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By A. O. Dufresne

The mineral wealth of pre-Cambrian rocks in Canada has been the subject of much study by geologists and engineers (members of this Institute), particularly so in the past few years, following discoveries of mineral deposits in areas far a part. This interest is well worth sustaining knowing the numerous rich producing mines within the pre-Cambrian formations, and the vast area covered by its rocks throughout this country. The pre-Cambrian has yielded minerals, both metallic and non-metallic; of these a much diversified list could be made. In more than one district we can point to mining as being responsible for the opening up of new sections, attracting a population into regions which otherwise would have remained virgin land of little commercial value. In these pre-Cambrian formations are found the rich copper deposits of Michigan, producing without interruption since 1845, and from which seven billion pounds of copper has been won; while in Minnesota and the adjoining district, at the head of Lake Superior, are mined iron ores which have rendered possible the great steel manufacturing industry of United States, the base of the economic structure of that wealthy country. The pre-Cambrian has given Canada the nickel-copper mines of the Sudbury district, the silver deposits of Cobalt and the gold camps of Porcupine and Kirkland Lake. With all of these our members are familiar; and it suffices to mention them to bring to mind pictures of the wealth and 'the growing population, in a word the importance of mining in?those sections of the country.

Jan 1, 1926

By Donald P. MacKinnon

"This paper is a commentary on selected trends within the transportation industry.In general, innovations are taking place within all modes of transport (road, rail and water) serving the industrial minerals industry which will affect future distribution patterns, methods and costs. Significant technical innovations in the transportation of solids by• pipeline will also appear, perhaps in the near future, permitting the transport of specific commodities, including some industrial minerals. However, the timing and magnitude of the commercial exploitation of solids pipelines are heavily dictated by marketing factors and distribution system logistics, as well as by the innovations likely to take place within competitive modes of transport. Competitive technological developments will include increased ship capacities, improved bulk-handling facilities, larger and specialized bulk-handling rail equipment, unit trains, containerization, larger ""off-highway"" vehicles and greater inter-modal integration. Equally significant are some ""soft-ware"" techniques such as the growing interest in total distribution cost concepts. However, the impact of the developments will not be spread uniformly over all Canadian industrial minerals."

Jan 1, 1967

By S. Fahland, P. Vogel

"The Gorleben salt dome has been investigated since 1979 for its suitability as a repository for the disposal of high-level radioactive wastes. The geoscientific surface exploration was followed by underground exploration of the site beginning in 1983: underground excavation work included the sinking of two shafts from 1986 to 1994, the excavation of the infrastructure area and of drifts located in the first exploration area EB1 within the following years. The exploration was interrupted for ten years from 2000 to 2010 as part of a moratorium. After the expiry of the moratorium in March 2010, the geoscientific underground exploration at the Gorleben site was resumed. The investigations were interrupted again in autumn 2012 due to a political decision. The exploration programme included extensive geoscientific investigations: geological exploration, geophysical investigations, mining exploration and mining observation, laboratory tests, in-situ geotechnical measurements, geological modelling and numerical model calculations. To analyse and interpret the results of the in-situ measurements and mining observation geomechanical, thermal and thermo-mechanical model calculations were carried out. One of the main elements of the in-situ geotechnical investigations were high-resolution geothermal measurements performed in boreholes used for geological exploration and geotechnical tests.The geothermal measurements are used to evaluate several geotechnical findings, e. g. drift closure, rock deformation, stress change, and are completed by thermal model calculations to analyse and interpret the results of in-situ measurements and mining observation. The model calculations have been carried out using the special purpose JIFE code. To consider the whole exploration mine with the adjoining host rock as well as the successive excavation of drifts and boreholes in detail a three-dimensional finite-element model was developed. The model calculations are used to analyse the cooling-off of the surrounding rock of the drifts caused by ventilation. The cooling-off of the surrounding rock is an ongoing process affecting the results of further geotechnical measurements in the near field of the drifts. To predict a realistic time and space dependent distribution of the temperature field of the host rock within the exploration area which is influenced by ventilation thermal model calculations are necessary. Comparing the calculated temperature field with the in-situ determined rock mass temperature field within the exploration area EB 1 the results show a sufficient agreement. Furthermore there is very good correspondence, both qualitatively and quantitatively, between the experimental and the calculated findings regarding the temperature profiles including the effects of excavation and ventilation of the drifts."

Jan 1, 2015

Drilling is a common process in mining and petroleum engineering applications which have different objectives. For example, drilling deep boreholes in tight gas formations and gas shales is becoming more popular in the oil and gas industry. By contrast, drilling deep small sized holes for mineral exploration in hard rocks is performed to obtain samples for grade analysis purposes. In both applications optimising the drilling process includes using the most effective operating parameters such as rotation speed and weight-on-bit in order to maximise the rate of penetration. Obtaining the optimum drilling parameters requires sensitivity analysis over a range of data, which would be costly and time consuming during real field operations. Therefore, conducting several experimental simulations in the lab would be very beneficial before field operations begin. A drilling rig was designed and developed to simulate various drilling scenarios. The rig works in conjunction with an existing true triaxial stress cell (TTSC) which is in use for different petroleum related applications. The rig allows drilling into a cubic rock sample of up to 300 mm size. Three independent stresses can be applied to the sample to simulate real in-situ field stress conditions while the sample may be saturated with fluid. A significant feature of the rig is its ultra-high speed rotation which can rotate up to 8000 rpm: this is to simulate hard rock drilling for mineral exploration applications where large weight-onbit could damage the bit cutters. With the proposed design, a drilling fluid of any type can be circulated in the simulated borehole similar to the real situation, to study its effect on drilling performance. The TTSC drilling lid is equipped with torque and drag measurement systems which are two important drilling parameters to be recorded during drilling operation. It is believed that this new drilling rig will open opportunities for performing major new applied research in the area of more efficient drilling in both oil and gas bearing formations and mineral exploration applications.

Aug 1, 2013

By Michel Épiney, COREM, Mario Drapeau, Caroline Olsen, Claude Bolduc, Benoit Levasseur

"Several metal sulfide minerals (such as copper, zinc and iron), generally abundant in precious metal-containing ores, are known to dissolve during the cyanidation process. These unwanted reactions consume a significant amount of cyanide and oxygen, which is required for the extraction of gold and silver. Leaching kinetics of sulfide minerals are very fast in contact with oxygenated cyanide solutions. Therefore, the solution quickly becomes charged with oxidation products that are mostly metal ions, metallo-cyanide complexes, metal oxides and other sulfur species including thiocyanate, sulfides, polysulfides, thiosulfate, sulfites, sulfates, etc. COREM’s Extractive Metallurgy team has been conducting a research program on the improvement of the gold cyanidation process. As a part of this program, the current study aims to investigate the effect of certain operating parameters on the reactions involved during pre-oxidation and cyanidation. The effect of pre-treatment under ozone was investigated using an industrial pulp recreated from process water (charged with thiocyanates) and homogenized flotation tailings material from Agnico Eagle's LaRonde mine. In terms of mechanisms, the ozone treatment provides a complete deactivation of the material surface (characterized by EDTA extraction) and the solution (characterized by Ionic chromatography). This resulted in a lower reactivity of sulfide minerals that led to substantial gains in terms of consumption of cyanide and thiocyanate formation during the cyanidation process. The ozone-pre-treatment edges the classical pre-oxidation treatment (such as oxygen, hydrogen peroxides, etc) providing a quicker deactivation of the sulfide matrix and higher reagent savings in subsequent cyanidation process.INTRODUCTIONThe presence of sulfur in the process of gold leaching by cyanidation is a major drawback to optimizing the reagents consumption with suitable operating conditions. The coexistence of sulfide mineral species, such as pyrite, chalcopyrite, pyrrhotite or sphalerite along with the gold-bearing ore have, indeed, a negative impact on the extraction of precious metals by cyanidation (Bayat et al., 2003), (Azizi et al., 2010). These minerals are known to dissolve with cyanide under alkaline conditions and release in the slurry different kinds of sulfide by-products like polysulfides, thiosel, sulfite and sulfate (Seal II & Hammarstrom, 2003) (Breuer et al., 2008a), (Marsden & House, 2006) (Ghasemian Langeroudi et al., 2013). Once these sulfide by-products are released in solution they react with cyanide to form thiocyanate (Marsden & House, 2006) (Breuer et al., 2008b). The consequence of the dissolution of these cyanicides, is a significant increase in cyanide consumtpion as well as a slow-down of gold extraction."

Jan 1, 2016

By M. Bustin, A. Hosseinian, G. Preisig

Hydraulic fracturing and hydraulic shearing techniques are essential for the development of unconventional oil & gas and geothermal resources. Such techniques will also play a key role in the development of CO2 sequestration, and management of high stresses encountered with deep mining. However, the optimal design of hydraulic injections is often limited by continuum treatments of the rock mass without consideration of the influence of the natural fractures present. These may interact with the hydraulic fracture to promote offsets or arrest, or may cause the natural fractures to undergo shear and dilation. Given the limited access to the rock afforded by deep boreholes common to oil & gas and geothermal projects, advanced numerical modeling is critical for understanding key mechanisms and interactions. In this work, we first present a coupled hydromechanical distinct-element model focusing on the propagation of a hydraulic fracture. Normal and shear displacements arising from the generated hydraulic fractures are subsequently integrated into a fracture flow model for detailed analysis of specific flow behaviour and fracture permeability. For this, a scanned 3-D profile of a natural fracture is used to correlate surface roughness to dilation as a function of shearing. Fracture flow is computed at different time steps corresponding to different fracture propagation states and geometries. Modeling results indicate that the opening of a tensile hydraulic fracture is accompanied by millimetre-scale shear displacements associated with slip and wedging between adjacent blocks. This may leads to a mismatch between the upper and lower walls of the fracture if asperities are irregular and strong enough. However, fluid-induced tensile fractures have low Joint Roughness Coefficients (JRC), and associated millimetre-scale shear displacements are too small to ensure a significant offset of asperities that prevent a fully-elastic closure when the hydraulic fracture is depressurized. Injection of proppant is thus critical to keeping hydraulic fracture apertures open. Future work is planned that will see the models calibrated against field data including microseismic event locations, magnitudes and source mechanisms, tiltmeter deformations, stress change, and pore pressures.

Jan 1, 2015

By S. Isaac

The networks of interdependencies between elements in building projects, referred to as the project topology, are often complex and difficult for project teams to comprehend. It is hypothesized that a graphbased model of the project topology can be based on existing data in Building Information Models (BIM), facilitating the application of graph-theoretic algorithms to analyze this topology. The objective of this study is to propose an outline for the synthesis of BIM and graph theory. This synthesis is expected to contribute to the development of new tools for representing, managing and analyzing the design of building projects.

Aug 1, 2013

By N. Schreithofer

The deposition of octadecylamine (ODA) at the KCI crystal/NaCI-KCI brine interface was investigated using atomic force microscopy (AFM). The AFM images of freshly cleaved KCI specimens immersed in KCI-NaCI saturated brine at room temperature reveal disappearance with time of the atomic steps and formation of cubic NaC1 crystals. These crystals were found to form when the specimen was withdrawn from the saturated solution. Depending on the way of contacting the specimens with the octadecylamine dispersion, the AFM images show huge differences in the deposition patterns of ODA on KCI crystals. Adequate dispersion was found to help the formation of quite even ODA coverage. The coverage was several monolayers thicker when air/brine/solid contact took place, suggesting that in the potash flotation the collector is likely to be carried to the solid surfaces by air bubbles. The presence of methyl-isobutyl carbinol (M IBC) enhanced the dispersion of ODA in brine, thus helping the spreading of the surfactant on the KCI crystal surface.

Jan 1, 2006

By D. Ortiz, J. R. Frias, E. D. Mast, J. J. Fañas

Falconbridge Dominicana (Falcondo) has operated an integrated tpy nickel laterite mine and ferro-nickel processing plant since 1972 in the Dominican Republic. The operation includes mining, a processing plant, an oil refinery, and a power plant. Falcondo has improved process efficiency over the years via modernisation and better understanding of the process. The present business environment of high fuel prices and high nickel prices present a challenge and an opportunity to Falcondo's operation. This paper gives an update of Falcondo's process, improvements in energy consumption, factors affecting energy consumption and how Falcondo is facing up to the current business environment.

Jan 1, 2005

By M. Razavi

This investigation is part an overall investigation on the effect of sodium silicate on the properties of the mine backfill. The results presented will highlight the effects of binder dosage, sodium silicate concentration, and pulp density on the performance of stabilized sodium silicate-fortified sand pastefill samples. Binders implemented for these experiments consisted of cement, slag, and sodium silicate in various proportions. The binder content varied from 3 to 9 wt% (total dry weight) and sodium silicate concentrations was adjusted at 2 and 4% (total binder weight). Moreover, pulp density was adjusted to values between 80 and 83 wt%. For completion of the aforementioned phase of the study, series of sand pastefill test samples were prepared and cured for 28, 56, or 120 days, in a humidity and temperature controlled room. The specimens were tested for uniaxial compressive strength (UCS). In order to study the effect of sodium silicate on microstructures of stabilized sand pastefill, some MIP tests were conducted on selected samples. The results of this investigation evaluate the use of sodium silicate as a partial replacement of cement in stabilized backfill. The analyses of the results demonstrates that, with an increase in binder content and a decrease in pulp density, the UCS values of sand pastefill samples increase. Further more, the results indicate that increase in addition of sodium silicate does not necessarily result in higher strength minefill.

May 1, 2007

By D. Satish Kumar, D. Mazumdar

"95% bulk mixing times in three different size water model ladles of a 140 T cylindrical shaped , dual plug ( located diametrically opposite at mid bath radius position) stirred, industrial ladle were determined experimentally with and without an upper buoyant phase. Based on dimensional analysis and a regression of the experimental data and, it was shown that in the inertial and gravitational force dominated flow regimes, 95% bulk mixing times for a slag-less situation can be described via:[equation]Parallel to this, a large number of experiments were also carried out in one of the water models (D=0.30m) to quantify the influence of an upper buoyant phase on mixing. These indicated that mixing time, operating variables and thermo-physical properties of the upper phase liquid can be correlated via a dimensionless relationship of the type:[equation]in which, Q is the ambient gas flow rate, L is the depth of liquid , (AL) is the slag layer thickness and 6 and t are respectively the surface tension and viscosity of the upper phase fluid The dimensional analysis, regression of experimental data as well as the adequacy of the proposed correlations are discussed in the text."

Jan 1, 2004

DOME MINES, Limited, is a gold producer situated in the Porcupine area of Ontario, 500 miles north of Toronto. During the year 1960, '71 4,600 tons of ore were milled, yielding gold bullion valued at $6,025,370. Prior to conversion to natural gas, an average of 3,200 tons of coal was consumed annually, one third of which was obtained from Canadian sources with the remainder coming from the United States. Due to the distances involved, the freight charges increased the pithead cost by as much as ISO per cent. Steam is generated at a central boiler plant and used for timber treatment, plant heating and process steam. Until August, 1960, steam was supplied during the winter months by two water tube coal-fired boilers, each rated at 200 boiler horsepower at 100 per cent output. Steam requirement was as high as 150 per cent of boiler rating in the colder periods. The summer load was

Jan 1, 1962

By Dave M. Jakelski, Gerhard W. Heinrich, Peter F. Wells, Daniel F. Suarez, Jamie B. Beauchamp

"A need for increased copper concentrate production and for less nickel contamination in that concentrate at Falconbridge's Strathcona Concentrator during 1993 required the installation of a third flotation column and improvements in the operation of the existing circuit. Innovations in wash water distributor and launder design were fundamental in achieving objectives on a new 3 meter diameter column. Minnovex plug-type spargers were tested on a 2.1 meter diameter column in order to reduce maintenance requirements. The paper details the measures taken to enhance column flotation circuit performance and the results obtained.IntroductionFalconbridge's Strathcona Mill receives 10% of the ore feed from a rich copper zone in the Strathcona mine. This ore typically grades 7% copper and 1 % nickel and, because of its high copper content, it is processed in a separate circuit ('C' circuit) which consists of conventional grinding, rougher flotation with the concentrate being treated with lime to pH 12.3 and cyanide followed by column flotation. The columns are operated with mechanical flotation scavengers and the scavenger concentrate is returned to the column feed. Testwork conducted in 1991 showed that the original flotation column (Column 2) could only produce 5.5 mtph of concentrate with less than 0.5% nickel (Figure 1).Between 1991 and spring of 1993, production was increased at times by open circuiting the scavengers. Metallurgical improvements were obtained by improving the wash water distributor of Column 2 and by wash water sprays in conventional cells (1 ). However, the scavenger concentrate assayed 0. 7 -0.8% nickel and was not acceptable for long term operation. When Copper ore production targets were significantly increased for 1993, it became clear that an additional flotation column was required. The new flowsheet employs mechanical scavenger cells on the column tails as in Column 2 circuit (Figure 2). A -parallel configuration was chosen as pulp solids fraction has been shown to be a critical variable and the second column in series would receive a lower density feed."

Jan 1, 1994

By S. Orangi

A representative sample of ramming paste from a peripheral seam in an aluminium electrolysis cell was taken in order to develop a process to fabricate ramming paste samples in the laboratory. To this end, paste material was compacted in multilayers in a mould designed to be representative of peripheral seams in Alcoa's smelters. The density distribution in the representative sample was measured ranging from 1.51-1.76 g/cm3. The density range obtained by the proposed methodology in laboratory is 1.47-1.77 g/cm3. The results demonstrate that the proposed fabrication method adequately duplicates paste density from the cell for both one and two layer compaction. Finally, preliminary results related to the compressive strength and Young's modulus of laboratory samples were obtained at various temperatures and are presented in this paper.

Jan 1, 2011

By John Wightman

LOCATION OF PROPERTY THE property of Caribou Gold Mines, Limited, is situated in the north-eastern part of Halifax county, seven miles south of the Canadian National railway line at Upper Musquodoboit. Approach to the village is by a secondary road, improved recently by waste rock from the mine dump. A two-wire telephone line, seven miles long, built and owned by the present operators, provides communication to the nearest telephone exchange, Parker's Corner. HISTORY In 1870, the Caribou area was recognized as a proclaimed gold district. From then on, operations were intermittent, with periods of considerable activity by small companies until there were no fewer than seven mines in a district two miles long by three-quarters of a mile wide. These were the Holman, Truro, Caffrey, MacDonald or Elk, Lake, Dixon, and Hilchey properties, all of which have had separate stamp-mills, and have produced gold for varying periods. Depths of the workings range from 100 feet to 1,000 feet. Power was generated at each property by means of steam boilers. At the present time, the Consolidated Mining and Smelting Company of Canada, Limited, controls all the leased areas, approximately 800 acres, and is operating by means of one central vertical shaft. GEOLOGY The district in and about Caribou Mines has an elevation of approximately five hundred feet above sea level. The area is fairly well wooded, with rock outcrops here and there. These outcrops, along with information from test-pits and shafts, have been the basis for the very excellent geological map of the district prepared by E. R. Faribault some years ago. The rock structure, which is one of the best examples in Nova Scotia of an elliptical dome, has its anticlinal axis in a northeast-southwest direction, and flat plunges in the same directions.

Jan 1, 1938

By W. F. Moore

"In January 1981, Quintette Coal Limited (QCL) signed a 2a-year coking coal sales agreement with the Japanese Steel Industry which was followed by the commencement of mining operations in October 1982 and preparation plant operation in November 1983. During the mine 's startup, the town of Tumbler Ridge, the Anzac rail spur line, coal port facilities at Ridley Island plus numerous related elements of infrastructure were completed to support QCL and the neighbouring Bullmose operation in northeastern British Columbia. QCL's annual product coking coal levels have accelerated from 2.9 to 5.2 Mt between 1984 and 1986 with related increases in total mined volume from 14.8 to 41.0 M BCM between 1983 and 1986. This paper presents an overview of QCL 's current operation and related infrastructure. Development BackgroundDuring the 1970s, the Japanese Steel Industry (JSI) was forecasting a steady and significant growth in its steel production. By 1980 they were expecting crude steel production to increase from about 105 Mt in 1980 to 125 Mt by 1985 and almost 140 Mt by 1990.Discussions between Quintette Coal Limited (QCL) and the JSI for the development of the QCL project began in the 1970s and continued over a period of several years. During that time detailed and regular meetings took place, at which technical and commercial presentations were made to the JSI. The geology of the project area and the alternative mining methods and sequences were studied in detail. The new rail line which would connect the mine to tidewater was a critical factor and received particular attention. Alternate routes for the rail line from Tumbler Ridge to Prince George were the subject of much detailed study and discussions. The Anzac route was chosen in the best long-term interest of the northeast area development, after careful consideration and advice from the Japanese side.The new bulk coal terminal on Ridley Island at Prince Rupert was also a key factor and completed the development of an independent and new major coal field to supply the JSI. The QCL project and the development of the northeast area of British Columbia was a major strategical initiative of the JSI. It provided Japan with an important new coal field which was both self-sufficient and distinct from the traditional Japanese coal field resources in southern Canada, Australia, and the United States."

Jan 1, 1988

By D. L. Churcher, R. J. Perry

"In recent years much work has been don e to examine alternate underground backfill support systems with the objectives of improving ground support and reducing mining costs. This report deals with the work conducted at Placer Dome Inc.’s Dome Mine to develop a high density backfill system, taking advantage of the unique properties of this fill material, to address a backlog of large open stopes to sustain stable minewide ground conditions for future generations of Dome miners.IntroductionDome Mine began its existence in 1909 with the discovery of visible gold on a dome shaped outcrop located west of Porcupine Lake in northern Ontario. The orebody beneath this outcrop has supported one of Canada’s premier gold mining operations for 80 years. Production during this time of over 46 000 000 tons of ore has resulted in the recovery of II 500 000 ounces of gold and 2 000 000 ounces of silver. Mining continues today at a production rate of 3500 tons per day, with ore coming from both underground and open pit operations.During the life of the mine, different underground mining methods have been used to extract the ore from a complex deposit consisting of single and multiple vein structures.Cut-and-fill mining was introduced in the 1930s using sand fill and later hydraulic fill for support and to provide a working platform. A total of 1 800 000 tons of sand fill and 7 300 000 tons of hydraulic fill have been placed underground in cut-and-fill stopes. Until the late 1960sshrinkage mining was used extensively, particularly in narrow, steeply dipping zones. Bulk mining with small diameter longholes was introduced about this time, to take advantage of low production costs. Longhole blasting has often been used to recover low grade ore from the walls or sills of old shrink stopes, resulting in large open stopes. Backfilling of these open holes has been restricted to smaller stopes and associated with local ground conditions.In the late 1970s it was recognized that the number of large open holes which were being generated presented serious regional and minewide stability problems for future operations. With higher gold prices, economic ore reserves were being tied up in areas adjacent to multi-level open stope complexes. To stabilize these stopes and allow access, backfilling would be required."

Jan 1, 1990

"This document establishes standards and guidelines for scientific and technical disclosure by Issuers listed on the TSX Venture Exchange on their mineral properties. It incorporates and expands upon the minimum standards prescribed by Securities Laws and applies to all oral statements and written disclosure made by an Issuer or on behalf of an Issuer involving mineral properties.1. Introduction1.1 General(a) This Appendix establishes standards and guidelines for scientific and technical disclosure by Issuers on mineral properties. These standards and guidelines should be applied prudently and with common sense by those Issuers in conjmction with the applicable requirements of section 1.2.(b) This Appendix incorporates and expands upon the minimum standards prescribed by Securities Laws and applies to all oral statements and -written disclosure made by an Issuer or on behalf of an Issuer involving mineral properties.(c) This Appendix is not intended to be exhaustive or all-encompassing and greater detail may be appropriate and required in certain situations. Issuers are encouraged to contact Exchange technical staff where they are not certain about the requirement for disclosure on mineral properties."

Jan 1, 2003

By L. Yaun

In underground coal mining operations, gas content in a coal seam is used to assess the risk of coal and gas outbursts. To estimate the gas content, a number of systems have been developed, however issues remain about the rapidness and accuracy of these systems. To address these issues, a new and improved system has been developed that includes a sampling-while-drilling unit for coal sampling, a coal canister, an underground-based portable measurement unit, a surface-based measurement apparatus, and gas content calculation software. The system has been successfully applied in underground coal mines at Huainan, China. This new, rapid and accurate system, its main components and field trials are described in this paper.

Aug 1, 2013

By Waghmarem Umesh V., Vinay Jain, Pradip, Beena Rai

"The hematite surface plays a vital role in several processes of industrial and technological importance, such as, in beneficiation of iron ores, catalysis, and geochemical processes. Therefore, it is imperative to have a clear description of the structure and composition of this surface, which forms the underlying basis for such a wide variety of complex phenomena. Particularly, from the perspective of beneficiation of Indian alumina-rich iron ore slimes and fines, a clear understanding of the surface structure and composition of hematite surface and its difference from the alumina surface will facilitate identification and/or design of selective reagents which can be used to separate the two minerals. In this work, the hydroxylated hematite (0001) surface was modeled using density functional theory (DFT). The computed planar relaxations are consistent with X-Ray crystal truncation rod diffraction results reported in the literature. It is demonstrated that only one type of surface, that is, the (OH)3-Fe-H3O3-R is stable under aqueous conditions, as the relaxations for the second type of termination: (OH)3-Fe-Fe-R do not match quantitatively with experiments suggesting that its coexistence with the (OH)3-Fe-H3O3-R surface is unlikely. A detailed analysis of this surface shows that two of the three (OH) groups are not connected to the Fe surface atom. Instead, they form H2O molecules by combining with the H-atoms on the O-layer beneath the Fe-terminated surface leaving the Fe surface-atom bonded to only one OH-group. This undercoordination of Fe-atoms on the surface explains its higher reactivity as compared to hydroxylated alumina.INTRODUCTIONThe hematite surface plays a vital role in several processes of industrial and technological importance. A few examples are: flocculation/froth flotation of iron ores (Ravishankar, Pradip & Khosla, 1995), catalysis (Muhler, Schlögl & Ertl, 1992; Samsonov, 1973), and geochemical processes (Brown, Henrich, Casey, Clark, Eggleston & Felmy et al., 1999; Sposito, 1989). Therefore, it is imperative to have a clear description of the structure and composition of the hematite surface, which form the underlying basis for such a wide variety of complex phenomena. Particularly, from the perspective of beneficiation of Indian alumina-rich iron ore slimes and fines, this is an important problem, as a clear understanding of the surface structure and composition of hematite surface and its difference from the alumina surface will facilitate identification and/or design of selective reagents which can be used to separate the two minerals. Our current research focus is at employing molecular modeling techniques to come up with such selective reagents and then test their efficacy in the practical scenario through selective dispersion – flocculation labscale experiments and subsequently plant trials. Obviously, the correct structure and composition of the hydroxylated hematite surface is a fundamental prerequisite for such investigations."

Jan 1, 2016