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By D. C. Goldring

Many high-grade iron ores are considered to result from the supergene enrichment of banded iron formations. The secondary processes may be related to either present-day or ancient erosion cycles and may reach a considerable depth. Other high-grade ores hosted by banded iron formations are regarded as either sedimentary or metamorphic in origin although often also subjected to the secondary processes. The evidence for this multiplicity of origins is reviewed with descriptions of selected deposits: Kedia d'Idjil and M'Haoudat in Mauritania, Bomi Hills and the Nimba Range in Liberia, the Itabira district in Minas Gerais, Brazil, and El Pao in eastern Venezuela. Emphasis is placed on the recognition of textures that show that some ores are tectonites, the precursor materials having undergone pervasive deformation accompanied by metamorphism. The question whether such ores are pre- or syntectonic is difficult to resolve, the evidence being inconclusive, but a diagenetic/early deformation origin is preferred. The possible range of origins has to be taken into account in exploration, particularly as regards the depth of drilling, and in the characterisation of ores for metallurgical use

Jul 1, 1991

By A. R. Biggart

Twenty-sixth Sir Julius Wernher memorial lecture, presented at the Tunnelling '94 symposium held in London, 5-7 July 1994. In describing 18 projects with which he has been involved over a period of 36 years, the author aims to illustrate how technological change and an increase in scientific knowledge have influenced tunnelling practice, which he nevertheless maintains does continue to be an art. Tunnels discussed are: the Silver Street, Blackfriars, Whitechapel, St. Paul's and Waterloo Post Office tunnels, 1958-1969; metro tunnels on the Victoria Line, London, 1962-1970; the introduction of tunnel boring machines (TBMs), 1971-1978, in the Empingham reservoir diversion tunnels in Rutland, the bentonite tunnelling machine experiment at New Cross, the Southern tunnel water main section of the London Ring Main and the Warrington sewer in Cheshire; tunnels in rock 1975-1981, for the Lune Wyre and Megget Manor aquaducts, Weymouth sea outfall and Bristol interceptor sewer; Priestley TBM tunnels 1969-1982; the Greater Cairo wastewater project 1983-1987; Anacostia River crossing, Washington DC 1985-1987; the Channel Tunnel 1987-1992; and the Storebaelt eastern tunnel in Denmark, 1992-1994.

Dec 1, 1994

By N. B. J. Kieser

Paper presented at the IAGOD international symposium on mineralization related to mafic and ultramafic rocks, held in Orleans, France, 1-3 September 1993. Platinum-group minerals (PGM) in the enriched zone at Dust Mountain occur in two separate parageneses, the first representing primary magmatic PGM and the second primary magmatic PGM that have been reduced to alloys during serpentinisation. Minerals in the first group were unaffected by hydrothermal alteration on account of their textural setting or stable chemical composition. Despite substantial alteration of the serpentinised assemblage, most evidence points to the dominant role of primary magmatic processes in determining PGM occurrence. Several base metals have nevertheless been introduced hydrothermally. With respect to surficial dispersion the single most important paragenetic factor was the reduction of sulphides to alloys, rendering them more susceptible to mechanical erosion and less so to chemical leaching. The different textural setting of Pd-group and Ir-group phases results in different dispersion characteristics, with major implications for stream sediment sampling

Apr 1, 1994

By Boorder De, B. S. Panov, A. B. Westerhof, V. A. Korcemagin

Paper presented at the conference on Economic geology in Europe and beyond II, models for <mineral deposits> in sedimentary <basins>, held in Keyworth, UK, 13-14 April 1994. The Hg and Sb deposits of the Mediterranean and Circum-Pacific Belts are often found at elevated structural levels, suggesting that their preferential occurrence in young orogenic belts is not a fundamental metallogenic feature but merely reflects their chances of surviving post-orogenic peneplanation. In western Europe their emplacement appears often to be related to late orogenic extensional events accompanied by a notable increase in heat flow. Although Nikitovka and Almaden have quite different settings, both appear to be related to deep-reaching shears. Together with brittle fault zones at higher levels, these provided pathways for fluid phases that originated at least partially within the mantle. The Nikitovka deposits are located in the Donets segment of the 2 000 km Pripyat-Dniepr-Donets palaeorift in the East European Platform. Initiated in the mid-Devonian with a possible Precambrian precursor, its listric boundary faults displace the Moho from a depth of about 50 km north and south of the rift to 35 km along the axes of the Pripyat and Dniepr segments. The steep central anticline of the Donets segment, within which the main Hg-Sb district is located, is interpreted to be associated with a reactivated fault reaching into the upper mantle. The Almaden syncline, formed during the Variscan Orogeny, may be an older pull-apart basin or half-graben associated with the collapse of the Cadomian Orogenic Belt. It is situated on a major ENE-WSW-striking shear zone which may represent a Late Cadomian transfer zone reaching into the mantle

Apr 1, 1995

By M. J. Scoble, L. M. Daneshmend, C. Hendricks

Paper presented at a meeting on: Artificial intelligence in the minerals sector, held in Nottingham, UK, 20 April 1993. An attempt is made to relate emerging technologies to education and training requirements by examining the nature of the Canadian mining industry's human resources. Particular attention is given to the trends evident in mine automation and their likely impact on instructional needs. The characteristics of "computer-aided instruction" systems are reviewed and related to the implementation and support of mine-wide monitoring and communication networks, which are seen as fundamental to the eventual automation of underground hardrock mines

Apr 1, 1994

By H. R. Thorpe

A floating gold dredge operating in coarse alluvial gravels of the Grey River on the west coast of the South Island, New Zealand, generated high concentrations of clay and colloidal particles in the dredge pond, which entered the groundwater system. Sampling was carried out at depths down to 20 m and it was found that variation of the length of the flow path occurred because of the movement of the dredge towards the piezometers. The alluvial gravels, the suspended sediments, the groundwater system and the water chemistry were all studied. Sediment concentrations were found to be highly variable with depth, but the relative concentrations in the depth profile were generally consistent as the flow distance shortened. The sediments were extremely fine and travelled further through the gravels than predicted. Comparison of field results with the available theory of deep filtration in clean beds of porous media gives some basis for estimating the behaviour of fine sediments in other alluvial systems

Jun 19, 1905

By Gruenewaldt von

Paper presented at the IAGOD international symposium on mineralization related to mafic and ultramafic rocks held in Orleans, France, 1-3 September 1993. The principles of shear-driven aggregation of particulate matter suspended in fluids, a common industrial method of concentration and separation, were applied to a convecting magma to estimate the time required to sparge or strip the PGE and Cr content and concentrate it into the boundary layers. It was calculated that an ore-grade (e.g. 6 ppm PGE) boundary layer about 1 m thick would require 100 000 years at most to form from a body of magma 500 m deep with a PGE content of 20 ppb. Since concentration would be most vigorous when the magma was warmest, at least half of this concentration would take place in the first 10 000 years. The effect of dispersive pressure in the boundary layer would generate a concentration high of refractories just below the top of each boundary layer and another just above the bottom. If the magma was a double-diffusive system, it might evolve by the downward cascade of enriched boundary-layer material into the hotter, lower magma layers, where depending on saturation levels chromites would equilibrate and sulphides undergo partial or total resorption, enriching PGE levels in any remaining sulphides. This cascade process would in time greatly enrich the lower regions in PGE-bearing sulphides and chromites

Apr 1, 1994

By B. R. Reddy, Y. V. Swamy, B. V. R. Murthy, H. S. Ray

The Ni oxide was reduced with a CO-CO2-N2 gas mixture and the effects were observed of process variables such as roasting temperature, time and CO partial pressure. Extraction of over 90% of Ni was achieved by ammoniacal leaching of ore that had been reduced for 1 h at 760 degrees C under a gas mixture with a volumetric CO/(CO+CO2) ratio of 0.57. The kinetic data were found to conform to the Ginstling-Brounstein equation. The applicability of this model was confirmed by evaluating the apparent activation energy with the use of independently constructed differential and integral plots, which showed an excellent match

Dec 1, 1995

By M. Moinpour, Y. K. Rao

The catalysed direct reduction of copper sulphide with carbon and lime was investigated in the range 850-1000 degrees C using Cu2S-CaO-C and Cu2S-4CaO-4C reaction mixtures. The effects of the catalytic additives K2CO3, Li2CO3, Na2CO3, NaF, Na2SO3 and the ternary eutectic (K,Li,Na)2CO3 were determined. Potassium carbonate, sodium fluoride and the ternary appear to be the most effective catalysts for the direct reduction process. The rate enhancement of the catalysed carbothermic reduction of copper sulphide in the presence of lime was explained in terms of the catalysis of the Boudouard reaction

Jul 1, 1991

By G. Kill

Although other energy commodities have developed successful futures contracts, long-term contracts still dominate the coal market. To establish whether coal markets will develop in the same way, coal price and volume data are tested against a set of criteria considered to represent some of the factors contributing to the development of a successful futures contract. Coal meets only some of the criteria: market players are subject to little risk in quite a stable market, have strong preferences for the specific nature of long-term contracts and profit from product uniqueness, each trade being individually negotiated. Potential structural changes in the western European market are not felt to be sufficient to create demand for a coal futures contract, but an empirical model has been developed that could form the basis of a further study to predict the potential for success

Aug 1, 1994

By P. H. Morris

Nineteen field trials of the co-disposal of fine coal tailings and coarse coal wastes were conducted at the dual Goonyella-Riverside mine in Queensland and at the Hunter Valley No. 1 and Warkworth mines in New South Wales, Australia. The profiles of and the sorting that occurred on the co-disposal deltas are described and an existing theory of subaerial deposition, originally developed for mine tailings alone, is shown to apply to the co-disposed wastes. This enables the dimensionless profiles of large deltas, which may take years to deposit, to be predicted from data obtained from a small delta formed in a few days or even hours

Jun 19, 1905

By H. Y. Sohn, Hang Goo Kim

Computer simulations were carried out using calcium ferrite slags containing 25 wt% CaO, and the results compared with those obtained using fayalite slags. There was little difference in overall elimination of Pb and Bi, but elimination of Sb and As was much lower with calcium ferrite slag. When calcium ferrite slag is used only in the converting stage and fayalite slag in the smelting stage, as in the Mitsubishi process, the contents of Sb and As in the blister copper can be kept to reasonable levels. This allows advantage to be taken of the considerably higher iron oxide-holding capacity of calcium ferrite slag than of fayalite slag at the high oxygen potential under converting conditions, thus preventing precipitation of magnetite. Satisfactory agreement was obtained between predicted values and observed data from a Mitsubishi converter

Jun 18, 1905

By R. A. Lord, H. M. Prichard

efficiency is discussed from both experimental and

Apr 1, 1994

By P. H. Morris

The profile of a delta formed by fine-grained mineral processing wastes, disposed of as aqueous slurries by subaerial deposition from a pipeline, has a significant bearing on the volume that is available for waste and water storage in a given containment structure. Earlier field data and laboratory experiments suggested that mine waste delta profiles could be predicted with high levels of accuracy using data from small-scale laboratory deposition tests. The relationships between the profiles of full-size and laboratory-model deltas were analysed using the principles of kinematic similarity and a recent theory of delta formation based on engineering hydraulics. Measured profiles of full-size and model coal-mine tailings deltas are compared and the prediction of full-size profiles discussed. It is shown that the data-derived laboratory-model deltas are insufficient to allow accurate prediction of full-size delta profiles. Initial slope data or other, equivalent data for the full-size delta are also required

Apr 1, 1996

By M. C. Ruiz, M. E. Godoy, J. B. Rivarola, M. W. Ojeda

The amount of Pd recovered from an exhausted olefin hydrogenation catalyst was found to depend on mixing technique, particle size, carbon percentage, chlorine flow, reaction time and temperature. Pd extraction was total when a sample in the 125-175 micrometre particle size range was chlorinated for 60 min at 723 K with 20 cm3 Cl2/min, for 60 min at 748 K with 30 cm3 Cl2/min and for 30 min at 773 K with 30 cm3 Cl2/min. No C addition was needed; the initial C content of the catalyst was sufficient for total recovery. Pd extraction was also affected by heat treatment in different atmospheres before chlorination. Treatment with O2, N2 and N2 with traces of O2 led to different degrees of oxidation of C and permitted the formation of oxidised Pd species. Thermal pretreatment in N2 with traces of O2 was most conducive to Pd extraction

Jun 21, 1905

By S. A. Sayed, M. N. M. Ahmed, M. A. Doheim

The performance of a 12.7 cm hydrocyclone was investigated by considering the effect of design variables (diameters of the vortex finder and apex) and operating variables (pressure drop and solids content of the feed) at a medium feed solids concentration of mixed minerals. Cut-size was found to be the most important parameter in hydrocyclone design and operation. The effect of feed pressure in reducing hydrocyclone cut-size is less pronounced at medium feed solids concentration with a mixed mineral feed. The choice of vortex finder diameter and apex diameter becomes more sensitive at medium feed solids concentrations. The effect of feed solids concentration in increasing the cut-size becomes less marked at higher concentrations. Predictions of an empirical model were found to be in good agreement with experimental data. Comparison of results obtained from the model with those predicted by theoretically derived models showed the latter to be more promising, with the turbulent two-phase model giving closer agreement with the experimental data

Apr 1, 1995

By W. E. Stephens, A. J. Boyce, D. Lowry

Paper presented at Mineralisation in the Caledonides, the Mike Gallagher memorial meeting held in Edinburgh, 27-28 June 1996. An integration of S isotopic, fluid and mineralogical data for granitoid-related mineralisation showed that the porphyry systems had a predominantly subcrustal magma source, but the inner magma pulse of two-mica granite in the Fleet pluton was derived mainly from reduced sediments. The porphyry-style mineralisation formed from boiling fluids at high crustal levels, with a moderately saline fluid percolating down to the upper veins as they cooled but not penetrating the deeper Talnotry deposit. Veins in peripheral greywackes have a significant magmatic component but also incorporated CO2-rich components and metals released by dewatering of host sediments in response to granitoid intrusion. The low grade of regional metamorphism resulted in the significant fluid input from country rocks which led to the more exotic mineral compositions, especially where argillaceous sediments were involved

Jun 19, 1905

By V. A. Melezhik, A. H. Green, L. N. Grinenko

Finally, a theoretical model is constructed that takes

Aug 1, 1994

By D. M. A. Flight, G. E. M Hall, P. R. Simpson

theoretical viewpoints.

Apr 1, 1994

By A. P. Whittlestone, J. D. Johnson, R. J. Pine, M. E. Rogers

standpoint. The effect on efficiency of collisions

Apr 1, 1995