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By N Belluz, L Johnson, N Wiwoho, P Manning

The Kucing Liar skarn deposit is located in the Ertsberg mining district, which also contains other skarn deposits and the Grasberg porphyry copper û gold deposit. The Ertsberg district is located in the province of Irian Jaya, IndonesiaÆs easternmost province. Mining development began in the Ertsberg district in 1972 with the mining of the Ertsberg deposit. Daily production in the district now averages about 230 000 tonnes of ore, with the bulk of the ore coming from the Grasberg open pit and the balance from underground mining of skarn deposits. During 1998, 45 218 additional metres of drilling were conducted to delineate and understand the Kucing Liar orebody. The deposit was first intersected in drill holes in 1994 and then was intersected in underground workings located about 1000 metres from the discovery drill hole in 1995. Initially, the two intersections were thought to be different orebodies but are now realised to be different parts of the same orebody. The Kucing Liar deposit consists of magnetite û copper û gold replacement and skarn mineralisation in favorable Tertiary and Cretaceous units. The deposit is approximately 2000 metres in length and averages about 200 to 250 metres in thickness. The width varies from 400 to 600 metres. Drilling in 1998 was directed towards delineating the deposit on its NW and SE ends and to determine its down dip extension. Reserves for the deposit at the end of 1998 stand at 320 million tonnes at 1.4 per cent copper, 1.4 g/t gold, and 5.3 g/t silver. Many important questions remain to be answered concerning the relationship of the Kucing Liar orebody to the major faults in the district and to the Grasberg intrusive complex which contains the Grasberg orebody. Continued exciting developments are anticipated as work to understand the deposit by drilling and geologic study continues.

Jan 1, 1999

By P A. Grossman, J H. Rubinstein, M Brazil, K G. Sirinanda

To date, the scheduling and access design of an underground mine have only been considered as two separate optimisation problems. First, access to the mine is designed and then the scheduling is completed. One drawback of this approach is that the costs of access construction fail to be reflected in the net present value (NPV) calculation. In this paper, designing the access and scheduling its construction are formulated as a single optimisation problem.The underground mine access construction process can be classified according to the number of faces being developed concurrently. An underground mine with a single decline branching at a junction point into two declines is considered. After construction reaches the junction, the two faces of the decline can be constructed sequentially or concurrently.This paper proposes an efficient algorithm for optimally locating a junction point to maximise the NPV where two faces are being developed concurrently. The NPV is defined by taking the locations of orebodies and their values, decline construction costs, decline development rate and discount rate into account. The variation of the NPV and the optimal locations of the junction point for one and two concurrent development faces for a range of discount rates are discussed and compared. The proposed algorithm is applied in a simulated case study based on hypothetical values for an underground mine.CITATION:Sirinanda, K G, Brazil, M, Grossman, P A, Rubinstein, J H and Thomas, D A, 2014. Strategic underground mine access design to maximise the net present value, in Proceedings Orebody Modelling and Strategic Mine Planning Symposium 2014 , pp 235–242 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 24, 2014

By K Zunica, A R. Penney

The principles of three-dimensional geological modelling are well understood and routinely used. Sample data is collated and geostatistical tools used to ensure that sample data is suitable for its end use, which is typically a block model that is appropriate for mine planning. What has become increasingly apparent is that physical rock properties and geotechnical parameters need to be incorporated into the three-dimensional geological model to create an integrated mine model.The approach to the collection of geotechnical information is not as highly prescribed and controlled as collection of geological data. Commonly, the geotechnical data set is incomplete and inconsistent, with little consideration of what the end use will be by those collecting the data, or how the geotechnical data might relate to the geological data. In some cases, specific geotechnical investigation programs are completed, yet correlation between those programs and previously collected data is rarely undertaken to the same level of diligence as found in the geology field.There are some obstacles that need to be considered when attempting to incorporate geological parameters, such as grade, lithology, and geological domains with geotechnical information such as rock quality designation (RQD), rock mass rating (RMR), rock strength, and geotechnical domains into the same three-dimensional block model. Interpolation or geostatistical estimation methods used for grade estimates might not be appropriate for many components in rock characterisation, particularly search geometries. A number of examples are provided to illustrate issues underlying some of the data collection procedures, and their effects on three-dimensional geotechnical modelling.The example presented attempts to highlight generally observed shortcomings in the collection of geotechnical information, parameters which need to be considered when combining geological and geotechnical data into the same model, and the benefits of having a combined block model from the beginning of a project.CITATION:Zunica, K and Penney, A R, 2014. Integration of geological and geotechnical data for three-dimensional modelling, in Proceedings Ninth International Mining Geology Conference 2014 , pp 291–298 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 18, 2014

By G Bournival, Y Saavedra Moreno, S Ata

Flotation frothers are heteropolar molecules that are preferentially adsorbed at the bubble interface to enhance the flotation performance by promoting the formation of small and stable bubbles. Frothers have different characteristics that can be used to classify them. A classification framework has been recently presented by Saavedra Moreno et al (2022) to classify non-ionic frothers by conducting a principal component analysis (PCA) and a hierarchical clustering analysis (HCA). However, for the purpose of the present research, only five frother characteristics, including molecular weight (MW), hydrophile–lipophile balance (HLB), critical coalescence concentration (CCC), the minimum Sauter mean diameter (DL), and foam stability index (DFI) were used in the PCA and HCA. All those characteristics were evaluated for a two-phase system in the absence of particles. Realising the important role that particles play in froth stability and behaviour, the effect of hydrophobic particles on the presented frother classification framework was investigated in this study. Four frothers with different characteristics, methyl isobutyl carbinol (MIBC), 1-pentanol, tri (propylene glycol) (TPG), and tri (propylene glycol) methyl ether (TPM), were chosen. The experiments were carried out in the presence and absence of silica particles esterified with 1-pentanol. It was evident that the results for 1-pentanol, TPM, MIBC, and TPG in the three-phase system agreed well with the frother classification presented for the two-phase system as frothers were clustered in the same groups. The findings from this research support the use of the frother classification system presented in two-phase system to select a specific frother for a particular application without the necessity of conducting laborious experiments in a three-phase system.

Aug 24, 2022

By P Breuer, X Dai, A Bergamin, D Hewitt

"Copper-ammonia-thiosulfate?leaching of gold has been researched for several decades as a potential alternative to cyanidation. However, this technology has not yet been applied commercially due to many challenges such as complex solution chemistry, reagent degradation and losses, system instability with losses of precious metals and difficulties in gold recovery from the leachate. Progress has been made at CSIRO in tackling some of these challenges including:better understanding and control of the leach conditions to minimise reagent losses whilst maximising gold recovery use of strong base ion exchange resins to recover the gold strategies to deal with polythionates that adsorb competitively with gold on ion exchange resins development and evaluation of process flow sheets.As a result there has been increased interest from the gold industry and renewed activities to develop thiosulfate based processes for gold recovery. One application area, which has been developed to the point of piloting, is the treatment of gravity gold concentrates using a copper-ammonia-thiosulfate leach with ion exchange recovery of the gold thiosulfate. This paper describes some of the advancements in the development of a potential process flow sheet for this application.CITATION:Dai, X, Breuer, P, Hewitt, D and Bergamin, A, 2013. Thiosulfate process for treating gold concentrates, in Proceedings World Gold 2013, pp 61-70 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Sep 26, 2013

By N N. Viswanathan, D Kumar, S Kumar

In secondary steelmaking, calcium treatment is practised to modify the solid alumina or spinel inclusions into liquid or partially liquid calcium aluminates. It has been seen that the dissolved calcium reacts with sulfur or oxygen present in the steel to form CaS or CaO type of transient inclusions. Post-calcium treatment these transient inclusions further react with pre-existing alumina or spinel inclusions and modify them. In addition, direct modification of pre-existing inclusions is also reported in the literature. In the present study, laboratory-scale induction furnace-based experiments are carried out to melt electrolytic iron in an alumina crucible followed by deoxidation with aluminium. The CaS-based composite material, prepared in-house, is added after the aluminium deoxidation to study the stability of CaS at the steelmaking temperature. Multiple steel samples were also taken to track the dissociation of CaS by means of sulfur pick-up in steel. Additionally, inclusion analysis of these steel samples was also performed to track changes in the chemical composition of inclusions in response to CaS addition. It has been seen that the CaS dissociates leading to a gradual pick-up of sulfur in steel. The scanning electron microscope – energy dispersive X-ray spectroscopy (SEM-EDS) analysis reveals that the alumina crucible and floated alumina inclusions are modified into calcium aluminates and the extent of modification depends on the contact time of CaS with the two sources of alumina mentioned earlier. However, the modification of alumina inclusions in the bulk steel did not occur during these experiments.

Jun 19, 2024

By S F. Rogers, P W. Booth

Digital photogrammetry is revolutionising the task of geotechnical mapping of jointed rock masses and has greatly increased in popularity and sophistication in recent years. Modern commercially available digital photogrammetry software systems can provide geotechnical practitioners with a user friendly tool for rapid data acquisition. The data can be acquired remotely from large exposure areas, some of which may be otherwise out of reach due to restrictions on time, access or safety.Photogrammetry is a complimentary technology to discrete fracture network (DFN) modelling because it can provide the large, statistically significant, spatially located geotechnical data sets required to produce the most robust results. It also provides the flexibility to selectively map structures at a range of scales, depending on the focus of the DFN modelling.Integration of the interpreted rock structure data derived from photogrammetry with modern DFN modelling methods really advances the rock engineering process. The ability to generate 3D fracture models driven by the statistical structural data and conditioned to the features observed by the photogrammetry yields a synthetic rock mass on which improved design methods can be applied. The generation of multiple equi-probable conditioned DFN models allows the use of probabilistic methods for assessing kinematic stability, rock block size distribution as well as a range of other applications.CITATION:Rogers, S F and Booth, P W, 2014. Integrated photogrammetry and discrete fracture network modelling for improved rock mass characterisation and engineering design, in Proceedings 15th Australasian Tunnelling Conference 2014 , pp 203–208 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 17, 2014

By H Fukaya T Miki, J Gamutan

Molybdenum disilicide (MoSi2) is a promising material for thermal applications due to its excellent heat and oxidation resistance. It can operate at temperatures of up to 1800°C as furnace heating elements and protect refractory metals such as molybdenum from rapidly reacting with air to form volatile molybdenum oxides at elevated temperature. In this work, the feasibility of forming MoSi2 on a molybdenum substrate by hot dipping in a silicon-saturated molten metal bath was investigated. This method is simple, predictable and can be used to coat large components and complex parts. It was found that tetragonal MoSi2 can be successfully synthesised on the surface of the substrate after dipping for 15 mins at 1000°C using molten tin (Sn), bismuth (Bi) and copper (Cu) baths. The growth of the MoSi2 layer was fast within the first 15 mins and then gradually slowed down with time. After dipping for 60 mins at 1000°C, the thickness of the MoSi2 layer were measured as 441.5, 19.5 and 13.1 μm for the copper, tin, and bismuth baths, respectively. The MoSi2 coating synthesised in this study provided oxidation resistance at 1150°C by forming a protective SiO2 layer on the surface. The SiO2 layer prevented the sample from rapidly oxidising by inhibiting direct contact between the molybdenum substrate and oxygen in the atmosphere. Compared to conventional methods, the proposed hot dipping method produces a MoSi2 layer more rapidly and at much lower operating temperatures. This makes it a more attractive option for coating large and complex components, with the potential to enable the use of MoSi2 in a wider range of applications.

Jun 19, 2024

By D J. Williams, S Islam

Fine-grained coal tailings slurry undergoes only limited settling and self-weight consolidation, and tends to remain slurry-like and unsuitable for conventional laboratory consolidation testing. In addition, constant rate of loading consolidation testing is more representative of the continuous disposal of tailings slurry into a tailings storage facility (TSF) than conventional step loading. The laboratory consolidation testing of coal tailings slurry under a constant rate of loading has been carried out in a purpose-built, large-scale, slurry consolidometer, instrumented with load cells and pore water pressure (PWP) transducers. In the slurry consolidometer, the rate of loading may be varied to represent the actual rate of rise of the tailings in the TSF. A slow rate of loading increases the test duration, while too fast a rate of loading may build up very high excess PWP, without achieving significant consolidation. For the particular fine-grained coal tailings slurry tested, the rate of loading in the slurry consolidometer is varied to access its effect on the development and dissipation of excess PWP. The resulting consolidation parameters are evaluated and explained using the recorded settlement and PWP data.CITATION:Islam, S and Williams, D J, 2018. Optimisation of constant rate of loading slurry consolidometer testing of fine-grained coal tailings, in Proceedings Mine Waste and Tailings Stewardship Conference 2018, pp 72–80 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 23, 2018

By D Horacek, I K. Sheppard

Ok Tedi is in a period of transition. By 2008 mill feed will consist of higher levels of high-grade but metallurgically challenging skarn ores. Additionally, the Taranaki pit will start production in 2008 along with the start-up of a new pyrite concentrator. Taranaki ores are very high in sulfur. Sulfur is captured in a pyrite concentrate prior to tailing entering the Ok Tedi River. These and other complex scheduling issues will need to be resolved over a critical three-year period. With these requirements in mind, Ok Tedi contracted AMC Consultants to develop a custom version of the Life of Business Optimisation System (LOBOS¬) to assist medium-term production scheduling at Ok Tedi. LOBOS utilities enable Ok Tedi planning engineers to:import polygon-based reserve data (Blast Masters) from MineSightÆs Interactive Planning Tools (IP Tools); graphically construct block sequencing and material flow constraints; edit constraints defining standard scheduling, processing and financial relationships; define dump and stockpile attributes; and assign capacities to production systems, plants, dumps and stockpiles. LOBOS converts Ok TediÆs production scenario into a mixed integer program (MIP) and submits the resulting model to IlogÆs Cplex MIP Solver. The Solver seeks an optimal production schedule that maximises net revenue per mill hour while meeting all constraints. This paper introduces Ok Tedi and its production requirements and relates these requirements to the facilities developed for an Ok Tedi version of LOBOS.

Jan 1, 2007

By P Pieterse

Kumba Iron Ore Ltd is currently commissioning the Sishen Expansion Project (SEP) û a brownfields project on the Sishen Iron Ore Mine located in the Northern Cape Province, South Africa. SEP is designed to produce 13 Mtpa of product from 21.7 Mtpa of ROM feed. The beneficiation section of SEP employs jigs to process narrow size fractions in the 25 x 0.8 mm size range. The -0.8 mm fraction is screened out ahead of the jig plant and rejected as waste without any prior beneficiation. The processing of this fraction was not included in the early stages of SEP development because no suitable beneficiation or dewatering technologies could be identified within the time-frame required to implement SEP. This paper presents the SEP 1B project, ie the metallurgical and process engineering study that was done to evaluate the techno-economic viability of processing the -0.8 mm material of SEP. To support this evaluation, metallurgical bench scale testwork was done on selected samples characterising the material types used in the SEP for gravity concentration beneficiation. Subsequently, pilot testwork on a 300-ton bulk sample demonstrated that an integrated teeter-bed/spiral circuit could be used to successfully beneficiate the -0.8 mm fraction. The study has established the viability of the proposed process and has concluded that approximately 390 000 tpa could be produced and added to the SEP fine ore product without violating the applicable product specifications. The proposed process has been designed to be implemented in modular units in order to facilitate implementation and ensure future expandability. Based on the recommendations of the study, approval has been granted for the detail design feasibility study. Production is scheduled to commence in the first quarter of 2010.

Jan 1, 2008

By N Dube, K L. Sandvik, C Mutevhe

Trojan Nickel Mine is the largest producer of Ni, Cu and Co in Zimbabwe. The mine has operated a nickel flotation concentrator and base metal refinery continuously since 1969, creating 28 million tonnes of sulfide bearing tailings, five million tonnes of permanent waste rock and about seven million tonnes of smelter slag. Exposure of the sulfide bearing minerals renders them susceptible to oxidation in the presence of water and oxygen, resulting in acidic solutions with elevated concentrations of total dissolved solids, sulfate, metals and residual flotation chemicals in various waters draining from the mine site. These pollutants pose a direct threat to the environment and human health, and understanding their deportment and behaviour in the various waste streams is essential in the mineÆs environmental objectives to prevent or minimise adverse impacts arising from its operations. A geochemical assessment of the pollutants was carried out to compute a mass balance between the major sources of pollution and the distribution and fate of pollutants in waste streams from the mine site. Waste rock, tailings, surface water, ground water and sediments were sampled, tested and analysed. Mineral composition and water chemistry data show that geochemical reactions are responsible for the release of pollutants from waste rock, tailings and plant spills. Drainage from the mine area is near neutral due to buffering by magnesium carbonates in the fine fraction of the tailings. The natural wetlands that exist downstream of the waste rock and tailings dams are effective in reducing metal loadings to water courses. However, solutes and heavy metals are occasionally released to surface and ground water, when their concentrations peak during the dry season. The results demonstrate the necessity to understand the natural chemical processes that characterise the distribution of pollutants in nature and how such knowledge can be used to develop cost effective methods to remediate pollution in the natural environment.

Jan 1, 2006

By P J. Bangerter, J Pan

Optimising for Net Present Value (NPV) with a strategic optimiser such as COMET, Prober-E, Blaser or Minemax has hitherto lacked a dynamic method for analysing the so-called third-order outcomes (such as Carbon emissions) of optimisation within life-of-mine planning. Optimisation, per se, has natural effects on carbon emissions in a life-of-mine plan. Contemporary strategic planning employs a mathematical optimiser to make sense of non-linear data (ie a block model) and produces a best-NPV optimised mining schedule, within a set of constraints. The very act of optimisation influences emissions, and in a dynamic way.

Aug 2, 2023

By F Soleimani

Coal and gas outburst is a common hazard in coalmines and due to the complexity of its nature, efficaciously predicting the possibility of its occurrence is intricate. The mechanical and gas flow properties of coal, in situ and mining-induced stresses and geological structure are involved in outburst occurrence, whereas suggested thresholds for its prediction do not consider them all. Numerical modelling is known as an effective method that can not only consider couple the effect of different physics but also analyse the effect of associated parameters. In this paper, a coupled fluid flow and geomechanics model has been developed in COMSOL Multiphysics to simulate outbursts by considering the effect of gas pressure and composition, damage mechanics on related coal properties, and progressive excavation and mining-induced stress. For the proposed fully coupled outburst model, the effect of pore pressure and sorption are applied to the stress while the influence of stress changes and damage are considered in updating coal porosity and permeability in each time step. In addition, to study the effect of mining-induced stress, the excavation process is simulated by changing the material properties over time according to the schedule of heading development. Then, outburst initiation is analysed from the energy point of view by using the concept of energy conservation law. The simulation results are used in calculating energy sources of the outburst initiation, also, the effect of particle size and ejection velocity are studied, and the significance of particle size effect on the energy analysis and deformed coal on outburst initiation is discussed.

Oct 12, 2022

Cannington Mine is an underground, hard rock, metalliferous mine located in North-Western Queensland, Australia. Weld mesh is installed to prevent the failure of rock from between the installed reinforcement elements. Corrosion reduces the capacity and life expectancy of mesh and presents a real hazard to underground personnel and equipment as it reduces the effectiveness of the support system. Corrosion influences the economics of the mining operation through the need to conduct rehabilitation of the ground support which involves re-installing new mesh or shotcreting over the affected mesh to protect it from further corrosion. The requirement for rehabilitation is determined by the geotechnical engineer based on an individual visual assessment with little or no engineering input. It was identified that a more quantitative method was required that considered the safety and economic risks involved. A project was undertaken to develop a simple method to evaluate corroded mesh and to provide selection criteria for rehabilitation. A weld mesh corrosion classification has been developed that relates the average wire diameter of corroded mesh to the remaining capacity of the mesh. Accompanying selection criteria provides recommendations as to when rehabilitation may be required based on the estimated residual mesh capacity, the remaining development life, and the level of personnel exposure.

Nov 25, 2010

By Mizuta T, Sakurai M

The Pine Creek Inlier produced 12 440 kg of gold in the period from the first gold discovery in the 1860s to the early-1900s. During the 1930s renewed large-scale prospecting took place and gave a foothold for today's gold mining operations. The rise of the gold price and improved mining methods in the 1970s and 1980s made possible low cost, bulk low grade mining operations. Various gold deposits including vein, network and stratiform types occur in the Pine Creek Inlier (Nicholson and Eupene, 1990). The Tom's Gully deposit is located 100 km south-east of Darwin in the Northern Territory. It is hosted in the early Proterozoic Wildman Siltstone and lies north-east of 1800 my old Mt Bundey Pluton (Figure 1). Around the Mt Bundey Pluton, there are several prospective base and precious metal deposits such as Quest 29. The Tom's Gully gold deposit was discovered in 1986 and yielded a total of 3070 kg of gold from ore averaging 9.35 g/t gold between 1987 and 1990 when the mining operation was terminated.

Jan 1, 1994

By S Hanke, J Burden, P Spies

The Waterview Connection will complete Auckland’s long-planned Western Ring Route, a 48 km north-south motorway alternative to State Highway 1 that bypasses the central city to the west. The project involves construction of 5 km of new motorway – half of it underground in tunnels – to connect the Southwestern (State Highway 20) and Northwestern (State Highway 16) motorways.The Western Ring Route will link the major population and industrial centres of Manukau, Auckland and North Shore to give the region the connected and resilient strategic road transport system it needs to underpin economic growth and sustainable development. It will also provide a direct motorway link between Auckland’s central business district (CBD) and international airport.The project involves construction of twin 2.4 km driven tunnels with an outside diameter of 14.41 m beneath residential suburbs, a major arterial road and a rail corridor. Enabling works began in January 2012 while tunnel construction using an earth pressure balance (EPB) tunnel boring machine (TBM) began in November 2013.This presentation introduces the Waterview Connection project, its role in the development of the Auckland motorway network, its procurement process, the alliance delivery model and an overview of the project’s design features and construction progress to date.Design and construction highlights of the presentation include the TBM start-up, turnaround and breakthrough arrangements as well as the experience gained during the first tunnelling drive. The presentation also covers an innovative process developed for invert construction behind the TBM that is independent of tunnel excavation.CITATION:Spies, P, Burden, J and Hanke, S, 2014. The Waterview Connection Project – progress to date, in Proceedings 15th Australasian Tunnelling Conference 2014 , pp 519–540 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 17, 2014

By J Boshoff, D Reid

It has been recognised worldwide that the liquefaction risk of unconstrained tailings stacks or cyclone underflow embankments requires careful consideration. The stability of a tailings deposit where the perimeter embankments are made up of hydraulic fill is often governed by post-liquefaction stability.Cyclones are frequently used around the world to classify tailings into a coarse underflow for building a tailings impoundment wall and a finer fraction that is disposed of into the basin. The shear strength of the tailings that form the outer embankment of a tailings storage facility (TSF) and the location of the phreatic surface are the two most significant factors influencing the structural integrity of the facility. The coarse underflow is placed in such a way as to contain the overflow, which is finer, has low strength and is often poorly consolidated.A cyclone field trial was undertaken at a gold mine in Western Australia to assess the feasibility of using the cyclone deposition method to optimise and increase the capacity of an existing tailings cell. The aim of the cyclone trial was to collect information to demonstrate to the client and the regulators that cyclone deposition was a feasible option for raising TSF embankments. The cyclone trial provided an opportunity to assess the cyclone under field conditions and the quantity and quality of the underflow fraction produced on-site. A variety of methods were used to assess the flow liquefaction susceptibility of the tailings underflow sample produced during the cyclone field trial.The field trial, laboratory testing and analysis will be discussed in this paper.CITATION:Boshoff, J and Reid, D, 2015. The resistance of cyclone underflow material to flow liquefaction, in Proceedings Tailings and Mine Waste Management for the 21st Century , pp 151–156 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 27, 2015

By Nava-Vasquez E, Torres-Torres J, Mendez-Nonell J

The ZA-27 zinc base alloy was poured into cylindrical moulds and solidified under different conditions ie normal freezing and unidirectional freezing. In addition a cylindrical ingot with rheocast material was obtained by stopping the stirring action and, at a specific solid fraction, gravity casting it into a graphite mould. It was observed that the material obtained under normal freezing conditions is likely to present both segregation and inverted pipe. In contrast, the unidirectional solidified and the rheocast cylinders showed the absence of inverted pipe. The segregation pattern was quite irregular in the rheocast ingot while such segregation was more uniform in the unidirectional solidified cylinder. By virtue of these observations, the inverted pipe formation may be ascribed to the interdendritic flow, while the irregular segregation pattern in the rheocast ingot may be attributed to an irregular distribution of the liquid and solid fraction along such a cylinder.

Jan 1, 1993

By J Zhang, L Klemettinen, A Jokilaakso, J Biswas, J Partinen, H O’Brien, A Klemettinen

Waste lithium-ion batteries (LIBs) are important secondary sources of many valuable materials, including Critical Raw Materials (CRMs) defined by the European Union (EU): lithium, cobalt, manganese, and graphite. Additionally, LIBs typically contain nickel and copper, which are classified as Strategic Raw Materials for EU since 2023. In recent years, great effort has been made to develop efficient recycling processes for waste LIBs. Pyrometallurgical processes have been essential in industrial production of metals for many decades. These technologies are relatively mature, with high adaptability for different raw materials. Pyrometallurgical treatment in LIB recycling typically involves the use of smelting processes, in which waste batteries are heated above their melting points and metals are separated through a reduction reaction in the liquid phase. Through this recycling route, cobalt, copper, and nickel can be efficiently recovered in the form of a metal alloy, whereas lithium and manganese are lost in the slag phase. The goal of this work was to increase the recoveries of valuable battery metals through a combination of hydro- and pyrometallurgical unit operations. First, industrial Li-ion battery scrap underwent a selective sulfation roasting stage, where the aim was to transform LiCoO2 and Mn-oxides into Li, Co and Mn sulfates. After roasting, the battery scrap was leached in distilled water with a solid to liquid ratio of 100 g/L at 60°C and recovered 95 per cent of Li, 61 per cent of Mn and 35 per cent of Co. After leaching, the solid leach residue was mixed with industrial Ni-slag and biochar, followed by reduction at 1350°C in argon atmosphere. The high-temperature smelting experiments were conducted as a function of time (5–60 mins) to investigate the reduction behaviour of battery metals. The results show that Co and Ni from the slag and leach residue can be efficiently recovered in the slag cleaning stage.

Jun 19, 2024