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By Singleton T

Increasing world competition puts pressure on sales volumes and prices. This in turn reduces potential profit margins. This in turn increases the focus on costs.Increasing demands on quality and service puts pressure on delivery performance - the right product at the right time. This in turn reduces the scope for errors and delays - and this in turn increases focus on equipment reliability. In the mining industry, both costs and equipment reliability have one significant thing in common - they are driven substantially by maintenance.

Jan 1, 1998

The Geological Survey of the U.S. Department of the Interior is primarily a domestic agency whose responsibility is furnishing impartial data and analyses to the public, private, and academic sectors of the Nation. The Survey concentrates on earth-science issues, such as mapping the land surface, determining the quality and quantity of water resources, estimating the nation's endowment of fuel and nonfuel minerals, and predicting and mitigating geologic hazards, such as those inherent in the tectonically active Pacific Rim. One of the challenges to managing this program is striking a sustainable balance between concentrating on the problems society wants solved today and investing in the research that seeds our vitality for the future. The Geological Survey's role in the Pacific results from the Nation's geography and the Nation's long standing interest in and commitment to the region. The longest segment of the U.S. coastline borders the Pacific Ocean, one of our states is a Mid-Pacific island chain, our lands are 80 degrees--nearly one-fourth--of the Pacific perimeter, and our Exclusive Economic Zone (EEZ) underlies significant parts of the eastern, northern, and central Pacific waters. Thus, the program of marine and terrestrial science operating in these areas make substantial contributions to the world's growing understanding of the Pacific realm.

Jan 1, 1990

The developments in hydrocyclone classification in the milling circuit at Bougainville Copper Limited are discussed. A major change in cyclone size and improve- ments in operating conditions have been made. Test work has been carried out to assess the classification performance of a modified Linatex cyclone, Wemco cyclones and a two stage cycloning circuit. The use of a scalping cyclone, to remove coarse material from the present overflow product for regrind, has also been investigated.

Jan 1, 1978

The optimum plant capacity for a new mine is usually based on empirical studies or ærules of thumbÆ, subject to confirmation by detailed scheduling of the proposed mining operation. The mining industry has a record of poor returns on investment and a high rate of project failure using these methods, with under-performance in grade being a common experience. The assumption that æeconomies of scaleÆ will result from increasing throughput rates needs to be balanced by an awareness of the adverse effects of increasing the rate beyond a level that issupportable by the resource. For each scale of operation considered, it is a reality that for any intended head grade, at the associated intended cut-off grade, the actual head grade achieved will fall as the mining rate increases. This effect is known to people at operations but is not recognised in current ore reserve estimation methodology. Once recognised, this dependency of head grade on mining rate can be quantified and used to establish the economically optimum mining and processing rate for a new project. A simple analysis is proposed, which may be extended to detailed spreadsheet modelling for financialoptimisation.

Jan 1, 2002

By Forssberg E

This paper presents the experimental results on the effects of slurry Theology on ultra-fine grinding by a stirred ball mill. The amount of dispersant, slurry density and the particle size were selected as the parameters. The viscosity of dolomite-water slurry was measured by rotational viscometers. It was found that by adding enough dispersant, the effect of particle size from 1 to 10 pm on the slurry theology could be eliminated, but a strong effect of slurry density (tested for a range of 65 to 75 wt per cent) remained. The use of dispersant transformed the slurry from Bingham plastic flow to dilatant flow, which reduced the yield stress to zero, but increased the viscosity at higher shear rates. During the milling process, the viscosity was stable. The yield stress, however, increased suddenly from zero after a certain milling time. The mill operation stopped at the point where the yield stress increased due to poor slurry fluidity. The milling efficiency was found to be higher at a lower amount of dispersant addition or a lower slurry density within the experimental limits.

Jan 1, 1993

Various aspects of the history of mining at The Zinc Corporation, Limited (ZC) and New Broken Hill Consolidated Limited (NHHC) are examined. There are some discussions about the various methods used to mine the pillars left after the primary mining operations, with an enphasis being placed on the more modern pillar mining methods. Some new pillar mining proposals are presented. INTRODUCTION In the past, pillar reserves at ZC/NBHC have been scheduled for mining by labour intensive and high unit cost mining methods. These methods include both undercut and fill and overhand square set timber stoping. Recent technological advances in large diameter longhole drilling and high charge density explosives have culminated in the mechanised Vertical Crater Retreat (VCR) mining method and this method has been successfully used for the extraction of two pillars at NBHC and more stopes are planned. However the use of VCR methods for mining pillars at ZC/NBHC is restricted to approximately 50 per cent of the total pillar reserves and it appears that high cost methods will be needed to mine the remaining Pillars.

Jan 1, 1983

By Hendrix JL, Nelson JH

Three ores (sulfidic, oxidized and carbonaceous) were analyzed to determine the effects of leaching time, ore depth, and ore mineralogy on cyanide species concentration. NaCN solutions were percolated through opaque columns filled with milled ore. Column design made liquid sample collection possible from various depths at specific times. The concentrations of weak acid dissociable(WAD) and total cyanide, Fe(CN)63 , Fe(CN)64 , SCN , and Cu(CN)43 were determined for each sample. Extended percolation time led to increases in WAD cyanide concentra- tions and decreased SCN and Cu(CN)43 concentrations regardless of ore depth. WAD cyanide concentration decreased while Fe(CN)64 concentra- tion increased with ore depth. Highest concentrations of Fe(CN)64- SCN and Cu(CN)43 were found in the sulfidic ore, with expected low WAD cyanide concentrations. Lowest concentrations of Fe(CN)64 , SCN 3 and Cu(CN)4 were found in the oxidized ore. Intermediate concentra

Jan 1, 1988

Ventilation challenges are often encountered when an underground mine expands to new zones and it often is the case to make a thorough review of the existing system and assess immediate and future airflow needs at the desired quantity and quality. An unexpected mine plan change that calls for increased development and production from new areas can impose a strain on the existing ventilation system. Budgetary constraints can also demand creativity in design on the mine ventilation engineerÆs part. Since the addition of several mining horizons it had become obvious at the Meikle mine that something had to be done to increase airflow quantity and quality in the old main zones because most of the ventilation resources had been channelled for development in the new mining horizons. An airflow assessment of the existing system had to be performed and it was determined that the airflow quantity had to be increased by at least 30 per cent and the quality of the air had to be improved by reducing nuisance and respirable dust and at the same time reducing the airflow temperature before it was used in a few mining zones. At the conclusion of the airflow assessment it was determined that a third centrifugal fan would be installed on a new 3.05 m diameter borehole from surface to underground. By a careful study of temperature conditions over time it was determined that an evaporative cooling spray chamber would be sufficient to cool the airflow down from the high dry bulb temperatures observed down to saturation at the wet bulb temperature. At the same time excessive nuisance dust generated as a result of the airflow travelling a long way in a haulage drift will be knocked down in the spray chamber resulting in cool, clean air in the mining districts. Expansion of the existing surface ammonia refrigeration plant was out of the question for several reasons. The fact that the airflow was hot and dry meant that evaporative cooling spray chambers could achieve lower working temperatures at a very low cost compared to the expansion of the chilled water plant. The expansion of the ventilation system at Meikle mine and the use of evaporative cooling spray chambers were demonstrated to be very successful and the information presented in this paper can be of benefit to other mines experiencing the same ventilation problems as was the case at the Meikle mine.

Jan 1, 2005

Traditionally, the predominant drilling method in open pit mining has been large hole rotary drilling using cumbersome, inflexible equipment offering merely limited scope for improvements in pit design and overall costs. By contrast, the recent development of comparatively light high-pressure down-the-hole hammer crawlers has paved the way for new ideas and trends. High penetration rates coupled with superior mobility and fast set-ups contributing to substantial productivity gains have resulted in a renascence for this drilling method in open pits. The ability to cover a wide range of hole diameters and angles gives designers unique drill pattern possibilities especially when establishing steep and stable pit slopes. As pre-split holes, buffer holes and production holes all can be drilled by using the same equipment, there are, there are obvious advantages in production scheduling as well as in materials handling and service. This paper presents some case stories, which will demonstrate the benefits and improvements that the introduction of new drilling methods and equipment has brought to open pit mining operations.

Jan 1, 2003

By R Berry, A Escolme

"Predictive geometallurgical models are being developed for the Productora Cu-Au-Mo deposit based on geochemistry to reflect variability in Cu species based on Cu sequential leach data (ie oxide, transitional-oxide, transitional-sulfide, sulfide and non-recoverable Cu).Productora, located in the coastal range of northern Chile, is a magmatic-hydrothermal tourmaline breccia-hosted, structurally controlled Cu-Au-Mo deposit hosted by a thick sequence of Jurassic rhyodacitic volcanic rocks. North and north-west striking fault sets control the distribution of mineralised breccias. Alteration is widespread, complex and pervasive. Hypogene alteration assemblages range in composition from distal magnetite-amphibole, to sodic-calcic, to sodic, to phyllic, to proximal potassic. Low-temperature advanced argillic assemblages are locally juxtaposed next to proximal high-temperature K-feldspar-tourmaline assemblages. The dominant hypogene Cu phase is chalcopyrite.A simple Cu species classification scheme based on sequential leach data and S per cent was devised to account for non-recoverable Cu (ie non-sulfide Cu), which is insoluble in weak acids. Through machine learning, a proxy for this Cu species classification scheme was developed based on: depth, Ca per cent, Cu per cent, Fe per cent, K per cent, Mn ppm, S per cent and Ln(Cu/S) plus logged regolith class, thus allowing classification to be extended to areas of the deposit where no sequential leach data are available. The modelled data has been used to generate deposit-wide 3D models for Cu species classification.The validity of the proxy Cu species classification model is being tested against the results of flotation analysis. Initial results indicate that geochemical proxies can be used to successfully predict Cu species class and provide a high density of classification data.CITATION:Escolme, A, Berry, R and Hunt, J, 2016. Predicting Cu Species Classification Using Geochemistry at the Productora Cu-Au-Mo Deposit, Chile, in Proceedings The Third AusIMM International Geometallurgy Conference (GeoMet) 2016, pp 113–118 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Jun 15, 2016

By M, C A. RosiFre, R C. Figueiredo e Silva

Jaspilites and underlying basalt contacts of the Archaean volcano- sedimentary Grpo Parß Group, Carajßs, host giant iron mineralisation in the ~100-km long, E-W trending Carajßs fold. Preliminary, unpublished geochronological data point to a Palaeoproterozoic mineralisation event. Geochemically, jaspilites are typical volcanogenic banded iron formations. Basalts exhibit evidence of spilitic seawater interaction. Iron-associated hydrothermal alteration of mafic rocks was induced by fluid infiltration in amygdales, with development of chlorite- and hematite-dominated zones. In the case of jaspilites, iron mineralisation encompasses: partial replacement of jaspilitic microcrystalline hematite by blasts of martitic magnetite; jasper recrystallisation, producing fine-grained, hematite-free granoblastic quartz; martite recrystallisation, forming lobate¦subhedral hematite; pervasive porosity development by quartz-chert leaching; incipient cavity filling by microlamellar hematite; and advanced filling by coarser, euhedral and comb-textured, tabular- shaped hematite.Peak hydrothermal ore textures indicate typical epithermal-crust conditions, supported by preliminary fluid-inclusion calculations at 160 - 200¦C. Such temperatures and extreme fluid-to-rock ratios during alteration must have exceeded the ambient metamorphic conditions, with the infiltrating fluid relatively hot and capable of leaching SiO2. Therefore, mineralisation developed over exhumed, Archaean, brittly deformed rocks, with mineral associations representative of very low- to low-grade metamorphism. Considering that chlorite (¦talc) abounds in mafic rocks; hydrothermal albite is developed; dolomite fills veins and vugs; the typical rare-earth-element (REE) pattern of jaspilites is significantly modified in higher-grade hard hematite ores (higher LREE); pyrite, copper sulfide minerals and rare gold occur in association with carbonate-quartz-rich alteration zones, it is suggested that an alkaline, H2O-Fe-CO2 mineralising fluid dominated, also containing species like S¦Cu¦Au. Peak-mineralising conditions are likely to have resulted from a single, evolving fluid, via incipient- through advanced-stage alteration phases. The porous, high-grade soft hematite-type ore (SH), rich in microlamellar and anhedral hematite, must have derived from interaction with this relatively hot SiO2-leaching fluid, whereas the high-grade massive hard hematite-type ore (MH) developed due to closer fluid-rock temperature equilibrium conditions, attained by mineral reactions, with relative increase in the Fe/Σcations ratios allowing the precipitation of subhedral-tabular hematite that partially cements the soft-hematite ore. SH and MH hematite ore types must thus reflect intermediate and high fluid:rock ratios, respectively. Since the N5 deposit is to date understood to contain the largest amount of the MH ore, its units are interpreted as the loci of the highest fluid:rock ratios in the district. Preliminary mineralogical information regarding the S11 deposit of the Serra Sul (south range) implies higher-temperature conditions. The near-equant grain size and the granoblastic intergrain relationship, coupled with the presence of riebeckite, augitic pyroxene and garnet, suggest hornfels textures. The data collected, though still relatively sparse, permit the speculation that the immense driving force for the Carajßs world-class iron deposits was a relatively shallow, igneous-related hydrothermal system. If such a model is correct, then the Carajßs Palaeoproterozoic iron deposits could represent an end-member of the iron oxide-copper-gold hydrothermal system in the province.

Jan 1, 2005

With some notable exceptions, marine placers located just below, or just above, present sea level, are responsible for much of today's production of detrital ilmenite, rutile, zircon, and other minerals of value. The purpose of this paper is to discuss the paleogeographic and paleo-oceanographic factors which may have determined the location of presently submerged marine placers. These factors-include changes in sea level, burial by recent marine sediments, stream capture and other i changes in drainage patterns, and recent changes in climate. Selected geologic situations in the Yellow Sea off the coast of Korea, in the Atlantic Ocean off the coast of Portugal, in the Bering Sea off the coast of Alaska, and in the Arabian Sea off the coast of India, will be used to illustrate the author's point of view.

Jan 1, 1980

By Henderson J

Iron ore samples selected from the Deepdale, Iron Prince and Mt. Newman ore bodies have been pelletised on a pilot scale plant and subsequently reduced under laboratory conditions by hydrogen or carbon monoxide. Pellets approximately 1 cm in diameter have been reduced by hydrogen over the temperature range 5000- 900¦C and the results examined by thermogravimetric, microscopic, electron probe and x-ray techniques. After an initial time delay it was found that up to 95% reduction the rate of reduction could be described by a transport con- trolled porous model, in which the effective diffusivities of hydrogen in theòpr¦duct layer and the reaction zone are filar. Independent measurements of effective diffusivity supported the values obtained from the reduction data. ve 95% reduction the rate decreased markedly due to the formation_of retained wustite or fayalite. Comparison with reduction by carbon monoxide over the temperature range 7500 - 900¦C showed that the rate eduction by carbon monoxide was approximately five times slower than the rate by hydrogen. The rate of reduction was found to be a function of the properties of the pellets, which may account for the ely conflicting results that have been obtained in previous investigation on porous pellets.

Jan 1, 1970

By I Ametov, G Levay

It is now common practice to use substantial amounts of recycled water in mineral processing plants to minimise both environmental discharge and withdrawal of fresh water from often limited water resources. Recycled water additions to process water are frequently obtained from sources such as tailings dams, tailings thickeners and concentrate dewatering. It has been suggested for some time that addition of recycled water to process water will impact the quality of the process water and that changes in water quality may influence flotation performance. To date, investigations of process water quality changes as a result of water recycling have been limited and as a consequence there are very few data available to substantiate these ideas. Thus the impact of recycling on process water quality remains largely unquantified. Over recent years we have conducted water quality studies at a number of mineral flotation plants with varying degrees of water recycle. This paper describes the results of these investigations, including data which suggest that build up of salinity due to recycling while it occurs, is reduced by fresh water make-up. The fate of flotation reagents such as collectors, promoters, frothers and flocculants during process water recycling has also been investigated. Results show that process water concentrations of these reagents vary from plant to plant, but that, with the exception of frothers, most reagents are generally removed from the system through mineral adsorption. In general, the results of these investigations suggest that recycling process water will not result in continuous increase in solute concentrations as appears to be the commonly held view.The effects of changing water quality on flotation can vary. In many cases, flotation conditions can be optimised to suit the water quality, while in others, treatment of the water may be necessary to obtain acceptable plant performance.

Jan 1, 2009

The collapse of the I.T.C., the subsequent fall in the price of Tin, and the lifting of quotas saw the Renison concentrator resuming full seven- day operations at maximum capacity in 1985/86. Performance was sus- tained in terms of grade and recovery, and in some areas improved, over this period. A further challenge was declining head grades, and the need to treat higher proportions of less amenable ore types. The complexity of the flowsheet and the method of mining and ore handling predisposes the process to unstable operation, and solving this problem comprises a major component of the current development effort. The concentrator has an imbalance of capacity between processes, and excess in some areas is being adapted to enhance the capacity of others. Magnetic susceptibility of various minerals is being exploited to greater effect. Significant performance gains are achievable by improving exist- ing unit process efficiency, particularly in grinding, gravity processes and Cassiterite Flotation. This paper reviews the metallurgical developments, both recently implemented and planned for this year, which have contributed to main- taining Renison Limited in a competitive position in the post I.T.C. Tin industry.

Jan 1, 1988

By Frazer E. J, Lwin T

Measurements of coulombic efficiency (QE) for zinc electrodeposition were carried out under mass-transfer-controlled conditions using a rotating disc electrode in synthetic acidic zinc sulphate solutions. Various methods of solution preparation and purifi- cation were investigated using reagents vary- ing from analytical grade to high purity; the purest solution was obtained-by dissolving 99.9999% zinc (Koch-Light) in sulphuric acid solution (BDH Aristar). Improvements in sol- ution purity did not necessarily increase QE, especially where apparently beneficial impur- ities (e.g., Pb) were initially present. The maximum QE obtainable through variation of temperature (T), current density-(i) and elec- trode rotation rate was established using a statistical optimization technique. The QE was determined principally by T and i, with significant interaction between these factors in the highest purity solution. QE contours, which gave an overall view of solution per- formance, were constructed and predictions about the response under conditions similar to plant practice were made. Wark's Rule (the dependence of QE on zinc/acid ratio) was obeyed in the purest solution over the range of composition commonly encountered in zinc plants. High concentrations of Na2SO4 and K2SO4, which occur in some plant solutions, were found to increase QE marginally ("1.2%). The intrinsic effects of individual impurities such as Cu and Ni were evaluated by additions (up to 5 ppm) to the purest solution. Decreases in QE were found to be minimal at the impurity levels normally encountered in zinc plants.

Jan 1, 1987

By D B, M A. Sares, D W. Coulter, D C. Peters

This presentation discusses NASA-funded research on the ability of hyperspectral remote sensing to map diagnostic acid rock drainage (ARD) mineralogy that adversely affects water quality within watershed and to determine the relative contributions of natural ARD sources of metals and acidity to that drainage. Ground-based reflectance spectroscopy, combined with water chemistry, is used to identify mineralogical and chemical variations throughout a watershed. Integrated with hyperspectral data acquired from airborne remote sensing platforms, such as the NASA Airborne Visible Infrared Imaging Spectrometer (AVIRIS) sensor, a methodology has been developed that should improve environmental assessments and tracking of impacts on and from drainages. Phase I of this project focuses on a drainage basin (Lake Creek), tributary to the upper Arkansas River in central Colorado, which is impacted by natural acid rock drainage from areas of high-sulfide hydrothermal alteration. This project builds upon research and inventory efforts by the Colorado Geological Survey (CGS) to identify hydrothermal alteration that is the primary source or is contributing to acidic and toxic drainage in Colorado. This presentation will cover ground and airborne hyperspectral remote sensing techniques and results and water analyses for seasonal high-flow and low-flow conditions in Lake Creek. Identifying correlations between mineralogy, especially mineralogy that can be identified through airborne remote sensing, and water chemistry is a key focus of this project. Of particular interest are low-pH iron phases such as jarosite, ferrihydrite, schwertmannite, copiapite, and transitional amorphous phases as well as AlOH phases from higher, although still acidic, pH environments which are observed to mix with the iron precipitates within the streams draining from the hydrothermal systems. Drainage in the Lake Creek watershed derives from the Grizzly Peak caldera (Oligocene), which exhibits extensive hydrothermal alteration. Alteration types include silicic, quartz-sericite, quartz-sericite-pyrite, advanced argillic, and argillic. By understanding the chemistry of a naturally impacted drainage and its relationship to the surrounding geology, the project goal is to allow more efficient and complete identification of such sources in mineralised terranes through remote sensing technology.

Jan 1, 2003

By R Hindstr÷m

The demand for iron ore has increased dramatically in the last years and is forecast to remain on a stable high production level for years to come. ItÆs expected that the world economy is facing a stable continuous growth of iron ore to two billion tonnes and more over the next decades (Beddows, 2007). Furthermore it is expected that the existing and known high-grade ore resources will decline, and the iron ore industry will be forced to implement more and more advanced beneficiation plants. As a consequence of the more complex beneficiation requirements, there will be a need for modern solutions for iron ore dewatering that are reliable mechanically as well as cost effective and with high capacity per unit at the same time. Conventional vacuum filtration methods have been the most prevalent in fine iron ore dewatering. Product quality needs, lower ore grades, complex mineralogy and energy costs have resulted in iron ore producers seeking better solutions for dewatering, in particular pelletising feed. New advanced filtration methods have been introduced to the market. This paper describes how these modern methods are answering the needs of the industry. Performance of advanced dewatering technologies (pressure filtration and ceramic capillary action filtration) for iron ore applications has been studied, and the findings are based on both industrial and pilot scale experiences on different materials. For example, the results show that the cake moisture content of iron ore pelletising feed can be optimised more effectively by using modern filtration technologies. By selecting the most suitable and adjustable equipment, the effects of variations of feed material on downstream processes can be minimised and the possibilities of processing more difficult raw materials to high-quality pellets are better. The Larox Corporation develops, designs and manufactures industrial filters and is a leading technology company in its field. Larox is a full service solution provider in filtration for separating solids from liquids. As such, this paper compares the new developments in this market area with the prevailing known vacuum filtration technology, but focuses on a comparison between capillary action filters and rotary vacuum disc filters (RVDF). The trade name CeramecG is used to differentiate the Larox filter from the generic term.

Jan 1, 2007

By Ritter K-C, Sturgul J. R, Filess T

The proposed Lihir open pit gold mine is located on Lihir Island in New Ireland Province, Papua New Guinea. The mine will be located within a volcanic caldera, part of which forms the adjacent Luise Harbour. Kennecott Corporation started engineering design work in 1988 and ended in 1993 when a Feasibility Report was submitted to the Papua New Guinea government by RTZ/Kennecott. The project will be managed by the Lihir Management Company. The mining operation will produce approximately 350 Mt of waste and 62 Mt of low-grade ore over the life of open pit mining. Landforms and traditional land use by Lihirians preclude storing mine waste and some of the low-grade ore on land close to the mine site. The mine waste will be composed of hard rock and soft soild like material which cannot be safely used to construct large land waste repositories by truck dumping. Submarine disposal by bottom discharging barges is the only safe disposal method. The barges will also be required to construct a waste platform along the shore for stockpiling low-grade ore. A simulation model of the waste handling system was written in GPSS/H¦ to assist engineers in selecting the optimum size and quantity of barges and loading docks by analysing the interaction between excavators, trucks and barges. The simulation model was written in enough details to model the various functions that will be encountered during mining. Input parameters allowed for variations in the size and number of trucks, shovels, barges and loading docks. Variations in loading, hauling, and dumping times were from user specified distributions. In order to visualise the interaction between the components of the waste mining operation, the simulation was animated using Proof AnimationT""'. It is believed that this is the first application of an animated simulation study for a mine still in the planning stages.

Jan 1, 1995

By K S. Smith, B P. Jackson, P J. Lamothe

The upper Arkansas River south of Leadville, Colorado, USA, contains deposits of fluvial tailings from historical mining operations in the Leadville area. These deposits are possible non-point sources of acid and metal contamination to surface- and ground-water systems. We used stable-metal isotopes to help ascertain metal retention and release mechanisms that influence metal transport from the deposits to shallow ground-water systems. To accomplish this, we excavated an intact core from a small fluvial tailings deposit and performed laboratory column experiments to examine the amount of metals leaching through the core. Deionised water was continuously applied to the top of the core, and effluent was collected from the bottom of the core for a period of about two months. Three saturation conditions were used, including unsaturated, partially saturated, and fully saturated. Reducing conditions developed upon partial and complete saturation of the core. During the unsaturated leaching phase, core effluents were acidic (pH 2.8 - 3.5) and contained elevated metal concentrations. During a portion of the unsaturated leaching phase, stable-metal isotope spikes and conservative tracers were simultaneously applied to the top of the core. The isotopes provide a means to delineate metal behaviour within the core. During the unsaturated leaching phase, the isotope spikes did not exhibit breakthrough with simultaneously added conservative tracers. However, some of the stable-metal isotope spikes did break through when reducing conditions occurred in the core (during the partial- and completesaturation conditions). In this paper, we use Cd as an example of the utility of stable-metal isotopes in geochemical studies. In the case of Cd, after the core was partially saturated, the 111Cd spike was released as evidenced by a change in the Cd isotope ratios in the effluent. This release continued during the fully saturated leaching phase, however, the total Cd concentration did not increase. These results suggest that the 111Cd spike was retained inside the core during the unsaturated leaching phase, and only partially released as reducing conditions developed. Results from this core-leaching experiment indicate there is a large reservoir of water-soluble material within the fluvial tailings deposit, which yields elevated metal concentrations and high acidity, and which may degrade adjacent ground- and surface-water quality. Use of stable metal isotopes in this study facilitated the determination of different metal-retention processes, metal-release processes, and metal sources in the fluvial tailings deposit in response to changing geochemical conditions.

Jan 1, 2003