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By Fidelis T. Suorineni

HydraboltTM is a Swellex-type dowel support element developed and manufactured by New Concept Mining in South Africa. Like Swellex, the HydraboltTM is a folded tube which can be inserted into a larger diameter hole without pushing. It is then activated by injection of high pressure water which inflates the folded tube to intimate contact with the walls of the borehole at a set pressure, normally 25 MPa. Unlike Swellex however, the set water pressure at the end of the inflation is maintained throughout the life of the dowel. An integral non-return valve makes this possible. The HydraboltTM is being investigated as a possible stress change measuring cell. This paper presents the results of closed form solutions, numerical modeling and laboratory test to date. Preliminary results indicate that the HydraboltTM can be used as a stress change monitoring cell in addition to its conventional role as a rock mass reinforcing element. If successful, the HydraboltTM will supplement microseismic monitoring systems in rockburst-prone ground conditions where they will give quantitative stress change data for both mine design model calibrations and means for proactive safety measures.

Oct 1, 2010

By A. Ockewitz, A. Trondl, D. -Z. Sun

"Numerical simulation of extrusion processes offers an efficient method for tool design and optimization of geometries and properties of extruded parts. However, until now there are few systematic investigations about influences of material model and different parameters e.g. for friction and thermal processes on calculated local and global responses. Since extrusion processes are essentially influenced by friction between billet and extrusion tools, new friction tests were performed in this work to develop a reliable friction model. Compression and torsion tests were performed at different temperatures and velocities to calibrate the material model for extrusion simulations. Extrusion processes for circular rods and U-profiles were conducted at TU Berlin with backward and forward extrusion for different extrusion ratios, billet temperatures, product velocities and cooling conditions. This work focuses on numerical simulations of the extrusion tests with the FE code HyperXtrude. Based on the calculated distributions of local strain, strain rate and temperature the recrystallized volume fraction and grain sizes were calculated with empirical models and compared with the experimental results from optical micrographs and EBSD scans. The calculated total and friction forces and temperatures were compared with the experimental results and the deviations between experiment and simulation were analyzed.INTRODUCTION Extruded aluminum components are widely used in vehicle constructions due to light weight and manufacturing consideration. Local mechanical properties in the components are inhomogeneous as a consequence of the spatial distribution of microstructure which is influenced by numerous factors like material composition, temperature, tool design, friction, extrusion ratio and speed during the extrusion process. For the optimization of the extrusion process with regard to all these factors numerical simulation can be an essential tool. Based on results of finite element simulations of the extrusion process the microstructure in the extruded components can be predicted and then the resulting mechanical properties can be numerically determined instead of by costly trial and error methods. The aim of the work presented in this paper is the development of a numerical method for the simulation of extrusion processes with modeling of microstructure."

Jan 1, 2018

By Farid Mirahadi

Forecasting productivity of construction operations is a difficult but crucial task in planning construction projects. Over the past decades, many models have been developed to forecast productivity for different construction operations. Models made up of several functional relations and controlled by a specific number of control rules are more in line with human reasoning and logic. Neural-Network-Driven Fuzzy Reasoning (NNDFR) structure as one of these models shows a great performance for modeling datasets among which clear clusters are recognizable. Lack of the compatibility of conventional NNDFR with fuzzy clustering algorithms besides the insufficient attention paid to the optimization of number of clusters in this model, created a potential area for further research. The main contribution of the proposed model is to develop a modified NNDFR system to model construction data. To this end, Fuzzy C-Means (FCM) algorithm is substituted for K-means in NNDFR structure, and its parameters such as the number of clusters and weighting exponent are optimized through genetic algorithm. The proposed model is further verified through simulation of a construction operation in which several qualitative and quantitative factors are considered. Its implementation to the case study shows a considerable improvement of model performance with lower Mean Squared Error (MSE). The developed model assists researchers and practitioners in utilizing historical construction data to forecast productivity of construction operations with a high accuracy that could not be obtained by traditional techniques.

Aug 1, 2013

The concept and practices of co-extraction of coal and methane have emerged in recent years to improve coal mining safety and productivity, utilise methane resources, and reduce fugitive emissions in environments that involve multiple coal seams with low gas permeability. The system of co-extraction integrates two previously separate operations of coal extraction and methane drainage. The coal mining operation reduces the coal seam gas pressure and creates strata fractures that enhance gas migration and capture from mine workings and surrounding coal seams. An effective methane drainage operation produces a consistent and quality clean energy product and, at the same time, reduces the methane concentration in underground workings and the methane content and pressure in the adjacent coal seams. This is a significant benefit in preventing gas explosions and outbursts, and promotes a safer and more productive coal mining environment. In addition, the co-extraction with enhanced utilisation of coal mine methane directly leads to a reduction in greenhouse gas emissions. Presented in this paper are key results and outcomes of a major Asia Pacific Partnership project carried out from 2008?2012 by the Commonwealth Scientific and Industrial Research Organisation in collaboration with Huainan Mining Industry (Group) Co. Ltd., to develop and demonstrate advanced technologies at Pansan mine, Huainan, that promote the concept and practices of co-extraction of coal and methane. A comprehensive approach was adopted to assess fundamental strata and coal seam methane conditions during mining, and optimise mining sequences and coal mine methane capture systems. The project has not only demonstrated a practical approach and procedures of advanced co-extraction of coal and methane systems but also delivered significant benefits and outcomes in improved mining safety and efficiency, increased methane capture and utilisation, and reduced fugitive methane emissions at the Pansan mine. The total mine gas drained increased from 25.36 Mm3 in 2007 to 47.0 Mm3 in 2011, and the mine gas utilisation increased from 4.94 Mm3 in 2007 to 21.15 Mm3 in 2011. The improved methane capture resulted in reduced coal and gas outburst risks and methane concentration levels at the mine workings, provided a safe working environment for coal production, boosted the mining efficiency, and eliminated methane related incidents over the last few years at Pansan mine.

Aug 1, 2013

By A. C. Ter-Oganesyants, N. N. Anisimova, G. P. Kotukhova, G. N. Dylko

The process utilized at Norilsk Nickel Polar Circle Division for treating slimes from the electrorefining of copper and nickel was developed in the late nineteen fifties and has survived without any fundamental changes. This technology is a combination of pyro and hydrometallurgical operations to produce PGM concentrates that are sent away for refining. The characteristic feature of the current technology is multiple-stage, extended cycle treatment with significant incomplete production, low labour and automation efficiency and poor hygiene and sanitary conditions. To eliminate all negative aspects mentioned above, specialists of Norilsk Nickel Polar Circle Division have developed a new hydrometallurgical process for treating electrolytic slimes. The main steps of the flow sheet developed are autoclave leaching of the slimes and electrochemical opening-up of a cake from autoclave leaching. The implementation of the new process will allow Norilsk Nickel Polar Circle Division to shorten the process cycle 4-5-fold thus reducing the volume of incomplete production, considerably increase labour efficiency, simultaneously improving working conditions, upgrade the final concentrate, reducing costs and increasing PGM recovery during refining and, ensure higher security of precious metals by employing automated processes and vacuum sealed units.

Jan 1, 2004

By D. H. Schwarz

The performance of proton exchange membrane (PEM) fuel cells depends on catalyst layer composition and structure. Experimental observations reveal that state-of-the-art catalyst layers consist of microporous agglomerates of carbon-supported catalyst sites bound together by polymer electrolyte. In between the agglomerates are macropores which provide pathways for the transport of gaseous reactants. In this work, three-dimensional, multicomponent and multiphase transport computations are performed using a computational fluid dynamics (CFD) code (FLUENTTM) with a new PEM fuel cell module, which has been further improved by taking into account the detailed composition and structure of the catalyst layers using a multiple thin-film agglomerate model. In this model, it is assumed that thin films of polymer electrolyte and liquid water surround the catalyst sites. The results of CFD computations show that transport limitations associated with the thin film of polymer electrolyte and the presence of liquid water in the catalyst and gas diffusion layers have substantial negative effects on PEM fuel cell performance. Also, the results of computations with variable distributions for a given precious metal loading show that, in general, uniform catalyst loading provides the best fuel cell performance.

Jan 1, 2005

By K. .. Sadayappan

The increasing cost of selenium made the conventional low lead alloys such as EnviroBrasses not economically viable. Efforts were made to develop newer alloys without selenium for plumbing applications. Recently a new copper alloy, C89836, was introduced. This paper discusses the properties of the new alloy including mechanical properties at ambient and elevated temperatures as well as corrosion behaviour.

Jan 1, 2007

By Lorant B. Geller

Sixteen miners died tragically at the Paymaster gold mine at Timmins, Ontario in February, 1945, when a badly corroded hoist rope broke. The investigation of the Royal Commission that followed arrived at a number of recommendations (Investigations, 1947) aimed at avoiding future disasters of this kind. One consequence was the development, and legislated use in Canada, several decades ago, of powerful electromagnetic (EM) instruments for the nondestructive testing of mine shaft wire ropes. The authors have been involved for many years in the design, production, and testing of EM instruments (Geller and Udd, 1990 and 1992, Geller and Kitzinger, 1991, Geller et al., 1993). Since the mid-1990s particular attention was paid to the design and operational results obtained from the computer- controlled portable MagnographJ II wire rope tester (Geller et al., 1995 and 1998). In the present article the authors summarize further hardware- and software-related developments of this instrument. Further, an account is given of the results obtained from the most recent design known as the PermaScanJ testing system. This is also a computerized dual-function system. In it, however, the sensor head is designed primarily, if not solely, for permanent installation and for remotely controlled operation. This represents a basic departure from traditional designs, which were intended for ad hoc temporary installations. The remotecontrolled instrument described in this paper has now been in operational use for more than 4 years.

May 1, 2003

By E. G. Gaylord

THE material improvements which have been made in the practice of exploiting oil and gas reservoirs in the United States during recent years may be attributed largely to: (1) The necessity for drilling deeper wells at costs not much greater than was formerly expended on shallower wells. (2) The necessity for producing oil at a lower cost per barrel. (3) A growing recognition of the importance of the nature of production practice upon ultimate yield of oil and gas. The first two of these factors result, to a large extent, from the fact that a greater proportion of new development has been deeper development, and these wells have been drilled in the face of progressively lower per well allowables. In California, for instance, maximum allowables have declined from 400 barrels per day in March, 1938, to 156 barrels per day in September, 1940, and during this same period some 125 wells were drilled to the deeper 10,000-foot producing horizons discovered during this time. The third item listed above results from our increasing knowledge of the basic factors which influence the amount of recovery we may expect from reservoirs. In addition to the longer-range planning now being undertaken by the more prudent operators, State proration and conservation laws have focused attention upon the importance of methods conducive to obtaining progressively greater quantities of the hydrocarbons in place. In a paper of this length it will be possible to discuss only a few of the recent advances. An effort has been made to select the more important of these and to indicate, where possible, the factors which have made these advances possible.

Jan 1, 1941

By I. Ciabatti

Inorganic salts of hexavalent iron (ferrate (VI)) are versatile reagents for water and industrial effluent treatment because of the strong oxidising effect of the ferrate ion (FeO42-) and the well-known coagulation properties of the resulting ferric ion. Among other applications, ferrate can effectively remove arsenic, cyanide and phenols from industrial effluents. Furthermore, ferrate salts can be prepared from ferrous sulphate, a common byproduct of the steel and titanium industries, and possibly from other iron wastes. Notwithstanding their many potential advantages, the industrial-scale application of ferrate salts, such as potassium ferrate (K2FeO4), for effluent treatment has been hindered by the difficulties inherent in their synthesis and stabilisation. Within a project co-funded by the European Commission, the large-scale synthesis of stabilised potassium ferrate was realised through a new synthesis process, and different applications of the resulting ferrate to effluent and wastewater treatment are under investigation. This paper reports the results of the application of stabilised potassium ferrate for the purification of textile effluents. Laboratory and pilot-scale tests were carried out and the performance of the ferrate was compared to that of chemicals currently used in wastewater treatment. According to these experiments, potassium ferrate is a promising reagent for an effective treatment of textile and other industrial effluents.

Jan 1, 2006

By Q. J. Xu

In blasting sensitive areas, the use of traditional blasting for rock fracture is restricted. Soundless cracking technology has been presented to achieve rock fracture instead of blasting. However, when the diameter of a borehole is larger than 50 mm, it is very dangerous that the soundless cracking agent (SCA) will have a tendency to gush from the borehole, which also leads to cracking failure. In this paper, a new large scale borehole soundless cracking technology is presented, using a new enlarged drill bit and mechanical plugging, which could solve the hole gush problem. Experiments were made to measure the expansive pressure of the SCA working in boreholes of F40 mm and F100 mm. The difference between two sizes of cracking phenomenon was compared and analyzed to show that large scale borehole soundless cracking has larger expansion pressure and faster reaction speed than traditional soundless cracking. Based on the experimental data, finite element analysis was utilized to study the stress concentration and stress distribution between two neighboring large boreholes in several media during the cracking process. Using the data from experiments with finite element numerical simulation, the brittle material fracture condition was analyzed to design the parameters of the borehole mesh. With the theoretical analysis, the technological process and reference parameters of large scale borehole soundless cracking were proposed, including the borehole spacing, burden distance, depth of the borehole and so on. Then a single rock was cracked with the new enlarged drill bit and new plugging, and the results proved the feasibility of the new large scale borehole soundless cracking technology, which achieved the expected goal of improving the cracking ability and reducing the cracking time. This paper presents a new efficient rock cracking method for blasting sensitive areas, and which could apply to mining engineering, demolition engineering, excavation engineering and other engineering applications where there is a demand soundless and non-vibration fracturing of rock.

Aug 1, 2013

By M. Sukhram

This paper presents a technique to determine the direction of velocity in liquid aluminum (Al) by measuring the temperature distribution within a cylindrical rod while it is inserted into the flow. The heating pattern of the rod is a result of the interaction of the thermal fields of the rod with the liquid Al. This interaction freezes aluminum onto the cylinder in a characteristic pattern and as a result the temperature response within the rod also follows a distinctive heating pattern. Monitoring the temperature within the cylindrical rod as a function of spatial and temporal coordinates, the direction of velocity can be inferred. Experimental research work involving liquid Al was conducted at the University of Toronto using the Revolving Liquid Metal Tank (RLMT). The RLMT is a resistance furnace which can hold up to 50kg of liquid Al. In this RLMT tangential velocities up to 0.35m1s can be generated. Experimental data for different superheat and magnitude of velocity demonstrate that the sensor records different heating patterns under different fluid flow conditions. Using the transient temperature information, the direction of velocity of the molten Al flow field can be detected.

Jan 1, 2011

By J. H. Ambrose

Introduction The copper smelter of the Hudson Bay Mining and Smelting Company, Limited was constructed to handle the concentrates produced by the concentrator, the residues from the zinc plant, concentrates from Sherritt-Gordon Mines, Limited, and other custom material that might be available. Construction work was started in 1929 and the first concentrates were smelted in November, 1930. From that time until June, 1931, the operations were more or less of an experimental or tuning-up nature. In designing the smelter, it was believed the following tonnages would be available for smelting per day: Copper Tons Content H. B. M. & S. Co. concentrates 331 14.0 per cent H. B. M. & S. Co. zinc plant residues 77 2.5 per cent Sherritt-Gordon concentrates 200 20.0+ per cent Consideration was given to wet-smelting the charge, but, in order to give greater flexibility to the operation, it was finally decided to roast the concentrates before smelting. Briefly, the smelter equipment consists of three Nichols-Herreshoff roasters, one reverberatory furnace, two Peirce-Smith converters, a Walker casting wheel, and a four-unit Cottrell plant, two units' for the roaster gases and two for the converter gases. A general plan of the smelter is shown in Figure 1. Prior to the commencement of smelter operations, a stockpile of about 9,000 tons of concentrates had been built up by the concentrator and the old pilot-mill. The zinc plant was in operation, but the equipment for drying the residues at the smelter had not been completed. Sherritt-Gordon did not commence their shipments of concentrates until April, 1931. The only flux available was barren sand from a pit ten miles south of Flin Flon, adjacent to the railway. Several small deposits of metal-bearing siliceous ore had been discovered in the district, but none of these were sufficiently large to be considered as a source of smelter flux. At the beginning of March, 1931, the entire stockpile of concentrates had been consumed, and available tonnage for smelting was limited to the daily production of the concentrator.

Jan 1, 1935

By Samuel Frimpong

Green house gases have become a major concern within the international community over the last two decades due to their potential link to global warming. Carbon dioxide (CO2) is the principal greenhouse gas. In the Kyoto Agreement, Canada has committed to reduce emissions by 6 % below 1990 levels by 2012. This presents a serious economic challenge to Canada and Alberta. Over the next decade, oil sands production expansion, population and industry growth and energy demand will increase CO2 emissions. Current and future CO2 emissions and their economic implications in Alberta will be critical in formulating a comprehensive and balanced policy for dealing with concerns in this area. Disposal of carbon dioxide (CO2) in land aquifers is a potentially viable option for Alberta in dealing with long-term CO2 emissions. Studies have confirmed the existence of appropriate aquifers in the Alberta Basin for CO2 storage over a long geological period. Carbon dioxide is an ideal candidate for aquifer disposal because of its high density and solubility in water at relatively high pressures. In this study, the authors develop a computer simulation model of a scaled aquifer disposal system. The scaled model consists of an injector well, aquifer environment with dominant Ca++ and Mg++ cations. Liquefied CO2 is injected at an appropriate pressure and concentration through an injector well model. The injected CO2 migrates from the point of contact between the injector well and the aquifer domain to the main regime of the latter. The rate of migration is a function of porosity, permeability, cations, aquifer fluid flow regime and CO2 injected pressure. These models are validated using flue gas data from the 546 MW Wabamum Power Plant in Alberta. The total energy requirements for aquifer CO2 disposal system are distributed between a minimum of 105 MW and a maximum of 172 MW, with a mean of 132 MW and a coefficient of variation of 10%. The results show that there is significant variability in all the energy requirements for the CO2 disposal system. The total energy requirements for the disposal system as a fraction of the total power generated by the Wabamum plant of 546 MW could be between 0.19 and 0.32. This is a very significant energy requirement and thorough analysis must be carried out to reduce this variability and energy requirements.

May 1, 2001

By D. O. Tansey

This paper will describe the mechanisms involved in delay blasting and how they are applied with the use of D.S.B. It will examine the control of potential damage resulting from detonations, and show how good fragmentation and efficient recovery of this material blasted can be achieved.

Jan 1, 1979

By Tim J. Carew, Dennis C. Martin

"One approach to stabilization of rock slopes is to place a buttress at the toe of the slope to provide additional resisting forces and increase the length and strength properties along the failure surface. This paper describes the rock mechanics and mine planning aspects of incorporating a buttress of intact rock in the lower part of the slope as part of the slope design for the south wall of the final pit at Cassiar Mine. Stability analysis techniques and results are described. Analyses results have indicated that, in order to maintain steep over-all slopes in the final pit, a buttress of intact rock shoud be incorporated into the lower section of the slope until late in mine life. The effect of the buttress is to flatten the slope and reduce the slope height thereby improving slope stability. The mining plans would be such that the buttress would be mined out during the last four months of mining when the consequences of instability would be least severe.IntroductionThe concept of using a buttress to stabilize slopes has been used in mining and civil engineering construction in may locations (Richards and Stimpson, 1977). Most buttresses involve placement of coarse rock fill timber cribs or other material as a load at the toe of an already unstable slope to provide forces which resist failure by counteracting driving forces and increasing the length and strength of the failure path.This paper describes the geotechnical and mine planning aspects of incorporating a buttress of intact rock in the design of the south wall of Cassiar Mine. The effect of an intact rock buttress is to flatten the slope and reduce the slope height, thereby improving slope stability. No actual construction is required other than normal excavation of the slope. The ""mine plans would be such that the buttress would be mined out at the end of mine life when the impact of instability would be less severe and additional ore might possibly be recovered from the slopes. Mining of the buttress could induce instability at the very end of mine life at a time when maximum ore extraction has been achieved."

Jan 1, 1986

By J. Bouchard, M. Levesque, D. Georges-Filteau, P. Radziszewski, G. LeBlanc

"Grinding mills are infamous for their extremely low energy efficiency. This paper reports the results of an investigation that characterized energy outputs in industrial grinding mill circuits. It identifies and discusses the potential for recovering energy from grinding circuits. Agnico-Eagle Goldex Division, Mine Canadian Malartic, and New Gold New Afton Mine participated in the study by providing operating data for three semi-autogenous grinding mills and four ball mills. Results showed that on average, 79% of the supplied electrical energy was converted to heat absorbed by the slurry, 8% was lost through the drive system, and approximately 2% was transmitted to the ambient air. Only 9% of the input energy was actually used for grinding. The remaining 91%—wasted as heat—could potentially be recovered using suitable technologies or integrated energy management systems. This topic remains to be further investigated. ¦ KEYWORDS Comminution processes, Energy recovery potential, Grinding mills RÉSUMÉ Les broyeurs sont tristement célèbres pour leur rendement énergétique médiocre. Cet article présente les résultats d’une étude qui caractérise les rendements énergétiques des circuits industriels de broyage et examine les possibilités de récupération d’énergie dans les circuits de broyage. La mine Goldex d’Agnico Eagle, Mine Canadian Malartic et la mine New Afton de New Gold ont participé à l’étude en fournissant des données de fonctionnement pour trois broyeurs semi-autogènes et quatre broyeurs à boulets. Les résultats montrent qu’en moyenne 79 % de l’énergie électrique fournie sont convertis en chaleur absorbée par la pulpe, 8 % sont perdus dans le système d’entraînement et environ 2 % sont dispersés dans l’air ambiant. Seuls 9 % de l’énergie primaire sont, de fait, utilisés pour le broyage ; les 91 % restants (perdus sous forme de chaleur) peuvent potentiellement être récupérés à l’aide de technologies adaptées ou intégrées dans des systèmes de gestion de l’énergie. Cette question demeure toutefois ouverte. ¦ MOTS CLÉS broyeurs, potentiel de récupération de l’énergie, procédés de comminution INTRODUCTION Grinding is largely recognized as a very inefficient process; energy efficiency estimates range from < 1 to 2% (Fuerstenau & Abouzeid, 2002; Tromans & Meech, 2002, 2004) when comparing the input energy to that required for generating new mineral surfaces. Criticizing an “ill definition of the reference for the output energy,” Fuerstenau and Abouzeid (2002) proposed a “more meaningful baseline” would be “the energy for producing new surface area by the ¬mens.” Based on this reference, they concluded that “the ball mill is reasonably efficient energetically,” exhibiting an efficiency of approximately 15% for quartz."

Jan 1, 2019

By B. Coupal, F. D'Hennezel

Sorption measurements show that peat moss has much stronger affinity for oil than straw, which is currently used. Microscopic studies of peat moss show a highly porous and fibrous material, and this property, associated with the phenomenon of selective absorption, had been used to absorb oil. Laboratory experiments show that peat moss absorbs up to eight times its weight of oil. Field tests have proved that peat moss can be an effective absorbent and can be used on a large scale.

Jan 1, 1972

By Jorgen Elbrond, Yve Lizotte

"A mine evaluation method based on the use of a computer program that models mining with an open-ended dynamic program is presented in this paper. It is demonstrated with an example how the method is applied, how some of the decision variables are related in the particular industrial environment and how these decision variables affect the economic benefits of mining.IntroductionTwo distinguishing characteristics make mining a particular industrial environment: exhaustible resources of a given ore deposit and heterogeneousness of the ore grade spatial distribution in the ore deposit. These characteristics, inflation, uncertainty and cyclical price variations which greatly affect estimated cash flows also contribute in rendering difficult the evaluation of the economic outcome of mining at the preliminary planning stage.Decision variables and their ranges are associated with the mine plan; basically, they include choices of the mine&apos;s nominal capacity (mining and milling), the sequencing of mining through the deposit, the ranges of possible production rates and cutoff grades, and the stockpiling policies. The mine&apos;s nominal capacity must be decided at the planning stage, but this capacity choice must take into account flexibility to modify other decision variables as mining commences and uncertainty resolves.Although it is generally accepted in discounted cash flow analysis that the sequence of mining must proceed from the richest to the lowest-grade stopes (with correspondingly ajusted cutoff grades), this may not produce optimum benefits when cyclical price variations are considered.Mining rates and cutoff grades can also be adjusted to changing economic conditions, taking into account the limited resources of the ore deposit. Thus, when prices are thought to be in the trough of a cycle, production can decrease to preserve ore for expected greater future profits. When prices rise, mining rates can increase possibly even over the mine&apos;s nominal capacity. In both cases, the machinery&apos;s effectiveness shall not be-optimally utilized; this will be reflected particularly by the variations in the concentrator&apos;s metal recovery and the concentrate grade output."

Jan 1, 1982

By Lei Pan, Roe-Hoan Yoon

"Sea water flotation is becoming a reality due to shortages of fresh water. To better understand the mechanisms involved in sea water flotation, we have studied the effects of KCl and MgCl2 on the surface forces present in the wetting films of water formed on hydrophobic surfaces. The measurements have been conducted using the force apparatus for deformable surface (FADS), which is capable of measuring both the surface and hydrodynamic forces responsible for bubble-particle interactions. The results obtained with the gold surfaces hydrophobized with butanethiol (C4SH) show that the wetting films of Ultrapure water do not rupture despite the relatively high water contact angle (??= 80o) and the presence of a long-range hydrophobic force with a decay length (D) of 25 nm in the film. The film is metastable with its equilibrium thickness (he) at 140 nm, where the repulsive double-layer force is equal in magnitude to the capillary force as shown in Figure 1. The film loses its metastability and ruptures in a 10-2 M KCl solution, in which the double-layer force decreases substantially due to the decrease in Debye length (?-1) while the decay length of the hydrophobic force remains as large as 23 nm.The effects of MgCl2 has also been studied using a C4SH-coated gold surface with a water contact angle of 87o. It has been found that in a 10-4 M solution double-layer force decreases due to the decrease in the negative ?-potentials and Debye length, which should help destabilize the wetting film. However, the film remains stable due to the decrease in the decay length of the long-range hydrophobic force from 45 nm in Ultrapure water to 14 nm in the MgCl2 solution. Thus, the results obtained in the present investigation support the view that the difficulties in sea water flotation may be due to the presence of MgCl2 rather than the presence of NaCl in sea water (Ramos, et al., 2013)."

Jan 1, 2016