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By B. Kenney

For SOFCs, composite cathodes comprising an electronically conducting electro¬catalyst (e.g. LSM) and an conically conducting electrolyte material (e.g. YSZ) are considered to improve the electrochemical performance by extending the active reaction zone to regions beyond the electrolyte-electrode interface, as in the case of conventional cathodes. Interpretation of experimental data for composite cathodes, however, is complicated by the mixed conducting behaviour which results in local overpotential distributions throughout the composite cathode. These local overpotentials depend on many factors, such as the composition, particle size, porosity and thickness of the cathode. Reliable experimental data obtained from composite cathodes requires carefully crafted microstructural parameters in order to minimize the overpotential variations. A mathematical model of a composite cathode was developed using coupled differential equations describing transport and consumption of chemical species, oxygen ion and electrons. Simulations under various oxygen concentrations were used to obtain the reaction order of the oxygen reduction reaction. An apparent po2 dependency was then extracted from the predicted Rp vs P02 data. It was found that this p02 dependency can be significantly influenced by the micro-structural parameters of a composite cathode, primarily due to local overpotential distributions.

Jan 1, 2005

By A. L. Mular

This paper provides a worthwhile contribution to the knowledge needed for calculating and using mathematical models of grinding circuits. The computer search algorithm proposed should remove much of the guesswork as well as reduce computer processing costs and improve the accuracy of estimated parameter values for grinding mill models.

Jan 1, 1970

In this study, we develop a detailed model of the likely future carbon footprint of primary copper supply. We develop a peak copper production model, based on a detailed copper resource data set, and combine this with a comprehensive life cycle assessment model of copper mining and milling to predict greenhouse gas emission rates and intensities of Australian and global copper production up to 2100. By establishing a quantitative prediction of both copper production and corresponding greenhouse gas emissions of Australian and global copper industry, we then analysed the emissions intensity of various energy input scenarios, such as business-as-usual, solar thermal electricity and solar thermal electricity with biodiesel. The Australian Government has an aspirational goal for long-term greenhouse gas emissions of an 80% reduction from the 2000 level by 2050. For the copper sector, this means moving from about 12.6 Mt CO2e in 2000 to a goal of some 2.52 Mt CO2e in 2050 (assuming equal emissions reductions across the economy). Based on the energy sources modelled, only the solar thermal plus biodiesel scenario was capable of achieving this goal at about 0.15 Mt CO2e, since the solar thermal alone scenario still includes normal petro-diesel as a major source of emissions. Overall, it is clear that there are abundant resources which can meet expected long-term copper demands, the critical issue is more the carbon (and environmental) footprint of different copper supplies and use rather than how much is available for mining. It is clear that the switch to renewable energy can have a profound impact on the carbon intensity of copper supply, even allowing for increased energy intensity as ore grades decline, and a complete conversion to renewable energy will position the copper sector to meet existing annual greenhouse gas emissions targets and goals.

Aug 1, 2013

By Emmanuel Henry

Hanging wall deformation monitoring at the Kiruna Mine is a major concern for Luossavaara- Kiirunavaara AB (LKAB) since underground production is deepening towards the Kiruna Town. In the quest for more effective monitoring techniques, LKAB decided to evaluate satellite-borne Synthetic Aperture Radar (SAR) interferometry?s ability to monitor ground subsidence by generating continuous deformation maps from satellite radar images. While adopted by other geoscience-related industries, SAR interferometry is still relatively untested in the Mining industry. This paper describes how subsidence is actually monitored on the Kiruna Mine?s hanging wall and gives an insight on SAR interferometry?s principle. The encouraging results are discussed as well as the technique?s benefits (continuous deformation mapping, low cost, fast, etc) and limitations (sensitivity to snow and vegetation cover).

May 1, 2003

By R. A. Nemchek

Over the years, concentrator plant design has evolved from a large number of small grinding mills to a small number of large mills. In many cases, all of the tonnage runs through a single mill (typically a large SAG mill), so that the plant?s performance hinges on the productivity of this one machine. Industry specifications attempt to address the critical nature of today?s grinding mills in a manner that is often overly complex, neglects economics, and is not clearly focused on the end user?s goals. This paper surveys current industry practices, and proposes an improved approach to standards writing recognizing that product design, procurement, manufacturing, and quality are all inter-related in contributing to a project?s success. The lessons learned here can be extended to specifications for all types of machinery.

Jan 1, 2012

By Mahmood Alemrajabi, Ake Rasmuson, Kerstin Forsberg, Kivanc Korkmaz

"In the present study, the recovery of rare earth elements (REE) in the nitrophosphate process of fertilizer production is investigated. The apatite has been recovered from iron ore tailings by flotation. After digestion of apatite in concentrated nitric acid, Ca(NO3)2.4H2O is first separated by cooling crystallization and then the REEs are recovered by precipitation. Optimum conditions in these steps have been determined in a previous study. The precipitate mainly consists of CaHPO4.2H2O and REE phosphates.In the present study, selective dissolution and re-precipitation have been studied in order to obtain a precipitate that is more concentrated in REEs. The precipitate was selectively dissolved in nitric and phosphoric acid at different acidities (pH 6 to 0) with the liquid /solid ratio of 100 mL/g. It is shown that most of the CaHPO4.2H2O and other calcium containing compounds will be dissolved at pH 2 while the REE phosphates are not dissolved above a pH of approximately 2. Thus, by partial dissolution of the REE precipitate at pH 2.5 most of the solid calcium phosphates will be dissolved and the remaining solid phase, which is more concentrated in REEs, can be filtered off as a fairly concentrated REE solid mass and the liquor can be recycled back to recover more P nutrients. Alternatively, the REE enriched precipitate was dissolved completely in nitric acid and re-precipitated again by addition of ammonium hydroxide to pH 1.2. A chemical equilibrium software, MEDUSA (Puigdomenech, 2013) has been used to evaluate the experimental results and to estimate the optimum conditions for selectively dissolving the precipitate."

Jan 1, 2016

By R. Hans

Removal of toxic anions from aqueous solution was studied using a Magnetic Ion Exchange (MIEX) resin which is a polyacrylic, strong base resin. Gravity based settling is made more efficient due to the magnetic nature of the resin which is advantageous over conventional ion exchange resins. In addition, the magnetic microspheres of MIEX have larger surface area in comparison to conventional ion exchange resins. Over the years MIEX has been successfully used and has gained significant popularity for efficiently removing dissolved organic matter from wastewater and groundwater. In the present study the efficiency of the MIEX resin was tested for the removal of chromium(VI), molybdenium(VI), vanadium(V) and arsenic(V) anions. Effects of pH (2-10) and temperature (25oC-55oC) were examined. In general, low solution pH values were favorable for anion uptake by MIEX. Except for chromium(VI), the metal ion uptake was significantly increased by the increase in solution temperature. The adsorption data were analysed on the basis of chemical speciation and heterogeneous kinetic models.

Jan 1, 2014

By K. Svens, M. Lahtinen, L. Lehtinen

"Outotec's direct leaching process is an atmospheric leaching process for sulphidiczinc concentrates. The direct leaching process, based on special leaching reactors developed by Outokumpu and leaching know-how, is the most economical way to produce electrolytic zinc. The newest industrial-scale application of Outotec's direct leaching process will be started up in 2008 in China at Zhuzhou smelter. The process isintegrated to the existing production plant, replacing part of the old production facilities by modern technology and increasing the production capacity significantly. The process equipment supplied by Outotec includes also tailor-made reactors designed on the basisof the work and experience of Outotec Research Centre."

Jan 1, 2008

By V. Bondarenko

The importance and necessity of gas hydrates deposits development followed by natural gas extraction is considered in the present paper. Analysis is given to world sources focused on methane hydrates formation conditions. Information covering the most perspective gas hydrate deposit of the Black Sea is presented in the article. Two most common methods of gas hydrates development ? thermo stimulation and inhibitor injection are analyzed presenting their comparative characteristics. Basic scientific trends and developments of underground mining department in the field of gas methane extraction from gas hydrates are scrutinized. Schemes and methods of natural gas hydrates development are shown together with formulas, parameters and factors influencing the extraction process. Also the analysis is given to the possibility of gas hydrates formation from methane-air mixtures of degassing wells from coal mines of Ukraine. Improved experimental unit for gas hydrates formation under laboratorial conditions is presented with its basic characteristics. General conclusions and basic tasks requiring further research are given in the end.

Aug 1, 2013

By S. K. Sharma, Sanket Bacchuwar, Prabal Kumar Agrwal, G. V. Rao

"Iron ore processing industries play a vital role in the Indian economy. At present Iron ore of around +64% Fe is used for production of Iron through blast furnace. To produce +64% Fe from low/medium grade ores, crushing & beneficiation is compulsory. But during these processes, large amount of slime is generated. It is estimated that 18% -25% of tailing is generated during the processing of iron ore. The iron ore slime is discarded because of its particle size and chemical composition not being suitable as feed to the blast furnace. Although the fines/slimes can be agglomerated to larger particle, the alumina to silica ratio which is normally more than one pose serious problem during sintering process and subsequent smelting in blast furnace. The alumina content in the slime needs to be reduced for it to be used as the feed for blast furnace. The sample assayed 61.40% Fe, 7.68% SiO2, and 1.52% Al2O3, LOI 2.63% and all other elements were found in critical limit. A series of 27 tests were conducted by using a spiral for optimisation of process parameters to produce a pellet grade concentrate from the stacked slimes obtained from Kirandul. This paper deals with the optimisation studies of various parameters of a spiral concentrator and helps to utilize the fines from tailing ponds.INTRODUCTIONReserves of high-grade iron ores are diminishing all over the world at an alarming rate. As a result, alternative ways of augmenting and conserving precious and non - renewable natural resources are being seriously considered. One such attractive option is the recovery of metal values from slimes / tailings. Iron ore tailings containing around 48 - 60% Fe are generated from the iron ore washing plants and are disposed into tailing ponds without any further utility. These tailings in the form of slimes are not suitable in iron and steel making due to the presence of higher amount of gangue constituents. Several beneficiation techniques have been tried from time to time to reduce the gangue so that the beneficiated products could be effectively used."

Jan 1, 2016

By Donka H. Andreeva

Gold catalysts based on different supports, titania, zirconia, ceria and mesoporous titania and zirconia, nonpromoted and promoted by vanadia in the reaction of complete benzene oxidation have been studied. XRD, HRTEM, TPR, Raman and ESR spectroscopy were applied for the characterization of the catalysts. The influence of gold on the reduction behavior, state and structure of vanadia on the surface was studied, as well as the role of supports nature on the properties and catalytic activity. A strong synergistic effect between gold and vanadia was observed for the all studied catalysts with an exception of the catalysts supported on mesoporous zirconia. In the last case the catalysts containing gold and gold-vanadia exhibit high and equal catalytic activity. The catalysts on ceria show highest and stable catalytic activity in the studied reaction among the all studied catalysts.

Oct 1, 2003

By P. Personnet, D. Wheaton, E. Couzinie, V. Demetriou, Brooks. W., G. Girault, M. Meyer, L. Charbonnel

A common problem in Gas Treatment Centers (GTC) from primary aluminium smelters is the temperature of the gas to be treated : above a threshold, filtering media are irreversibly damaged. The traditional way of dealing with high gas temperature is to dilute with fresh air, which implies over sizing - and therefore higher cost for - the GTC in order to have the capacity to treat this dilution air without compromising on pot suction. A system was developed which decreases gas temperature without having to use dilution air. This system is based on water pulverization in gas collectors. The water vaporization leads to a temperature decrease of the gas. A pilot system was trialed in our R&D unit. Satisfactory results led to the development of an industrial system based on Envirocare equipment (partnership), which was trialed in our production plant in Tomago (NSW, Australia). This patented system was then generalized in this plant, which is now using it with success during austral summer.

Jan 1, 2006

By M. Cousineau, S. Gariepy

"Current business and corporate environments push for improving metal accounting practices in smelters. The ensuing projects commonly proceed along a bottom-up approach. As such, efforts are first put on reviewing the measurement system and then on remedying the identified weaknesses. The focus is thus moved to mass/metal balance only after the measurements upgrade process has been completed. However, practice has shown that assessing the high variances related to suboptimal measurement processes is complicated without the help of statistical data reconciliation. This bottom-up approach leads to a to-do list that can not only exceed available resources but also lack prioritization in view of achieving the targeted end use. This paper describes an upgrade project done differently where all the three dimensions of the metal accounting system: hardware, software, and people were instead involved at the onset. Personnel was thus trained on data reconciliation software at the beginning of the project to make the reconciled mass balance benefits available earlier in the upgrading project. This has pinpointed the most critical measurements where accuracy and reproducibility should be improved. Overall, not only the instrumentation retrofitting process has been streamlined, but the global risk for the whole upgrading project has been significantly lowered.INTRODUCTION Mining companies are pressured to improve their production accounting practices in response to the strengthening of corporate requirements for timely and accurate production reporting (Gaylard, Randolph, & Wortley, 2014). Smelters are not spared from these changes. However, their unique situation in the mining value chain set them as strategic targets for upgrading projects. They usually have a longer lifespan than concentrators thereby offering an extended lifecycle to justify investments. Furthermore, numerous smelters have toll agreements with third parties. Accurate cost and production accounting is, therefore, a vital piece of information to fix acceptable contract conditions. Mining companies are ultimately aiming at a clearer view of the operating performance of each business unit to improve their business decisions in a competitive environment. This sought for increase in visibility through plant performance can only be achieved through an upgrade of the metal accounting system. Figure 1 shows the different components of a state of the art system (Gaylard, Morrison, Randolph, Wortley, & Beck, 2009)."

Jan 1, 2017

By H. Miki, S. Wheatley

The addition of precipitated silica greatly enhances chalcopyrite leaching in the presence of sodium chloride at moderate temperatures (65-90°C) in acid media with ferric ions as the oxidant. The beneficial effect increases with the increase in chloride concentration and temperature. The addition of sodium silicate and silica sand has no significant influence. The analysis of solubility data in acid/salt solutions indicates that the solubility of silica as Si(OH)4 as the dissolved species is controlled by the activity of water, as expected from the hydration theory. Kinetic analysis shows the trends that copper dissolution from chalcopyrite in the presence of precipitated silica with sodium chloride follows a shrinking sphere model indicating a chemically controlled surface reaction. The effect of temperature on copper dissolution in the presence of both precipitated silica and sodium chloride was also larger compared to the results in sodium chloride alone. The SEM analysis shows that chloride and silica facilitates the precipitation of sulfur on the surface of the silica particles rather than the chalcopyrite particles which avoids the blockage of the mineral surface and thus improves the leaching kinetics.

Jan 1, 2014

By J. R. Fisher

"Uranium may be leached to some extent in situ from the Blind River conglomerate uranium ores by using the products of bacterial activity from the bacterium Thio-bacillus ferrooxidans his paper describes some of the laboratory techniques used to investigate the characteristics of the bacteria, and to utilize their properties in uranium leaching. The application of some of the laboratory results underground at the Milliken mine of Rio Algom Mines Limited are de-scribed, along with the method of uranium recovery from the mine waters."

Jan 1, 1966

By O. Lashkari, A. Charette, R. Ghomashchi

Conventional casting at low pouring temperature was employed to produce semisolid metal, SSM, billets of A356 Alloy. The deformation behavior of the as-cast SSM billets was studied using parallel plate compression viscometry. The compression tests were carried out at different applied pressures, and fractions solid. The rheological studies were conducted assuming the SSM slurry behaving like Newtonian and non Newtonian fluids respectively. The calculated viscosity numbers confirmed pseudoplastic behavior of the SSM billets and were correlated to fraction solid and shear rate proposing the following empirical equation which is valid at low shear rates, less than 0.01 s-1, and fraction solid of0.33-0.46: 0 log77 =5.56-l.38fs -(l.56fs +0.14)logy Aluminium 2006 45th Annual Conference of Metallurgists ofCIM Montreal, Quebec, Canada Edited by G. Dufour, F. Paray and J. Tessier 0.33<fs<0.46

Jan 1, 2006

By S. Hosseinpour

Chromate conversion coatings (CCCs) are usually applied to these alloys to enhance their resistance to localized corrosion and to improve paint adhesion. The special properties of these coatings such as their low electrical contact resistance (ECR) make them suitable for satellites. This study is aimed to develop advanced CCCs with the proper appearance, morphologies and surface roughness and to evaluate their role on the ECR and thermo physical properties on hardened aluminium alloy of Alclad-7075-T6. Coating characterization was performed by means of scanning electron microscope (SEM) and atomic force microscope (AFM). ECR of coatings were measured by special laboratory designed instrument and a and c were measured by Emissometer and Reflectometer respectively. In addition, corrosion performance of the CCC-coated alloys was determined by 168 hr exposing to salt-spray testing in accordance with ASTM-B117. The results of accomplished experiments on the developed CCCs in this study have been agreeable concerning available acceptability criteria for satellite surfaces.

Jan 1, 2007

About Barrick Paste Backfill at Barrick Goldstrike Rodeo Paste Plant Cyclone Lab Testing Challenges and Lessons Learned Future Barrick Projects

May 1, 2013

By M. L. Smith

"In the Phosporia formation of SE Idaho, ore quality varies by depth, seam and distance along strike; phosphorus recovery is sensitive to these variations. Plant ore feed can be blended over time to minimize this fluctuation by using a combination of mine production and inventory stockpile scheduling. Mixed-integer and goal programming has been used to optimize short-term mine production, but the seasonal nature of mine haulage requires the use of stockpiles both at the mill and the mine. The contents of the stockpiles can also be optimized as part of the production scheduling problem, but introducing inventory control introduces a nonlinear term into the formulation. A solution using a piecewise linear formulation is modelled and solved using AMPL/Cplex, and solution strategies are discussed for similar large-scale problems. IntroductionIdaho’s minable deposits of phosphate rock are found in the Meade Peak member of the Phosphoria Formation; two separate zones of this formation are mined with a combined thickness of 30 ft to 60 ft. A generalized stratigraphic section of the Phosphoria section is shown in Figure 1, illustrating the degree of complexity encountered when scheduling mine production. Alteration of the formation results in higher grade ore zones near the surface and variable in P2O5 levels between seams and along strike. This variability is seen as well in other quality characteristics critical to the production of acid and elemental phosphorus. Further, plant recovery and nodule quality are sensitive to variations in ore feed; variability in SiO2, carbonates, moisture, organics (carbon), P2O5 and other constituents of the ore can strongly affect plant recovery. Because ore quality characteristics can vary as a function of the alteration zone (or seam) being mined as well as the depth and distance along the strike of the formation, scheduling of mine production can have a highly significant effect on recovery in the plant. As illustrated in Figure 1, there are nine seams containing 20% to 35% P2O5. Phosphoric acid and elemental phosphorus production requires an ore content of 30% and 25% P2O5, respectively. Variability between numerous beds that are mined and quality variation within a seam due to alteration greatly complicates production scheduling with the result that erratic mill feed characteristics greatly decrease recovery."

Jan 1, 1999

By F. Liu, H. A. Meier, D. M. Valiveti, P. A. Gordon

Hydraulic fracture is a frequently used technique in the Oil and Gas industry to create high permeability pathways for extraction of hydrocarbons. Numerical simulation of this method poses challenges such as representation of 3D fractures, propagation of randomly oriented fractures in 3D media, enabling fluid leak-off from fracture to poro-elastic medium. We have developed a numerical model using the Generalized Finite Element Method (GFEM) to simulate fluid driven fracture in a poro-elastic medium that addresses these challenges. In the GFEM framework, special enrichment functions are used to augment the solution space in the displacement and pore-pressure fields in order to accurately capture the response in the vicinity of the fracture. Adaptive refinement of the finite element mesh is also employed to facilitate accurate and efficient solution of the model. Our model fully couples fluid flow in the fracture, represented with the lubrication approximation, to the geo-mechanical behavior of the bulk poroelastic rock, comprised of an elastic rock skeleton saturated with fluid. Fracturing fluid exerts traction on the fracture surface and is also allowed to leak-off into the poroelastic medium using a transfer function approach. Stress intensity factors (SIFs) are evaluated based on the Contour Integral Method, accounting for the fluid pressure on the fracture surface. The SIFs are used to govern a full 3-D evolution of the fracture. Verification of the model is performed for known behaviors for the poroelastic response and fluid flow in the fracture.

Jan 1, 2015