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By A. Blackmore, A. Lamoureux, J. Woloshyn

This paper provides an overview of recent applications of Computational Fluid Dynamics (CFD) to combustion related fugitive emissions problems. The aim is to illustrate the capabilities and discuss the present limitations in this field. Examples include design of retrofitted NOx reduction technology in a kiln and in a boiler, and the prediction of pollutants such as SO2 and metallurgical dust emanating from a copper flash smelting furnace. It is demonstrated that CFD is an effective tool for reducing technical risk in design, for identifying the root-cause problems and testing solutions, and for concurrently assessing emissions reduction and process impact. In addition, the value of CFD for demonstrating due diligence for regulatory compliance is discussed.

Jan 1, 2015

By Rick Steen, Weldon Read, Morrism Tracy T.

Edging for starter sheet blanks used in conventional copper refineries has always been problematic for getting the edging to seal and adhere to the titanium material used for the blank so that copper is prevented from plating under the edging and cause undo problems in getting the copper sheets to separate from the blanks. A method was developed at the Amarillo Copper Refinery utilizing an injection molding process that better adheres the edging material to the titanium that makes the harvesting of starter sheets much easier to the point that robots are now used to strip with and which holds up very well to the unforgiving physical nature of the electroplating process. It is believed that this technology could be successfully utilized for permanent cathodes as well. INTRODUCTION ASARCO LLC (Asarco) was organized in 1899 as the American Smelting and Refining Company. Originally a consolidation of several lead-silver smelting companies, it evolved over the years into an integrated producer of primary non-ferrous metals, including copper, lead and zinc and associated co- products (Marcosson, 1949). Grupo México, S.A.B. de C.V acquired Asarco in 1999. Today, Asarco is a vertically integrated producer of primary refined copper and associated co-products such as gold, silver, molybdenum, selenium and tellurium. Asarco operates three open-pit mines and mills and two solvent extraction-electrowinning (SX-EW) plants all in Arizona plus a copper smelter in Arizona and a copper refinery in Texas. Figure 1 illustrates how the copper metal comes out of the ground at the mine and ends up as a refined product at the refinery. The copper refinery in Texas is known as the Amarillo Copper Refinery (ACR) and is located in Amarillo, Texas. It was built in 1975 to replace 3 other aging refineries and was designed to produce 550,000 tons (500,000 MT) of refined copper per year using conventional starter sheet technology. At the time it was commissioned it was the largest tankhouse in the world at just under 1/2 miles long under one roof.

Jan 1, 2019

By D. Paul Bishop, Kevin P. Plucknett, Hung-wei Liu

"Spark plasma sintering (SPS) process has been evaluated for producing the commercially pure (CP) Ti, TiAl and a TiAl-B4C composite. Comparisons were made between the materials in terms of the sintered density, resultant hardness and microstructures. In the present work, the titanium aluminide powders (Ti-48Al, producing a mixture of y-TiAl/a2-Ti3Al) were synthesised „in-house? using a simple reaction-sintering and mechanical attrition approach. This allowed various size distributions to be generated. The powders were then blended with a fine boron carbide (B4C) powder (up to 6 wt.%), and the resulting mixtures were consolidated using spark plasma sintering (SPS) under vacuum in graphite dies. An applied stress of 50 MPa was used for all SPS runs. The SPS parameters were varied in terms of the ultimate sintering temperature (up to 1300°C) and hold time (up to 10 minutes) for each material. It is demonstrated that high densities can be achieved this approach (exceeding 95% of theoretical, with optimised samples close to full density). Microstructural characterisation was conducted using optical microscopy, scanning electron microscopy, and X-ray diffraction. The B4C additions were seen to partially react with the TiAl to form reinforcements, such as TiCx and TiBx. Preliminary mechanical property assessment will also be briefly discussed.INTRODUCTION Titanium- and titanium aluminide-based alloys possess many unique properties, such as excellent corrosion resistance and high temperature strength, respectively (Cardarelli, 2001; Leyens & Peters, 2003). Compared to many other competing materials (e.g. stainless steel or Ni-based alloys), Ti- and TiAl-based alloys also have relatively low densities (~4.5 and ~3.9-4.1 g/cm3, respectively), which is critical for performance in aviation and automobile applications. However, the manufacturing cost is high, due to the expensive raw Ti material and difficulties in machining. TiAl-based alloys are particularly difficult to produce because of their limited ductility (Lütjering & Williams, 2007). To overcome those problems, powder metallurgy (PM) technologies have shown great potential as near-net shape processes for Ti- and TiAl-based alloys. The general PM process largely avoids laborious post-machining and minimises material use. In industrial production, the PM approach has been successfully utilised to manufacture aluminium- and iron-based alloys (Huo & Heath, 2008)."

Jan 1, 2017

By K. Horikawa, S. Kitahata, H. Kobayashi

"It has been clarified that the Al-5%Mg alloys containing 200 mass ppm of sodium showed grain boundary (GB) fracture, even when tested at room temperature, as well as at high temperatures (~500°C). SEM/EDX study revealed that the GB fracture was associated with the segregation of sodium on grain boundaries of the Al-Mg base alloys. Differential scanning calorimetry (DSC) revealed that the GB fracture at room temperature of Al-Mg alloys was caused by sodium segregation in the solid state. It was also shown that the tendency of the GB fracture strongly depended on the heat treatment; the alloys after the solution heat treatment showed severe GB fracture compared with the alloys after the homogenizing treatment. Moreover, it was shown that the GB fracture at room temperature by sodium segregation was suppressed by the addition of bismuth or indium. The suppression of the GB fracture by the additional elements was believed to be the scavenging effects by forming the sodium bearing compounds in grains.INTRODUCTIONIt is widely known that Al-Mg base alloys containing high amount of magnesium(~5 mass%)show better workability at room temperature, while that the alloys show grain boundary (GB) embrittlement at higher temperatures ranging from 200 to 500°C, depending on grain size(Otsuka, 1984), sodium impurity level(Ransley, 1959, Okada, 1997, Horikawa, 2001)and testing strain rate(Yamada, 2012). In the case of coarse-grained Al-5%Mg alloys (~300 ?m), 2 mass ppm of sodium causes severe GB fracture around 300°C, however, the Al-5%Mg-2ppm alloy does not show GB fracture at room temperature. It has also been shown that the GB embrittlement caused by 2ppm of sodium was suppressed by the additional elements, such as bismuth (Talbot, 1995), antimony (Ueda, 1997) and indium (Horikawa, 2012). Basedon these facts, we have concluded that the GB embrittlement at higher temperatures of Al-Mg alloys is attributed to the synergy effects of GB segregation of atomic sodium and GB sliding. For the GB embrittlement mechanism of Al-Mg alloys, involvement of low melting point metallic phases has been pointed out (Lynch, 2002),since the GB embrittlement appeared only at high temperatures. Up to date, the effects of high amount of sodium addition more than 2 ppm on GB fracture were not fully investigated in Al-Mg alloys. In the present study, the effect of 100 ppm ordered sodium impurity on GB fracture of Al-5%Mg alloys was examined, together with the effect of another additional elements."

Jan 1, 2017

By J. W. McCammon

WHEN times are booming and metal prices are high, most mining men pay little attention to the industrial mineral industry. However, when metal prices drop and mines close down, many mining eyes begin to scan the less glamorous non-metallic field. For some this proves a temporary diversion, but others find this branch of mining, with its generally more stable conditions, to their liking and enter it permanently. The resulting gradual influx of trained mining men into the industrial mineral industry ?has been one of several factors responsible for the rise in production of non-metallic materials in our Province. Another and ?perhaps the most important factor influencing the production of industrial minerals has been the growth in the population of British Columbia. Because most industrial minerals .are low priced and either heavy or bulky commodities they are normally sold on relatively local markets. Thus the extent of the development of the industrial mineral industry of a region is largely governed by the size of the population and the level of industrialization of that region. This point is well shown by com-paring population and industrial mineral production statistics for 1936, 1946, and 1956 (see Figure 1)9. Note that not only has the overall production rate grown with the population increase, but that the per capita production has risen greatly.

Jan 1, 1958

By H. Utsunomiya, J. Su, K. S. Tamimi, S. Yue, M. Sanjari, L. Kestens, A. S. Kabir, R. Petrov

The recrystallization and texture evolution of AZ31 sheets obtained through two stages was investigated at different stages of post-rolling annealing. The specimens were rolled at the temperature of 100? and at a fast speed of 1000m/min and low speed of 15m/min with a reduction of 30% in one pass. The results show thatAZ31B sheets rolled at 15 m/min and 100 °C has fractured for reductions of more than 30% per pass. However, by increasing the rolling speed to 1000 m/min the rollability was improved significantly and the material can be rolled to reductions of more than 70% per pass. The high speed and heavily deformed materials are fully recrystallized even at 100 °C.

Jan 1, 2015

This work illustrates the potential of two welding processes for joining AA1100-16 vol.% B4C metal matrix composite: laser welding process using a 4 kW Nd:YAG laser and Friction Stir Welding. A comparison is made between these two welding techniques in terms of microstructure and mechanical properties of welded joints. A large amount of brittle needle-like phases, together with some residues of B4C particles were observed in the fusion zone of laser welded joints. The use of Ti filler can improve the microstructure and increase the joint efficiency from 63% to 75%. On the other hand, the friction stir welding process being a solid state welding technique is interesting as it avoids the formation of brittle intermetallic phases. In addition, the breakage of B4C particles and the grain refinement of the matrix were observed in the weld zone. Consequently, FSW joints show much better mechanical properties than laser welded joints. Up to 100% joint efficiency can be achieved by FSW for annealed AA1100-16 vol.% B4C materials.

Jan 1, 2011

Mining companies around the globe have long struggled with the need to ensure that earth moving equipment is designed to be operated and maintained under all site conditions without causing harm to people. Incident and accident data from a range of sources clearly identify mining equipment related issues as major causal factors. One Australian source, the NSW Department of Primary Industries? International Mining Fatality Database Project Report (2008) noted that ?Approximately 77% of mining accidents resulting in a fatality have? involved equipment?. The largest number of fatalities were associated with trucks; the next with LHDs. Many of the technical advances in equipment design over the past few decades have not been matched by advances in the human factors design of mining equipment, resulting in a ?design vacuum? that must be filled prior to commissioning new equipment. This ?design vacuum? is generally filled by local dealers. They retrofit equipment according to customer requirements to mitigate risks that have not been designed out by the Original Equipment Manufacturer (OEM). Mining companies have been frustrated by lost time and additional costs associated with this need to retrofit ex-factory designs. Some companies have attempted to address the problem by negotiating company or site-wide ?solutions? to equipment designs, but this has not simplified or clarified the issue from the point of view of the equipment manufacturers. A number of mining companies operating in Australia first discussed the concept of a joint customer approach to improve the Human Factors design of earth moving equipment at the factory level in 2004. They agreed that a new approach to engaging with OEMs was needed; one that would define the ?Problem?, in other words, the basis of the risks, rather than dictate the ?Solution?. The Earth Moving Equipment Safety Round Table (EMESRT) was formally established in 2006 by six global mining companies to establish a process of engagement between Original Equipment Manufacturers (OEMs) and mining customers.

May 1, 2009

By D. Kong, A. Klyashtorin, L. McGilp, I. Wilson

This work reports on applying iron oxide coated sands media in an experimental permeable reactive barrier to remove uranium species from uranium containing water. A field experiment was conducted at the legacy Gunnar uranium mine & mill site that was abandoned in the 1960s with limited to no decommissioning. The flooded Gunnar mine pit presently contains about 3.2 million m3 of water contaminated by dissolved U (1.2 mg/l), Ra-226 (0.4 Bq/l), and minor concentrations of other contaminants (As, Se, etc.). The water is seeping over the pit rim into Lake Athabasca posing environmental and health concerns. Iron oxide coated sands can be used to immobilize uranium species through an adsorption process. Methods for preparation of hydrous ferric oxide sorbents and their supported forms onto silica sands are described. Fourier transform infrared spectroscopy (FTIR), and powder X-ray diffraction (pXRD) were used to characterize the physical-chemical properties of the sorbent. The monolayer uranium uptake capacity (Qm) was estimated through the Langmuir adsorption isotherm. Adsorption kinetic experiments were performed in a lab environment before moving to a field trial. Based on these lab results and the input on field-scale appropriate geometries, a pilot permeable reactive barrier was fabricated and a field test conducted near the Gunnar pit in June 2019. This pilot test provided technical data and information needed for designing a full-scale permeable barrier based on the iron oxide coated sands, which may be applied for in-situ water treatment at Gunnar and other legacy uranium sites.

Jan 1, 2020

By E. Eccleston, E. Gardner, F. Letarte, R. Schonewille

"In 2005, after nearly a decade of process development and feasibility work, the commercialization of the Falconbridge Nickel Smelting Technology (NST) began in earnest with the design and construction of a grassroots ferronickel plant at Koniambo Nickel in New Caledonia. The NST process was developed as an alternative to the conventional Rotary Kiln-Electric Furnace (RKEF) process for production of ferronickel from saprolitic nickel laterite ores. The NST process promised environmental and energy efficiency advantages over the conventional route. A key step of the NST process involves fluidized bed pre-reduction of calcined laterite ore using direct injection of pulverized coal as the reductant. Two parallel fluidized bed reduction roasters (FBRs) were installed at Koniambo Nickel, each designed for a maximum capacity of 4,200 MTPD of calcined nickel laterite ore. This paper describes the process development and scale-up of the fluidized bed pre-reduction process, the design challenges associated with the prototype commercial units, and the current status of the FBR operation at Konaimbo.INTRODUCTION In the mid-1990s, Falconbridge began to develop a new flowsheet for production of ferronickel from nickel laterite ores. The process that developed came to be known as the Falconbridge Nickel Smelting Technology (NST). The flowsheet, which is particularly appropriate for saprolitic ores, involves several major unit operations, including: drying in a hammer mill-flash dryer, calcination and preheating in a flash calciner, pre-reduction in a fluidized bed reactor, and smelting in a DC arc furnace to produce the ferronickel product. This paper focuses on the fluidized bed pre-reduction step of the process and provides an overview of the process chemistry, laboratory and pilot plant development work, scale-up and commercialization of the pre-reduction step, and the results obtained in the prototype commercial units."

Jan 1, 2017

By T. Senga, T. Namihira, S. Terada, S. Owada

"Electrical disintegration (ED) has been well known as a good comminution method to improve liberation of compositional phases because it was reported that electron avalanche could occur preferentially at phase boundary. But the detailed mechanism of the ED has been still not known. This paper describes the results of ED experiments using synthetic binary sample, copper/resin, under the conditions of various distance between electrodes, and discusses the energy distribution in the three kinds of phenomena in the ED process, which are(1) streamer progression in water, (2) electron avalanche in water, and (3) electron avalanche in solid sample, by measuring current and voltage with elapsed time. Then, it has been found that the energy distribution in the phenomenon (1) is quite low and that the distribution in the phenomenon(2) had a considerably large compared with that in the(3), which indicates that the shockwave generated in water could contribute much to the sample breakage.INTRODUCTIONElectrical disintegration (ED) has been well known as a specific comminution technology which enhanced selective breakage at phase boundary and lead to a good liberation among compositional phases1-6),but the detailed mechanism has not been clarified yet. This study describes energy distribution among the phenomena in the ED process by using a synthetic binary sample, copper/resin, the phenomena of which are (1) streamer progression in water, (2) electron avalanche and shockwave generation in water and (3) electron avalanche in solid sample usually at phase boundary. The energy distribution could be calculated from ED experiments and from voltage-current changes between electrodes as a function of elapsed time.SAMPLE AND EXPERIMENTALSampleThe sample used in this paper was a synthetic binary solid of copper/resin as shown in Figure1.Cut and polished pure copper lump was put into silicone mold and melted epoxy resin was poured into it and cooled, then, finally the binary sample was polished and molded in the form of 10 mm * 10 mm * 10 mm."

Jan 1, 2017

By L Munholand, G. Soucy, P. Quintal

This work presents early results from the first study to optimize the hydrodynamics of a Plasma Lift Reactor (PLR). The PLR is designed to break down organic contaminants in aqueous solutions. New experimental results are presented for air/water tests and for plasma degradation of organic contaminants in Bayer liquor. In addition, a multiphase Computational Fluid Dynamics (CFD) model has been developed which predicts the hydrodynamic behavior in the PLR. These results of this work suggest the PLR is effective at reducing contaminants in the Bayer liquor and that the CFD model adequately describes the hydrodynamic flow.

Jan 1, 2005

By L. C. So, S. Faucher, S. Mostaghel, A. Triwahyuono, D. Sauter, S. -Y. Oh, S. K. Lee, K. Aswin

"Molten hauling and water granulation are the commonly used slag treatment methods in the production of nickel. Water is present in these processes either to accelerate cooling of the dumped slag or in the granulation itself which creates an inherent safety risk of explosions. Even good design and operation are not sufficient to prevent explosions or injuries from occurring. Several dry methods to treat slags have been intensely studied. However, most of these technologies have never been commercialized due to numerous challenges including scalability, cost, low heat recovery efficiencies, and difficulties in heat utilization. Ecomaister-Hatch has recently developed and commercialized a reliable and simple Dry Atomization process, which eliminates water and allows for heat recovery. As part of the development towards other sectors, laboratory-scale and pilot-scale trials have been completed in a number of base metals and PGM facilities. Recently, Dry Atomization of a nickel laterite slag was successfully demonstrated at the laboratory-scale. The current paper introduces the technology and reports the test results obtained from atomization of the nickel slag.INTRODUCTION The processing of nickel laterites produces vast amounts of slag with over 90% of the feed to the furnace reporting as slag. Slag handing is therefore of critical importance to a laterite smelter. Traditionally there are two ways in which the slag is handled (1) Molten hauling, dumping, cooling and quarrying (2) Water granulation, dewatering, stockpiling. There are inherent disadvantages of both methods that will be outlined in this paper. An alternate route of Dry Atomization provides distinct advantages over the two conventional routes that are of particular interest to the nickel producer such as elimination of molten hauling, dumping and quarrying, elimination of water and improved safety. There is also the potential to convert the slag, which is typically regarded as a waste product, into a value added product and the continuous nature of slag tapping makes it amenable to heat recovery. Hatch has recently conducted laboratory-scale test work on laterite slag to demonstrate its viability for Dry Atomization. Results of this work are presented."

Jan 1, 2017

By Seong-Ho Ha, Shae K. Kim, Young-Ok Yoon

In the this study, surface segregation of Mg and Ca with Mg addition range from 5 to 10wt% in Al-Mg alloys with Mg+Al2Ca master alloy and its effect on the oxidation resistance were investigated. The addition of Mg+Al2Ca master alloy as the Mg alloying element led to the surface enrichment of Mg and Ca during high temperature oxidation. As a result of the oxidation test by TGA, the oxidation resistance of all the examined alloys was significantly improved with increasing Al2Ca content. The weight change of Al2Ca added Al-5Mg and Al-7.5Mg alloys indicated the complete oxidation resistance during the whole oxidation test time, while a slight weight increase was shown in the case of Al-Mg alloys even with Al2Ca addition. The improvement of the oxidation resistance in Al2Ca added alloys may be attributed to the formation of the protective oxide layer mixed with CaO and MgO on the surface.

Jan 1, 2015

By Zhong Zhang, Xijia Wu, Prakash C. Patnaik

"The integrated vehicle health management (IVHM) aims to provide life cycle management decisions for military platforms and their propulsion systems with reduced life cycle cost and increased operational readiness and safety. Among all the issues of IVHM, understanding the physics of failure and predicting lifetimes of the critical components are at the core: the decision makers have to know when and how components may fail in order to plan ahead. The difficulties to tackle failure problems lie in determining the material response to cyclic and dwell loading in a hot and/or corrosive environment, which all combined to induce multiple deformation and damage mechanisms, resulting in mix-mode failures. Decisions on component replacement (material substitution) and mission planning must be based on quantitative knowledge of the failure physics to mitigating the risk. This paper addresses the critical failure issues including creep, low cycle fatigue (LCF), thermomechanical fatigue (TMF); and presents a mechanism-based approach to life prediction. The mechanism-based approach, by its physics, is widely applicable over the entire operational spectrum of both structures and engines, and therefore is suitable for IVHM purposes."

Jan 1, 2015

By T. P. Johnson, A. Vathavooran

"Conventional mining operations can produce a wide range of wastes containing gold and other precious metals but which are less suitable for processing by traditional methods. There are also types of ore that do not fit easily into a traditional processing flowsheet, e.g. because the refractory nature of their minerology or the combination of valuable metals is less suitable for traditional processes. Nevertheless, these potential sources of valuable metals remain unexploited resources that have attracted growing interest in the metals and mining industries over recent years. The challenge is therefore to develop and use alternative processing methods that have the flexibility of operation to cope with a wide variety of material types and tonnages, whilst providing high recoveries for valuable metals. Tetronics’ DC plasma smelting technology achieves industry-leading recovery rates for precious metals from a wide range of input materials and initial precious metal concentrations, whilst generating an inert slag-based material as a by-product (even when starting from a hazardous waste input material), approved within the EU for use in construction applications. This paper describes how this technology can be used as a key part of an overall process for the recovery of precious metals from these interesting materials.INTRODUCTION The extraction of gold from its ores by various forms of cyanide leaching has been practised by the mining industry for over a century (Minerals Council of Australia, 2005) and it remains the primary extraction method in a wide range of mining operations. The ability of cyanide to extract gold efficiently and quickly from lower grade ores without extensive additional processing, coupled with well-known methods to recycle the cyanide for re-use within the process mean it is often both the most economically preferable and environmentally acceptable method for recovering gold. As a result, 88% of all gold produced from mines in the USA in 2014 was recovered via leaching of open heaps or dumps (UGGS, 2016). Nevertheless, there are occasions where certain combinations of mineralogy and other circumstances reduce the effectiveness of cyanidation techniques, so that ever more elaborate additional processing steps are required, with inevitable increases in operating costs (Swash, 1988). In these circumstances, which are likely to be more common in future as ore qualities diminish, other methods of extraction may offer better alternatives. Whilst much less commonly used for Au extraction at present, pyrometallurgical methods are amongst the longest-established of these alternative approaches and merit serious consideration in such cases."

Jan 1, 2017

By R. L. Bruening, R. M. Izatt, N. E. Izatt, S. R. Izatt

"Molecular Recognition Technology (MRT) is a simplified, green chemistry process with applications in selective separations of Ni(II), Co(II), and platinum group metals in primary ore beneficiation processes and secondary recovery operations from spent products, scrap, and environmental waste solutions. Simplification in MRT processes is achieved by non-use of solvents, reduced space requirements, and a simple separation system involving columns packed with metal-selective SuperLig® resins. Minimal waste is generated and metal recovery is achieved at 99% levels from g L-1 to <mg L-1 concentrations. MRT systems are attractive technologically and economically compared with solvent extraction, ion exchange, and precipitation separation processes. Commercial examples of MRT use include removal of impurity metals Cd, Cu, Ni. Fe, and Pb to mg L-1 or lower concentration levels from Co streams to produce battery-grade Co. Highly purified Co is required for optimal function of lithium ion rechargeable batteries and superalloys associated with aerospace and gas turbine operations. Impurity metals are recovered for reuse or proper disposal rather than being discarded to landfill. Green chemistry processes, such as MRT, are needed in metal separations going forward into the 21st century to achieve global metal sustainability in processing of native ore and treatment of secondary sources.INTRODUCTION Maximizing efficiencies of metal separations and optimizing metal recovery rates during separation processes are important goals on the road to achieving metal sustainability. Achievement of these goals is consistent with stated principles of green engineering (O'Connor, Zimmerman, Anastas, & Plata, 2016) and green chemistry (Anastas & Eghbali, 2010). Molecular Recognition Technology (MRT) separation processes using SuperLig® resins have a 25-year record of performing competitive, commercial metal separations with metal recovery rates approaching 100% (Izatt, Izatt, Izatt, Krakowiak, & Bruening, 2017). SuperLig® resins are characterized by high selectivities for specific metals over concentration ranges from g L-1 to mg L-1 or lower. MRT systems use no solvents and are simple in design and operation resulting in reduced capital and operating expenses."

Jan 1, 2017

By W. Hawker, A. M. Ivana

"Pressure oxidation is used to liberate gold from refractory sulphide ore and concentrates with over fifteen autoclaves in operation. Despite the importance of pressure oxidation, the autoclave chemistry and chemical thermodynamics are not well established. For example, there is no consensus on aqueous iron speciation or stability of jarosite phases. Additionally, there remains questions about basic ferric sulphate formation and stability. In addition to a review of the current state of knowledge, a methodology to study the ferric precipitation reaction and relate the results to chemical thermodynamic predictions is presented which will be used to accurately define the phase boundaries of the iron precipitates in the future (hematite, jarosite and basic ferric sulphate).INTRODUCTION With declining availability of orebodies that respond to simple leaching conditions, pressure oxidation has become a prevalent technology to liberate gold locked in sulphide mineral matrices. Gold pressure oxidation was established 32 years ago, with McLaughlin being the first facility in 1985 (Thomas & Pearson, 2016). Pressure oxidation is carried out at elevated temperatures ranging from 180 to 240°C as shown in the summary of operations in Table 1 (Ruonala et al., 2016; Fleming, 2010).A considerable amount of research has been done to study iron solubility and precipitation under autoclave conditions (Tozawa & Sasaki, 1986; Umetsu et al., 1977; Sasaki et al., 1993; Fleuriault, 2016; Cheng & Demopoulos, 2004; Papangelakis et al., 1994; Yue et al., 2003). These reports provide a description of the process chemistry and iron behaviour in the autoclave. However, there remain questions about the type and stability of aqueous species and solid phases. This detailed information is required to build a robust chemical thermodynamic model of the system, allowing for equilibrium and kinetic reaction limitations to be discerned."

Jan 1, 2017

By Henrik Saxén, Mikko Helle

The operation of hot stoves used for preheating the blast in the ironmaking blast furnace has a strong effect on the consumption of reductants, economic performance of and CO2 emissions from the steelmaking site. Generally, it is recommended to maintain as high blast temperature as possible, because this minimizes the rate of reductants in the blast furnace. The blast temperature is affected in a complex way by the time periods of heating and cooling of the stoves, and by the amount of gas combusted in the stoves. Furthermore, as the hot stoves show degraded performance with age, it is a non-trivial task to select optimal operation parameters for the stoves. The paper addresses this computationally by applying a one-dimensional heat-transfer model of the hot stoves for optimization of the performance of the system. The complexity and strong coupling of the decision variables is demonstrated by numerical examples, where the blast temperature is maximized under different constraints.

Jan 1, 2015

By Farzad Khodabakhshi, Adrian P. Gerlich

"Multi-pass friction stir processing (FSP) was performed to fabricate a new Al-Mg-Graphene nanocomposite. Microstructural developments and distribution of graphene were studied by using electron backscattering diffraction (EBSD) and transmission electron microscopy (TEM) analysis. In the stirred zone (SZ), grain structure was refined down to about 2 µm attributing to the operative dynamic restoration mechanisms and the locking effect of graphene phase. As a result, the yield strength of Al-Mg alloy was improved more than two times due to incorporation of graphene nano-sheets. Also, the indentation hardness resistance of nanocomposite was increased up to ~60%.INTRODUCTION Aluminum-matrix nanocomposites have garnered significant in recent years due to their superior performance and potential advantages for several industrial applications including the automotive and aerospace sectors. Among various reinforcing nano-materials, carbon-based structures featuring sp2 or sp3 hybridization bonds have been found to offer considerably improved physical and mechanical properties. Such carbon allotropes form at micro- and nano-scales including; graphite, carbon nano-tube (CNT), nano-fiber, and graphene. The potential of two-dimensional (2D) carbon materials was introduced in 2004, with the development of graphene as an alternate 2D allotropic form of the carbon structure with a honey-comb lattice at the atomic-scale. It has been shown that it is currently among the strongest materials ever tested with an intrinsic tensile strength of 130 GPa and Young’s modulus of 1000 GPa, and also offers unique thermal and electrical properties.To fabricate metal-matrix nanocomposites reinforced by graphene nano-sheets with typical metallurgical processing techniques, some attempts have been reported in the literature for various solid-state techniques including; hot rolling, mechanical alloying, and friction stir processing (FSP) of pre-cast plates or surface dispersed graphene oxides. The main challenge in those methods was to facilitate the considerable high temperature and pressure for attaining a uniform dispersion of the nano-sheets during the consolidation process. In most cases, significant difficulties have been reported in obtaining a uniform dispersion of graphene within the metal matrix. Among various techniques for production of metal-matrix nanocomposites, FSP has attracted significant attention as a method of surface modification since it was first reported by Mishra et al. In this process, a non-consumable rotating tool is plunged into the surface of material for the aim of microstructure modification. Extreme material plasticity is induced without melting as a result of friction between the tool and workpiece. Frictional heating and severe plastic deformation induced by the FSP process enables metal matrix nanocomposite fabrication by softening the base material and mechanical stirring to disperse the reinforcing nano-materials into the matrix."

Jan 1, 2017