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By C. G. Anderson

The treatment of concentrates for the recovery of the precious metals imposes many processing and environmental challenges. Hydrometallurgical technology for recovery of values from refractory precious metal materials has been developed at Sunshine Mining and Refining Company. Historically, conventional pyrometallurgical methods have been used for to recover values from refractory precious metal materials. However, enhanced environmental awareness has worked to constrain typical refractory material processing methods. This hinders and limits the ability of established smelting or roasting technologies to fill the needs of new sources of refractory materials. An alternative is to treat refractory precious metal bearing materials by hydro metallurgical techniques. These methods are considered more environmentally appropriate since they do not produce gaseous pollutants like sulfur dioxide. Industrially, Sunshine Mining and Refining Company employs hydrometallurgical technology to process refractory precious metal materials. The Sunshine antimony leach uses a mixture of sulfur and caustic under ambient pressure and boiling conditions. The Sunshine oxidation leach uses a mixture of sulfuric acid and a minimal amount of sodium nitrite under relatively mild oxygen pressure and temperature conditions. These conditions result in a nitrogen species catalyzed sulfuric acid pressure leach. Since hydrometallurgical technologies provide industrially proven processing options for many types of refractory precious metal containing materials, their usage should be considered. Ample work has been conducted to prove the effectiveness of Sunshine refractory processing technologies on various materials. This has included platinum group metal materials, refractory gold concentrates, silver materials and indium materials. In some cases, complete process flowsheets have been designed to recover both base and precious metals from these materials and to treat the generated waste streams in environmentally sound manners.

Jan 1, 1996

By F. A. Campbell

This paper reports on mineral facies, ore textures, distribution of iron in sphalerites, and fractionation of sulfur isotopes in the Anvil ore body, Yukon Territory, Canada. Because the detailed structure and stratigraphy, both regional and local, are being studied by the geological staff at the mine and members of the Geological Survey of Canada, these topics will be discussed only briefly. The results of our study of the Anvil ore body have implications on theories of the genesis of ore deposits of this type, and these will be discussed. The Anvil ore body is the largest and most significant of three lead-zinc discoveries in an area of the central Yukon where major lead-zinc deposits were unknown only twenty years ago. The Vangorda deposit consisting of 22 million tons was discovered in 1953, followed in 1954 by the Swim Lakes deposit consisting of 10 million tons. The Anvil deposit, which consists of three ore zones, was discovered in 1964. The total reserve at Anvil mine is 63.5 million tons, with an average grade of 3.4% lead, 5.7% zinc, 0.16% copper and 1.2 ounces of silver per ton. This study is concerned primarily with the number one ore body which is about 2,400 feet long, up to 1,100 feet wide and 300 feet thick.

Jan 1, 1973

By R. R. Klimpel

The grinding of coal-water slurries has received increasing industrial attention during the last decade. In particular, there is long-term interest in the use of pulverized coal-water slurries to replace oil in combustion equipment and the development of coal gasification/liquefaction processes which require coal-water slurries as feed. More specifically, the use of coal-water slurries in gasification requires grinding a high density slurry containing the smallest amount of water consistent with slurry pumping and spraying. As part of a fundamental engineering research support program aimed at the industrial implementation of dense coal-water slurry grinding, this author has published several papers on how specific rates of breakage vary as a function of slurry rheology, Klimpel (1982, 1982/83). These papers demonstrated that there is a consistent pattern of change in specific rates of breakage of coal in dense slurries with controlled variations in slurry rheology. By matching rheological data with laboratory grinding results, it was possible to identify directly slurry conditions that correspond to: (1) slowing down of breakage rates, (2) the occasional acceleration of breakage of some sizes, and (3) conditions where chemical additives will increase rates of breakage.

Jan 1, 1990

By J. Choi

For the first time, the influence of stearyl trimethyl ammonium chloride (STAC) as a collector, on the flotation behavior of lepidolite (Uljin, South Korea) was systematically examined in Denver Sub-A cells. Flotation tests were carried out by varying amount of STAC (50?200 g/ton), feed size (-65, -100, -150, and -200 mesh), and solution pH. The impeller speed of 1000 rpm, flotation time of 10 min and AF-65 (a frother) of 250 mL/ton were invariably applied. In order to complement flotation experiments, zeta potential measurements and XRD analysis were conducted. XRD results showed that the ores were mainly composed of lepidolite, muscovite, quartz, calcite and albite. In addition, zeta potential results showed that isoelectric points were about 2.5, 2.3, and 9.7 for quartz, albite, and calcite, respectively, and lepidolite was determined to be less than 2. Overall, the results of 3-stage flotation showed that Li2O grade and recovery tended to increase with increasing STAC dosage and decreasing feed size. In addition, Li2O grade increased with decreasing pH. The results were explained by the extent of the interaction between STAC and each mineral.

Feb 23, 2014

By T. Yue, Z. Gao, X. Tong, R. Liu

"Lead ions (lead nitrate) were introduced to modify the surface properties of scheelite, effectively and selectively improving the flotability of scheelite, with benzohydroxamic acid (BHA) serving as the collector. A series of experiments about the mode of addition and the ratio of lead ion to BHA were conducted and indicated Pb-BHA complexes were the active species responsible for the flotation. And two adsorption models of BHA on the surface of scheelite were established. For both the two adding methods, some kind of complexes formed by lead ions and BHA played a key role in the flotation process. Zeta potential, FTIR, and XPS studies indicated that the adsorption amount and intensity of BHA on the surface of scheetlie were larger by adding the reagents as a mixture. The mixed addition is conducive to form Pb-BHA complexes and improve the adsorption efficiency of BHA on the surface of scheelite, as well as the recovery of scheelite. INTRODUCTION Scheelite, as an important tungsten-bearing mineral, is nowadays utilized mainly by flotation (YIN and WANG, 2014; Sun et al., 2011; Gao et al., 2015; Gao et al., 2015). Flotation separation of scheelite from calcium minerals creates difficulties because of the existence of the same cation in the minerals and similar physico-chemical characteristics such as solubility, hardness, specific gravity, point of zero charge (PZC), etc. (Arnold and Warren, 1974; Deng et al., 2016; Deng et al., 2015; Ozcan and Bulutcu, 1993a; Yongxin and Changgen, 1983). The conventional collectors used in the flotation of scheelite ores are generally fatty acids or fatty acid derivatives (Bo et al., 2015; Oliveira and Sampaio, 1988; Shi et al., 2014; Sivamohan, 1988; Yongxin and Changgen, 1983). It is difficult to separate scheelite, especially from calcite, with these reagents because the adsorption mechanism of these collectors occurs through chemisorption of the oleate ion onto the mineral surface (Atademir et al., 1979; Changgen and Yongxin, 1983; Hiçyìlmaz et al., 1993; Hu et al., 2011). Therefore, it is almost impossible to separate them by fatty acid flotation without using any selective depressant. Although oleoyl sarcosine was used as a selective collector in the flotation of fluorite and siliceous scheelite ores (Ozcan and Bulutcu, 1993b; Ozcan et al., 1994), this selectivity is inadequate for a low-grade calcitic scheelite ore. Unfortunately, reagents such as organic colloids (dextrine, starch), quebracho, sodium phosphates, sodium silicate solutions containing polyvalent cations (hydrosols), etc. (Bo et al., 2015; Schubert et al., 1990; Shi et al., 2014; Yongxin and Changgen, 1983), used for calcite depression also depress scheelite to a large extent. Cationic collectors, such as amine and quarternary ammonium (Yang et al., 2015) and collector mixture (Gao et al., 2015) have been used to improve the scheelite flotation. However they have not been applied in industry due to the poor separation from silicate minerals."

Jan 1, 2017

Operation of a pilot-scale Floatex density separator was studied using a pyrite concentrate slurry feed. Experimental measurements were further utilized in parameterization of a hindered settling simulation model. The model incorporates particle slip velocity calculation and also a separation efficiency function, adjusted to describe the feed material characteristics. The model was used to compute the overflow and underflow compositions when both fluidization bed pressure and teeter water flow rates were varied. In addition, prediction accuracy and the model validity were evaluated. The simulations gave good results when the teeter interstitial velocities were moderate enough to avoid excessive turbulence in the fluidization. Prediction of the cumulative overflow and underflow size distributions in most experiments yielded essentially less than 10% relative error between the sample data and the estimated value of the 50% passing sizes.

Jan 1, 2011

By S. A. Sass

The design and construction of Solvay Minerals (formerly Tenneco Minerals) Soda Ash Expansion Project, which is the world's most modern natural soda ash facility, is detailed. Along with a discussion of design considerations, the international joint venture ownership and teaming arrangement for design and construction companies is examined.

Jan 1, 1994

By G. G. Marino, Z. R. Widup

Marino Engineering Associates, Inc. (MEA) was asked to determine the effects of mining beneath a proposed roadway structure. In order to determine the subsidence potential and the magnitude of the mine stabilization costs it is important to know whether underground mining is present, and if so, to what a real extent. The site investigated had the potential to have mining in three different coal seams. To determine where mining was present MEAÕs borehole radar system was used. In summary, the borehole radar subsurface investigation validated that the available mine map in the most shallow coal seam was fairly accurate despite its age (1888), found no mining in the underlying coal seam and detected an area of unknown mining at a depth of about 300 ft in the lowest coal seam which was verified by subsequent drilling.

Jan 1, 2004

By Lana Alagha, Keitumetse Cathrine Monyake

The abstract discusses the synthesis and investigation of polyacrylamide functionalized chitosan polymers (CS-PAMs) as selective depressants for pyrite in the flotation of galena and chalcopyrite from complex sulfide ore. The study employed response surface methodology (RSM) to model and optimize the flotation process, varying parameters like the degree of deacetylation of chitosan, weight ratio of chitosan to acrylamide, and CS-PAM dosage. The developed RSM models effectively predicted iron and lead grades and recoveries, while optimization showed optimal pyrite separation from galena and chalcopyrite using CS-PAM synthesized from chitosan with a high degree of deacetylation and a specific chitosan:acrylamide weight ratio.

Apr 9, 2022

By James E. Myers

This study is a survey of the current "state-of-the-art" of commercially-available sonar tools to monitor the true shape of man-made cavities within the Hutchinson Salt of south-central Kansas. The work entailed ferreting out the available information, most of which is proprietary in nature; then examining actual existing conditions and arriving at a reasonable scientific evaluation of the method. Our studies were confined to one LPG field and two brine well operations in south-central Kansas. No field testing of any devices was performed, only questioning user firms, and studying cores, logs, and sonar surveys graciously made available by the companies we have contacted. Since these data are still somewhat proprietary, the company participants have asked that their company names be omitted from this presentation.

Jan 1, 1973

By J. S. Hall

The performance of a full-scale balling drum circuit is well known to fluctuate, and is difficult to control. The fluctuations stem from causes that are not readily quantifiable. Results from plant tests show that surging of the recycle tonnage is dependent, inter alia, on the method of bentonite addition, small variations in drum or cutter bar speed and the method of drum water addition. This paper presents detailed observations from experiments on full-scale drum circuits, including preliminary results of a computer measurement and control scheme. Size distributions measured at points along an industrial drum are presented, together with the results of a mathematical model fitted to one plant data set. Model predictions are also included emphasizing the importance of screen performance on circuit stability.

Jan 1, 1983

By P. Bissert, M. Klein, L. Yan, D. Yantek

"Mine Safety and Health Administration (MSHA) regulations require underground coal mines to use refuge alternatives (RAs) to provide a breathable air environment for 96 hrs. One of the main concerns with the use of mobile RAs is the heat and humidity buildup inside an RA. The accumulation of heat and humidity can result in miners suffering heat stress or even death. MSHA regulations require that the apparent temperature in a fully occupied RA must not exceed 95°F. To investigate this issue, the National Institute for Occupational Safety and Health (NIOSH) conducted testing on a 23-person tent-type RA in its Experimental Mine (EM) in a test area that was isolated from the mine ventilation system. The test results showed that the average measured air temperature within the RA increased by 9.4°C (17°F) and the relative humidity (RH) approached 94 %RH. The test results were used to benchmark a thermal simulation model of the tested RA. The validated thermal simulation model predicted the average air temperature inside the RA at the end of 96 hours to within 0.6°C (1.0°F) of the average measured air temperature. INTRODUCTION If an accident occurs in an underground coal mine, miners who fail to escape from the mine can enter an RA for protection from adverse conditions, such as high carbon monoxide levels. One of the main concerns with the use of mobile RAs is the potentially adverse thermal environment inside an RA from the metabolic heat of the occupants and the heat released by the carbon dioxide (CO2) scrubbing system. Moreover, the humidity within the RA will increase through occupants’ respiration and perspiration and from the chemical reaction within the CO2 scrubbing system. The accumulation of heat and humidity can result in miners suffering heat stress, heat stroke, or even death. In its 2007 report to Congress, the National Institute for Occupational Safety and Health (NIOSH) Office of Mine Safety and Health Research (OMSHR) recommended that RAs should be designed to ensure that the internal apparent temperature (a temperature-humidity metric) in an occupied RA does not exceed 35°C (95°F). However, a standard method to determine compliance with this metric does not exist. The heat transfer process within and surrounding an RA is very complex, and is not easily defined analytically or experimentally. To investigate the related issues, OMSHR conducted heat and humidity testing on a 23-person tent-type RA in its Experimental Mine (EM) in a test area that was isolated from the mine ventilation system. During the testing, numerous parameters were measured: heat input to the chamber, the air temperature and relative humidity inside the RA, the air temperature in the mine, the mine strata temperatures versus depth, and the airflow inside and outside the chamber. The focus of this paper is on the temperature rise within an RA. TAITherm heat transfer analysis software was used to develop a thermal simulation model of the RA as it was tested in the mine, using the test results as the benchmark. Both sensible and latent heat were used in the test and the model."

Jan 1, 2016

By J. P. Earnhardt

Recycling of such municipal solid wastes as glass containers, metal cans, and newspapers has received increasing attention recently. However, municipal solid wastes account for only 1% of the total solid waste stream in the United States. The remainder includes hazardous and non-hazardous industrial wastes. Generators of industrial wastes are facing higher landfill costs. Future liability potential, and public image concerns which are forcing them to seek innovative and often profitable solutions to minimize, reuse, and recycle their waste streams. Opportunities for the mining industry in industrial recycling include recovery of mining wastes and by-products, and utilization of mineral products for treating waste streams.

Jan 1, 1993

This one day field trip is sponsored by the Denver Region Exploration Geologists? Society, May 14th 2009. The trip highlights major geologic features and some notable uranium occurrences along the north-south mountain-basin boundary southwest of Denver and continuing north to Fort Collins, Colorado. Uranium deposits visited include sandstone?hosted roll front type and polymetallic veins hosted in metamorphic rocks. A replacement ?episyenite? type occurrence is considered via description and hand samples but is not visited owing to logistical constraints. Recovery methods addressed include underground mining and in-situ leach recovery. Samples of Precambrian basement rocks, deposit host rocks, uranium ore samples, and ore polished sections viewed by reflected light microscopy will be available. A road map showing the locations of the stops serves as the front cover of this field guide. The Robinson episyenite-hosted occurrence (not visited) is labeled as Stop 6. A stratigraphic column is provided which shows the position of the host rocks at each stop (Figure 1-1).

Jan 1, 2009

By C. R. Pelley

This paper is intended to describe the utilization of Western subbituminous coal as used in a utility-sized steam generator. It compares this coal's characteristics with those of a typical Midwestern and Eastern coal as a base and reviews the various design considerations when blends of these coals are used. The effects of blending various low-sulfur Western coals with Midwestern or Eastern coals to achieve a predetermined sulfur dioxide emission and the resulting alteration in the coal characteristics as they apply to utilization are also reviewed. The blending of coals as one means of complying with sulfur dioxide regulations will take on increasing importance as the various deadlines for compliance with new and existing regulations approach. We must first consider the availability of these low-sulfur coals; and insofar as the Eastern low-sulfur coals have been mined for many years, we have focused our attention on the availability of the coal reserves west of the Mississippi River in the United States, as this is the area to which many people are turning in order to meet this requirement.

Jan 1, 1976

By Greg Sanders, Bill Lueck, Michael Gilbert, Mahmood Khwaja

"The city of Minneapolis contracted with CDM Smith to update and provide a conceptual design for improvements to mitigate surcharge flooding in the Central City Storm Water Tunnel System (CCSTS). As a part of the project, CDM Smith conducted a field survey and condition assessment of the existing tunnel system. Information from the survey was then used to update the existing XPSWMM model and develop system wide alternatives.The CCSTS provides storm-water runoff drainage for nearly the entire area of the city’s downtown commercial district. The system consists of deep storm-water tunnels constructed in the St. Peter Sandstone, approximately 21 m (70 ft) below the street’s surface. The primary tunnels comprising the Central City storm water tunnel system are located below Hennepin Avenue, Nicollet Mall, Lesalle Avenue, Marquette Avenue South, 2nd Avenue South, South 5th Street, Washington Avenue South, Portland Avenue South, 2nd Street South, and Chicago Avenue South, as shown in Fig. 1. This network of tunnels conveys the runoff from a 305-acre tributary area that is generally bound by Hennepin Avenue and 1st Avenue North to the east, 12th Street to the south, 4th Avenue South and 7th Avenue South to the west, and 2nd Street South. These tunnels were constructed between 1936 and 1940, except for the Marquette Avenue South tunnel, which was constructed between 1963 and 1964.The CCSTS operates as a gravity flow system. These tunnels were constructed within the St. Peter Sandstone layer of bedrock and emerge from the bedrock at the Mississippi River below St. Anthony Falls. The Central City and the adjacent Chicago Avenue tunnel system converge into a single outfall at the Mississippi River. The runoff discharges from the converged outfall to a side channel of the Mississippi River, called a tailrace, located near the Guthrie Theater. The Minneapolis Division of Surface Water and Sewers provided 32 historic plats detailing the plan and profile of the tunnel system.The tunnel plans show nine different cross-section configurations. Eight configurations within the overall system generally show the same geometric “cathedral” shape with the inside dimensions varying from 1.2 to 1.8 m (4 to 6 ft) in width and 1.8 to 2.4 m (6 to 8 ft) in height. For analysis, these eight configurations were reduced to three configurations with regards to tunnel liner, cross-sectional area and support. For simplicity, the three configurations are described according to the three types of tunnel support used during construction: none required, light timber and heavy timber"

Jun 1, 2019

By Barry D. Simmons

The Millenbach copper-zinc orebody is an ideal Canadian example of a stratabound base metal deposit in volcanic rocks. The mine, operated by Lake Dufault Divison, Falconbridge Copper Ltd. is located five miles north of the city of Noranda in northwestern Quebec. The deposit occurs within an Archean volcanic sequence which forms part of regional acidic volcanic center within the Abitibi greenstone belt. Preproduction ore reserves totalled 2,075,000 tons grading 3.5% copper, 3.6% zinc, 1.1 ounces per ton silver, and 0.02 ounces per ton gold. Stratabound lenses of massive sulphides together with underlying stringer sulphides are closely associated with a dome of quartz-feldspar porphyritic rhyolite approximately 3000 feet below surface. The paper describes the presently known geology of the deposit and includes documentation of sulphide mineralogy and textures as well as sulphide/ host rock relationships. The stratigraphy, petrography and chemistry of the volcanic host rocks are described with emphasis on the alteration intimately associated with the sulphide bodies. Although the volcanic stratigraphy is complex within the mine area, the presence of only low-grade metamorphism and the relative lack of structural deformation allow detailed interpretation of geological history. Presently recognized evidence strongly suggests that the sulphides were deposited at and near sea-floor, by hydrothermal solutions. The dome of porphyritic rhyolite appears to have been the most significant factor controlling sulphide localization.

Jan 1, 1975

By Raymond E. Zimmerman

The cleaning of coal by the use of jigs is one of the oldest methods of separating coal from its impurities. Although in many situations jigs have been replaced by other methods, by far the largest percentage of coal today is still being cleaned by some form of jigs. Some piston- or plunger-type jigs are still in use throughout the world; however, the greater number are air pulsated, generally called the Baum jig, named after the original inventor, Fritz Baum of Germany. This standard jig, with slight modifications, has been in use for over 75 years. Up until recently, however, it has had certain limitations in obtaining the high performance and efficiencies required in modern coal preparation practice. TO improve its performance, some radical modifications have been made in its design and operation SO that there is now a Baum-type jig giving much higher performance in terms of capacity, efficiency and sharpness of separation- This new jig is called the Batac, and the purpose of this paper is to describe its characteristics and present data giving its performance in treating coarse and fine sizes of coal.

Jan 1, 1974

By Charles J. Johnson

The United States is totally dependent on imports for all primary chromite and most ferrochrome supplies. Although the United States imports chromite and ferrochrome from a number of countries, the long-term future of chromite supplies appears to lie in southern Africa (Republic of South Africa and Zimbabwe) where 88 percent of known world reserves exist. Floreover, low mining costs and the availability of low-cost electricity for ferrochrome production gives South Africa a comparative advantage over most other chromite and ferrochrome-producing nations. A well-known problem faced by the United States is that when viewed from a longer-term perspective, the major sources of supply of metallurgical grade chromite and ferrochrome may be subject to disruption. The three countries that have caused the greatest concern have been the Republic of South Africa, the Soviet Union, and Zimbabwe. South Africa presents a particularly difficult problem because it may be subject to internal political unrest and/or U. N, economic sanctions. South Africa has increased its share of world chromium production from about 30 percent in 1968 to 62 percent in 1978.1

Jan 1, 1982

By Emily Sarver, Cigdem Keles, Jonathan Gonzalez

The study re-examines respirable coal mine dust samples using scanning electron microscopy (SEM) and thermogravimetric analysis (TGA). It finds that SEM tends to overpredict the abundance of dust from rock strata and underpredict coal content, possibly due to coal-mineral microagglomerates (MAGs). The findings suggest that MAGs could be valuable in improving dust controls in mines.

Feb 10, 2022