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By Bowdler RJ, Lowson RT, Sarbutt JV

There have been few long-term studies of sulphide oxidation under controlled conditions. The object of this study was to investigate the oxidation and leaching characteristics of pyritic mine material under conditions that were commensurate with field conditions but which could be controlled and monitored on a long term basis. The test material - overburden from Woodlawn Mines Pty Ltd - was packed into a 300 cm high column and leached with water at an infiltration rate of 256 mm y-1 for 5 years. Chemical conditions within the column were continuously monitored by sensors embedded in the overburden and leachate from the base of the column was analysed weekly. The study examined the relationships between heavy metal release and gas, moisture, and chemical conditions in the column.

Jan 1, 1988

By Jaczkowski B. M, Cox T. J, Domfeh I. A, Stalker I

Mining and treatment of gold ore in the Ashanti region at Obuasi, Ghana has been continuous for more than 100 years. Earlier production from this world class deposit can be traced far into the history of West Africa's gold trade. As part of a general development and expansion program, Ashanti Goldfields Corporation (Ghana) recently undertook a program to heap leach oxidized near surface ore. Kappes, Cassiday & Associates was given a major role in the design, equipment supply, installation and start-up management of the 3000 tonne/day heap leach. Unusual conditions included a high annual rainfall and an ore which could be characterized as a soft, decomposed, water saturated schist. Production began in March 1990. Startup problems and their solutions are discussed.

Jan 1, 1991

A continuous casting machine, of the Concast curved mould design casting billets in four strands, was commissioned at the Newcastle Works of The Broken Hill Proprietary Co. Ltd., in November, 1967. Quality assessment of early casts from this plant indicated that steel cleanliness was sometimes inferior to that of equival- ent ingot cast steel. Extensive trials to develop a modified deoxidation technique were not successful in improving clean- liness to the desired level. A "contra-flow" gas shroud, to cover the steel stream between the tundish and the mould, was developed, and proved successful in achieving the required levels of product cleanliness. The inclusion content of six grades of steel ranging in carbon content from 0.10 to 0.70 per cent is examined, and an attempt is made to explain theoretically some of the results obtained.

Jan 1, 1972

By Kitzinger F

The economic climate of the Canadian mining industry forced an increased interest in rapid, continuous excavation techniques for hard rock formations. The potential applications and advantages of continuous mining over the present drill- blast-muck labour intensive cyclical methods are considerable. Noranda investigated an electrical technique, Plasma Blasting showing considerable promise for mining hard rock. The background of the technology and the theory of blasting rock with electricity is described. The Plasma Blasting process is based on the fast discharge of stored electrical energy into a small amount of electrolyte, suitably located in the rock. The electrical energy converts the electrolyte into high pressure plasma, which expands very quickly, thereby, generating a shock wave. This shock wave produces a stress field inside the rock, resulting in a blast similar to that made by chemical explosives, but without the deleterious fumes. Noranda is currently blasting boulders of 4-5 tonnes and is at present constructing a mobile, autonomous secondary rock breaker for underground and open pit applications. Tests on in situ hard rock formations will lead to the development of a continuous mining machine. Production rates of 500 tonnes per man-shift could be obtained with such a machine.

Jan 1, 1990

By G, F Beach, D Jazzini, R Rounsley

Over the past 20 years within Australia, there have been a number of incidents at mine sites where ammonium nitrate-based explosives have reacted with certain rock types containing sulfide minerals. These rocks have commonly been referred to as æreactive groundÆ. These reactions have frequently led to fires (particularly in ground susceptible to spontaneous combustion) or premature detonation of the ammonium nitrate-based explosives. Clearly, this introduces an element of risk when using ammonium nitrate-based explosives in these areas. Dyno Nobel has been proactive in developing ammonium nitrate-based explosive products that can be used in these types of æreactive groundÆ environments that minimise the risk of premature detonations occurring. A system for assessing æreactivityÆ of sulfide containing rocks has been developed that can be used in the field. Previous literature has been reviewed, identifying Differential Thermal Analysis (DTA) as the most common method for determining the æreactivityÆ of the ground. In the present investigation, DTA has been rejected as a suitable technique for determining ground reactivity, since it measures thermal reactions at higher temperatures over short time periods, conditions that are unlike those in the field. For example, ground at ambient temperature has been found to react with ammonium nitrate-based explosives over long time periods, reactions that are unable to be evaluated using DTA. Other more suitable techniques have been developed to monitor rock conditions that can be measured in the field and give a good indication of potential ground æreactivityÆ with ammonium nitrate-based explosives. Dyno Nobel is currently investigating the reaction mechanisms of spontaneous combustion in reactive ground, the decomposition mechanisms of ammonium nitrate and the role of inhibitors in ammonium nitrate-based explosives. Once complete, this fundamental research will lead to the further development of even lower risk ammonium nitrate-based explosive products for use in æreactive groundsÆ in a variety of mine environments.

Jan 1, 2003

A study of the effect of nickel on the cupellation process has shown that a very low "nickel limit" must be imposed for cupellation (0·08 grams nickel or 0·05 grams when copper is present). In the presence of slightly greater amounts of nickel, lead tends to spreadon the cupel with detachment of drops from the main lead pool. In crucible fusions nickel contaminates the lead button to a small extent, and this contamination is increased.in the presence of either iron or copper. Nickel also causes "shotting" of the lead, this effect being more apparent in the presence of iron.Both the spreading during cupellation and the shotting during crucible fusion are considered to be caused by adsorption of insoluble NiO at the Pb-PbO interface, lowering the interfacial tension.Excess litharge crucible charges are' fused at 116boC. to eliminate shotting. A brief· soaking in molten basic litharge slag effectively reduces the nickel content of lead buttons. The solubility of silver in litharge slags is considerably decreased in the presence of nickel. Corrections can be applied for silver losses in slags but these corrections are not as accurate as with copper ores.INTRODUCTIONThis paper on the effects of nickel on fire assays for silver is the second of an intended series describing investigations into the fire assaying method.In the first paper, discussing the effect of copper on fire assaying processes (Guerin, 1957), it was shown that certain elements, because of their relatively low affinities for oxygen, will tend to contaminate the lead button during crucible fusion and scorification. Nickel, having a slightly greater affinity for oxygen than has lead, would be expected to be oxidized and slagged readily, and would not be expected to appear in the metal phase (lead button) to any appreciable extent. Thus, judged solely on this basis of...

Jan 1, 1960

By Cripps-Clark CJ, Deague TK

In order to study conditions under which SiO(g) may be formed in a blast furnace, equilibrium phase diagrams were constructed for the combustion of high and low ash cokes with oxygen-enriched blast and oil injection under conditions of high and low raceway pressures. Free energy minimisation techniques were used to calculate the composition of gaseous and condensed phases. Where coke ash is assumed, for simplicity, to comprise Si02 only, the coke can be comple- tely gasified, mainly to SiO and CO, under restricted conditions of coke to blast ratio and at temperatures greater than 1600 - 1650¦C, depending on system pressure. The formation of SiO(g) is partially suppressed by the introduction of alumina into the ash, because of the formation of solid and liquid alumino- silicate compounds. The minimum temperature for complete silicon gasification is raised to about 1700¦C. The results of the equilibrium calcula- tions are related-to actual raceway conditions. It is proposed that virtually all silicon in the coke ash is gasified such that, on condensation, it affects hot metal chemistry and slag properties and secondly, that the effects will be greater with higher ash cokes.

Jan 1, 1980

By Smith T. N, Wild M. B, Elliot B. J

The process of flash smelting of nickel sulphide ores, as practised at the Kalgoorlie Nickel Smelter, is described. The critical variables in the operation of this process are identified. The design of a pilot-scale, turbulent-jet flash reactor which models the essential features of the industrial smelter is described. A report of its operation and application to an investigation of the ignition of particles of sulphide species is given.

Jan 1, 1991

By C R. Sundberg

Despite nearly a half-century of continuous production, the low-grade iron ore (taconite) deposits of North America remain economically competitive sources of raw materials for the domestic steel industry. The continued viability of these mature integrated mining-concentrationagglomeration complexes requires highly efficient utilisation of assets, especially the mineral resource. At Cleveland-CliffsÆ five North American managed operations, enhanced ore characterisation techniques are playing a critical role in their continued success. Due to the low-grade nature and complex mineralogical composition of these deposits, ore characterisation cannot solely rely on assay grades. Historically, taconite ore characterisation has augmented assay grades with bench-scale concentration tests to quantify recoverable mineral. The economic necessity for improvements in mill efficiencies and final product quality has mandated significantly greater knowledge of ore-related impacts. Cliffs Technology Center has met this challenge by developing a variety of novel iron ore characterisation techniques. The applications developed include both in situ and laboratory procedures, plus unconventional data integration methods uniquely suited for these deposits. This paper details the evolution of these novel ore characterisation techniques and their application to each phase of the operation: mining-concentrating-and pelletising. The improved ore characterisation techniques have contributed to successes at individual Cleveland-Cliffs managed operations including mineral recoveries exceeding 95 per cent and productivity increases exceeding ten per cent while consistently achieving customer product quality objectives.

Jan 1, 2002

Seam gases are the most important atmos- phere contaminants in Australian collieries, their importance increasing with depth; C02 as well as CH4 may be important in intruded envir- onments. The generally high rank of the coal, with low moisture content, makes for abnormal dust production. The other contaminants are introduced and subject to better control, in- cluding products of spontaneous combustion. Due to market situations the generally lower rank and higher sulphur coals more prone to self heating are mined less. Future mining at greater depths should see greater problems with atmosphere contaminants.

Jan 1, 1983

The Koongarra uranium deposit was discovered in August 1970 by Noranda Australia Limited. Denison Mines Limited acquired the rights of ownership in October 1980 and has continued the 'struggle' to bring the proposed mine, containing approximately 13 300 tonnes of U308 of Indicated ore and having a value of $1 billion (1984 dollars), into operation. During the 14 years that have passed, the owners have found it necessary to deal with numerous Federal, State and Territory government departments, aboriginal representatives, handle thousands of communications, attend and convene countless meetings and spend millions of dollars. This paper addresses the history, the requirements, the problems and the costs to date for what - no return.

Jan 1, 1984

By Johnson D. P, Beamish B. B

The northern Bowen Basin has a very large resource of coalseam methane gas-in-place - 136 TCF(7ohnson and White, 1988). The gas is pipeline quality, being 98-99 per cent methane with traces of carbon dioxide and higher hydrocarbons. The largest resource of natural gas within the coalseams of the northern Bowen Basin is contained in the Moranbah Coal Measures (75 per cent). The next most important resource is in the combined upper Fort Cooper (16 per cent) and Rangal (nine per cent) Coal Measures. The far northern parts of the basin have low gas contents due to the combined effects of limited extent of the coal measures, shallow depth and low rank. Reserves per well are more than double that of the best coalseam methane wells in any basin in the United States. In some areas of the Moranbah Coal Measures, the gas-in-place estimates exceed 225 million cubic metres per well (80-acre spacing). A distinction is made between resource base, as determined from this basin assessment, and the deliverability potential. Parameters used to estimate gas-in-place (coal area, thickness, density, rank and depth) can be adequately extrapolated from areas of high- to low- data density. Parameters affecting methane production (permeability, gas depletion factor and critical desorption pressure) cannot be generalised. Exploration and development programs must rapidly develop a predictive capability for these factors, on a local scale, through geological modelling and confirmation drilling.

Jan 1, 1991

By Moyes A. J

The Intec Copper Process uses a strong chloride electrolyte at atmospheric pressure and 80 - 85¦C to produce high purity, 99.99 per cent copper granules and elemental sulphur. A recent, exhaustive study by an independent, major Australian corporation has shown the capital cost of an Inter plant to be approximately half that of a copper smelter at the 200 000 tpa capacity level and approximately half the operating and capital cost at the 50 000 tpa level. The Inter process costs were also shown to be greatly superior to the best available leach/SX/electrowin technology. The process utilises a multi-stage counter current leach at 80 - 85¦C with the addition of air at atmospheric pressure to precipitate iron as a goethite type compound, followed by a two-stage purification process separating impurities in metallic- and other forms. Purified cuprous chloride/sodium chloride solution is fed to an electrolytic diaphragm cell where high purity copper granules are produced at current densities of 1000 - 1500 A/m2 withoutthe need for conventional electrode stripping. Power consumption is approximately half that of the cupric route. The product is suitable for the direct powder metallurgical conversion of the granules to products such as wire or strip. All the steps in the 'furnace free' conversion of copper mineral to product have been demonstrated The process can treat low grade and contaminated concentrates without penalty, thereby offering greater returns to the miner. Lead, zinc and silver may be recovered as metals, with the high oxidation potential of the electrolyte allowing extraction of gold at high efficiency. The gold is selectively precipitated on activated carbon with negligible copper and silver contamination.

Jan 1, 1992

By Smith E. L

The Ore Reserve/Exploration System implemented at Mount Isa for M.I.M. Holdings Limited is a comprehensive computer system designed to process assay, geological, structural and survey data input via special purpose logging sheets from daily activities at Isa Mine, Hilton Mine and various Carpentaria Exploration Company prospects. The system performs two basic functions; (1) data acquisition, validation and file maintenance to prepare the data for retrieval, and (2) generation of routine and optional reports. The types of reports available range from masterfile detail printouts and retrieval of data by key items to survey computations, structural analyses, cutoff calculations, statistical analyses and ore reserve calculations by the polygonal, inverse square or moving average techniques. The use of various optional reports available through the system is illustrated by several examples, and planned future development is discussed.

Jan 1, 1973

By R. A. Frith, M D. Goodz

Ore-bearing minerals that are located along microfractures are always susceptible to loss during the breakage and sampling of the material. Further losses occur with on-site sample preparation and splitting prior to laboratory analysis. In these cases solid whole rock channel or core samples should be handled with due care to ensure all fines and loose particles are collected and included in the sample for total chemical analysis.Similarly open hole and reverse circulation drill methods are not usable in areas containing old mine workings, heavily fractured ground or highly degraded/oxidised mineral assemblages. Nor are these methods usable to assess a bulk mineable target where the enriched zones were peripheral to or between old mine cavities.

Jan 1, 1993

The Mobile Miner MM130 (Figure 1) is designed to tunnel or mine in hard rock. It has a 4.1 m diameter cutterhead mounted on a horizontal axis which in turn is perpendicular to the line of the machine. The cutterhead rotates at 15 rpm and is supported on a boom which swings the cutterhead through a horizontal arc.

Jan 1, 1993

By J Abols, T Hughes

The selective recovery of gold and silver from solutions containing other metals, such as copper, is possible using AuRIX«100 resin in conjunction with the Gekko Resin Column. Selectivity is driven by controlling the solution pH, which enables activities such as loading copper, gold and silver and then selectively stripping copper before gold and silver. Alternatively gold and silver can be loaded and the copper left in solution. The selective loading of gold while reducing the silver loading has also been demonstrated, opening the possibility of producing high grade gold dorT from high grade silver pregnant leach solutions. This paper reviews the AuRIX«100 resin and Gekko Resin Column Technologies, discusses the uses of AuRIX«100 in the recovery of gold and silver and the chemistry relating to several projects for which AuRIX«100 is being tested.

Jan 1, 2005

By Scott A

The object of most blasting operations is to destroy the insitu structure of the rock mass so that mechanical equipment can efficiently excavate the rock fragments. In achieving this objective the blasting engineer is also concerned with minimising damage to the adjacent rock which forms the mine structure relied upon to provide support. Damage to this "structural" rock is undesirable but usually occurs as a result of two distinct processes: ò readjustment of stresses around the excavation as a result of the mining process itself ò impact of vibration and high pressure gases from blasting operations. Gross damage to mine structures from either cause is observed as visible alteration to the appearance of the rock structure in the form of cracking, slabbing, back or over break and visible displacement. Recent work at the Julius Kruttschnitt Mineral Research Centre (JKMRC) has shown that significant reduction in the strength of a rock mass can take place well before the onset of these obvious signs of damage. It has been demonstrated that the effect of blast damage on the behaviour of the rock mass can be many times more prominent than the effect of stress redistribution. This offers the blast design engineer the opportunity to significantly reduce blast induced damage to rock structure by modifying blasting practices. This paper introduces the current JKMRC postgraduate research projects investigating the evaluation and control of blast damage.

Jan 1, 1990

When a thin film of volatile matter is deposited under vacuum on a polished coal surface, and the coated surface is examined microscopically in piano--polarized reflected light, colour changes are observed characteristic of the various macerals present. The colour changes appear to be mainly due to interference between light reflected at the upper surface of the film and at the film/coal interface. A variety of source materials for the volatile matter required have been tested, including powdered bituminous coal, coal tars, boron oxide, and certain resins.

Jan 1, 1969

By Fourney W. L, Weaver T. A

A large number of single borehole crater-forming shots were analyzed in terms of correlating the crater parameters with explosive weight. The objective was to determine a scaling rule for which the explosive weights varies over many orders of magnitude and covers many different geologic materials. Included in the data base are type and weight of the explosive, geologic medium and degree of saturation, charge depth-of-burial, crater dimensions, and crater rim (lip) measurements. An alternative scheme to the usual plot of scaled depth-of-burial versus scaled volume removed was desired. The proposed technique uses a plot of the logarithm of the explosive weight, Y, versus the logarithm of the slant length, R', calculated from the known depth-of-burial of the explosive and the measured crater radius. A plot of Log Y in kilotons versus Log R' in meters from all the crater tests in this data base resulted in a straight line with a of slope 0.31 and showed good correlation between the variables Log Y and Log R'. Since the crater data includes many geologic materials, different explosives (including nuclear tests), and large differences in charge weight, the straight line fit suggests that the type and strength of the geologic materials play a subordinate role to explosive energy in crater formation.\

Jan 1, 1990