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By D. J. Bauer

Solvent extraction techniques were used to determine the extraction sequence of yttrium and the rare-earth elements in an amine solvent extraction system. Single-stage extraction with Primene 81-R resulted in separation factors of 3.8 between yttrium and dysprosium and 25 between yttrium and cerium. Yttrium was concentrated in the aqueous phase. EDTA and DTPA, as aqueous phase counterextractants, enhance separation factors in mine-rare-earth sulfate systems. Yttrium separation from heavy rare-earth elements exhibits marked sensitivity to the position of yttrium in the selectivity scale of the rare-earth elements with the sequestrants. Yttrium-ytterbium separation is more effective with EDTA, whereas yttrium-dysprosium separation is more effectively increased with DTPA.

Jan 1, 1963

By Thomas J. Peters

In 1978, the U.S. Bureau of Mines and the U.S. Geological Survey completed a joint mineral survey of the Chemise Mountain and King Range study areas as mandated by the Federal Land Policy and Management Act of 1916, Public Law 94-579. The U.S. Bureau of Mines examined all identified mineral prospects and deposits; the results of these examinations are included in this report. The U.S. Geological Survey studied the regional geology, geochemistry, and geophysics; the results of these studies are available in USGS Map MF-1196. No mineral resources were identified in either the Chemise Mountain or King Range study areas; however, a high-grade silver and base-metal occurrence, and minor manganese resources were identified in between the two study areas, within the King Range Conservation Area. The only mining activity in either area was a placer gold prospect on Honeydew creek in the northeastern part of the King Range study area. Three samples from this prospect contained no gold. The Chemise Mountain and King Range study areas are in a mountainous region along the coast of northern California, 230 road miles north of San Francisco, and 70 miles south of Eureka by way of U.S. Highway 101, through Garberville and Redway. The Chemise Mountain study area consists of 3,941 acres; it includes the 2,598-ft Chemise Mountain, and the cliff-lined seacoast southeast of Shelter Cove. a resort and fishing village. The King Range study area consists of 39.764 acres northwest of Shelter Cove, and includes the northwest-trending King Range with elevations above 4,000 ft. The Chemise and King Range study areas are underlain by deep-water marine sandstones, shales, and minor pillow basalts of the Late Cretaceous and early Tertiary Franciscan Subduction Complex. Mineral production was 1,650 tons of manganese ore within a manganiferous bed overlying pillow basalt at the Queen Peak mine southeast of the King Range study area. However, no significant manganese resources were found in the Queen Peak area. The Point Delgada area, directly south of the King Range study area, has prospects with high grade copper, lead. silver, and zinc. Exposures are inadequate to estimate resources; however, the metals may be associated with Franciscan volcanism (volcanogenic). The Chemise and King Range study areas may contain similar economic silver-rich, base-metal deposits.

Jan 1, 1992

To improve a miner's chance of survival during an emergency by providing immediately avail-able breathable air and protection from toxic gases until a longer-duration breathing apparatus, stored nearby, can be reached. Approach: A belt-carried apparatus which can provide a closed-circuit atmosphere for ten minutes breathing has been developed under a Bureau of Mines contract. How It Works: Water vapor and carbon dioxide in the user's exhaled breath are removed, and oxygen is supplied, by chemical reactions. When the user exhales into the mouthpiece, water vapor in his breath reacts with potassium superoxide (KO2) stored In the canister to produce oxygen. The other product of this reaction (KOH) reacts with carbon dioxide and removes it from the air. The oxygen-enriched air then flows from the canister into two breathing bags. When user inhales through the mouth, that air is drawn out of the bags, makes a second pass through the chemical-containing canister, and flows into the mouthpiece tube. A nose clip is worn to seal off the nasal passages.

Jan 1, 1975

Native asphalt was produced in 1977 by six companies in four States. Leading States were Texas and Utah. Output declined 39% to 1,237,000 tons valued at $18,874,000. Bituminous limestone was produced by Whites Uvalde Mines and by Uvalde Rock Asphalt Co. in Uvalde County, Tex.; by Southern Stone Co. in Colbert. Ala.; and by Barton County Rock Asphalt Co. in Barton County, Mo. Gilsonite was produced by American Gilsanite Co. in Uinta County. Utah, and by Ziegler Chemical and Mineral Corp. in Weber County. Utah. The asphalt was used for streets and roads, and for other purposes.

Jan 1, 1980

By Karl R. Becker

Detonators representing a sampling of various domestic commercial delay detonators were fired at various direct-current (dc) firing levels. Results of firings using well-below-recommended firing levels showed marked increases in delay times above the nominal values. There was also a marked increase in variation, to the extent that out-of-sequence firings would be essentially assured in any typical blasting round at these low firing levels. Within the range of recommended levels the effects of current increases were not considered to be of great importance relative to other overriding effects, such as the significant difference noted in average values of detonators from different lots having the same nominal delay. This effect, when combined with the normal variation noted among members from the same lot, would cause out-of-sequence firings with detonators from a neighboring delay period. Where comparisons with results from another study were possible, it was found that both studies observed quite similar variations in delay times about the average values, and a lower probability of out-of-sequence firings for the shorter delay period groups. The criterion of the previous study for assessing the likelihood of observing out-of-sequence firings, when applied to the Bureau of Mines data, properly identified two neighboring delay period groups where out-of-sequence firings would occur.

Jan 1, 1981

By J. N. Van Sant

Lignite mining in North Dakota was begun about 1884 to supply the domestic needs of settlers. Annual production has grown rather slowly but steadily, exceeding 3 million tons in 1950. The western part of the State has lignite reserves, amounting to 351 billion tons, underlying an area of 28,000 square miles. Contour strip mining has almost completely replaced underground mining as the method of production. Lignite is often found under rather shallow and easily removed overburden, and this is the primary reason for the change in mining practice. Current mining operations are conducted where the overburden is 30 to 70 feet thick. Contour strip mining results in high production rates, at present 27 to 56 tons per man-day. These high production rates result in relatively low production costs.

Jan 1, 1959

By Fred N. Kissell

In this report the importance of diffusion in controlling the emission of methane in mines is examined. An in-situ diffusion parameter is defined and calculated for a hypothetical unfractured lump of coal in the Pittsburgh and Pocahontas No. 3 coalbeds. The values obtained are similar to those obtained with lump coal in laboratory experiments.

Jan 1, 1972

By E. Morrice

Techniques developed by the Bureau of Mines for the preparation of high-purity rare-earth metals and their alloys by electrolysis of the oxides in fluoride media are summarized. Cerium, lanthanum, neodymium, praseodymium, dysprosium, gadolinium, and yttrium metals, the mixture didymium, and specific alloys of these metals and samarium with iron, nickel, chromium, and cobalt were prepared. Individual metals were electrodeposited in the liquid state on tungsten or molybdenum cathodes. Alloys were prepared by electrodepositing the rare-earth metal on a consumable cathode, at a temperature above the melting point of the eutectic formed between the rare-earth element and the cathode material. Cells were designed for electrowinning metal products in gram and pound quantities, and methods for continuous electrowinning of cerium and lanthanum were developed.

Jan 1, 1968

By Thoms L. Chapman

The San Manuel is a deposit of low-grade disseminated copper ore. It was brought to the attention of the government in October 1942 through an application to the Reconstruction Finance Corporation for a development loan, supported by a report by Henry W. Nichols. Nichols’ sampling of two outcrops containing copper silicate and his geologic map indicated that a minable body of copper ore might be developed. The Federal Geological Survey was requested to examine the property. The Survey mapped the geology in March 1943 and cut a few check samples, which substantially confirmed Nichols’ sampling of the outcrops and a few shallow workings. The geologists of the Survey recommended some test drilling by the Bureau of Mines. The property was examined by the author and W. D. Hughes, associate engineer of the Bureau of Mines on March 22 and 26, 1943, and a preliminary drilling campaign was recommended. Five shallow churn-drill holes totaling 1,480 feet were put down under the supervision of Chas. A. Kumke, one of the Bureau’s engineers, from November 23, 1943 to January 15, 1944. This work indicated that the deposit extended deeper than the 350-foot depth attained in the deepest hole and might have very considerable areal extent. Additional funds were allotted, and the drilling contract was extended twice to a final maximum of 17,000 feet with 2,000 foot maximum depth of hole. Drilling was continued by the Bureau of Mines until February 2, 1945, when 15,844 feet of hole had been drilled. The Magma Copper Co. took options on this and adjoining property in September 1944 and commenced drilling with two machines. It also engaged the two contract drills used by the Bureau after it stopped drilling. It exercised its options in August 1945 and organized the San Manuel Copper Corp. to operate the property. That company is continuing to explore the ore body with six churn drills. Thomas Lyon took options early in 1945 on holdings adjoining the San Manuel property on the east and is operating two churn drills. Exploration up to the completion of the last holes started by the Bureau of Mines indicated a block of ore 5,100 feet long, 400 to 800 feet wide, and 500 to 900 feet thick, and averaging about 0.8 percent copper. Subsequent drilling showed that the ore body extends considerably beyond this block. The axis of the ore body strikes about N. 61º E. Copper minerals are disseminated in hydrothermally altered quartz monzonite and monzonite porphyry. Ore outcrops in two small areas over the northeast part of the block. Elsewhere the copper-bearing rocks are capped by Gila conglomerate, which thickens toward the west and south. Drilling showed that the ore is in a thick, tabular body with a steep dip to the south. The ore body lies near the surface in the northeastern part of the block. The south side of the block is much farther below the surface than the north side. There the upper part of the copper-bearing rocks is lightly mineralized, so that the hanging wall of minable ore lies deeper than the base of the conglomerate cap, which thickens southward.

Aug 1, 1947

By Donald R. Irving

THIS CHAPTER is new to the Minerals Yearbook and will appear regularly hereafter. Its purpose is to present statistics that reflect technologic trends in the minerals and metals industries (except fuels). Much useful information has been collected annually through the Bureau of Mines mineral commodity and employment and injuries canvasses. However, these data must be supplemented by further data to permit evaluation of the type, direction, and rate of technologic change, which are vitally important in long-term mineral planning. In addition to, and fully as important as, expanding the available data is the need to ascertain that the various items collected are obtained from identical reporting units, to enable direct comparisons to be made.

Jan 1, 1960

By Slavoljub D. Maksimovic

At some coal mines, methane gas is released during raise drilling. At the request of the Mine Safety and Health Administration (MSHA), U.S. Department of Labor, the Bureau of Mines conducted ventilation surveys at different raise drill sites to assess various methods of reducing methane concentration. The resulting data indicate that raise drill shaft cavities are ventilated by air compressors, vacuum pumps, auxiliary blower fans, and free intake air from the surface. The compressors, pumps, and fans operate simultaneously or separately. At the bottom of the shaft cavities, ventilation is controlled by regulators and airlocks. Methane is monitored, measured, and periodically sampled on the surface, at the bottom, and at different levels in the shaft cavities. Maximum concentration of 3.5 percent was measured in one shaft in West Virginia. Air velocity down the raise drill shafts is always very low, Maximum recorded air down the drill stem was 3,000 cfm, which can be increased by adding air compressors. The best way to ventilate shaft cavities is through the simultaneous use of air compressors and vacuum pumps. If the methane concentration cannot be reduced with additional compressors, then the inside diameter of the drill rod should be increased, or larger pilot hole drill bits should be used.

Jan 1, 1981

Develop a down-hole replaceable diamond core bit that will reduce overall drilling costs and increase total available drilling time per hole. Approach A one-piece diamond core drill bit of unique geometric shape has been designed, fabricated and field tested. The bit can be withdrawn (or replaced) from the bottom of the well-bore without removing the drill rods from the hole, saving a significant amount of non-productive drilling time. How It Works The replaceable bit system consists of two basic subsystems: the removable core bit, and the equipment necessary to replace the wornout bit without pulling the drill rods out of the hole. The geometric configuration of the bit is that of a one-piece diamond studded cutting element created by "slicing off" two parallel sides of a conventional diamond cone bit. This geometric configuration, along with some minor modifications to the outer core barrel, allows the bit to be rotated in two planes and, with the retraction-insertion tools, raised or lowered through the interior of the drill rods using a conventional wire-line system. For example, to retrieve the bit, a retraction tool is lowered through the drill rods using a conventional wire-line system and at the hole bottom, the tool automatically orients itself within the outer core barrel.

Jan 1, 1981

By John E. Hamak

The identified helium resources of the United States were estimated by the U.S. Bureau of Mines at 617 Bcf, as of December 31, 1992. This includes 285 Bef of demonstrated reserves, 85 Bcf of demonstrated marginal reserves, and 37 Bcf of demonstrated sub-economic resources. The identified resources also include 166 Bcf of helium in inferred reserves and inferred marginal reserves and 44 Bcf in inferred sub-economic resources. The identified helium resources contained on Federal lands are approximately 172 Bcf, including 32 Bcf in underground storage in the Cliffside Gasfield near Amarillo, TX. Undiscovered helium resources in the United States are estimated at a most likely volume of 104 Bef, with a maximum volume of 249 Bcf and a minimum volume of 41 Bef. Also reported are 51 Bcf of helium in nonconventional and low-helium-content natural gases. Extraction of helium in the United States occurs mostly from natural gases produced from the Hugoton gas area in Kansas, Oklahoma, and Texas, and the Riley Ridge area in southwest Wyoming. Helium extracted from natural gas in the United States in 1992 was 3.3 Bcf. Some shortfalls in helium supply may occur in about 5 to 10 years.

Jan 1, 1995

To recover metals as sulfide concentrates from contaminated waste streams using hydrogen sulfide (H2S) generated by the bacterial digestion of waste organic materials. Approach The goal of this research is to develop a treatment method for metal mine effluents that will rival the cost and convenience of conventional lime treatment, and that will provide better effluent water quality, result in less expensive sludge disposal, and allow for the selective recovery of metals.

Jan 1, 1993

Design a high-production coal mining machine with inherent low dust generation and low frictional ignition potential. Approach Constant depth linear cutting (CDLC) provides a longterm solution to excessive dust generation from shearers and continuous mining machines through new design of the rotary drum culling system. Problems with rotary drum systems, which must be eliminated to control the dust generation at the source, include the effect of a con¬stantly varying depth of cut using fixed bit spacing, secondary fragmentation of already broken coal and, frictional heating of bits and entrainment of dust by fanning action due to high drum rotational speed, Each bit on a rotary drum enters the coal face at zero depth of cut, goes to some maximum depth at the horizontal centerline during sump, and exits at zero depth.

Jan 1, 1989

Develop a cost-effective, flexible method for extinguishing underground coal mine Fires that can be readily used in fire conditions encountered in both abandoned mines and coal outcrops. In addition to the abatement of an underground coal fire, a secondary objective was to prevent subsidence by filling the voids with a material having sufficient compressive strength to minimize subsidence. Approach The Colorado School of Mines Research Institute was awarded a research contract to determine the viability of using Foaming Mud Cement for abating underground coal mine fires and preventing subsidence. The program consisted of a laboratory and pilot scale investigation and process development. An extensive, controlled test program was conducted simulating floor, rib, roof and rubble fire conditions. Field demonstrations were conducted after the pilot scale research was completed. How It Works Traditional techniques have targeted the control of burning by eliminating the air, fuel source or heat. This has been accomplished by trenching, quenching, mothering or combinations of these three methods. These techniques were not always successful, particularly in the case of fires in abandoned mines.

Jan 1, 1991

By J. J. Cummins

Green River oil shale previously extracted by benzene was heated at 150°, 200°, 250°, 300°, and 350° C for 0.5 to 360 days to determine the rate at which kerogen degrades to thermal products, the types of thermal products formed, and the effect of prolonged low-temperature heating (preheating) upon subsequent assay yields. Thermal decomposition of kerogen at 150° to 350° C is treated as a first-order reaction. The specific reaction rate for kerogen decomposition increases from 2.2 X 10-4 per day at 150° C to 2.0 X 10-1 per day at 350° C. The calculated kerogen activation energy is 19 kcal. Variations in the rate of formation of individual type components of the pyrolytic products were found. Carbon balances show an increase in the amount of kerogen converted to bitumen and oil (from assay of preheated oil shale) as the temperature of preheating increased from 150° to 350° C. Total product from shale preheated at temperatures of 150° and 200° C gave less than 100 percent of Fischer assay yields while the total products from shale preheated at temperatures of 250° to 350° C gave greater than 100 percent of Fischer assay yields.

Jan 1, 1972

By Robert A. Bruce

A motion transducer based on coherent mixing of laser light backscattered from rough surfaces is evaluated in terms of sensitivity, bandwidth and range. Tests made with a prototype composed of a 4-mw HeNe laser, a silicon avalanche photodiode, and a 15-cm aperture telescope demonstrate that remote measurements with reasonable bandwidth and accuracy are feasible at distances up to 100 meters.

Jan 1, 1977

Reduce the cost and incidence of low-back pain in underground coal mines through redesign of materials-handling tasks. Background Approximately 25 pct of all injuries in mining involve trauma to the hack. These injuries account for at least 30-40 pct of worker compensation payments made by the industry, are the leading cause of lost work days in mining, and have been estimated to cost the industry $50 million annually. It is clear that the traditional approach to reduce back injuries (i.e., training) has been largely ineffective. Thus, new approaches are necessary to control this problem. This document briefly describes methods that can be used to redesign hazardous materials-handling tasks to reduce the threat of worker injury. Approach A model for redesigning materials-handling tasks is shown in figure 1. The model outlines the sequence of steps that should be followed (and questions that should be asked) when developing new strategies for handling materials in underground coal mines. A critical examination of the current supply-handling system is the first step to developing safer materials-handling procedures. The purpose is to identify hazardous tasks that can be modified to reduce injury risk. Accident analysis (a review of past accident records) and task analy¬sis (usually a videotaped analysis of hazardous jobs or tasks) arc effective methods of distinguishing areas where job redesign is needed.

Jan 1, 1992

To enhance safety and efficiency when moving large mining equipment under energized trolley lines, and to assist in compliance with Section 75.1003.2, 30 CFR. Approach A system was designed, using established technology, that permits a remotely located circuit breaker to be controlled from the cab of a mine locomotive moving large mining equipment under energized trolley lines. This control consists of setting the desired trip current, automatic or manual tripping, resetting, and voice communications between the locomotive and a remote Circuit breaker location. How It Works According to 75.1003.2, 30 CFR, whenever a piece of off-track equipment (such as a longwall chock or a continuous miner) is moved by rail under energized trolley or feeder lines, power for the locomotive that is moving the equipment must come from only one' circuit breaker. This circuit breaker must be adjusted to permit no more than one-half its rated short-circuit current to flow. The intent is to lessen the danger if an accident should occur, and if the equipment contacts the trolley line. Even so, the danger is great. This half setting can still represent many hundreds or even thousands of amperes, enough to endanger personnel, the equipment, or the mine. The Remote Control System reduces this danger substantially by giving the personnel associated with the move total control over the associated circuit breaker. The system as designed, is intended to be used with portable circuit breakers that are pulled on a small flat car by a mine jeep, and either precede or follow the equipment, depending on the direction of the power. This portable circuit breaker is equipped with a commercially available solid state overcurrent relay and associated shunt. This circuit breaker is connected via heavy duty clamps around an open trolley line tie breaker such that the current through the shunt is also the current in the trolley line. A receiver, interfaced with the overcurrent relay and shunt, completes the remote system.

Jan 1, 1981