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By Ali Bunjaku, Lauri Pesonen, Hannu Johto

It is well known that there are many ways to process copper concentrates into copper anodes using the pyrometallurgical route. All modern copper smelting technologies are fundamentally energy efficient and environmentally safe options, and therefore choosing one depends on the desired capacity range, feed impurity levels, plant location, flexibility needs, overall energy use, and of course smelter economics in both the short and long term. This paper focuses on comparing different solutions which have potentially the lowest variable opex (operational expense), meaning in practice finding out which technology offers the best chances for profit maximization under certain scenarios. For the comparison, we chose to have a closer look at Outotec Flash Smelting (FSF) – Peirce-Smith Converting (PSC), Outotec Flash Smelting (FSF) – Outotec- Kennecott Flash Converting (FCF), Outotec Ausmelt TSL Smelting (ASF) - Peirce-Smith Converting (PSC), Outotec Ausmelt TSL Smelting (ASF) - Outotec Ausmelt TSL Converting (ACF), Mitsubishi Smelting Process (MIT), Bottom Blowing Reactor (BBR) – Bottom Blowing Continuous Converting (BCC), and Side Blowing Furnace (SBF) - Top Blowing Converting (TBC) since these seem to be the main state-of-art technologies now being applied in many recent copper smelter projects around the world. The work was carried out by modelling each smelting route by using the new HSC SIM 9 simulation software and applying operation time, energy, and consumables consumption numbers for each unit process and stream. Combined with cost data, the exercise produced a rich set of information which will be shown in detail for each area per scenario. The authors’ goal here was to provide a fair comparison where each technology can be evaluated from various perspectives such as electricity use or refractory consumption. INTRODUCTION Copper can be produced either pyrometallurgically or hydrometallurgically. The hydrometallurgical route is used only for a limited amount of the world’s copper production (~20%) and is normally only considered in connection with in-situ leaching of copper ores. On the other hand, most of the copper extraction from Cu-Fe-S minerals is pyrometallurgical (~80%) (Schlesinger 2011, ICSG 2017). Thus, several different processes can be applied for copper production, including the following state-of-the-art technologies: Outotec Flash Smelting (FSF) – Outotec-Kennecott Flash Converting (FCF) Outotec Flash Smelting (FSF) – Peirce-Smith Converting (PSC) Outotec Ausmelt TSL Smelting (ASF) - Peirce-Smith Converting (PSC) Outotec Ausmelt TSL Smelting (ASF) - Outotec Ausmelt TSL Converting (ACF) Mitsubishi Smelting Process (MIT) Bottom Blowing Reactor (BBR) – Bottom Blowing Continuous Converting (BCC) Side Blowing Furnace (SBF) - Top Blowing Converting (TBC)

Jan 1, 2019

By A. I. A. Salama, M. W. Mikhail

"A comprehensive software package has been developed at the Western Research Centre to meet many of the coal preparation requirements in the Canadian coal industry. This package performs three main functions: (1) data handling and manipulation; (2) data analysis, including the generation of washability data, performance evaluation and prediction, density and size modelling, evaluation of density and size partition characteristics, and attrition curves; and (3) graphics output.The software described in this paper is potentially a valuable tool for coal preparation plant engineers and operators for evaluating process performance and adjusting plant density separator cutpoints. Moreover, the analytical laboratory technician could find this package very useful in manipulating and presenting laboratory results."

Jan 1, 1997

By John Mair

The Ilimaussaq Intrusive Complex in south Greenland is a layered alkaline igneous body that is predominantly comprised of agpaitic nepheline syenites. The Complex is now recognized as containing vast resources of uranium in polymetallic ores that are also strongly enriched in rare earth elements (REEs) and zinc. Uranium and REEs are dominantly hosted in phosphate minerals with a minor proportion hosted in zirconium silicate minerals. Equivalent ores are yet to be mined for uranium anywhere in the world; however, studies are well advanced in confirming a process route to economically extract uranium. The Ilimaussaq Complex is considered the world?s type-locality for agpaitic rocks. Formation of the complex is attributed to four successive pulses of magma. The first produced an augite syenite, which now forms a marginal shell. This was followed by intrusion of a sheet of peralkaline granite. The third and fourth stages make up the bulk of the intrusion and are peralkaline to hyper-agpaitic in composition. The third batch of magma differentiated to produce pulaskite, foyaite and naujaite. Stage four produced the kakortokites and lujavrites, which are the units of particular economic significance. Kakortokites are strongly enriched in zirconium, niobium and tantalum, whereas the lujavrites are strongly enriched in uranium, rare earth elements, fluorine and zinc. Lujavrites are vertically zoned with arfvedonsite (black) lujavrites grading downward into aegerine (green) lujavrites. The upper most portions of the black lujavrites contain uranium concentrations of greater than 450 ppm, which decreases toward green lujavrites where uranium concentrations rarely exceeds 200 ppm. Resources defined to date in accordance with the Australian JORC code include 282 M lbs of uranium oxide at a grade of 280 ppm. With scope for several other similar sized resources within complex, the overall potential resource is of immense global significance. Metallurgical studies to date indicate that uranium can be successfully extracted from black lujavrites via an alkaline pressure leach method. This involves selectively leaching uranium with solutions containing carbonate and bicarbonate at elevated temperature and pressure. Uranium can then be recovered by hydrogen reduction to create a uranium oxide product. There is also scope to beneficiate ores as uranium and REE?s are hosted in specific mineral groups. Phosphate minerals can be effectively concentrated by froth floatation and uranium-bearing silicate minerals can be concentrated by gravitational methods. Studies indicate that REEs can be extracted from the residue following the alkaline leach process by a dilute hydrochloric acid wash, with REEs then precipitated in the form of a REE concentrate.

Aug 1, 2010

By K. D. Peaslee, J. M. Soto, IéDé Smith, A. D. Saikia

Spinel-forming refractories reduce penetration of metal and slags through a tightening of the lining resulting from the volume expansion associated with spinel formation. Sintered spinel is often added to reduce the overall volume increase that results. Tests were carried out to evaluate the difference between performance in spinel¬forming and spinel-containing refractory mixes. Eight refractory linings, one (1) pure magnesia, three (3) magnesia-base spinel-forming and four (4) alumina-base spinel- containing dry vibratable mixes, were tested for four hours in contact with a low-carbon, low-manganese steel in a coreless induction furnace at temperatures in excess of 1600°C. Afterwards, sample were cut, and wear and penetration were measured. For magnesia-based mixes wear was minimized using 20-30wt. spinel formation although further experiments are required to determine the optimal value. For alumina-based mixes, there seemed to be an optimal ratio of spinel added to spinel formed that minimized penetration and wear at the slag line. Sidewall accretion occurred and the accretion was the highest for the mix with the ratio of spinel formed to spinel added near the optimum value. Therefore to design an optimum refractory mix the benefits of higher ratios of spinel added to reduce penetration and wear at the slag line will need to be balanced with the tendency to form accretions on the sidewalls of the furnace.

Jan 1, 2004

By A. J. Rigby

Computer generated, actual-scale furnace models have been imported into a rendering software application to provide for impressively realistic surface features and lighting. When these models are imported into a 3D engine framework, it is possible to create content-rich virtual environments allowing for complete interactivity and could provide for a powerful tool to conceptualize refractory lining designs. This technology has been applied to illustrate the optimized design concept of an anode-refining vessel, which can be expected to be completely relined in six days and to last for 4-5 years with minimal partial relining. This technology could easily be applied to other smelter furnace, converter and refining vessel designs.

Jan 1, 2007

By Alexander Smith

"The three principal known mineral deposits of the Taku River area lie in the Tulsequah synclinorium. The axis of this north-south trending structure is along Tulsequah River valley; about 6 miles east of the eastern contact of the Coast Range batholith.The one proven mine of the area, the Polaris-Taku, is on the west side of the valley. It is a gold property, the gold occurring in fine needles of arsenopyrite disseminated in carbonatized volcanics. The mine was originally called the Whitewater, and the adjacent area the Whitewater gold belt. During the years 1937 to 1942 gold having a value of $3,284,000 was produced from 313,500 tons of ore milled."

Jan 1, 1954

By RAYMOND C. HARTVIKSEN

The Drumbo Mine is located near Highway 401 between Woodstock and Kitchener in southwest Ontario. The tabular flat-lying gypsum bed is between 1.5 to 2.4 m thick and is situated near the base of the Salina Formation, about 116 m below surface. The mine is owned and operated by Westroc Industries Limited. The 3.8 m diameter shaft was drilled using a Hughes CSD 820 drilling rig and a liner sinking technique new to the North American continent. The shaft was completed in the fall of 1977, and remaining facilities were finished in the fall of 1978. Gypsum production started in December 1978, employing the conventional room-and-pillar method of mining.

Jan 1, 1984

By Richard C. Williams, Herman Pieterse, Ken Thomas, K. S. Fraser, Ron H. Colquhoun

"The Banick Goldstrike Mines Inc. (Goldstrike) operation is located in Eureka County in north-central Nevada on the Carlin geological trend. Gold in the sulphide mill feed, occurs primarily as submicroscopic inclusions or possibly solid solution in a pyrite and marcasite matrix. Sulphide mill feed is pretreated in a pressure oxidation plant allowing gold recoveries of 90 per cent and greater to be achieved. Anticipated 1994 gold production for the sulphide gold facility is approximately 1,500,000 ounces.In January 1989 American Banick Resources Corporation (Banick) announced the US$365 million Betze Development Plan for the Goldstrike property. The Betze plan was based on a three (3) staged expansion of the original 4,500 STPD oxide gold plant. This expansion would involve addition of ore and gold processing capacity and the total conversion of all ore handling facilities to treating Betze sulphide ores.Phase 1 of the Betze Development Plan involved the construction of a pressure oxidation circuit, including a single autoclave and supporting ancillary services. The pressure oxidation circuit was commissioned in February 1990. Currently a throughput of 2,000 STPD is being achieved.Phase II of the Betze Development Plan, commissioned throughout April and May 1992, included the expansion of grinding, leaching, and gold recovery facilities enabling the treatment of combined oxide, and sulphide ore. Pressure oxidation capacity was increased by the addition of two (2) autoclave circuits each treating 2,600 STPD of sulphide ore and other required ancillary services. By June 1992, the Phase II gold facility had achieved a combined throughput of 15,000 STPD of oxide and sulphide ore.Phase Ill, the final stage of the Betze Development Plan, was successfully commissioned in February and March 1993. This final stage of development increased the design throughput of the pressure oxidation plant to 15,000 STPD by the addition of three (3) autoclave circuits with combined capacity of 7,800 STPD."

Jan 1, 1994

By V. C. Pandolfelli, S. F. Santos, L. A. Rodrigues

Under conditions of stable crack propagation at room temperature, the elastic energy stored in ceramic materials is converted mainly to surface energy. However, at high temperatures, creep may also occur in such materials, in which case it will present a ductile behavior. This paper discusses the brittle-ductile transition of a refractory material. Stable crack propagation and creep tests were carried out under a three-point bending device. A commercial ceramic containing 63 wt-% of SiO2 and 31 wt-% of Al2O3 was used as testing material. The results revealed that the change in behavior from brittle to ductile was caused by softening of a vitreous phase present in the material's microstructure.

Jan 1, 2004

By R. von Bonsdorff

Electrochemical and quartz crystal microbalance (QCM) methods were used to investigate the dissolution rate of gold in a solution similar to those utilized by the Outokumpu HydroCopper® process. The measurements were conducted in an electrolyte solution where [NaCl] = 2.8-280 g/L, pH = 1-2.5, [Cu2+] = 0-30 g/L and T = 70-95°C. According to these measurements, the solution flow has the greatest impact on the dissolution rate of gold in the HydroCopper® process. Under adequately acidic conditions (pH < 3), the dissolution rate of gold increases with increasing cupric concentration, increasing chloride concentration and increasing temperature. The results and trends observed compared well with the literature.

Jan 1, 2007

Cambior has been involved in the Guiana Shield since 1990, first in Guyana and then in Suriname starting in 1994. This paper presents the history of Omai Gold Mines Limited in Guyana, where commercial production started in 1993 after an investment of US $150 million. In 1995, the mine was expanded in order to increase the milling capacity to 21,000 tonnes per day. After ten years of production, approximately 3 million ounces of gold have been produced. Building on this experience, Cambior became involved in Suriname with the Rosebel Project. A US $95 million pre-production program started in the fourth quarter of 2002, and the mine should be in commercial production early in 2004.

May 1, 2003

By Z. Trojanová

The deformation behaviour of ternary magnesium alloys AJ (Mg-Al-Sr) and AX (Mg-Al-Ca) were investigated in tension as well as compression tests. The samples were deformed at temperatures between 20 and 300 °C and at an initial strain rate of the order 10-4 s 1. The flow stress decreases with increasing temperature. The macroscopic work hardening rate decreases with increasing flow stress and temperature. The stress and temperature dependence of the work hardening rate is a result of the hardening and softening processes. Stress relaxation experiments were performed in order to reveal features of the thermally activated dislocation motion. Internal and effective stress components of the applied stress were estimated. A decrease in the internal stress was observed at elevated temperatures, which indicates recovery process (-es). A more detailed analysis of the estimated values of the activation volume and activation energy helped to interpret the thermally activated processes during plastic deformation. It is concluded that the deformation behaviour of the alloys depends on the activity of non-basal slip that is strongly influenced by temperature.

Jan 1, 2007

By Michael S. Moats, Alex Luyima, Tomas Oliveira

Some commercial copper electrowinning facilities use Cyquest N-900 (a polyacrylamide) or HydroStar (a modified polysaccharide) to improve the density and smoothness of copper electrodeposits. However, the effects of these additives have not been studied extensively in the open literature. Thus, the electrodeposition of copper at 40 oC from a non-stirred synthetic electrowinning electrolyte (40 g/L Cu2+, 160 g/L H2SO4, and 20 mg/L Cl-) in the presence of various concentrations of either additive was evaluated using cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS). CV results show that neither additive has much effect on the nucleation overpotential of copper electrodeposition on stainless steel. However, Cyquest N-900 polarized the copper deposition reaction upon the return sweep. The EIS data indicates that Cyquest N-900 increases the reaction’s charge transfer resistance and creates a second low frequency loop. HydroStar had minimal effect on the electrochemical data generated by CV or EIS. Thus, the mechanism by which HydroStar affects the copper deposition reaction still needs to be determined.

Jan 1, 2014

By Bradford P. Simser

Increasingly sophisticated rock mechanic tools are becoming more and more available for today?s ground control specialist. However many problems are still beyond our ability to explicitly calculate or measure. There is often a gap between the ?art? and the ?science? of rock mechanics. This paper focuses more on the ?art?, giving relatively simple examples of underground observations and micro-seismic records to help explain ground control issues. Ground support techniques such as in cycle shotcrete with high pressure water scaling, mesh and bolting, pumpable resin bolts/cablebolting, and yielding bolts with load spreading straps are discussed. The use of primary/secondary type blasthole sequences in moderate to high stress situations is also discussed with several examples of the micro-seismic response to the stoping. Relatively erratic geology with high material strength contrasts is currently being mined with blasthole methods at Nickel Rim South. Although the mine is still in its? ?early? days, over 1 million tonnes has been extracted and some empirical experience is highlighted with potential longer term issues also being discussed.

Oct 1, 2010

By J .. R. Dalton

"Blasting in high sulphide content ores presents at least two major safety considerations: (1) compatibility of the explosives with the ore while resident in the borehole; and (2) introduction of a flame and shock producing explosive into this environment, while minimizing the risk of reactive ignition in the chemical reaction products/sulphide dust cloud resulting from the detonation. This paper will discuss only the second consideration, i.e. post detonation reactivity.The ETI (Explosives Technologies International) Technical organization, in consultation with the U.S. Bureau of Mines, reasoned that the most relevant considerations in the development of an explosive for this application are:• minimization of reactive gaseous detonation reaction products;• flame duration reduction;• flame temperature reduction;• increased explosive sensitivity;• reduced probability of ""low order"" detonation; and• maintenance of energy level as high as possible.Obviously, not all of these are totally independent properties, i.e. increased sensitivity will reduce the probability oj low order detonation as will higher energy levels. However, these considerations were examined separately as if they were independent."

Jan 1, 1994

By Benoît Valley

Optimization of the mining sequence in terms of economics (maximizing net present value) often leads to multi-front mining methods generating pillars. Significant resources are tied up in these pillars, but mining them is often challenging. In order to improve our understanding of rock mass behaviour while extracting these pillars, an extensive monitoring program has been designed and implemented at Vale?s Coleman mine (Sudbury, Canada). The program focuses on existing and new technologies that have potential for monitoring deformation and rock mass property changes. It includes both active and passive methods: gravimeters, multi-point borehole extensometers, fiber optic strain meters, fixed and portable three-component seismic arrays, borehole imaging and sonic logging, and, repeated LiDAR surveys. This paper reports results from an initial project phase, when only a small amount of mining has taken place. The goal was to test and compare technologies in order to assess their sensitivity, accuracy, repeatability and suitability for underground mining conditions. Value is gained by having a broad range of monitoring devices running side by side, enabling comparisons and benchmarking.

Jun 1, 2012

By A. G. Matyas, B. Wasmund, R. C. Francki, K. M. Donaldson

"The construction of large. high-power electric furnaces has been an important factor in the growth of electric smelting technology . New developments in the design and operation of electric furnaces have been spurred by the escalating cost of electric power and increasingly stringent environmental constraints. Key areasofprogress include the application of high voltage to enhance furnace productivity; the installation of novel furnace cooling elements and robust binding systems to extend furnace life; development of process schemes to reduce power consumption by preheating and prereduction of the charge; and environmental control improvements for handling fine dusty feedstocks, and for furnace sealing.This paper reviews these developments and outlines a systematic approach for their application in the custom design of new or retrofit electric furnace facilities.IntroductionThe use of electric smelting furnaces has continued to progress during the last decade. Electric furnaces offer high throughput capacity and productivity. In addition, they produce minimum environmental impact, as the furnaces can be readily sealed, and only a small quantity of off-gas is generated. Electric furnaces present the most favourable choice of smelting technology where high process temperatures in excess of about l400°C are required.Their application is burdened by the escalating cost of electric power, hence it is important to seek new opportunities through further technological development. This paper reviews recent developments in the design and operation of high-power electric smelting furnaces, in the following areas:"

Jan 1, 1993

By John Rowson, Caitlin Brown, Kebbi Hughes, Joseph Esslifie-Dughan

The McClean Lake mill in northern Saskatchewan, Canada, is operated by Orano Canada Inc. and has been in production for the last 20 years. The tailings preparation process at the mill has been designed with decommissioning in mind, to produce tailings that are geochemically stable over the long-term within the site’s tailings management facility. Twenty years of study have contributed to a detailed understanding of geochemical and geotechnical properties of the McClean Lake tailings. Validation of the tailings properties has occurred through in-situ sampling campaigns conducted initially every year, and later every five years. Each sampling campaign has applied the same rigorous sampling procedure to provide data with useful correlations year over year. Each campaign result compares elements such as the inherent variability of the tailings, consolidation of the tailings and variations in the tailings placement methods. We will discuss lessons learned from seven sampling campaigns over 20 years and present data to show the reliable tracking of geochemical evolution of the in-situ tailings over time; providing opportunities for continuous improvements.

Jan 1, 2020

By K. Ohto, B. B. Acihikari, H. Kawakita, M. Gurung, S. Alam

Two kinds of adsorbents were prepared from persimmon tannin extract to investigate their adsorption behavior of metal ions from hydrochloric acid solution; one was prepared by treating with concentrated sulfuric acid while another was prepared by immobilizing functional groups of quaternary amine. The former adsorbed only gold(III) and its maximum adsorption capacities was evaluated as high as 1510 g/kg while the latter adsorbed not only gold(III) but also palladium(II) and platinum(IV), the maximum adsorption capacities of which were evaluated as 820, 89 and 101 g/kg, respectively. For both adsorbents, practical adsorption of base metals was not observed.

Jan 1, 2011

By T. ?kre, O. M. Dotterud, S. Haarberg, J. Thonstad, G. M. Haarberg

An electrowinning pilot plant has been constructed at Falconbridge Nikkelverk A/S, Kristiansand, Norway. The equipment consists of a mixing tank where the electrolyte composition and temperature are controlled, an electrowinning tank equipped with five cathodes and six anodes of commercial size and design and a dechlorination facility. Electrowinning experiments were carried out in this pilot plant using acid cobalt chloride solution from the cobalt tankhouse. Key parameters were varied to obtain an improved understanding of the cobalt electrowinning process, focusing on the detrimental deposition of cobalt oxide on dimensionally stable anodes. The extent of anode scaling was found to be dependent on the electrowinning conditions. Low pH, temperature and cobalt concentration resulted in less scale being formed, however at the expense of cobalt current efficiency and cell voltage, adversely affecting electrowinning production capacity and energy consumption. When operating at high acidity, pH in the anolyte was higher than in the catholyte, which is believed to be due to H+ ions taking part in the current transport across the diaphragm, migrating out of the bags surrounding each anode.

Jan 1, 2005