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By Zhigao Xu, Ruan Chi, Zhenyue Zhang, Yaoyang Ruan, Zhengyan He

Thorium is frequently the main radioactive element in rare earth ores and is a resource that can potentially substitute for uranium. Thorium must be separated from rare earths in order to obtain products with low radioactivity. There are abundant resources of thorium in the rare earth ores in China, especially in Baiyunebo mixed ores. As an associated element coexisting in rare earth ores, thorium is, or can be, separated from rare earth concentrate, iron concentrate, as well as from waste water and slag to achieve recovery of thorium. The methods of separation include ion exchange resin, liquid-liquid extraction, and liquid-solid extraction. TBP extraction has been the main method applied to separate thorium by domestic and foreign scholars. This paper presents a comparison of different processes for the separation of thorium from rare earth ores, especially Baiyunebo mixed ores, single bastnaesite and monazite ore, and provides suggestions for the future recovery of thorium resources.

Jan 1, 2014

By T. H. Adair

"IntroductionCONTINUOUS casting of ferrous and non-ferrous metals is not a new innovation. Patents describing machines for continuous casting are on file as far back as the year 1842. In the middle of the last century, Sir Henry Bessemer conceived and built a continuous casting• machine for the production of mild steel sheet.The production of billets and slabs of both non-ferrous and ferrous metals is being carried out by the continuous method on a fairly large scale on this continent and abroad. At present, the volume of production of •copper and aluminum and their alloys in billet and slab form is much greater than the continuous casting of steel products. The new installation of a continuous casting unit at Atlas Steels, Limited, is designed primarily for the casting of alloy steel billets and slabs.As an introduction to the art of continuous .casting of metals, it is interesting to examine a few of the many devices which have been developed. As previously mentioned, Sir Henry Bessemer constructed a machine for the direct casting of mild steel sheet. His discoveries and ideas of continuously casting steel formed the foundation for the work of other pioneers in this field, all of whom have contributed to the improvement of this art through the ensuing years. The machines which will be selected for examination are those of Bessemer, Poland-Lindner, Williams, Ennor, and Junghans. The last unit to be discussed will be a modification of the Junghans machine recently installed at Atlas Steels."

Jan 1, 1954

The morphology of environmentally assisted cracks in stressed pipeline steel has been investigated, For a dilute and neutral solution (NS4) simulating ground water in contact with the steel, semi-elliptical cracks grow faster on the surface (2c) than in the depth (a), hence, the aspect ratio (a/c) decreases, This is explained using a deterministic concept since corrosion is dominant and the primary constraint is the conservation of charge, By contrast, when mechanistic conditions prevail, significant growth occurs in the depth, When underloads are imposed in the loading history, temporary accelerations in crack growth occur because corrosion rather than mechanical effects become dominant.

Jan 1, 2005

By W. D. Fogwill, P. J. Clarke

"The Dawn Lake uranium deposits are located 340 km north of La Ronge, Saskatchewan, in the Athabasca Basin between the Midwest Lake and Rabbit Lake deposits. Four zones of uranium mineralization, called the ""11, 14, 11A and 11B Zones,"" lie within the Athabasca Sandstone, at the sub-Athabasca unconformity and in the basement.At Dawn Lake, approximately 100 metres of Helikian Athabasca Group clastic sediments overlie Aphebian Wollaston Group pelitic and calcareous metasediments and pegmatites. Uranium with some nickel, cobalt and copper, occurs near the sheared stratigraphic contact between calc-silicate gneiss and graphitic, pyritic pelite. The mineralization lies in an area of low magnetic susceptibility which is thought to represent a rock sequence lying stratigraphically high within the Wollaston Group. There is no obvious vertical displacement of the unconformity by faulting, despite considerable brecciation, shearing and slickensides seen in the basement rocks. This suggests horizontal displacement on steeply dipping wrench faults as the main tectonic control along the 11, 11A and 11B trend.Below the Athabasca unconformity, the Wollaston Group rocks are altered to fine-grained mixtures of clays, chlorite and silica commonly called regolith. Along the mineralized trend post-Athabasca fracturing and (or) compaction have occurred through this clay-rich alteration zone, causing the steeply-dipping primary foliation to become contorted. This ""crenulated"" horizon can reach depths of 35 metres below the unconformity and is thickest along fault zones in the calc-silicate rocks. The ""crenulite"" is a distinctive unit which at Dawn Lake is commonly found above pods of ore located deep below the unconformity.Much of the mineralization in the 11A and 11B Zones occurs above, beside and below the thickest part of the crenulated zone, although the crenulated rock itself contains negligible amounts of carbonate, pyrite and uranium. Intense vuggy alteration and collapse breccias are found in calc-silicate rocks deeper and to the west of the 11A and 11B mineralization. There are at least two ages of uranium deposition in the basement zones, shown by small bright cubes of ""pitchblende /"" overgrown and replaced by duller botryoidal ""pitchblende II. ""Sooty pitchblende and yellow secondary minerals are the result of still younger reworking.The geological setting of mineralization, along the contact between carbonate-rich calc-silicate rock and pyritic pelite, suggests that the uranium was concentrated at a pH/Eh boundary located between deeply weathered, carbonate-rich and sulphide-rich basement rocks."

Jan 1, 1986

Flotation of a mineral bearing particle is the result of successful completion of a chain of events, such as, producing particles with sufficient exposure of the valuable mineral on the surface, reagent adsorption, suspension of the particle in the pulp, collision of particle with air bubbles and subsequent attachment, ascending to the froth column and transport to the concentrate stream, among others. These sub-processes in turn are affected by the feed properties such as size and density, and process variables such as size of air bubbles, degree of turbulence in the cell, particle/particle interactions etc.. Thus, inefficiencies occurring in any one or more of the above processes will result in inefficient flotation performance. In spite of its dependency on a wide variety of sub-processes, flotation performance is commonly modelled based on first order kinetics using two or three parameter models. As the model parameters may be affected by several of the sub-processes mentioned above, interpretation of their variations and identifying the specific causes is extremely difficult. Of the many factors that influence the flotation performance, liberation information of the particles such as the grade distribution and surface exposure are considered vitally important. In this paper, it has been demonstrated a) how a predictive liberation model may be derived and used in quantifying the liberation information of the particles produced at various grind sizes and b) how the flotation process may be modelled by explicitly incorporating the liberation information, thereby improving the accuracy of the model. Comparisons of the observed data with the proposed model and those of published liberation/flotation models have also been made.

Jan 1, 2016

By G. Tairova, J. Ioffe

Arsenic, selenium and mercury species are common contaminants in mining aqueous streams and present significant environmental and health problems. The objective of this project is to investigate methods to lower the concentrations of these elements in mining aqueous streams. A new composite media for removal of these elements of concern from mining effluents was developed. The results of bench scale and pilot plant experiments, using the media, indicated removal of arsenic, selenium, mercury and other elements of concern below detection limits.

Jan 1, 2014

By E. Ghali, B. Arsenault

Aluminum alloys play an important role in the manufacturing of air and ground vehicles. However, with such alloys, corrosion damage is often found on structural components subjected to fatigue loading. The alloying provides large benefit in terms of the high specific tensile strength (ultimate strength/density ratio) to the aluminum alloy but causes the aluminum alloy to be more sensitive to localized corrosion due to complex microscopic heterogeneities such as secondary phases. This paper investigates thermal spray coating namely arc spraying to evaluate the protection against environmentally assisted cracking (EAC) and localized corrosion on Aircraft structural 7075 T651 aluminum alloys. In particular, EAC and pitting corrosion at the interface coating-substrate are a challenge for thermal spray protective coatings on aluminum alloys under cyclic load and immersion. To address these issues, different surface preparation techniques prior to arc spraying were considered such as chemical de-oxidation, laser ablation, shot peening and grit blasting. Results indicate that surface preparation and improved coating process parameters play an important role to provide a coating conferring a protection against both localized corrosion and EAC.

Jan 1, 2006

By Craig Faulkner

Discharge cones for large Semi Autogenous Grinding (SAG) and Autogenous Grinding (AG) mills are subjected to high wear as significant volumes of ground ore and slurry exit the mill. With the larger diameter mills of 32ft to 40ft in size becoming the norm, very high, concentrated wear is highlighting the limitations of conventional discharge cones and frequent changes are subsequently required. This paper outlines the advances made in the design of the Bullnose discharge cone. Superior wear materials to increase wear life over conventional rubber or chrome-moly steel discharge cones and the introduction of key design features to reduce reline times and improve fit and safety during installation, offer significant opportunities for the mill operator. Collated from multiple case studies, the wear data and reline history from 2004 to present clearly illustrate the way in which superior component longevity has reduced the frequency of relines over the life of the product to increase mill availability and effectively increase the tonnes milled in a period.

Jan 1, 2012

By B. Hart, D. J. Miller, J. T. Francis, M. C. Biesinger, Smart. R. St. C.

Diagnosis of the surface chemical factors playing a part in flotation separation of a valuable sulfide phase requires measurement of the hydrophobic and hydrophilic species that are statistically different between the concentrate and tail streams. Time of flight secondary ion mass spectrometry (ToF-SIMS) can be used to identify sufficient particles of a specific mineral phase for reliable statistics determining a mean value for each species with 95% confidence intervals (1). Using the region of interest (ROI) facility in the Tof-SIMS software, a mass spectrum from each particle, at 1-2 monolayer sensitivity, is recorded and stored. This analysis is reported for a chalcopyrite / pyrite / sphalerite mineral mixture conditioned at pH 9 for 20 minutes in order to study transfer of copper from chalcopyrite via solution to the other two mineral surfaces since this mechanism can be responsible for their inadvertent flotation in copper recovery. Analysis from mineral selection based on specific ToF-SIMS signals (eg. Pb, Zn, Cu, Fe, Fe/Cu) indicated no statistical difference in the copper intensities on pyrite and sphalerite after this conditioning. Principal component analysis (PCA) of the ToF-SIMS imaging data identifies combinations of factors strongly correlated (positively or negatively) in images or spectra from mass spectra recorded at each of 256x256 pixels in a selected area of particles. PCA is a better method of selecting minerals due to multi-variable recognition. It has clearly separated a statistical difference in copper intensities between the sphalerite and pyrite phases. The method has been extended to samples from an operating plant again with excellent phase recognition and diagnostic surface chemistry.

Jan 1, 2004

By Behzad Vaziri Hassas, Firat Karakas, Esra Tanisali, Mehmet S. Çelik, Ahmad Hassanzadeh

Coagulation is basically an aggregation process where particles settle under the influence of interfacial forces with electrostatic forces playing a governing role. Although particle morphology consisting of shape and roughness dictates the physical encounter of two particles, their eventual coagulation is not only influenced by columbic forces but also other interfacial forces such as hydrophobic interaction, which affects the extent of aggregation of particles through increasing the distance of interaction. Roughness is well known to increase the effective contact angle on hydrophobic surfaces and also enhance interfacial forces. In this study, the effect of morphology of particles and particularly roughness on the settling velocity and in turn coagulation tendency was investigated. Batch settling tests (BSTs) of different particle morphologies were investigated as a function of pH. Two different morphologies of silica particles were utilized with the same particle size distribution (PSD) including smooth-spherical and rough-spherical (Etched). Rough particles were prepared by acid etching technique using hydrofluoric (HF) at different time intervals (15-300 sec). Etched samples were identified and quantified by optic profilometry. Settling test results showed that the settling velocity of particles in a suspension of 2% solids in the massive settling region is significantly affected by particle morphology of the suspension. Coagulation results further revealed that aggregation of rough particles is faster than smooth-spherical particles. Coagulation results are elucidated on the basis of particle morphology and its effect on distance of separation through hydrophobic forces.

Jan 1, 2016

By C. R. Edwards, D. G. Feasby

"Over the last 50 years disposal of uranium mill tailings has evolved from dumping untreated tailings into the nearest depression to depositing chemically-stabilized tailings into highly engineered management facilities. This paper describes the evolution of disposal methods and the criteria which have determined the development path followed. Remediation techniques to bring older and now unacceptable tailings deposits into satisfactory compliance with today's· regulations are reviewed.With the closure of the uranium mines in Elliot Lake, Ontario, considerable effort is being made on decommissioning the tailings areas by developing long term maintenance of water covers. The innovative methods being used to develop these water covers are detailed. Methods now under development in Saskatchewan for subaqueous deposition of high density or paste tailings for permanent disposal in mined out open pits are described.SummaryThe technology for uranium mill tailings disposal in Canada has evolved considerably over the past 51 years. This evolution has been driven by an improving understanding of how best to safely and permanently store tailings, in conjunction with stricter environmental protection regulations. Old sites are being decommissioned in situ, but may require long term care and maintenance. The use of water covers is an important technique in eastern Canada to prevent intrusion, radon evolution and, for the Elliot Lake tailings, acid generation. The major drawback of water covers in any above ground disposal method is the requirement that a long term maintenance and monitoring plan be put into effect for each site.New higher grade mines in Saskatchewan will increasingly use disposal in mined-out pits using the pervious surround method and/or paste tailings technology as a method to permanently dispose of these wastes and to permit “walkaway” after a few years of monitoring."

Jan 1, 1996

By Nabeel Khan

Annual oil production from the Canadian Oil Sands in Northern Alberta has been rising for several decades, and more ore and overburden are excavated each year from an increasing number of open pit mines. Overburden meeting certain specifications will be used to dam tailings and fill open pits, but the remaining material must be stored in overburden storage structures (OBSS). Well-designed overburden storage structures are more stable and cost less in the short- and long-term. The purpose of this paper is to explore OBSS designs that will be stable yet economical in the short- and long-term. The geological background of the site is briefly discussed, including the effect of each of the main geologic layers (recently deposited till and muskeg, Clearwater Formation clay shales, McMurray Formation oil sands, and the Devonian limestone) on the slope stability of the OBSS. Cost is considered in the analysis when balancing between minimizing costs (steeper slopes) and acceptable factors of safety (flatter slopes), all the while considering the financial consequences of failure. Potential failure planes are identified and probabilistic analysis is conducted on the critical failure surface. The variations in the factor of safety caused by varying pore water pressure, friction angle, and cohesion, are plotted and discussed.

Jun 1, 2012

By B. Jakovljevic, M. D. Soderstrom, T. McCallum, A. J. Quilodrán

Cytec has developed a new organophosphorus based solvent extraction (SX) reagent for rare earth separations. The new product, CYANEX® 572, has been formulated to allow efficient extraction while minimizing the strip acid requirements. The optimization of formulation strength is expected to significantly reduce the operating costs of these circuits. Modeling capabilities for CYANEX® 572 (similar to those used successfully in Cu and Co/Ni SX) have also been developed to aid in the design and optimization of the SX circuits. Simulations will be shown comparing CYANEX® 572 to a traditional rare earth extractant.

Jan 1, 2014

By Francois Charette

Corrosion is a significant factor affecting the capacity and working life of ground support. The paper explores a relatively simple method to predict the load capacity of a support system using a Monte Carlo stochastic approach. The analysis uses published field data on existing ground support to evaluate the applicability of the method and its predictive performance. Discussion on corrosion rates found in the field and predicted from laboratory measurement is provided.

Jun 1, 2012

"There are a number of disciplines in the minerals industry for which concern has been expressed regarding the sustainability of human capital. The boom-bust cycles that occur in the industry, the trend in tertiary education towards consolidation or in some cases cessation of minerals related programs and the increasing frequency of fly-in fly-out operations can all contribute towards a decline in the number of professionals with basic skills in process mineralogy. This paper describes approaches taken by the authors to incorporate process mineralogy into three levels of education, namely undergraduate, recent graduate and experienced professionals. The primary objective in designing the learning activities is the development of authentic learning experiences that provide participants with relevant skills in process mineralogy. Selected examples of approaches used by other education groups globally to address this issue are also provided.INTRODUCTIONThe boom and bust cycle of the mining industry has trickle down effects in tertiary education in terms of the ability of universities to consistently provide high quality graduates with relevant skills. When the commodity price surged in 2002 skills shortages in critical resource related professions were reported and despite investment in skill development there was a view from employers that not enough young people were graduating from relevant education programs (PricewaterhouseCoopers, 2012). At the time this signalled positive growth for engineering disciplines catering to the mining industry, however during the downturn cycles, most recently since 2012, graduates exiting from the discipline can find employment difficult and this contributes to reduced enrolments in subsequent years. From an AusIMM (Australasian Institute of Mining and Metallurgy) members’ employment survey conducted in 2013, more than half of the graduates exiting from disciplines related to mining and minerals were not confident of finding employment (AusIMM, 2013). In the long term the concern is not only how to sustain enrolment and graduate numbers but also to provide the opportunity for students to acquire the professional skills that they require to make them attractive to industry.Maintaining and sustaining core competencies in the minerals discipline is an ongoing challenge. There have been a number of recent papers on this issue presented at international conferences (e.g. McCaffrey et al, 2014; Drinkwater and Napier-Munn, 2014) and there is general agreement that one of the ways in which the deficit in foundation concepts can be addressed is through workplace development. Drinkwater and Napier-Munn (2014) presented data from a survey of industry professionals that indicated that more than 90% of respondents undertook on average 30 days of training each year of which approximately 5 days was professional short courses."

Jan 1, 2016

By P. Nelson

Extending the campaign life of the Mitsubishi furnaces at Xstrata Copper's Kidd Metallurgical Division Copper Smelter has been a major focus of attention for many years. One aspect of this effort is real time monitoring to detect abnormal conditions and safely shut the furnaces down before significant damage occurs. Traditional real time methods of monitoring the integrity of refractory furnaces containing molten metal include alarms on individual temperatures of the refractory or cooling water. The need to set alarm limits which are not exceeded across the range of normal operating conditions leads to a system that only provides a limited warning, if any, before a failure occurs. Integrity monitoring systems that look at many different signals and alarm only changes in the relationships between the signals have been implemented on the smelting and converting furnaces. The systems are based on principle components analysis (PCA) models and implemented with the monitorMV software package. These provide much more sensitive and selective alarms so that changes in integrity are alarmed well in advance of any event. At a critical alarm level, the converting furnace is set to automatically shut down so that operating and technical personnel can review the situation. The configuration of the systems and operating experience with them will be discussed.

Jan 1, 2007

"INTRODUCTIONThe Department of Energy, Mines and Resources has recently developed two automatic controls for use in the cyanidation circuits of Canadian gold mills. These controls are the alkalinity probe and the Continuous Cyanide Titrator both of which are discussed in the paper ""Instrumentation in the Cyanide Process"".(1)In May 1966 these process controls and associated recording equipment were installed in the Bralorne mill by two Scientific Officers from the Department. The object was to determine if the equipment was amenable and applicable to this particular circuit. The purpose of this paper is to discuss the performance of the equipment over a test period of 4 months.CONCLUSIONSThe results of test work to date indicates that both the Conductivity Probe and the Continuous Cyanide Titrator would be an as set to the operation of the Bralorne mill.The conclusions are generalized as follows:-(1) At a milling rate of 100, 000 tons per year the expected reductionin reagent consumption would give a direct saving of 37, 660 lbs of lime@$0.030 per lb and 15, 790 lbs of sodium cyanide@ $0.175 per lb. Such cost savings would pay for the equipment and installation costs within a 30 month period"

Jan 1, 1967

By J. Walenzyk

This report investigates the limited use of super large backhoes in surface mines around the world. The demand for super large (> 700 t) hydraulic excavators is rising and most of the machines are sold as front shovel (FS) application. Despite advantages in faster cycle times super large backhoe (BH) machines are a minority (ca. 1% of the total machine population). This investigation is based upon the comparison between the volumes available to the BH and FS in one block and before the machine needs to move. The working conditions are created with standard parameters as given by Original Equipment Manufacturers of hydraulic excavators regarding bench height, angle, and material density. The travel amount of both machine types is derived from these volumes and compared. Furthermore, the travel amount of super large BHs is compared to the travel amount of smaller mining BHs and evaluated based on attachment length and bucket size. The calculations conclude that the volume of material recoverable in a single spot is about 75% higher for FSs. This leads to an increased travel for BHs. The combination of both the increased appearance of electrical driven machines (in the class of > 700 t excavators) and the travel amount lead to a high risk of damaging the cable or the excavator. Enlarged wear on the travelling parts is also attended by the higher travelling. A direct comparison of commonly found working set ups shows that the ratio between volumes is 32% which leads to an increased travel amount. In comparison with a 250 t BH, the calculation shows that the smaller BH is able to reach nearly 50% of the volume of the super large BHs. The main reason for this is the respectively high reach on smaller machines which, combined with other factors, leads to a significantly higher number of BHs in lighter classes.

Aug 1, 2013

By D Martín, G. Díaz, F. Cubeddu, A. B. Mejias

The Modified ZINCEXTM Process (MZP), developed by Técnicas Reunidas, is an industrially proven flexible process. It can handle a wide range of primary and secondary raw materials, producing SHG zinc. The core of the Modified ZINCEXTM Process is the zinc solvent extraction unit. This unit is an effective barrier for any leachable impurities present in the raw material. As a result of this an ultra-pure zinc solution is always obtained. The high versatility of the process makes the application of the technology in different scenarios possible. MZP can be effectively applied when developing a whole new plant (Skorpion) or adapting its scheme to an existing refinery (Akita), in both cases giving the same results. Flexibility in terms of capacity of the plant is a great advantage of the MZP, there is the possibility to adapt the global process to a wide range of production capacities. Zinc production capacities of over 150 000 t/a may be achieved with a single solvent extraction plant train. The robustness of the Modified ZINCEXTM Process has been recently proven on two new plants currently in operation: Portovesme (Italy) and Horsehead (USA) after start up during 2013. The status of both plants is described in this paper.

Jan 1, 2014

By D. C. Reid

This paper describes the latest results in research and development currently being undertaken by the CSIRO Mining Technology Group to advance the automation capability of continuous mining equipment in underground coal mining operations. This research delivers enabling technologies that are essential in achieving increased roadway development rates as well as providing a safer working environment for underground mine personnel. Details are presented on technical developments and results of large-scale above-ground experiments conducted under field-realistic conditions. These experiments demonstrate the performance of the ?self-steering? capability which will enable a continuous miner (CM) to automatically maintain a given mining heading and mining horizon under production conditions. A primary technical requirement of this automated functionality is the means to accurately determine both the location and orientation of the CM in real-time. Test results of a high performance navigation system utilising vehicle motion aiding technologies are presented. This system combines high performance inertial sensors, and custom-developed radar to achieve a navigation-grade guidance system. Comprehensive performance evaluation has been conducted using a scale skid-steer mobility platform operating autonomously through a typical roadway development mining pattern with a total path length of 2700 m and mission duration of 112 min. Results from this evaluation demonstrate that the sustained accuracy of the navigation system exceeds the original project expectations and is well suited to the requirements for this underground mining application. There are presently no known alternative methods for providing a practical and accurate three-dimensional guidance solution in this application. This achievement represents a significant milestone in delivering a step change improvement in underground coal mining roadway development.

Aug 1, 2013