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Etching solutions containing hexavalent chromium ions (e.g., chromic acid) are used in brass finishing, printed circuit board etching, preparation of plastic for plating, anodizing, and various other industrial surface treatment operations. As the solutions are used, hexavalent chromium ions are reduced to their trivalent state, contaminants accumulate in the solution, and the effective acid concentration is reduced. When the etching rate becomes unsatisfactory for the particular operation, the solutions are discarded. This is a problem because the discarded solutions are pollutants, and because replacing the etching solution is expensive. The Bureau of Mines has developed a process for regenerating these spent solutions and returning them to the surface treatment operation without interrupting the etching process. An electrolysis cell containing anode and cathode compartments that are separated by permeable membranes, is used for regenerating the spent solutions. The spent chromic acid solution is fed to the anode compartment and sui (uric acid is circulated in the cathode compartment. Application of a steady electrical potential of a few volts dc across the electrodes causes the copper ions and other contaminants in the spent solution to migrate through the membrane to the cathode compartment where copper is plated onto the cathode. Zinc and the other contaminants remain in the sulfuric acid. At the same time, the complex, trivalent chromium ions in the spent solution are attracted to the anode where they are oxidized to their original hexavalent state. The regenerated solution in the anode compartment is then recycled back to the plant?s etching operation for reuse.

Jan 1, 1980

By V. A. Marple, K. L. Rubow

"IntroductionA particle dispersion system has been developed to aerosolize bulk powders or material deposited on surfaces such as filters. The size distribution of the aerosolized particles can then be obtained by sampling the particles with an aerosol sizing instrument such as a TSI aerodynamic particle sizer (APS) or a cascade impactor.Of particular interest is the applicability of using this technique to obtain the size distribution of particles collected on filters. This system has been used to determine the size distribution of coal dust particle collected on membrane filters. The use of this device in this application is quite intriguing in that, if this technique can be shown to accurately determine the size distribution of airborne particles, one can easily collect particle samples using either personal or area particle samplers, determine the mass concentration of the collected material through gravimetric techniques and then use the particle dispersion system coupled with the APS to determine the particle size distribution. With this technique one can determine the particle size of dust in environments, such as underground mines, where it would be inconvenient or impossible to use a particle sizing instrument.Particle Dispersion SystemA prototype particle dispersion system has been developed for aerosolizing particles. A schematic diagram of the system is shown in Figure 1. The system consists of mechanism for advancing the particle sample beneath a dust pickup tube, a venturi for deagglomerating the particles, and a instrument for analyzing the aerosolized particulate matter.The procedure to analyze a particle sample is as follows. The particles to be aerosolized are placed on a sample plate from where the particles are picked up by an air stream flowing upward in a small capillary tube (dust pickup tube). This tube operates as a small vacuum cleaner passing over the sample plate. The air is drawn up the capillary tube at a rate of 2 L/m by a venturi aspirator. This is accomplished by placing the outlet of the capillary tube near the throat of the venturi. The accelerated velocity of the air creates a low pressure in this region which draws flow up the capillary tube. From the outlet of the capillary tube particles are transported to the inlet of the APS where a small fraction are sampled and the aerodynamic diameter of the particles determined. The particles which are not measured by the APS are passed into a HEPA filter."

Mar 1, 1989

By C. A. Komar

Laboratory-scale hydraulic fracture tests were conducted by the Bureau of Mines on directionally oriented sandstone material, along with measurements of directional rock properties such as tensile strength, permeability, ultrasonic velocity, and dynamic elastic constants. In these tests, fracture orientation was determined as a function of various combinations of stress, rock saturation, rate of borehole pressurization, and direction of minimum tensile strength relative to minimum horizontal compressive stress. The objective of the experiment was to investigate whether horizontal stresses always controlled the orientation of induced vertical hydraulic fractures, or if under conditions of small differences in stress and/or slow borehole pressurization rates, the induced fracture direction was influenced by directional properties of the rock matrix. This study shows that the expected influence of horizontal earth stress on the orientation of an induced hydraulic fracture becomes negligible when¬ever the magnitude of the difference between the compressive stresses is 200 psi or less. When this occurs, fracture orientation is controlled by the directional properties of the rock--primarily permeability and tensile strength.

Jan 1, 1973

By Ronald A. Vary

This paper is one of a series prepared by the United States Bureau of Mines dealing with milling methods and costs. In view of the current revival of interest in gold mining, information dealing with practices and costs in the development of gold properties is apropos. Milling practice at a small gold property in the prospect stage is described where, with a small outlay for plant and equipment, development has been carried on for about 20 months on the proceeds of the mill operation with little additional expenditure. The paper shows about what may be expected as to costs at a small property operated under northern climatic conditions and with rigid economy throughout the plant.

Jan 1, 1931

By Richard D. Miller, Geraldine P. Norrell

This publication contains routine analyses and related source data for 295 natural gas samples from 18 States collected during calendar year 1963 as part of a continuous survey of the United States for occurrences of helium in natural gas. This survey has been conducted by the Bureau of Mines since 1917. The analyses published herein were made by mass spectrometer and a special helium analysis apparatus, which are described in Bureau of Mines Bulletins 4863 and 576.4 Five previous publications have been made to present the results of 5,998 gas analyses made by the Bureau of Mines Helium Activity , prior to 1963. The first three , Bulletin 486,5 Bulletin 576,6 and Bulletin 617,7/ contain analyses and source data on 5,214 gas samples collected from 1917 to January 1 , 1961. The fourth and fifth publications , which are published as Information Circulars , supplement the three Bulletins and contain 784 analyses of samples collected during 1961 and 1962. The present Information Circular is the third annual publication supplementing the three Bulletins .

Jan 1, 1965

By L. E. Geyer

"The following list gives the title and author of various publications of the Ceramic Experiment Station, Columbus. Ohio, of the Bureau of mines, together with other ceramic publications of the bureau, which have been published in technical journals and by cooperating agencies. The list also includes the publications on ceramics which have been issued as bulletins, technical papers, or mimeograph Report of Investigations of the bureau.Papers Published in the Technical Press.The Effect of some Electrolytes on the Properties of Clays. Schurecht, H.G. Jour. Am. Cer. Soc., Vol. 1, #3, March, 1918.A Pycnometer Operated as a Volumeter. Schurecht, H.G. Jour. Am. Cer. Soc.,Vol. 1, #8, August, 1918.The Properties of some Ohio and Pennsylvania Stoneware Clays. Schurecht,H.G. Jour. Am. Cer. Soc., Vol. 1, #4, April, 1918.The Fusibility of Graphite Ash and its Influence on the Refractoriness of Bond Clay. Booze, M.C. Jour. Am. Cer. Soc., Vol. 2, #1. Jan., 1919.Behavior under Brass Foundry practice of Crucibles containing Ceylon, Canadian and Alabama Graphites. Stull, R.T. Jour. Am. Cer. Soc., Vol. 2, #3. March, 1919."

Oct 1, 1924

By John H. Soulé

"INTRODUCTION The Mining Branch of the Bureau of Mines has used the wagon drill to sample mineral deposits in New Mexico. This method of sampling was successful and con¬stituted an important phase of the work on five exploratory projects undertaken in 1943, 1944, and 1945. The deposits varied in topographic features, geology, mineral content, and in the physical characteristics of the rocks drilled. The altitudes ranged from 630 to 7,800 feet. Three hundred and seventeen holes totaling 6,852 feet were drilled. The deepest hole was 66 feet; the average depth was a little less than 22 feet.The results of the above-mentioned work form the basis of this report. Special attention is given to the later and more improved techniques used. This report was written with the expectation that the procedures might prove advantageous to others in the exploration and sampling of near-surface mineral de¬posits, and that a more extended use of the technique might result.AcknowledgmentsAcknowledgment is due Charles H. Johnson, chief of the Rolla Division, Mining Branch, for helpful suggestions in starting this work, and to J. H. Hedges, chief of the Tucson Division, Mining Branch, W. R. Storms, engineer-in-charge of the Silver City, N. Mex., Field Office, and Donald H. Mullen, mining engineer attached to that office, for assistance in preparing and editing this report."

May 1, 1947

By A. Wahib Khair

"This article first describes the impact of respirable dust on the health of miners in underground coal mines in the United States of America. Second, it identifies the major sources of dust generation, namely cutting tools in the road headings. Two surveys associated with cutting tools were made to determine the useful life of these cutting tools, and to determine the effect of cutting tool wear on productivity of the continuous miners. Third, this article presents the results of a series of experiments carried out in the Rock Mechanics Laboratories at West Virginia University in order to study: 3.1 the effect of cutting tool rate of wear on respirable dust generation, 3.1.1 the effects of rock materials on tool wear and respirable dust generation, 3.1.2 the effect of cutting tool geometric parameters on respirable dust generation, and 3.1.3 the effect of tip materials used in the cutting tool on respirable dust generation. Recommendations in regard to cutting tool design are also presented in this paper.Silica and coal dust are the two major elements affecting the health of underground miners. According to Lemen [1] approximately 1,500 men died due to breathing in silica dust in 1936 while tunneling through a mountain of mostly silica, near the town of Gauley Bridge, West Virginia. Coal dust resulting in lung diseases in one of the major health hazards in underground coal mines. The impact of black lung on miners, coal workers' pneumoconioisis (CWP), has ranged from 16,000 to 23,000 each year since 1982 [1].The trend for conventional mining to continuous machine cutting of coal, using more productive machinery, is inexorable. Intolerable level of dust generated at the face is an indication of inefficient coal/rock cutting by these machines. The federal goverment of the United States paid about 11.7 billion dollars in workmen's compensation to more than 470,000 miners with CWP [2]. Bieniawski and Zipf [3] reported that annual benefit payments were about 2 billion dollars. The enactment of the Health and Safety Act in 1969 in the United States triggered the initial investigation into coal cutting mechanisms and cutting tool designs.The surveys concerning the utilization of cutting bits and performance of continuous miners in underground coal mines were made in order to have first hand information about bit consumption and coal produ¬ction.Three types of used bits, commonly utilized cutting tools on continuous miners, were collected from different coal mines. The used bits were grouped into symmetrically and asymmetrically worn bits. Distribution analysis for weight loss and conical height loss was done. Details of the results are presented elsewhere [4], here the results are summarized briefly. The analysis shows that approximately 50% of the collected bits have worn asymmetrically, which shows that many bits do not rotate properly during cutting. Analysis of the distribution of bit wear showed that the degree of bit wear varied from one type to another and with mining conditions. On average, the weight loss of the used bits was 4% to 7% with a maximum of 31%. Correspondingly, the loss of the conical height was observed to vary between 11% and 23% with a maximum of 71%. Figure 1 shows typical data associated with some of the used bits."

Jan 1, 1998

By W. L. Crentz

San Juan County, which occupies the extreme northwest corner of New Mexico, contains large reserves of coal in the Fruitland formation and in the Menefee formation of the Mesaverde group. The coals have bright luster, are brittle, and break easily in handling. All mines sampled are in the La Plata-Fruitland and Rio Chaco districts of the Durango-Gallup coal field. This large area, all within San Juan County, contains numerous coal beds 5 to 15 feet thick. Ellis2/ mentions the Carbonero (Fruitland in this report) bed in the La Plata-Fruitland district attaining a thickness of 36 feet. This bed has been correlated with the Carbonero bed, formerly mined at Carbon Junction, near Durango, Colo. During the field investigation covered by this report, no operating mine in the Fruitland bed was working a bed thickness of more than 15 feet.

Jan 1, 1957

"Health standards in the U.S. are among the highest in the world. Achieving these standards have often had an impact on productivity, slowing output, and raising prices to levels that make it difficult to compete with many foreign industries. The answer to many of these problems lies in the development of new and advanced control techniques. This overview has identified some of the major respirable dust technological hurdles that have been overcome, and provided some insight into current and future approaches underway to remove these obstacles and to provide the United States with the most advanced state-of-the-art mining industry in the world from a respirable dust standpoint. The necessary developmental research is costly and time-consuming. The long-term, high-risk aspects of this effort are being addressed by the Bureau and the Generic Center on Respirable Dust, with support by industry. This should be recognized as one of the principal agents through which the great mineral potential of this Nation can be realized, and our international status as a mining power be assured without compromising the health and welfare of those who ensure it.The problem of more stringent dust standards will continue to grow. To date, approximately 40 pct of the coal mining industry has been placed on more stringent dust standards due to quartz. Control techniques must be improved if mandated levels are to be met. As longwall production increases, dust levels will also increase. In light of the industry trend toward longwall mining, if no new control technology is available, the Federal dust standard will act as a constraint on future output per hour. The Bureau has recently completed a survey of 18 coal preparation plants; 50 pct of these operate at dust levels which exceed 2.0 mg/m3; future work will be directed toward solutions in this area. The 2.0 mg standard for respirable dust is for dust particles which are below 10 pm in diameter. Recent studies have shown that dust in the range between 10 and 25 pm can cause obstructive airway disease. The Bureau is currently determining the extent of exposure to dust in this size range from various mining operations."

Nov 1, 1988

By C. F. Davidson

The Bureau of Mines studied the extraction of lithium from lithium-containing clays by chlorination with hydrogen chloride (HC1). In bench-scale laboratory investigations, HC1-H20 mixtures were used to selectively chlorinate lithium, but not calcium or magnesium, in lithium-containing clays. The addition of calcium carbonate to the clay was found to improve the lithium recovery. Reaction conditions found to affect the lithium recovery were ratio of clay to carbonate, reaction temperature, and HC1 concentration. The best conditions for selective chlorination of the lithium were 2:1 clay-carbonate, 750° C, and 20 wt-pct HC1. The experimental results and trends in lithium extraction are explained using thermodynamic relationships.

Jan 1, 1981

By S. J. Page, W. R. Reed, J. A. Organiscak

NIOSH continues to conduct respirable dust control research for surface mine blasthole drilling operations. Research areas have included testing variables (shroud leakage area, drill deck cross-sectional area, shroud height, collector-to-bailing airflow ratio, etc.) that have the most impact on respirable dust control, development of a dust collector inlet hood, development of a dust collector dump point shroud, and testing of a small diameter water separating sub. This paper summarizes the results of the aforementioned research that has been completed. Additionally, past dust control research for drilling operations of both underground and surface mines completed by the U.S. Bureau of Mines, created in 1910 and incorporated into NIOSH in 1997, is reviewed.

By Chas. F. Jackson

This paper is a tabular compilation of data contained in a series of information circulars dealing with mining methods and costs at a large number of mines in the United States and some foreign countries. There circulars have been published from time to time during the years 1929 to 1934 inclusive. From time to time, as enough data became available in these circulars, other circulars and. bulletins have been published in which the data bearing upon different phases of nine operation were summarized, discussed, and analyzed. The present paper is a compilation of data on costs of drifting and crosscutting contained in earlier circulars, .designed to assemble this information in a convenient form for reference without attempting lengthy discussion of details of drifting and crosscutting practice. For such details the reader is referred to the circulars on individual mines.

Jan 1, 1935

By Sara J. Davenport

Hydrogen sulfite has been listed (1)3/ as a possible hazard in 50 occupations, many of which are in the mineral industries. The effects of its occurrence in the petroleum industry made themselves felt more than two decades ago, resulting in a comprehensive study (2) of the toxic gases from Mexican and other high-sulfur petroleum products. The mining industry, likewise, has had cause to guard against this gas. Enough hydrogen sulfide has been found in coal and some noncoal mines during normal operations to cause severe eye irritation, some serious illness, end even fatalities. It is usually a product of the decomposition of sulfur compounds and may be produced by burning explosives containing sulfur; the gas in harmful qauntities is formed by the use of block blasting powder or by the use of dynamite in blasting sulfide ores. Hydrogen sulfide is readily soluble in water, and enough may be released from water streams in coal and noncoal mining to cause fatal poisoning it is found sometimes in stagnant water underground, particularly where ventilation currents are absent, and great care must be exercised when accumulations of such waters are disturbed, as exposure to comparatively low concentrations of the gas evolved therefrom has caused fatal accidents.

Jan 1, 1945

By Janet Torma-Krajewski

Job tasks that involve exposure to work-related musculoskeletal disorder (WMSD) risk factors may impact both the risk of injury and production downtime. Common WMSD risks factors associated with mining tasks include forceful exertions, awkward postures, repetitive motion, jolting and jarring, forceful gripping, contact stress, and whole body and segmental vibration. Mining environments that expose workers to temperature/humidity extremes, windy conditions, and slippery and uneven walking surfaces also contribute to injury risk. National Institute for Occupational Safety and Health (NIOSH) researchers worked with powder crew members from the Bridger Coal Company to identify and rank routine work tasks based on perceived exposure to WMSD risk factors. This article presents the process followed to identify tasks that workers believed involved the greatest exposure to risk factors and discusses risk reduction strategies. Specifically, the proposed prill truck design changes addressed cab ingress/egress, loading blast holes, and access to the upper deck of the prill truck.

Jan 1, 2009

By D. S. Kingery, F. F. Kopsch

The practice of using two or more main ventilating fans is common at large coal mines throughout the coal-mining industry. To assure adequate and efficient ventilation at may mines, such multiple-fan systems are necessary. The hazards associated with interrelated ventilating currents if a fan fails are controversial, and to date little effort has been made to study this specific problem and to determine corrective measures. The obvious questions are: 1. Is there a hazard? 2. Under what circumtances does it exist? 3. How serious is it? 4. What are corrective measures? Most members of the mining fraternity agree that reduced quantities of air and changed airflow patterns introduce potential hazards, especially where gaseous conditions exist when mechanized methods are used in concentrated mining 0 The seriousness of the hazard depends on the ease with which methane accumlates in face areas or haulage roads, the quantity of methane in workedout areas, and the extent to which reversed air currents interfere with escape and recovery operations after mine fires or explosions. These studies cover three mines and give the distribution of air for the specific conditions show. Each mine probably has somewhat different airflowpressure relationships between fans. This depends on the number of fans, the

Jun 1, 1959

By G. R. Hopkins

A fifth successive record in fuel efficiency was established by the petroleum-refining industry in 1937, when the average heat requirement per barrel of crude oil run to stills was 554,000 3. t. u. compared with 597,000 3. t. u. in 1936. These amounts represent roughly the heat ob¬tainable from a tenth of a barrel of fuel oil (see fig. 1). Innumerable factors can influence heat consumption at rep aeries, but only a few are important enough to be subject to statistical measurement. Foremost of these is the ratio of runs to capacity, it being generally recognized that because the fuel demands for other than stills are comparatively inelastic, total heat requirements do not increase in direct proportion to crude runs. Thus, in 1937, crude runs of 1,183,440,000 barrels wore 11 percent higher than in 1930; the average operating ratio was 93 percent compared with 79 percent in 1936; but the total heat requirement increased only 4 percent, or from 639,149 billion 3. t. u. in 1936 to 663,966 billion 3. t. u. in 1937.

Jan 1, 1938

By Robert C. Hickman

"INTRODUCTION The Big Four fault and the Sandy Creek fault, with several cross faults, traverse the Stalion-Curnel fluorspar prospect in a northeasterly direction. The Big Four mine, about three-quarters of a mile northeast of the prospect, is the only active mine in the immediate area.A resistivity survey was made of a portion of the prospect by the Division of Geophysical Exploration, Bureau of Mines, in May and June 1946. As a result of this survey, five holes were drilled by the Bureau of Mines during the period from October 8 to December 16, 1946. Two Longyear No. 12 Junior Straitline diamond drills were used for the work.ACKNOWLEDGMENTSIn its program of investigation of mineral deposits, the Bureau of Mines has as its primary objective more effective utilization of our mineral resources to the end that they make the greatest possible contribution to national security and economy. It is the policy of the Bureau to publish the facts developed by each project as soon as practicable after its conclusion. The Mining Division, Lowell B. Moon, chief, conducts preliminary examinations, does the actual investigative work, and prepares the final report. The Metallurgical Division, Oliver C. Ralston, chief, analyzes samples and makes beneficiation tests.The project was under the supervision of Mitchell H. Kline, chief, Raleigh Branch, Mining Division."

Mar 1, 1948

By Robert Lundquist

REAM is a unique method of rock breaking using high energy projectile impact. This report-describes the most recent in a series of tests demonstrating mining applications for the REAM method. In an underground limestone mine at Greer, West Virginia, REAM was used to drive a short tunnel and drill a large diameter borehole. Along with breakage data from these tests the goal of the program was to examine environmental problems which might result from the use of cannons under-ground. A total of 103 shots was used to advance a 14-l/2-feet high by 10-feet-wide face a distance of 5-1/2 feet. It is estimated that the 9.3-pound-concrete projectiles launched at 5000 feet per second will break an average of 0.78 tons of limestone or 67 percent of the 1.125 tons of granodiorite broken in previous tests. The 9-inch-diameter borehole was drilled horizontally by repeated axial impact for 7 feet, 2-1/2 inches by 21 shots giving an average of 4.12 inches per shot. Scaling this result to compressible impact energy yields an estimated 5.8 inches per shot for a 12.8-inch-diameter hole compared to 8 inches per ~hot for a 16-inch-diameter hole in granodiorite. Noise measurements indicate that a silenced cannon can be used within a few hundred feet of mine personnel in a room and pillar mine within the legal limit of 140 dB impulse without additional protection. Some fume measurements were made with satisfactory results, even though the military propellants used produce much greater quantities of toxic fumes than the liquid propellant proposed for the future.

Jan 1, 1976

By K. Rubow, Z. Zhlqun, V. Marple

A theoretical technique has been developed and verified experimentally for determining the aerodynamic diameter of irregular shaped particles. The aerodynamic diameter of a particle is a very important property in determining where that particle deposits in the respiratory tract. Many instruments, such as impactors and cyclones, will determine the aerodynamic size distributions of aerosol particles but few analyze the particles individually. The theoretical approach of our technique is to solve, by use of high speed computers, the three dimensional Navier-Stokes equations to obtain the flow field around an irregular shaped particle of any contour. The computer program will then determine the drag on the particle, and thus the aerodynamic diameter of the particle can be calculated. The experimental approach has been to pass the particles through a centrifuge and collect the particles upon a collection foil. The position of a particle on the foil is an indication of its aerodynamic diameter. These particles were then shadowed in two orthogonal directions and inspected under an SEM. The top view of the particle in the SEM plus the views of the two orthogonal shadows allows one to determine the three dimensional shape of the particle. Studies have been performed on silica, coal and talc particles with aerodynamic diameters in the 1 to 4 um size range. The three dimensional shape, as is determined from SEM analysis was used in the theoretical computer program and the results compared. It was found that in most 'cases the agreement between the experimentally and theoretically determined aerodynamic diameters was within 5%.

Jan 1, 1988