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By N. Djilali

Many of the transport phenomena encountered in proton exchange membrane fuel cells occur intrinsically at the microscale level. Physically representative models that fully account for the salient physico-chemical and transport processes in PEM fuel cells are necessary to achieve truly predictive models that can be used with confidence to: (i) gain a better understanding of in-situ processes and couplings, (ii) explore new concepts, and (iii) support design and optimization. The development of more general, rationally based macroscale models requires use of knowledge on the microscale level to provide guidance, and to determine the required parameters and coefficients (model "constants"). In this paper we present a new membrane transport model, the binary friction membrane model (BFM2), recently developed to account for coupled protonic and water transport in polymer membranes. This general model is based on rational and physical consideration, removes several of the limitations of the empirical models used to date, and is formulated for all purfluoro-sulfonic acid membranes. The use of the BFM2 in a fuel cell model is illustrated highlighting significant performance predictions compared to existing empirical model. The second part of the paper addresses the fundamentals of two-phase transport in hydrophobic gad diffusion media. Computational and experimental visualizations resolving the microscale dynamics of water transport between the fibres of a GDL are presented, revealing transport mechanisms that are, contrary to assumptions used to date, dominated by fingering and channeling.

Jan 1, 2005

By R. F. Engler

"IntroductionThe Coal Branch region of west-central Alberta has been the focal point for unprecedented exploration and development activities over the past ten years prompted by the renewed markets for high-quality thermal coal. Although mines were developed and operated extensively throughout the region from 1910 until 1960, information relating to the detailed stratigraphy of the coal measures and their areal distribution tended to be localized to individual mine sites. Continuity along trend was impaired by a paucity of outcrop restricting geologic mapping to stream bank and roadside exposures. Recent studies and subsequent publications by Jerzykiewicz and McLean of the Geological Survey of Canada (1978, 1980) have established a detailed sedimentological model and defined the stratigraphic nomenclature for the region . The term Coalspur Beds has been adopted to describe the coal-bearing sequence between the overlying Paskapoo Formation and underlying Brazeau Formation. Complete sections of the Coalspur Beds have been compiled from sub-surface borehole data and published by Manalta Coal Ltd ., Dentherm Resources Ltd. and Luscar Stereo Ltd. This paper is an attempt to correlate this information on a regional basis to illustrate trends within the Coalspur Beds."

Jan 1, 1986

By L. Bichler

Utilizing thermal analysis techniques, pioneering research into the solidification mechanism of a popular magnesium alloy AZ91E cast by the Lost Foam Casting (LFC) process was carried out, Foam characteristics, section thickness and application of vacuum were seen to have profound effect on the cooling rate, thermal gradients and casting temperature profiles.

Jan 1, 2005

By J. P. McGeer

"With the ever-increasing flood of new science and technology has come a new approach to design. The combination of these factors has produced an ever-accelerating pace of materials substitutions.Examples to illustrate the points made above will be given. An overview of the current new materials fields will follow. Finally, the particular nature of the challenge for Canada will be discussed. IntroductionThere are a number of forces currently at work which make it mandatory that the Canadian resource sector re-examine its strategies and policies. The author thinks there need to be very significant changes in the business plans of Canadian mineral processing corporations. Current changes in our environment demand such a reaction.The changes in our environment include more rap id substitution of materials; a significant alteration in design philosophy; the global economy; and market saturation and market diversification in dev eloped countries.This paper will cover the changes and illustrate how they will affect the Canadian resource industry. It will show some of the ways that Canadian corporations are reacting to maintain profitability. Finally, some policy issues will be considered"

Jan 1, 1988

By Denni Nikols

"Planning for coal beneficiation in the electric utility industry is relatively complex, involving the coordination of experts and specialists in a broad range of fields, as well as compliance with a wide variety of government regulations.This paper examines the role of the planner, reviews possible benefits of coal beneficiation, identifies potential problems and illustrates a typical planning schedule.The steps involved in the planning process are:Step I-Bench- and pilot- washability studyStep 2- Wash plant designStep 3- Power plant and boiler designStep 4-Mine designStep 5-Major environmental and technical problems to address.IntroductionElectrical utilities and coal have a long and intimate relationship . Cleaned coal is becoming an increasingly popular fuel with the utilities for a variety of reasons. Generally, the greatest impetus to burn a cleaned or prepared coal fuel comes from the need to control airborne pollutants.Long-range planning is a standard practice for electric utilities, forecasts of demand must be made well into the future. Since the lead time required to provide new facilities is often as long as 10 years and the cost very high , planning becomes an important task.For a utility that owns and directs the operation of its coal mines, the mine planning or fuel acquisition planning takes on the magnitude of other corporate planning functions. It is from this perspective that a utility would view coal preparation. Except for the interaction of a coal-fi red plant on the actual mine design the planning considerations o f a beneficiating facility for a captive mine or a contract raw coal supply are about the same. Because TransAlta Utilities is currently supplied from captive mines, this discussion will tend to focus in that direction.It is the role of a planner to plan. This is easy to say but it is not always easy to do. Often we are working within a context that resembles the geological time scale. Frequently the objectives are not clearly defined when we begin and ultimately our plans are tested in the waters of government regulations and cost benefit analyses .Planning for beneficiation of Plains coal, or any coal, provides just such a test. The planner's role in this endeavour requires a wide vision. While parts of the process may be amenable to classical methods of project scheduling, the broad range of subjects and interaction of seemingly unrelated tasks is sure to obscure some of the considerations that must be made. Therefore, the planner's chief role is coordinating the work of many experts and specialists toward the final objective.Among the specialists are combustion , geo technical, mining, civil , and mineral processing engineers , geologists, hydrogeologists, soil, and reclamation experts to list a few.When one considers coal beneficiation, the planning part o f that consideration is probably more complex than any other single engineering function. Due to the company's location in the Alberta Plains and the proximity o f the mine to the thermal generating station, this paper will tend to emphasize that situation.Beneficiation may offer some advantages over run-of-mine coal to the power plant opeator. Some of these advantages are: removal of a contaminant, power plant efficiency gains , lower plant capital costs (for new plants), possible lower mining costs."

Jan 1, 1984

By L. E. Gutiérrez

A new filtration model based on porous media transport theory is presented. It predicts capacity and final moisture content in the filtered cake as a function of design and operational variables at the plant. FilterSim® is the computer code where this new model is programmed. Application of FilterSim® to ten-month operation of an industrial copper concentrate filtration plant is shown on a daily basis and using a single set of internal parameters for the whole period. Average error is less than 5%, both in capacity and moisture estimation. FilterSim® abilities to optimize industrial filtration plants as well as to estimate future budgets are illustrated with several real examples.

Jan 1, 2007

By Robert D. Brown

"All ten Canadian provinces have now tabled their 1981 /82 budgets . Only the provinces of Ontario, Quebec and British Columbia made more than minor modifications to their tax structures, with both Ontario and Quebec imposing major tax increases. In the past year, the federal budget was also released in the spring. Not so this year: we have that to look forward to in the fall!This month, Tax Notes presents a brief summary of the more significant tax changes introduced at the provinciallevels in the last months.Summary of provincial tax rate changesThe tax changes in this year's provincial budgets were both up and down- but there were far more tax increases than tax cuts.At the corporate tax level, two provinces, New Brunswick and British Columbia, increased their general corporate income tax rate; the former by two percentage points and the latter by one percentage point. Quebec, rather unexpectedly, sharply cut its corporate tax rate on business income, but increased some of its other business taxes at the same time. British Columbia reduced its corporate tax rate on small business income by two percentage points and Saskatchewan by one percentage point."

Jan 1, 1981

By R. C. Beard

"The Ontario Ministry of Natural Resources has recently initiated several incentive programs to encourage and facilitate the development of new mines in northwestern Ontario. Some are privatized out to consultants and contractors. The status of three of these programs will be reviewed in this paper.IntroductionOne of the main objectives of the Mineral Resources Group of the Ontario Ministry of Natural Resources is to encourage and assist mineral exploration and the development of new mines in the Province. Programs to accomplish this objective are largely carried out through two Branches in the main office (in Toronto), the Mineral Resources Branch and the Ontario Geological Survey, and also a number of regional field offices scattered across Ontario.The function of the Mineral Resources Branch is to identify and administer effective policies that will ensure maximum benefits to the Province from mineral resource extraction.One of the most important factors in ensuring effective exploration in the Province is the availability of a good geosciences data base from which to work. It is the responsibility of the Ontario Geological Survey to develop and continually update this data base, providing, to both the public and private sector, an inventory and analysis of the geology and mineral deposits of the Province.The main functions of the regional field offices are to provide technical data and advice to exploration companies and prospectors, to encourage and assist exploration, and to provide information and general assistance to producing and developing properties to facilitate resource development and extraction. This is accomplished through the offices of the mineral resource coordinators and resident geologists. In northwestern Ontario, these field offices are located at Thunder Bay, Kenora, Red Lake and Sioux Lookout.To accomplish their objectives, the Ontario Geological Survey and the regional field offices carry out regular, ongoing geoscience and other mineral resource programs, under their base funding."

Jan 1, 1982

By K. Bachmann, M. Rudolph, U. A. Peuker, H. H. Duong, T. Heinig, T. Leißner, H. Schubert, Helmholtz-Institute Freiberg for Resource Technology, Technische Universität Bergakademie Freiberg

"Minerals can be liberated by random fracture of particles into smaller fragments or by detachment along phase boundaries. These two mechanisms represent borderline cases. When ores get comminuted the liberation of minerals is achieved to some extent by both mechanisms. This article describes a method to determine the extent of transgranular and intergranular fracture on surface exposure of minerals based on 2-dimensional liberation analysis.The approach uses the non-biased surface information like phase specific surface area (PSSA), phase specific free surface (PSFS) and phase specific locked surface (PSLS) of minerals and their change with comminution. The amount of transgranular and intergranular fracture on surface exposure can be calculated using the phase specific surface parameters.A sedimentary rock (apatite ore), an igneous rock (nepheline-syenite) and an artificial material (copper slags) were ground to different fineness. Based on the mineral liberation analysis (MLA) of feed and products, the extent of phase boundary fracture on the surface exposure of the minerals is studied.INTRODUCTIONMinerals can be liberated ether by comminution or by detachment (Gaudin, 1939). Liberation by comminution is a random fracture mechanism, which is not being influenced by ore texture, grain boundaries and mineral features (transgranular fracture). Liberation by detachment represents a fracture along grain boundaries (intergranular fracture). Random fracture often is named as the dominating mechanism for the liberation of ore minerals. This has been the basis to simplify models for liberation modelling (Barbery, 1991; King, 1979; Meloy, 1984) assuming that the probability of cracks moving along grain boundaries is zero. Thus, no interfacial area is lost during comminution."

Jan 1, 2016

By Nural Kuyucak, Bohumil Volesky

"Extensive screening revealed a seaweed (alga) biomass type which in its non-living state possesses a very high cobalt sequestering capacity comparable to that of activated carbon and the ion-exchange resin currently used in the cobalt production process. Performance of the new bio-sorbent material was studied by examining its equilibrium metal uptake isotherms generated under different solution conditions such as initial cobalt concentration pH, temperature, and the presence of selected cations and anions. The rate of cobalt uptake was determined, which is a crucial parameter for recovery process design. Almost all cobalt sorbed can also be desorbed with a solution of CaCI2. The bio-sorbent material can be used repeatedly in the sorption-desorption cobalt concentration process. IntroductionIt has been well documented that certain types of microbial biomass, living or non-living, possess a high potential to sequester and accumulate inorganic ions present in aqueous solutions. Metal concentration by microbial biomass from a solution is termed bio-sorption. This phenomenon is quite complex and includes adsorption of metals onto the surface of a microorganism and/or into the cellular structure in combination with ion-exchange, complexation, and/or micro-precipitation. Bio-sorption is generally considered to be a rapid physical/chemical process. The cell wall structure is porous and allows metal ions, as well as large organic nutrient molecules, to pass freely through. Polysaccharides of the cell wall could provide binding amino, carboxyl, phosphate and sulphate groups. In addition to these functional binding groups, polysaccharides often have ion-exchange properties. Sometimes, bivalent cations, such as Ca2+ or Mg2+, help the formation of ionic bond bridges between the negatively charged cell surfaces and positively charged cations in the solution, Proteins in the cell wall could offer functional groups and also offer peptide bonds to bind ions. Interactions between metal and the cell wall components are responsible for the sequestering of metals by way of bio-sorption. Many metals feature a complex solution chemistry and it is not always possible to determine what ionic species are actually present in the solution. The equilibria involved are dependent on pH, concentration, the anions present and other factors. The transport system for the ions are sometimes dependent on both temperature and energy. Biosorbent material could also be regenerated for multiple reuse."

Jan 1, 1988

By R. C. Bryce

"Accident prevention has been an on-going priorty for five years. In 1987, adherence to the ILCI five-star rating loss control program was started, and a first star was awarded. Extensive training programs have been undertaken to establish standard procedures and upgrade employee skills. Due to its location, Selbaie owns and rents housing in the town of Joutel and contracts a busing service to and from the mine. Employees from other areas are lodged in dormitories and fed in the site dining room. Accounting and warehousing services are carried out in efficient fashion. Employee relations are structured to provide prompt resolution of complaints and differences. No lost time due to industrial relations differences has been encountered during the history of the mine.Safety and Loss ControlAll mines are concerned and occupied with a wide range of activities to ensure the safety of its employees. Selbaie is no exception. Programs to achieve success in safety and loss control have been implanted since the start of construction and development at Selbaie and have followed three interesting stages of evolution."

Jan 1, 1990

By M. Fafard, F. Chevarin, D. Ziegler, H. Alamdari, M Kavand

"Carbon anodes, used in the Hall-Heroult process, are consumed by the electrochemical reaction to produce metallic aluminum. It is also consumed by parasitic reactions with air and CO2. The carbon anode is made of petroleum coke with different particle sizes, butts (recycled anodes) and coal tar pitch. The mixture of fine particles (less than 150 µm) of coke together with the pitch material forms a matrix, binding the large coke particles together. It is generally thought that the binder matrix is more reactive than the other anode constituents. This conjecture was not clearly proved in the literature. The present study is focused on the CO2 reactivity of binder matrix and anode constituents at 960°C, both under chemical regime (100% of CO2) and under a concentration gradient (diffusion). The apparent reaction rates of these materials were measured. The role of the binder matrix in anode consumption and its disintegration (dusting phenomenon) was discussed.INTRODUCTIONThe metallic aluminum production is one of the most important industries in Canada. The Al metal is obtained by the Hall-Héroult process. The principle of this process is the electrochemical reduction of alumina in molten cryolite carried out by an electrical current between carbon anodes and cathode at 960°C (Equation 1). The carbon anode is typically composed of calcined petroleum coke (65 wt.%) and recycled anode (called also butt, 20 wt.%) with coal tar pitch (15 wt.%), playing the role of cement to ensure the cohesion of the anode block."

Jan 1, 2016

By G. C. Weatherly, L Beitelman, M Gray, M. W. Bates, R Hadden

"A program of evaluation of in-mould electromagnetic stirring on the product of a straight-mould, billet continuous casting machine has been carried out. The effects on macrostructure, surface and internal quality, chemistry segregation and mechanical properties on carbon, low-alloy and resulphurized, free-machining steel billets and rolled bars are discussed. Operational aspects as a result of in-mould stirring are highlightedIntroductionA development program on electromagnetic stirring (EMS) in the mould of a continuous caster was started by Ferrco Engineering Limited in 1979, with the first experimental device being developed and installed at Lake Ontario Steel Company. As a result of these initial trials, new designs of in-mould EMS systems have been developed and are currently being used in continuous casters in North America and Europe. The rapid progress which has been made is in large measure due to the fruitful cooperation which has existed between the various parties, including Ferrco, the EMS equipment manufacturer, several operating plants and the University of Toronto.A brief review of some of the basic ' principles of electromagnetic stirring action on solidifying metal, and the landmarks of this process development, will explain the philosophy of this cooperation.From casting practice, it is well known that an equiaxed dendritic structure provides better' material properties than a columnar dendritic structure. Homogeneity of the equiaxed structure leads to better control of material properties, such as strength and ductility. Therefore, many efforts are being made to obtain this structure in continuous casting.The extent of the equiaxed zone is determined to a large degree by convective flow in the liquid. Fluid flow can fragment dendrites in the columnar zone, which then act as nuclei for grains in the equiaxed zone farther down the sump. This process is referred to as dendrite or grain multiplication."

Jan 1, 1982

The quality of refractory bricks and castables could be determined by direct measurements of their material properties such as elastic properties, porosity, density, etc. using conventional static or non-destructive testing (NDT) dynamic techniques. Quality monitoring of refractory linings is much more challenging and complicated. The static methods require undesirable drilling and sample extractions from the furnace structure. A more desirable alternative is the use of NDT techniques for material quality estimation. The Acousto Ultrasonic-Echo (AU-E) technique is a new stress wave propagation approach for monitoring the quality of refractory linings in operating furnaces. In this paper, the conceptual methodology for the AU-E technique is described, the capabilities and limitations are expanded, and the results from two case studies are discussed.

Jan 1, 2005

By E. I. Vargha-Butler

The determination of surface tensions and contact angles of coal particles is of great interest for coal beneficiation processes such as froth flotation and oil agglomeration and for the inclusion of coal particles into oil droplets as a means of enriching the fuel. Methods for contact-angle measurements on small irregularly shaped solid particles have not been available in the past. Therefore, we recently developed a novel technique to determine contact angles and surf ace tensions of coal particles. Two types of bituminous and one type of subbituminous coal particles have been tested. The technique used is called the freezing-front technique and it considers the behaviour of the test particles (in the range of 20-250 pm) at the solidification front of carefully selected, well-defined solidifying melts (matrix materials) such as thymol, biphenyl, naphthalene, salol and 2-phenyl phenol.The results show that the technique works well, providing quantitative and detailed information on the wettability of coal particles. The sensitivity of the method is so high that a difference in contact angle of approximately 4 degrees between the smaller and the larger particles is clearly registered.

Dec 1, 1981

By Q. Li, X. -L. Lei

Accompanying global energy shortage and high energy prices, shale gas has been the focus of exploration and it has attracted great attention from both academia and industry. The combination of horizontal drilling and hydraulic fracturing enables the extraction of huge quantities of shale gas from impermeable shale formations. During the process of hydraulic fracturing, great amounts of water, sand and chemicals must be injected into the shale formation at a high pressure, which may trigger seismicity. Such events could occur due to the presence of faults or the reactivation of these potential faults. Shale is the main component of source rock in the Sichuan Basin, China, and has the greatest contribution to the natural gas of the basin. In order to investigate the fracturing mechanism of shale in the Sichuan Basin, China, a series of rock fracture tests under triaxial compression were carried out in the laboratory in order to investigate the hydraulic fracturing behavior in relation to the seismicity. Based on the high multichannel waveform recording system, the detailed spatio-temporal distribution of acoustic emission due to micro-cracking was used to examine the deformation and fracture behavior of shale. In addition, the effects of confining pressure on the deformation and fracture in shale under triaxial compression by acoustic emission monitoring and X-ray computed tomography were discussed in the paper. The experimental results indicate that the shale samples demonstrate brittle fracture behavior. The confining pressure has a great effect on the complexity of the fracture planes and the spatial distribution of acoustic emissions, but few contributions to the location of the major hydraulic fracturing plane. The foliation of shale plays a dominant role in the rupture process and the geometry of the major hydraulic fracturing plane. The high confining pressure increases the strength and restrains the deformation of shale during compression process. These results shed some light on the understanding of onset of hydraulic fracture initiation not only for shale gas exploration and production, but also for CO2 geological storage and underground energy storage.

Jan 1, 2015

By C. J. Kerr

"A recent information sheet from the Mining Health and Safety Branch of the Ontario Ministry of Labour was sent to all Ministry inspectors and engineers. The subject title was' 'Two Brakes on a Hoist Carrying Persons"" and it quotes mining regulation 699, sub-section 206(i):No hoist shall be used for the transporting of persons unless it has a braking system consisting of at least two sets of mechanical brakes to stop and hold the drum for the shaft conveyance transporting the persons.The intent of the regulation is that each of these brakes is to be set so that, individually, they can safely stop the drum carrying persons and also hold the drum without movement with the maximum manload.This can be achieved in the following ways: Single Drum Hoist-one brake on each side of the drum, one brake on the drum, one brake on the pinion shaft, where disc brakes are used two separate disc brake assemblies on the disc. Double Drum Hoist, brakes on companion drum can serve as backup brake only pinion brake with one drum unclutched.Friction Hoist, one brake on each side of drum As new hoists can be manufactured easily with a two-brake system, attention will be focused on retrofitting pinion brakes to older hoists.A brake mounted on a pinion shaft is designed purely as an emergency brake in the event of main brake failure , controls malfunction, and power loss."

Jan 1, 1989

By I. Filzwieser, S. Konetschnik, A. Filzwieser, A. Anzinger

Production in copper electrorefining tankhouses mainly depend on two factors: The deposition area, which is a result of the amount of installed cells and cathodes, as well as the current density - the amperage per square meter of deposition area. The present paper shows, that the most economical way of achieving a certain production is to maximize current density by using the METTOP-BRX-Technology - as building and infrastructure can be kept more compact. This industrial proven technology applies a parallel electrolyte flow in each electrolysis cell. In 2011, the first fully industrial applications started up: At the secondary smelter Montanwerke Brixlegg AG, 156 cells are equipped with the METTOP-BRX-Technology; this allows a current density of 390 A/m². Xiangguang Copper Co., Ltd. - a primary smelter and refinery - operates its new tankhouse (720 cells) at 420 A/m²; this stands for an production increase of 50% compared to the same sized ISA tankhouse which is limited to 280 A/m². The first part of the present paper gives a cost comparison between a conventional copper electrorefining tankhouse and a high current density tankhouse when assuming a Greenfield project. The second part describes the cost savings when installing the METTOP-BRXTechnology in an already operating tankhouse.

Jan 1, 2014

By P. Mayer

"Determining the correct mechanism of a boiler tube failure is important for the prevention of future tube failures. Proper corrective measures can be undertaken to alleviate the root cause or causes for a failure only when the correct mechanism is known. A mechanism of boiler tube failure is defined as the process which degrades the tube and produces a failure.An expert system package was developed for use by electric utility power plant personnel during investigation into the cause of a boiler tube failure. It is intended to assist their efforts to recognize and identify a basic failure mechanism that can produce the type of boiler tube failure under investigation. The program guides the user to the most likely failure mechanism by asking simple questions, answers which can be obtained by determining the failure location, type of fuel, and from visual inspection of the failed tube. Expert systems are a form of artificial intelligence which imitate the decision-making process of experts.IntroductionBoiler tube failures (BTFs) continue to be the single largest source of forced outages in fossil fired electricity generating stations. Because of this a concentrated effort is being made to minimize boiler tube failure occurrences. Eliminating boiler tube failures could be worth $5 billion a year to the electric power industry(1).The aggressive service environment of fossil-fired boilers is largely the reason for these failures because the combined effects of stress, temperature, corrosion, erosion and vibration cause deterioration of boiler tube material properties and reduction in wall thickness.Determination of the boiler tube failure mechanism is important for the prevention of future problems. The root cause for a failure can be established and proper ameliorative measures taken only when the failure mechanism is identified correctly. The correct identification of failure mechanism is a complex process which may include many individuals and institutions. Technical specialists in metallurgy, chemistry, combustion, and boiler design frequently cooperate with the station staff in a failure investigation . These individuals rely on personal experience and numerous reports , theories, studies, private communications and investigations concerning the different failure modes and mechanisms."

Jan 1, 1990

Orebody classification systems ? Modern classification systems ? Genesis and environment of deposition (Important in economic geology) ? Shape and structure / Form, texture and mineral content ? Mining and geomechanics ? Size ? Massive versus tabular Requirements for mining method selection ? Classification of ore deposit ? Shape, size, attitude, continuity ? Grade and distribution, strength and large scale structures present, mineralogy and small scale structure, host rocks ? Classification of mining method ? Method of support (Stress ? strength ratio) ? The method selection ? Geographical and economic factors of the location

Feb 1, 2008