Search Documents

By P. R. A. Andrews

"Talc ore from Bakertalc, High water, Quebec analyzing about 60% talc, previously dry ground to about 95% minus 53 µm was beneficiated in an 11.4 kg/ h pilot-plant flotation circuit. A concentrate of 95.9% talc (necessary for paper-grade) was obtained at a recovery at 75.3% by employing 53 g/t of Dowfroth 250 collector at pH 9.2; further cleaning increased the grade to 97.2% talc at a recovery of 57.5%.Flotation of fresh ground 60% minus 44 µm ore at a feed rate of 18.6 kg/ h produced a grade of 96.4% talc with a recovery of 78.2%, using Aerofroth 70 collector a six carbon-branch chain alcohol, at pH 9.2.The similarity in the concentrate grade and recovery between pre-ground and fresh-ground ore indicated that it was not neces¬sary to grind to 95% minus 53/2m to achieve comparable selectivity. A grind of 60% minus 44 pm corresponds to 100% minus 300 µm.Flotation retention times obtained with fresh ground ore indicate 33 min. for combined rougher/scavenger, and 15 min. each for the first and second cleaners.Talc-magnesite flotation separation is explained in terms of physico-chemical forces, with reference to surface charge and adsorption mechanisms."

Jan 1, 1989

By Tim Gartner

This paper introduces a new application of a proven technology to provide dynamic, voltage regulation in underground mine electrical distribution systems. This technology acts to ?stiffen? the electrical power feeding continuous miners and generally raise and improve the voltage regulation at the continuous mining machines which may be located over long cable distances from the mine incoming electrical substation. This is extremely valuable for large underground continuous mining operations that use high power electrical mining machines fed over very long cable lengths (measured in 10s of km, from mine shaft to mine operating face). This new technology provides fast acting dynamic voltage regulation (voltage support) while starting continuous borers and extensible conveyor belts. Additionally, if the mine suffers from a lower distribution voltage due to long cable lengths, this new technology will raise the overall voltage at the mining machine, which can increased mining machine production and lead to longer motor life. The technology is based on voltage source converters operating as static VAR compensators specially packaged for the harsh underground mine environment. While static VAR compensator technology has been successfully used in utility and large industrial applications for many years (including open pit mining and arc furnaces), it has not (until now) been applied in underground mining. The paper will present the problem of poor voltage regulation in underground mines on weak electrical utility networks. It will then discuss some of the alternatives that have been used to resolve this voltage problem. It will then introduce the new technology used to solve the problem and review the issues involved in using this technology in the harsh underground environment. Finally, the paper will present preliminary performance results from an actual installation in a large underground continuous mining operation in Canada.

May 1, 2003

By A. Monballiu, J. A. Martens, Y. W. Chiang, A. Van Audenaerde, R. M. Santos, T. Van Gerven, B. Meesschaert

In this work, bioleaching of non-sulphidic materials by applying chemoheterotrophic bacteria and fungi is studied. It was found that the tested fungus, Aspergillus niger, leached substantially more nickel from olivine than the tested bacterium, Bacillus mucilaginosus. A. niger also outperformed fungal species Humicola grisae and Penicillium chrysogenum in the leaching of olivine. Contrary to traditional acid leaching, the microorganisms leached nickel preferentially over magnesium and iron. On average, a selectivity factor of 2.2 was achieved for nickel compared to iron. This can potentially facilitate postprocessing of the leach liquor and reduce the cost. The impact of ultrasonic conditioning on bioleaching was also tested, and substantial increase in nickel extraction with A. niger was observed. This was credited to an increase in the fungal growth rate, the promotion of particle degradation, and the detachment of the stagnant biofilm around the particles. Furthermore, ultrasonic conditioning enhanced the selectivity of A. niger for nickel, resulting in a selectivity ratio for Ni/Fe equal to 3.5. The chemical resistance of the selected microorganisms to several heavy metal and metalloid (As(III,V), Cd, Cr(III,V), Ni, Pb, Zn) was evaluated. It was found that, with the exception of As(v) and Cd, A. niger has high tolerance to these components. Therefore, this biohydrometallurgical route can potentially be applied to non-sulphidic wastederived materials, such as industrial slags, ashes and sludges.

Jan 1, 2014

By R. A. McIvor, R. S. Rafuse

"INCO Limited purchased a custom designed mobile hoist rope winder/tensioner in 1988 from TimberLand Equipment Limited to handle Large hoist ropes and serve as an emergency hoist. This paper describes the operation of the winder/tensioner and some of the different applications that the machine has been used to handle large loads.IntroductionINCO Limited operates 24 mine hoists in the Ontario Division and has approximately 50 miles of mine hoist rope hanging in the shaft plus an equal amount on spare reels. The mine hoist ropes range in size from )( inch to 2.305 inches in diameter with the majority being 1 3/4 inches and above. Prior to the procurement of a new high powered winder/tensioner in 1988, the mine hoist ropes were handled with a variety of methods and equipment using hydraulic or pneumatic powered reel winders. The largest such reel winder has a pull rating of 8000 Ibs and travels approximately 40 ft/min. Head ropes for the tower mounted friction hoists were installed and removed using a magazine on the hoist drum to wind and unwind the rope because the loads were greater than the capacity of the existing machinery. It was recognized that a large high capacity machine would improve the productivity for handling the larger hoist ropes and a feasibility study was undertaken to determine the parameters for such a machine."

Jan 1, 1995

By S. Koski, J. Vanderbeek, J. Enriquez

"The Cerro Verde copper-molybdenum porphyry mine, majority owned and operated by Freeport- McMoRan Copper & Gold, is located 30 km southwest of Arequipa Peru. The concentrator, which produces copper and molybdenum concentrates, started operating in late 2006 with a 108,000 tpd design capacity, processing primary sulfide ore (mainly chalcopyrite and molybdenite). Plant capacity was recently increased to 120,000 tpd. The comminution circuit consists of one 60” x 113"" primary crusher, four MP-1000 secondary crushers in closed circuit with dry screens, four 2.4m x 1.6m High Pressure Grinding Rolls (HPGRs) in closed circuit with wet screens, and four 7.3m x 11m gearless ball mills in closed circuit with cyclones. The HPGR circuit is fed by the Secondary Crushing circuit product at a T80 of 35 millimeters, and the HPGR circuit product feeds the Ball Mill circuit at a T80 of 3000 microns.This paper describes operating experiences with HPGRs during these first four years highlighting improvements in operating practices and presentation of data regarding operational efficiencies, also discussed are the primary benefits provided by HPGRs such as production of micro fractured particles, reduced ore Bond Work Index, and reduced power consumption. Cerro Verde represents the first installation of HPGRs in both the copper industry and large scale hard rock mining."

Jan 1, 2012

By Sylvain Picard

"RESUMELe gisement Silidor représente la dernière découverte effectuée dans le camp minier de Rouyn-noranda (fin 1985). Située à 5 km à I' ouest-nord-ouest de Rouyn-Noranda, ce gisement aurifère doit être mis en exploitation au cours du mois d’avril 1990. 11 est constitué par plusieurs facies minéralises comprenant une tonalité, un dyke mafique, une brèche carbonatée et par une veine de quartz. L’or se présente en particules très fines associées ou non à la pyrite. La zone d’altération hematitisee se développe sur une largeur de 30m environ de chaque cote de la veine. Une première étude structurale montre que la minéralisation s’est mise en place le long d’une zone de tension, orientée NNW, résultant de I' interaction de deux zones de cisaillement dextre orientées N270° et N300°. Les réserves diluées sont évaluées jusqu’ à 700 m de profondeur, à 4,78 Mt à 5,4 g/t Au. ABSTRACTThe Silidor ore deposit, located 5km WNW of Rouyn-Noranda, is the latest discovery made in the Rouyn-Noranda mining camp. Discovered at the end of 1985, this gold deposit will begin production in the spring of 1990. The deposit comprises several facies including a tonalite, a mafic dyke, a carbonated breccia and quartz vein. Gold is present as very fine grains, associated or not with pyrite. A 30m wide hematized alteration zone is developed on both sides of the structure. A structural analysis shows that the mineralization took place along a NNW oriented tension zone that resulted from the interaction of two dextral shear zones, oriented N270 and N300 respectively. The diluted ore reserves are estimated at4,78 Mt at 5,4 g/t down to a depth of 700m."

Jan 1, 1990

By F. Q. Barnes

"Uranium, thorium and yttrium have been recovered, since the 1950s, from pyritic quartz-pebble conglomerates occurring in the basal sediments of the Quirke syncline at Elliot Lake. Gold, an element of interest in similar type deposits occurring worldwide, is a very minor constituent of the Elliot Lake conglomerates because the provenance area of the sediments had few gold-bearing rocks.Uranium, thorium and rare elements are found in resistate and diagenetic minerals occurring in the matrix of the conglomerates. The valuable elements are recovered from the acid soluble minerals during the milling process.Large uranium reserves occur in mines found on both limbs of the Quirke syncline. Major reserves are being developed on the South Limb of the syncline, where the Stanleigh Mine, among four past-producers, has been reactivated.IntroductionUranium and thorium commonly occur in anomalous amounts in coarse basal sediments. Radioactivity in basal conglomeratic sediments is generally attributable to resistate minerals, that rarely occur in concentrations high enough to be of economic significance. One type of basal conglomerate found worldwide, in Precambrian cratonic basins, has uranium or uranium and gold concentrations large enough to be of economic interest. Principal among the occurrences are the pyritic quartz-pebble conglomerates of the Huronian in Canada, of the Witwatersrand in South Africa and at Jacobina in Brazil.The uranium and gold mineralization of these conglomerates was derived from provenance areas where both elements occurred and were later concentrated through source degradation and deposition in placers in a reducing environment. Only the Huronian conglomerates, generally much richer in uranium but with negligible gold, have been exploited solely for their uranium content.The uraniferous conglomerates of the Huronian at Elliot Lake, 500 km north of Toronto, continue to represent a major world source and supply of uranium concentrate."

Jan 1, 1986

By J. A. Russell

MR. M. W. Boom: I would like to congratulate Mr. Russell on his fine paper. One very good point which has always appealed to me is the smooth working of a steam hoist as compared with electrical. He does not mention the steam hoist at Springhill which has been working there for a good many years. MR. S. R. NEWTON: I have read with a great deal of interest the paper presented by Mr. Russell on the development of haulage engines in the mines of the Dominion Steel & Coal Corporation. He is to be congratulated on having produced a comprehensive article showing, step by step, the various improvements that have been made over the years in the design of such engines. I am quite in accord with Mr. Russell's statement that the positive tooth clutch can have too many teeth, and also that the method of driving a sliding clutch hub of any design should be by means of a hexagon or octagon on the shaft. Where the clutch hub does not of necessity slide on the shaft it can be pressed on and keyed to the shaft in the normal manner. With regard to the 'Cramp' internal-expanding jaw-type clutch, while it is true there are more moving parts than with the clutch consisting of a ring with internal cut teeth and a driver having a fewer number of teeth as .described by Mr. Russell; there are compensating advantages to the internal expanding jaw-type of clutch. The V shaped profile of the teeth permits of engagement of the clutch with very much less 'jockeying' of the drum. This is particularly the case in vertical-lift mine hoists, where it may be necessary to engage and disengage the clutching mechanism at frequent intervals.

Jan 1, 1944

By Michel Noël

This paper presents a partial compilation of adopted measures of waste rock dump closures at mine sites located in Canada and Alaska, where the climate includes cold winters. The paper also presents the selection process that was followed for some of those mine sites. Mining operations usually generate waste rock that can sometimes result in very large quantities. Additionally, the nature of the ore body and the host rock will often introduce environmental impacts. These impacts need to be managed not only during the operations but also in the long term. Mine closure plans consequently have to address the long term issues that sometimes require perpetual treatment. Closure planning often involves the evaluation of risks associated with environmental and financial liabilities. It needs to consider the science, some common definition of objectives, and there will be a need to manage resources and schedules. Closure planning is essentially an exercise in constrained decision making. A performance and risk based ranking matrix is often developed during this selection process to identify the preferred option(s). The case studies presented in this paper provides a few examples. The level of knowledge on acid rock drainage from waste rock dumps has increased considerably over the past decades. It did not necessarily increase the level of complexity of the adopted closure methods, as the selected closure methods are often kept simple. A common approach consists of stabilising the slopes of the waste rock dumps material by resloping and then covering the waste rock with a growth media to support vegetation. Such covers prevent direct contact of animals with the waste rock material, minimise erosion and reduce infiltration to various degrees. The inclusion of water treatment is obviously dependent on the water quality being released.

Nov 1, 2008

By Mike Power

Geophysical techniques have played a pivotal role in northern kimberlite exploration since the initial discovery at Point Lake in 1991. In the Slave Craton and surrounding regions, there are definite contrasts in physical properties between kimberlite intrusions and surrounding bedrock. Kimberlite commonly displays higher magnetic susceptibility, distinctive remnant magnetism, low electrical resistivity and lower density than surrounding rocks. In addition, the distinctive geometry of kimberlite pipes is reflected in geophysical responses which further facilitates target discrimination. There has been an evolution in geophysical exploration strategies over the past 12 years. Helicopter total magnetic field and electromagnetic (HEM) surveys have proven to the most cost-effective means of conducting first pass investigations in prospective areas. During the early 1990's, total magnetic field and frequency domain electromagnetic surveys were virtually the sole techniques employed during follow-up surveys. Inevitably, the initially high rates of kimberlite discovery declined in the areas surrounding the original finds. Marginal magnetic and EM anomalies were all that remained to be tested and this spurred interest in the improvement of existing interpretation algorithms and in the application of additional complementary techniques to reduce the exploration risk. Gravity has become a popular third survey following the deployment of the Falcon (TM) airborne gravity gradiometer system by BHP Billiton in 1999 and improvements in ground techniques. Ground penetrating radar (GPR) has proven to be particularly useful in delineating kimberlite pipes following drill discovery and in exploring for kimberlite dykes in settings where indicator mineral trains indicate such targets are likely. Seismic methods have been tested for both reconnaissance and delineation but remain underemployed. Given the high cost of drilling in the North and the proven success of geophysical techniques in reducing exploration risk, it is likely that an increasingly diverse range of geophysical techniques and innovative interpretation techniques will continue to be applied in kimberlite exploration.

May 1, 2003

By Jef M. van der Zel

The idea of veneering rich yellow gold alloys with a low-melting, high expansion porcelain, has been a driving force for metal-ceramic research in dentistry. Since 1990, with the advent of the Carrara System (1), a low firing temperature veneering ceramic allowed the use of gold alloys with a lower content of platinum and palladium than the traditional gold-platinum ceramic alloys and thus a richer yellow color. The earlier high gold-platinum ceramic alloys contained at least 12 percent platinum group metals to allow for dimensional stability when firing the relatively high melting traditional ceramics. This amount of platinum group metals gave the alloys a greyish tinge which made them unattractively steel colored and difficult to present as ?high gold alloys?. In the 90?s the new generation universal low-melting, high expansion gold alloys gained market share at a steady rate, starting in Germany, and have now for a great part replaced the traditional gold-platinum alloys (Fig. 1). The first alloys contained 75 wt-% gold and up to 9 wt-% platinum or palladium. They provided a metal-ceramic system in which a gold alloy having an aesthetic yellow colour is fired on with a dental porcelain tailored thereto. The tailoring is meant in respect of compatible coefficients of thermal expansion, and compatible melting or softening points of metal and porcelain. The major concerns in the beginning were with thermal stability during firing, the thermal expansion coefficient of the alloy against the porcelain (compatibility) and the yellow color. In a later stage, alloys with gold contents in the range of 50-60 wt-% gold were developed in analogy with the pale yellow gold-reduced alloys that were formerly used for crown & bridge work and the white gold-reduced alloys used for metal veneering where gold was substituted in part by palladium.

Oct 1, 2003

By Denis J. Kemp

The 20th Century saw changes in the mining and metallurgical industry not only technically but also in social and environmental expectations. As projects continue to become larger to maintain competitiveness the visibility of their potential impacts raise concerns among many groups. The need for transparency, openness and early engagement of all parties are fundamental to assure success. An equally important task is to anticipate the standards that will be required to meet society?s expectations in the 21st Century. Historical Observations The mining industry of the 18 and 19th Century was dominated by opportunistic Companies and individuals with an entrepreneurial flair for adventure and risk. Those who promoted had the chance of great reward, while those willing to risk their life were assured a short one for their efforts because of the physical and health dangers that abounded. Disregarding conditions miners rewards were high even in those days, with an average Cornish miner known to be earning two pound a month in 1800. Coal and iron ore mines were driven by the needs of the industrial revolution and were the first to embark on larger scale output. Base metal mines were smaller as industrial demands for their use did not start to expand greatly till the late 19th Century. Electrification, the automobile and the 1st World War drove the increased demand for a variety of metals. Early mines were foul smelling and dusty and what was taken from below ground left spoil piles around the surface countryside after recovery of the coal or concentrate. The image of barren blackened hills is one that is easily conjured up and is an environmental legacy that still lives with us today.

May 1, 2002

By Stephen G. Hardcastle

Worldwide, metal mines are going deeper. For example in Canada there are six such mechanized mines planning production at 3000m (10,000?). Working at such depths challenges all aspects of mining including the provision of ventilation to supply an equitable working climate for personnel and machinery. This paper explores the overall challenges of supplying ventilation in Canada?s deepest mines and how the volumes required could be minimized. This is essential because it must be remembered that ventilation and refrigeration are not only costly items to supply, but the magnitude of their cost is also very sensitive to the volume supplied. For ventilation this is obvious because of the cubic relationship between volume and cost. In deep mines, the main function of ventilation is the removal of heat transferred from the strata and generated by the mining machinery, and the air volumes supplied are designed accordingly. The second consideration is the removal of other pollutants that could be harmful to humans such as diesel and explosive fumes. However, the need for ventilation at its present design levels could be reduced. This paper discusses the implications of such technologies as: teleremote mining and alternatives to diesel equipment on the magnitude of the volume supplied; ventilation-on-demand which recognizes ventilation as a costly and limited resource; plus other aspects, such as the benefits of controlled recirculation, local cooling, and heat rejection back to the strata to gain further advantage from new developments. Furthermore, this paper advances the need to be able to design ventilation systems more cost effectively and how such new advances as process simulators can be used in conjunction with ventilation simulators to explore the diverse options that could affect the air volumes required and provide more realistic economic data upon which to base design decisions.

May 1, 2003

By J. Mullins

Coal was first banked by the Dominion Coal Company, Limited, in 1898, near No. 2 Colliery, the same site as is presently used for that purpose. Though today there are banks at Glace Bay, Sydney, and Sydney Mines, these notes, except when otherwise desirable, will be confined to describing the practice as developed at the No. 2 Banking Station, Glace Bay, as being typical of methods obtaining at all sites. Storing The manner in which the coal was piled is illustrated diagrammatically in the accompanying sketch. A train of coal was brought on the main trestle, which extended the full length of the banking ground at a height of 22 to 39 feet above the natural surface, and dumped into bins which were integral with the trestle work. Chutes from these bins permitted the coal to be fed into 3-ton cars, which were horse drawn laterally on narrow gauge tracks laid about 10 ft. centres, to a maximum distance of 400ft. from the trestle. These cars were end-dump and as the pile extended laterally the narrow gauge tracks were lengthened by shorter or longer filling pieces, so that their ends were always kept at the brow of the bank. Much coal, however, had to be dumped directly on the tracks and hand trimmed to fill the valleys, and level off, between the tracks.

Jan 1, 1931

By W. T. Boyes, J. M. Harrison

"Squall Lake Gold Mines, Limited, owns a group of claims at Squall lake, northern Manitoba, about 75 miles east of Flin Flon and 3 to 4 miles north of the Nor-Acme mine at Snow lake. Gold mineralization was discovered in this locality several years prior to 1944, but it was only in that year that a comprehensive examination of the occurrences was begun. Development work to the end of 1946 has been encouraging and the deposits show interesting relations to rock structure.GEOLOGICAL SETTINGThe gold occurs in a sill of biotite-hornblende diorite at or near its contact with gneisses derived from arkosic sediments . In detail, the contact between the diorite and the arkose to the southeast of it is irregular, with interfingering of the two rock types. On the northwest side of the sill, between it and Squall lake, the rock is staurolite schist (see accompanying sketch-map).Several mineralized shear zones are known, of which those shown are the most important. Within the zones, the diorite is silicified and somewhat carbonatized. Fairly coarse arsenopyrite is the chief sulphide mineral in these zones but, locally, they contain also pyrite and pyrrhotite. Where quartz and chlorite are present, rather coarse gold is associated with them. In that part of the main zone where gold assays have been most consistent, the diorite is rich in albite."

Jan 1, 1954

By A. T. GRIFFIS, R. J. GRIFFIS

A large magnesite-talc body is locared in Delora Township, 11 km sourh-southeasr of Timmins, Onrario. The deposit occurs in part of an Archean greensrone belt dominated by volcanic and sedimenrary rocks and large bodies of ultramafic intrusions. The magnesite-talc zane is abour 1800 m long, has a maximum width of 300 m and has been drilled ro 120 m below surface. Chemical analyses of rhe main carbonate zane average 20 ro 28% soluble MgO (magnesia), 5 ro 6% rota/ iron oxide and less rhan 0.1 % CaO (lime). Mineralogically, the zane consists of approximately 54% magnesite, 28% rate, /5% quartz and 3% hematire. Perrographic srudies suggest that rhe various assemblages of magnesite, rate, quartz and serpentine were derived from a parenr serpenrinire (after dunire). An early carbonitization stage, which produced a high-magnesite, low-talc assemblage, preceded a farer decarbonitizarion stage, which formed rhe main magnesite-talc assemblage. Despite a favourably low calcium oxide content of rhe magnesite-talc rock, considerable iron in the magnesire /at rice has limited the quality of the beneficiared product: rhe besr flotation concentrate to dare yields 92 to 94% dead-burned MgO. Experimen- I L t r i i c:~:.•-4- -------- ? -_;> ,•----1---- ta/ work continues on finding a process whereby high-purity magnesia can be produced on a commercial scale.

Jan 1, 1984

By J. T. Birkholzer, M. Rutenberg, K. -H. Lux, R. Wolters, J. Rutqvist, L. Blanco Martin

In this paper, we present numerical results corresponding to the Thermal Simulation for Drift Emplacement (TSDE) test, conducted in the Asse salt mine (Germany) between 1990 and 1999 to simulate reference repository conditions for spent nuclear fuel in rock salt. This test is of significant relevance for nuclear waste disposal in salt because extensive research and measurement programs were set up for the experiment. In our numerical study, we use two sequential simulators, TOUGH-FLAC and FLAC-TOUGH, and we investigate two-way coupled processes, focusing on thermo-mechanical analyses due to the main effect of heating. The two simulators used have recently been updated and are able to deal with large strains and creep processes. Moreover, specific constitutive relationships and coupling functions for rock salt and crushed salt under repository conditions are available. Within the framework of a benchmark exercise between Lawrence Berkeley National Laboratory and Clausthal University of Technology, the same scenario has been modeled in three dimensions using the two simulators mentioned. The main objective of the current, first stage of the benchmark is to evaluate the capabilities of these two simulators to predict relevant processes under repository conditions for high-level nuclear waste in saliniferous media. The comparison of the numerical predictions between them is very satisfactory, leading to a successful code-to-code verification. The comparison between measurements and numerical results shows that the most important processes are captured by the codes and constitutive models used. However, some differences exist between measurements and numerical results. These differences will be addressed in the next stage of the benchmark exercise, in which a parameter fitting effort will be undertaken. Overall, from the results obtained it can be concluded that TOUGH-FLAC and FLAC-TOUGH have the necessary capabilities to reproduce relevant processes under repository conditions for high-level nuclear waste in saliniferous formations.

Jan 1, 2015

By Joachim von Scheele

An oxyfuel-based technology - OXYFINES - has been introduced for in-plant recycling. It provides fines, dust, sludge (without any drying-step) and other by-products arising in the steel and metal producing industries to be recycled directly back into existing processes or a separate unit on-site. Results from full-scale installation (20,000 tpy) for dust treatment, full-scale and pilot-scale trials with dry and wet materials in the steel and ferroalloy industries are presented. Processing rates at 3.5 t/h have been demonstrated. The product is agglomerates or lumpy pieces, the latter if the product has passed an all-liquid stage and thereafter been crushed. The technology does not only provide a solution to the problems connected to dust and sludge generated in metal production. It also turns these materials into a low-cost raw material useful for the production in question, thus replacing part of the raw material input in electric arc furnaces, blast furnaces, etc. Elements harmful to re-use of the processed dust or sludge, e.g., zinc and alkaline components in steel production, are removed as secondary dust, and material yield of main components for re-use is very high, about 98%. The paper reviews the concept, the results obtained and its status; its use for sludge recycling is emphasized.

Jan 1, 2004

By Guohong Yin

Oxidized sulfidic tailings contain significant amounts of accumulated acidity in the form of water-soluble secondary sulfate minerals and thus constitute long-term sources of acid drainage at many metal mining sites. As part of site remediation activities, alkaline amendments are often added to the oxidized tailings to increase the pH and immobilize the metals. This study assessed the advantages and limitations of using lime mud, a byproduct of Kraft pulp mills rich in calcium carbonate (> 90 wt. %), as alkaline amendment. The inorganic and organic constituents of lime mud samples were quantified. Leachable impurities were determined by the TCLP method. The performance of lime mud was compared to that of reagent grade quicklime (CaO) and calcite (CaCO3). Tailings treated with lime mud or calcite have strong buffering capacities and remain at neutral pH conditions (pH ~ 6.7) for long times. In contrast, tailings treated with quicklime have a very low buffering capacity, and their pH decreases with time. Furthermore, lime mud has finer particle sizes and thus a greater specific surface area than most forms of commercially available calcite, which results in enhanced reactivity. Dissolved metal concentrations are similar in tailings slurries treated with lime mud or calcite. This study suggests that lime mud is an environmentally and economically attractive alkaline amendment for oxidized mine tailings.

Nov 1, 2002

By K. Madi, E. Yeugo Fogaing, S. Forest, M. Boussuge, L. Massard, M. Huger, Gaultm C.

This study has been carried out owing to the French research program PROMETHEREF, which aims to improve the knowledge of thermal and mechanical properties of industrial refractories at high temperature. In this frame, this paper relates a collaborative study between Saint-Gobain CREE, R&D Centre for Saint-Gobain Ceramics & Plastics in Europe (Cavaillon), the Materials Center P.M. Fourt of Ecole des Mines de Paris (Evry) and the Research Group on Heterogeneous Materials (GEMH) of ENSCI (Limoges). Data collected at high temperatures by using different means (bending tests, ultrasonic measurements,...) allows the identification of the high temperature behavior of two fused cast materials, produced by Saint-Gobain group for the glass manufacturing industry. The results emphasize the importance of the transformation of zirconia and of the viscosity of the glassy intergranular phase on the mechanical behavior. Damage under the form of microcracking caused by thermal expansion mismatch between the phases is also observed during cooling down at low temperature, when the material is elastic.

Jan 1, 2004