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By O N. Antzutkin, W Forsling, K J. Pike an

The adsorption mechanism of three different O,OÆ-di-alkyl-dithiophosphate (dtp) collectors, K[S2P(OR)2] with R = Et, i-Bu and i-Amyl, on the surface of synthetic chalcocite (Cu2S) was studied by means of solid-state 31P CP/MAS NMR spectroscopy. The morphology changes on the conditioned Cu2S surfaces, in the collector concentration range 0.1 - 10 mM, were also monitored with scanning electron microscope (SEM). In order to assign Cu(I)-dtp species on the surface of Cu2S, the corresponding bulk Cu(I)-dtp compounds, which are clusters of the monovalent copper containing either Cu6(antiprismatic) or Cu8(cubic) cores, were synthesised, and characterised by means of solid-state 31P CP/MAS and static 65Cu NMR. Further investigations on the crystal habits of the bulk systems were carried out by powder x-ray diffraction and SEM. A comparative analysis of the 31P chemical shift and chemical shift anisotropy (CSA) data estimated from the experimental NMR spectra of the polycrystalline bulk Cu(I) dialkyldithiophosphate complexes was used for assigning the 31P resonance lines in the NMR spectra of the collector treated Cu2S powder samples. The species formed on the synthetic Cu2S surfaces were assigned to polycrystalline phases of: Cu6L6 with L = Et2dtpû, Cu6L6 and Cu8L6(S) with L = i-Bu2dtpû, and Cu8L6(S) with L = i-Amyl2dtpû. A heterophase autocatalytic step process of both formation and growth of solid CuxLy (L = R2dtp, x = 6 or 8 and y = 6) complexes on the collector treated Cu2S surface is proposed. A possible role of the oxidised form of dithiophosphate collectors, bis[di-alkyl-thiophosphoryl]-disulfane (disulfide), is discussed in terms of a specific self-redox reaction. The second order quadrupolar lineshapes in 65Cu NMR spectra were simulated and the interaction parameters, CQ and hQ, for the bulk dialkyldithiophosphato-copper(I) complexes were obtained.

Jan 1, 2005

By G J. Wilkie, P A. Revell

The R&D landscape for ore pre-concentration technologies within mining is characterised by the development of individual technologies and point solutions. This presents METS and mining companies with the combined challenge of understanding how to apply pre-concentration technologies to create maximum value, and how to sustainably integrate the technologies into their businesses to maintain the value. The paper will consider the requirements of an integrated pre-concentration system and presents a portfolio of R&D projects that have co-developed and integrated a suite of new precencentration technologies and methodologies across the mining value chain. Focus areas include in-situ orebody characterisation, blast design, real time cross belt mineral sensing, and consideration of how much data needs to be acquired in order to make value based decisions between ore pre-concentration options. An ore pre-concentration workflow is presented to demonstrate how additional optimisation opportunities are enabled both by moving decision points further upstream in the value chain, and by integrating the concepts of pre-concentration into the design of mineral processing equipment. Additionally, several research projects examine the non-technical factors that present barriers to uptake of new technologies within mining companies. Organisational culture, risk management and socio-political factors are discussed and a set of management tools are presented that allow organisations to self-assess their readiness for new technology uptake, along with process models to assist management with identifying and navigating the ecosystem of stakeholders that are decision makers in the use of pre-concentration technologies.

Nov 10, 2020

By F Shi, W Valery

WMC Fertilizers (WMCF) operates a Beneficiation Plant at Phosphate Hill in Queensland, Australia. The plant consists of two-stages of crushing, followed by a wet scrubbing and desliming circuit. Ore is then fed to a tertiary crusher and a milling/classification circuit, with the final product going to a swing-lift thickener and storage tanks. From the slurry storage tanks, the phosphate rock is fed to a horizontal belt filters which dewater the phosphate rock ahead of a hemi-hydrate phosphoric acid plant. The water soluble recovery of phosphate in the phosphoric acid plant is dependent on the moisture content in the filter cake, as this governs the wash water addition to the hemi-hydrate filters. Since commencement of operation, the moisture content of the filter cake fed to the phosphoric acid plant has been higher than design reducing the phosphoric acid plant recovery and at times reducing the throughput through the phosphoric acid plant. The moisture content in the filter cake can be decreased by reducing the generation of fines in the milling and classification circuit (classified as û38 micron material). This paper identifies the causes of fines generation in the Phosphate Hill beneficiation plant. It discusses the options that were assessed to minimise fines generation, and outlines the results to date of circuit changes undertaken at Phosphate Hill.

Jan 1, 2003

Techniques and results achieved during the excavation of the Melbourne Underground Rail Loop (HURL) are summarised and discussed in the context of the various restraints present in a typical urban construction project. Mechanical methods (as distinct from those utilising blasting)accounted for the bulk of the excavation. Ground support was critical in this particular geological excavation setting, but is not discussed in detail except insofar as it constitutes a restraint to excavation progress.

Jan 1, 1978

The use of systematic review methods, derived from System Safety approaches used in the North American nuclear power industry, have become an accepted approach for seeking "approval" for new coal mining equipment and operational changes in NSW. Based on risk analysis, they provide a valuable and needed framework for the reduction of losses related to people, equipment and production.

Jan 1, 1991

By King D, Dickinson S. B, Matheson R. S

Graham Hall and V. M. Cottle (Rosebery, Tas.) : In their paper on "The Mineralized Rift Valleys of Tasmania", Campana, Dickinson, King and Matheson have summarized a wealth of data from many sources. In proposing the new concept of a rift valley structure, they claim to have found a new guide to regional ore control and distribution in North-west Tasmania.Although the authors acknowledge suggestions made by us prior to publication of the pa:per, we are still at variance with their conclusions. We are not convinced that a rift valley structure exist~d when the Ordovician conglomerate was deposited. We are unable to find evidence for Cambrian deposition in a rift valley or reason to project the structure to embrace Hercules, Rosebery, and "possibly" Mt Bischoff.That the Great Lyell Fault (the authors' Owen Rift Fault) is a promising place to look for ore is not a new idea, but the existence of important ore deposits away from the structure reveals its inability to provide an adequate explanation of regional mineral distribution. A well-known structure that does have an influence on ore deposition is not discussed by the authors.STRUCTURAL CONSIDERATIONSThe great thickness of coarse unsorted Ordovician conglomerate lying in an elongate but narrow belt of country is presented as evidence of its deposition centrally within a rift valley, the position-of which is now said to be outlined by resistant slabs of the conglomerate. The marginal shears of the rift are said to show up well along the edges of the conglomerate.

Jan 1, 1959

By Tsuchida N

The history of world nickel production has been affected significantly by the supply and demand situation and fluctuation of LME price of nickel metal. In the beginning of the 1980s, the decline of price and demand lead to the withdrawal of un-competitive producers and the shrinkage of the production capacity. During the same period, Sumitomo Metal Mining maintained the production level with continuous improvement of the traditional matte electrorefining process. However, Sumitomo has recognised that the continuous improvement alone does not promise us the ability to catch up with rapid changes in the world. In the meantime, Sumitomo intensively researched chloride hydrometallurgy and has developed the chloride process for the nickel refining. This includes the solvent extraction and chloride electrowinning in the mixed sulphide process and the chlorine leach of the anode slime arising from matte electrorefining. In the late-1980s, Sumitomo Metal Mining decided to develop a new nickel refining technology based on chloride hydrometallurgy. The new process was designed from the comprehensive aspects involving safety and the environment. Construction of the plant for the matte chlorine leach electrowinning (MCLE) process was commenced in 1991. The MCLE plant with a capacity to 2000 tonnes per month has been commissioned at Niihama since 1992. The process has provided high productivity, overall good economics and high quality of electrolytic nickel produced. After the establishment of the process, Sumitomo has maintained continuous improvement of the new process and has attained the best practice of the work classification.

Jan 1, 1996

By Wright S

Single pellets of mixed lead-zinc concentrate containing up to 20 % lead were roasted in the temperature range of 800-1100¦C. Variables studied included pellet size (from 9-8 to 3-2 mm diameter), gas flowrate past the pellet (from 0.05 to 5 ms t), composition of the atmosphere and the effect of additives such as zinc oxide and silica. After defined periods of time, the pellets were removed from the furnace, quenched and submitted for chemical, XRD, SEM and microprobe analysis. The oxidation of the zinc sulphide followed a shrinking core model. Temperature measurements showed that very high pellet temperatures were experienced at the start of an experiment but after 5-10 minutes these approached a constant temperature. The lead loss from the pellets was then constant with time. Thermodynamics predicted the presence of two bands of lead material in the reacted layer of the pellet. These were found in practice. The lead loss from the pellet occurred from the outer oxysulphate layer via the vaporization of lead oxide polymers. The vapour pressure of PbO, and the loss of lead, was dependent on temperature and bulk gas concentrations of SO2 and 02. At 1100¦C the addition of silica greatly reduced the loss of lead from the pellet. Physical factors such as pellet diameter and gas flowrate past the pellet affected the particle dynamics. These results were found to vary in accordance with the predictions of the Froessling equation.

Jan 1, 1989

By Li YQ, Yoon RH

The photoresponse of natural mineral pyrite and galena electrodes has been studied in aqueous solutions on freshly fractured surfaces (some fractured in situ) using moderate overvoltages. When fractured in situ, the electrode potential of both minerals instantly drops several tenths of a volt. Pyrite exhibits a spontaneous anodic photocurrent at fracture, which indicates upward band bending (depletion layer) on the n-type electrodes. The negative surface charge responsible for the depletion layer is believed to arise from a surface state that is intrinsic to pyrite surfaces, possibly modified by hydroxide ion adsorption. The flat band potential, Vty, of pyrite is at approximately -1.0 V (SCE) at pH 9.2 but to reach V(b, pyrite has to be cathodically decomposed. In contrast, galena assumes the flat band potential at fracture. Subsequent polarisation of galena at potentials positive of Vth produces an anodic photocurrent (upward band bending) and polarisation negative of Vro a cathodic photocurrent. Most of the galena electrodes studied were degenerate n-type and at potentials negative of Vtb, no cathodic photocurrents are observed, indicating the bands cannot be bent downward, consistent with the Fermi level at the surface merging with the conduction band edge near Vn,. Several were close to intrinsic, with the photocurrent changing sign near Vn,.

Jan 1, 1993

Increasing demands on quality of metallurgical grade alumina and for lower production costs led to the development of a new fluid bed calcining process. The process, jointly developed in Germany by Vereinigte Aluminium Werke A.G. and Lurgi Gesellschaften m.b.H., takes advantage of modern chemical engineering methods such as counter-current flow of combustion air and solids, direct heat-exchange between combustion air and fine solids and near stoichiometric combustion of oil in a fluid bed. Using a two-stage Venturi-type suspension preheater for heat-recovery from combustion flue- gases, the circulating fluid bed technique with internal oil combustion at 2.2000 F for the calcining step and 'a five-stage fluidized bed cooler for heat recovery from calcines, the process gives an outstanding heat- efficiency. In a first industrial plant for 560 sh. t. alumina per day heat consumption figures of less than 1.400 BTU/lb A12O3 were achieved.

Jan 1, 1971

Coal has been mined in New South Wales for nearly 200 years and prior to 1970 the vast majority of this coal was mined from underground mines using bord and pillar or similar systems.Since 1970 there have been two notable changes in coal production trends in New South Wales as can be seen from Figure 1.1. The steady growth in coal mined by open cut methods. Open cut output grew from about seven per cent of the State's output in 1970/71 to 43 per cent in 1990/91.2. The steady growth in coal mined by the longwall method. longwall output grew from negligible amounts in 1970/71 to 48 per cent of underground production in 1990/91. mines operating longwall units produced 61 per cent of underground production in 1990/91.

Jan 1, 1992

Since the earliest recorded prospecting of the 1860's mineral exploration and mining in Fiordland has been discouraged by the formidable physical difficulties presented by its isolation, extremely rugged relief, treacherous coastal waters and generally unfavourable weather conditions. Government assistance was often sought by the miners and prospectors but little, if any, support or encouragement was received after the initial period. During the 1840's decorative marble was quarried at Caswell and Dusky Sounds. A prospector discovered and attempted to mine copper sulphides to the north of Dusky Sound (Parks Mineral Beds) and near Mt Solitary. A small Pb, Zn, Cu, Ag, Au bearing quartz reef was discovered and driven on in the granite coast line of Preservation Inlet (Bradshaws Reef) and the ore roasted on site. Alluvial and quartz lode gold was discovered at Preservation Inlet in the 1890's and led to the recorded recovery of 11 000 oz of mainly lode gold. Falloff in grades with depth, thinning and splitting of the reefs and the high mining costs at this location led to a virtual abandonment of the field by 1906. In the late 1950's and early 1960's the geology of Fiordland was mapped by the Geological Survey at 1:250 000 scale, but field work was largely confined to the shore lines of the coast and fiords. In view of the physical difficulties it is not surprising that mineral exploration and mining up to 1970 was limited to the scant attention outlined above.

Jan 1, 1977

A new two-metre column self-heating test procedure has been developed at the University of Queensland, which clearly shows the hot spot development phases that take place in bulk coal self-heating. The column results provide a more reliable indication of the self-heating propensity of coal than small-scale index tests. At the same time, off-gas evolution patterns associated with hot spot development are obtained, including the recognition of hydrogen evolution from oxidation at temperatures less than 80¦C. Subtle differences in off-gas evolution from self-heating between gassy and gas-drained coal are also apparent. This new approach to coal self-heating assessment offers an opportunity to further the understanding of the complexities of spontaneous combustion and will enable more accurate risk assessment for the coal industry.

Jan 1, 2005

By James D

Fletcher Challenge Limited through its subsidiary Grampian Mining Co Ltd has carried out an ore evaluation of one of New Zealand's largest known deposits of ilmenite located at Barrytown on the west coast of the -South Island, New Zealand.The ilmenite is located in a beach sand environment which has previously been mined for gold. Two analytical techniques were developed to quantify the resource. Considerable difficulty was experienced in this phase of the evaluation due to the presence of major inclusions within the ilmenite grains. Wet and dry concentration circuits, utilizing spiral, wet magnet, high tension and plate electrostatic separators have been G47designed to produce ilmenite from the ore. Studies to utilize the titanium content of the Barrytown ilmenite have been made. Recent work has been directed towards a titanium dioxide pigment process.

Jan 1, 1986

By Morrison R. D, Davis J. J, Fraser B, Kojovic T

1991 saw the completion of a three-year $1.1 million research and development program in mineral sands beneficiation, funded in two associated projects by the Australian mineral sands industry through AMIRA, and carried out by the Julius Kruttschnitt Mineral Research Centre. It is believed to be the largest R&D project in mineral sands ever conducted by a university research group. It covered dry plant operation, and delivered several products to the industrial sponsors, including: ò A detailed characterisation of the radiation properties, mineralogy and size distribution of inhaleable dust arising in dry plants. ò New process models of magnetic and electrostatic separators. ò New on-line instruments for elemental assay (in association with AMDEL) and bulk conductivity measurements of dry process streams. ò Demonstration and evaluation of the Magstream magnetohydrostatic separation technology.

Jan 1, 1992

The nickel ores mined in New Caledonia for one century are mainly silicate ores. These ores are nickel enriched saprolites, formed by partial weathering of peridotites (predominantly harzburgites and some dunites), serpentinised to varying degrees. Saprolites constitute the lower horizon of lateritic soils, sometimes up to 100 metres thick, developed on peneplains now greatly modified by erosion. Saprolites are generally overlain by laterites, a more weathered horizon, where the main components are iron oxy-hydroxides with a low nickel grade. The structure of saprolites depends essentially on the serpentine content of peridotites and, on the other hand, serpentine minerals may have a high nickel content and, so, represent important nickel bearing minerals in silicate ores. Two types of serpentines can be found in nickel ores from New Caledonia: ò primary serpentines, formed by hydration of olivine at temperatures below 400¦C, during overthrusting of peridotites in late-Eocene (Paris, Andreieff and Coudray, 1979), are generally very abundant; ò secondary nickeliferous serpentines, associated with other sheet silicates in garnierites, are now relatively scarce but garnierites were selectively mined one century ago, because of their high nickel grade.

Jan 1, 1996

By Albano C, Antila A, Flykt B

A method for relating operating variables and dewatering parameters of Thunes disc filters in the LKAB pelletizing plant at Malmberget in Sweden, via empirical mathematical models is described. Near orthogonal experimental design was used, where all independentvariables were allowed to span over their domain of variation and pseudo-randomly distributed among the experiments. The dewatering parameters are dependent on many variables and instead of using a traditional mechanistic model, an empirical model based on multivariate data analysis was chosen. The way of expressing the relation is by regression coefficients obtained from partial least square regression (PLS). Two empirical models were generated. The models were validated using an extra set of 56 experiments. The dewatering parameters were related to the design variables with few experiments, and user-friendly response surface methodology was used to determine the optimal conditions.

Jan 1, 1989

By V K. Singh, G Sural

The problem of spontaneous heating/fire is very common in coal mines all over the world. The coal industry faces many problems day by day due to the occurrence of spontaneous heating in the open pit coal mines. Presently, about 70 per cent of total coal production in Indian mines is being carried out by open pit mining. Fire in coal, particularly in open pit mines not only causes irreparable loss of natural wealth but also damages the surface structures and pollutes the environment. It is well known that 75 per cent of the fires occur due to the spontaneous combustion of coal. Spontaneous heating is a very common occurrence in coal mines and is a major factor contributing to mine fire. The liability of coal to spontaneous heating causes many serious problems before, during and after mining. In opencast mines, coal immediately oxidises and catches fire due to the intrinsic characteristics of coal, such as low rank, high moisture, high volatile matter, presence of sulfur in the form of pyrites, low crossing point temperature (CPT) and ignition point temperature (IPT) value and less incubation period. In opencast mines, when the coal benches are left idle for a longer time, heat accumulation takes place in favourable conditions and sometimes leads to fire. The purpose of this paper is to present the different successful case studies regarding the safety management of open pit coal mines from occurrences of spontaneous heating/fire.

Jan 1, 2007

By J Pearce, B Miles, V de San Miguel

Incorporating industry best practice waste rock management methods can be a relatively straight forward task when preparing management documentation, such as an acid and metalliferous drainage management plan (AMDMP). However, a key difficulty is the incorporation of industry best practice methods that are practical and non-compromising on their purpose from a scientific standpoint. The second key difficulty is the implementation of these practical methods as various operational groups/departments are typically relied upon to execute and take ownership of different tasks or procedures.One approach to overcoming these difficulties is to develop an AMD Operations Manual (AMDOM) that:•Incorporates, where practicable and without compromising scientific merit, existing processes that those groups/departments ultimately responsible for the execution of the management action are familiar with; and•Provides standalone, simplistic, and easy to follow procedures for site personnel. The purpose of the standalone operations manual is to ensure site personnel who are responsible for undertaking specific procedures, have clear, step-by-step instructions for an individual procedure, without requiring interpretation and understanding of the more comprehensive AMDMP.In adopting a best practice approach to waste rock management for their iron ore mine in Western Australia’s Pilbara region, Roy Hill developed an AMD Management System that is comprised of both an AMDMP and an AMDOM that are connected through adaptive management processes. The Roy Hill iron ore mine, which has a mine life of 18 years, will require the management of more than three billion tonnes of waste rock.CITATION:de San Miguel, V, Miles, B and Pearce, J, 2018. Practical waste rock management at the Roy Hill iron ore mine, Western Australia, in Proceedings Life-of-Mine 2018, pp 80–82 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 25, 2018

By M Miller

Operators of nickel laterite pressure acid leach and gold pressure oxidation technology frequently employ a series of steam condensing heaters to preheat the leach feed slurry. The heaters are an economic pinch point û although the thermal performance of the heaters is critical to overall process viability and operating cost minimisation, they are also a significant capital item and must be sized accordingly. Despite this, discussions of the factors underlying heater design are conspicuously absent from technical literature, and existing operations feature a conflicting range of heater sizes and configurations. This variety would suggest that at least some of the chosen heater designs are oversized. As part of its detailed design stage, the Ravensthorpe Nickel Project (RNP) constructed and tested a pilot plant heater to develop an understanding of the heating process and to ensure that the RNP heaters were appropriately sized. This testwork used RNP slurry at design density and viscosity on a 450 mm diameter, 6500 mm high column. The pilot plant testwork demonstrated the intrinsic efficiency of the direct steam condensation heating process, which was essentially independent of slurry density and viscosity. Presence of non-condensable gases in the steam phase decreased the heat transferred in certain circumstances, but heater performance remained consistent with thermodynamic limitations. Stagewise heat transfer within the column was rapid, and suggested either a very high slurry surface area or excellent heat transfer within the slurry phase. While the testwork did not set out to distinguish between these effects, physical evidence pointed to droplet formation in the inter-tray shower zone, giving a high heat transfer area. For scale-up purposes, the key facts were that the heat transfer rate was not limited by using high viscosity slurries and heaters could be designed using the principles applied to the smaller of those in existing operations. This paper discusses existing slurry heater designs, the current understanding from open literature, the pilot plant testwork, results and analysis, and scale-up to commercial sized equipment.

Jan 1, 2005