The Krebcone overflow is thickened to 60 - 62% solids. Hydrated lime, along with a settling agent is added to the thickener. Some of the overflow water from the thickener is returned for use in the jigs. The balance of this overflow water goes to waste. To the thickened pulp entering No. 1 agitator, barren solution is added, along with sodium cyanide and hydrated lime. Cyanide strength is held at 0. 9 - 1. 0 lbs/ ton solution and lime at 0. 8 lbs/ ton solution. The lime content usually drops to 0. 5 lbs/ ton in No. 3 agitator. The two drum filters are in series and are washed with barren solution. The discharge of No. 3 agitator is fed to No. 1 filter and the discharge of No. 1 filter is repulped in barren solution and feeds No. 2 filter. No. 2 filter discharges to tails, The filtrate is clarified, deaerated and the gold precipitated. One hundred to two hundred tons of barren solution are bled to waste each day. The ore contains 1 % Arsenopyrite and 1. 5% Pyrite."

Jan 1, 1964

By P. Czaja

The paper presents a patented and copyright protected concept of constructing a shaft lining that goes through rock masses having strong rheological properties and being susceptible to leaching. In the case of salt layers, especially at significant depths (over 900 m) the relative convergence of the heading contour may amount to 40 ?/year. That results in the fact that any other method of securing the shaft lining, e.g. by making it flexible, will not be sufficient to ensure the stability of the shaft reinforcement geometry. In the new shaft lining concept the excessive rock creep into the outbreak inside the shaft diameter will be removed by local and controlled leaching of the shaft cheeks by means of fresh water directed through a porous medium at the contact layer behind the watertight tubing lining. The paper presents the structure of such a lining and an outline of the construction technology. In order to implement such a lining, a typical tubing will be applied. Separate design and manufacturing will be required for the technological rings used to control the leaching process behind the lining.

Aug 1, 2013

By Ji Wang

Reflective in-seam wave detection has the advantages of a far detection range and wide applicability. It has been successfully used in detection of many abnormal geological structures in work-faces, such as faults and collapse columns. However, a reflective in-seam wave is a dispersion wave. It has weak energy and is always covered by the direct in-seam wave. In the past, underground seismic explorations were not able to image the opposite roadway using reflective in-seam waves. To solve this problem, we propose a new method of reflective in-seam wave imaging based on adaptive dispersion filtering. This method processes the reflective in-seam wave using a filter with the parameter of transmission distance. The degree of similarity of the filtered and the explosion signal is used to estimate the transmission distance and image the reflective objects. We test and verify this method using real underground seismic data. This research is helpful for the detection of coal mine goafs and abandoned roadways in work-faces or in front of tunneling ends.

Aug 1, 2013

By R. R. Rogers

Introduction The subject of cathodic protection is not new. In 1824 Sir Humphry Davy, in publishing the results of his investigations for the British navy, pointed out that copper could be protected from sea-water corrosion by connecting it electrically with zinc or iron. Since that time much work has been clone in this field, particularly in the protection of metals from the action of sea water, neutral brines, and treated and untreated waters. Special mention should be made of the successful protection of underground pipe-lines which formerly were badly corroded by the water in the ground. So far, magnesium alloy and zinc anodes have been the most popular. However, fairly recent work has indicated that aluminium anodes will give good service under certain conditions. The principle of cathodic protection has been applied extensively in coating steel articles with zinc and in cladding aluminium alloy sheet with pure aluminium. A valuable discussion of the fundamentals and applications of cathodic protection recently was presented in the Corrosion Handbook. A useful list of references was included in the article.

Jan 1, 1949

By John Emery, George Wang

Research and applied utilization activities for the increased use of ferrous and nonferrous slags in construction are presented. The overall use of blast furnace slag is relatively well known for a range of construction applications from aggregates to slag cements. In contrast to blast furnace slag, which is volumetrically stable and straightforward in its construction uses, steel slag contains hydratable oxides that can result in volumetric instability that must be dealt with through appropriate steel slag aging, testing and quality control to ensure its appropriate use. Particular care must be taken to prevent potential steel slag expansive behaviour in confined applications. Quality requirements and guidelines on steel slag expansivity to further the use of steel slags, with demonstrated acceptable performance, are outlined. There is a full range of proven construction uses - from aggregate to cementitious materials - for copper, nickel and phosphorus nonferrous slag. The use of air-cooled nickel slag is presented, based mainly on practical highway construction experience. It has been shown that air-cooled, crushed nickel slag can be an excellent aggregate in granular base, engineered fill and hot-mix asphalt. There is a good potential for increased ground, granulated copper and nickel slags use as supplementary cementitious materials that is being developed, which takes advantage of the 'latent energy' content. The scope of a new technical text in preparation on the technology of slag utilization is reflected throughout to provide a practical context for the engineer.

Jan 1, 2004

By Sadan Kelebek, S. O. Fekete, Gerhard W. Heinrich, Peter F. Wells

"For many years, rejection of pyrrhotite at the milling stage has been a viable method for sulphur dioxide abatement. Pyrrhotite rejection options have included the use of selective pyrrhotite depressants in flotation; a depressant which has recently come into use is diethylenetriamine (DETA). This reagent has been the subject of recent research and development efforts in the processing of nickel-copper sulphide ores.In the present study, adsorption trends for DETA have been monitored under the dynamic conditions of flotation using a spectrophotometric method which has been adopted for this purpose at Falconbridge Limited. The results indicate that the adsorption of DETA is quite fast and in the majority of cases, accounts for the disappearance of 75-95 % of this reagent from pulp's liquid phase. The adsorption decreases linearly with an increase in the DET A dosage from 100 git to 600 git. The tailings produced in flotation tests were subjected to washing with deionized water at 60 °C to examine the desorption of DET A. These results indicate that the amount desorbed increases with increasing DETA dosage used during flotation but is less than 7 per cent of that adsorbed. It was found that adsorption of DETA alone, even at relatively high levels, does not always cause depression of pyrrhotite. A new combination of reagents identified in the metallurgical laboratories of Falconbridge Limited utilizes sulphur dioxide with DETA. These reagents together are capable of efficient depression of pyrrhotite on a consistent basis."

Jan 1, 1995

By N. W. Martison, J. E. Hawley

"The Moulton Hill deposit is in the Eastern Townships of Quebec, 3 miles northeast of Sherbrooke. It is complex, both structurally and mineralogically, consisting of a narrow, irregular, mineralized zone that has been traced for a length of 600 feet, and in places to a depth of 1,000 feet, containing copper, lead, and zinc sulphides with a low content of gold and silver. It lies in a series of highly schistose micaceous rocks, believed to be of Ordovician age, but the mineralization is probably post-Lower Devonian. New details of the structure of the ore have become available since it was first described (1) , and as these show some striking peculiarities a further discussion is here merited .As detailed elsewhere, the deposit was discovered in 1942 as a result of regional geological studies followed by the application of electrical geophysical methods.Actual production began in July, 1944, and ceased in June, 1945. During the period July, 1944 to June, 1945, 75,643 tons were milled§, yielding the following:"

Jan 1, 1954

By S. Sundararajan, J. Brousseau, P. Bocher, M. Galopin, N. Barka

This research is committed to the prediction of the hardness profile produced by induction heating, using a computer-modeling software. The paper presents the simulation of the induction hardening process to analyse the sensitivity of the induction parameters on the hardness profile of a low alloy steel specimen. The developed numerical model includes the coupling effect between electromagnetic and thermal fields, and takes into account the non linear behaviour of the material properties. The study applies an enlightened experimentation method to build the feasible domain of the process and to achieve predictive empirical modeling. The ultimate goal is to replace the trial and error method that is usually used for the development of new parts, by costless experiments with the numerical model. Further development of this approach will lead to the computation of the residual stresses and finally to the assessment of the mechanical properties of the part. The end result will be the ability to shorten the development time and to improve the quality of the hardened part.

Jan 1, 2006

By Art Hamilton

The Zn-Pb-Cu-Ag ore deposits of the Boundary and N-5 zones near Bathurst, New Brunswick, occur in a polydeforrned volcano-sedimentary sequence that is part of the Ordovician Tetagouche Group. Massive and disseminated sulfides are hosted by an argillaceous to cherty sedimentary sequence that is stratigraphically Wlderlain by a siliceous fragmental unit and is overlain by a feldspar-rich crystal tuff and related tuffaceous rocks. The deposits have a low iron sulfide content relative to that of most stratabound sulfide deposits of the Bathurst-Newcastle mining district. The ore is commonly associated with chlorite- and talc-rich sediments. The N-5 deposit is considered to be the fault-displaced extension of the Boundary deposit. The Boundary deposit is estimated to contain 891 000 t grading 3.31% Pb, 7.96% Zn, 0.32% Cu and 44 g/t Ag; the estimate for the N-5 zone is 330 000 t grading 3.24% Pb, 7.15% Zn, 0.33% Cu, and 37 g/t Ag. The ore is processed at 1000 tpd at the Heath Steele mill.

Jan 1, 1992

By G. Barbery, P. Dauphin

"In order to obtain reproducible and reproducible results in batch flotation, researchers have tried various approaches, from normalized testing, to modifying existing cells, and even designing new machines. The paper reviews the basic concepts that must be fulfilled in a laboratory flotation machine, and present the FLOTOMATEC design, which results from five years of testing and development. In addition to providing accurate measurements of air flowrate, power consumption, agitation speed, the cell eliminates most operator induced errors. Results of experiments comparing FLOTOMATEC to a conventional cell, as well as reproducibility tests are given. Introduction The use of batch flotation machines in mineral processing research and development is very common. These machines have been used for many years without almost any change in their design, instrumentation or automation. Various authors since Raffinot (1960) have criticized the available designs, especially with respect to the large errors that are introduced by the manual mode of operation. Barbery et al. (1986) have presented a review of the problems involved in laboratory testing in flotation research.Batch laboratory machines should have the following characteristics:"

Jan 1, 1989