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By V. T. McLemore

The Wind Mountain (WM) nepheline syenite deposit is part of the alkalic complex in the Cornudas Mountains, which ranges in age from 34.6 ± 1.5 Ma to 36.8 ± 0.6 Ma. The WM deposit consists of a complex, zoned pluton that ranges from syenite porphyry to nepheline syenite porphyry. The WM deposit has potential use for ceramics and dark-colored beverage containers and consists of nepheline, k-feldspar, albite, and varying amounts of other minerals. Analcime also is present locally but must be avoided because it is unsuitable for ceramic and glass. Chemically the deposit consists of 56-63 % SiO2 17-21 % Al2O3 and 4.0-5 % Fe2O3. Although initially iron is high, when the crushed rock is passed through a specialized magnetic separator, the iron content drops to below commercial maximum standards of less than 0.5% Fe2O3. The WM deposit is currently under exploration and testing to determine marketability.

Jan 1, 1994

By R. Mensah-Biney

The kinetics of loading of gold from bromide solution onto an anion exchange resin, PAZ-4, were investigated in a batch stirred reactor. The initial loading rate was described mathematically by a first-order reaction rate equation. The effect of agitation speed, temperature, resin particle size, resin concentration, initial concentration of gold and bromine in solution on the rate was investigated. The model described fairly accurately the loading process in terms of the variables investigated. The rate constant for the initial loading ranged from 0.5 to 1.3 x10-3 sec-1 and the half-time was 9.3 to 56 minutes. The initial rate constant increased with increasing temperature with an activation energy of 15.7 kJ/mole (3.8 kcal/mole). The rate constant was directly proportional to the concentration of the resin in solution. The subsequent reduction reaction was also modeled by the first-order rate equation and the apparent rate constant was estimated to be 3.0 x 10-6 sec-1 with a half-time of about 44 hours.

Jan 1, 1994

By VIVEK KUMAR HIMANSHU, PK SINGH, AK MISHRA, MP ROY, RAVI SHANKAR

Underground blasting has many challenges. The primary aim of blast designers is to optimize drilling and blasting parameters to deal with the associated challenges. Optimizing these parameters is currently based on various rules of thumb, which have many site-specific limitations. Accordingly, computation of these parameters using empirical rock fragmentation predictors can be useful for blast designers. This paper presents the results of work on burden-spacing determination by back-calculation from the empirical Kuz-Ram model for underground stope ring blasting.

By D. M. Thayer

Dry magnetic separation of feebly magnetic minerals and wet magnetic separators suitable for highly magnetic minerals have been commercially utilized for a number of years. The beneficiation of magnetic taconite ores by conventional, low intensity magnetic separators in combination with flotation is well established technology (1). However, over the past decade much effort has been expended in developing techniques for the upgrading of feebly magnetic oxidized iron ores (2,5). Such research and development have been stimulated by the limitations of the above-mentioned techniques in application to ores containing fine material; for example, ores requiring fine grinding for liberation or slime-forming ores such as the oxidized taconites or semi-taconites. Wet separation has allowed the reduction of the minim particle size that can be effectively treated from that allowable for high intensity dry magnetic separation. Consequently, the development of high intensity wet magnetic separation methods has received much attention in the search for an effective method to treat the weakly magnetic minerals. Recently Lawver and Hopstock (5) have provided an excellent review of the state of know- ledge of this technology. In addition, a valuable compendium of available laboratory and commercial devices is included. Nonetheless, the feasibility of the use of high intensity magnetic separation in a particular application is largly empirical in nature and requires experimentation to chazacterize the response of a particular ore. The purpose of this paper is to assess the incorporation of high intensity magnetic separation for the beneficiation of a non- sliming specular Michigan hematite. Particular attention is focused on the existence of a lower limit of particle size that can be treated effectively and is inherent in the use of these techniques. Additionally, a rationalization of various models presented in the literature is attempted.

Jan 1, 1979

By K. Fleck

Energy West Mining Co. (EWMC) has implemented a geologic program for improving stability and support requirements along deep two-entry longwall gateroads at its Deer Creek Mine operations located near Huntington, UT. Together with geotechnical monitoring and concurrent review of mine seismicity in cooperation with MTI staff, it has become possible to improve longwall layout designs for two seam extraction of the Hiawatha and Blind Canyon seams. The geologic program consists of surface and in-mine exploration drilling, surface and in-mine geologic mapping, rock mechanics testing and detailed measurements of changes in depositional and structural conditions during development of every longwall gateroad. The geotechnical program consists of underground measurements at seven locations in two neighboring mining districts located in the Hiawatha and Blind Canyon coal seams under moderate to deep cover. Within the last five years, additional measurements, including data on seismicity and face conditions, have been incorporated into the data collection program for verifying the in situ coal strength and load transfer mechanisms for improving two-seam designs and support systems.

Jan 1, 2012

By Daniel J. Dobbels, Eric R. Drooff, James R. Wheeler

Construction of Boston’s C11A1 Section of the Central Artery (I-93)/Tunnel(I-90) Project beneath the existing MBTA Red Line Subway at South Station required excavation to depths in excess of 33.5 m (110 ft) through permeable sand and gravel subject to almost 27.4 m (90 ft) of hydrostatic groundwater pressure. As tacked drift tunnel underpinning system was designed to provide positive support to the active station prior to mainline tunnel construction. As part of this system, a permeation grouting program was developed to facilitate tunnel excavation. This paper describes the design and implementation of the grouting program, in sit testing, and the overall performance of the grouted soil mass.

Jan 1, 1999

Sedimentation is used to clarify process effluents or to thicken process slurries. The sedimentation cycle of a suspension is presented as a settling curve. This curve is simply a plot of the height of the interface between the settled suspension and clear liquor versus time. Figure 1 shows a series of graduate cylinders which contain a suspension at various stages in its settling cycle. Cylinder 1 shows the suspension completely mixed at time zero. After a brief period of time (see cylinder 2), the suspension is observed to settle from its initial height Ho to height H1, leaving behind a volume of clear (or turbid) liquor, called the supernatant. The interface between the supernatant and suspension is termed the mud line. It is also possible to distinguish at the bottom of the cylinder a layer of sludge representing solids which have settled from the suspension. The interface between it and the suspension is called the sludge line. The sludge line moves upward in the cylinder.

Jan 1, 1992

By S. S. Xue

A study has been conducted to remove iron from sulfate solutions using Eichrom's Dipex® extractant, P,P?-di(2-ethylhexyl) methanediphosponic acid (H2DEH[MDP]). It is found that this extractant can effectively and selectively extract ferric ion from highly acidic solutions. Ninety-nine percent of the iron was extracted from a simulated feed solution in a single stage. The separation factor, Fe/Zn, was 10 6 Over 90% of the iron in a loaded organic can be recovered in an aqueous solution by reductive stripping. This paper presents the experimental results. A new process for iron removal using Dipex extractant is described and discussed.

Jan 1, 1999

By C. W. Hunt

I wish to register strong disagreement with the choices of drilling sites chosen by the Continental Scientific Drilling Committee, while endorsing the stated objectives. Of special significance is the lack of any site involving the metals most needed today in the US, while 9 to 13 km of drilling are allocated to gold and silver districts and 11 to 17 km to base metal (mainly copper) districts. Why is nothing proposed for platinum group or chromite? Is this because the committee did not know of such a site? If so, I offer such a site in California (see Fig. 1). The mineralization shown in Table 1 occurs in a large peridotite body in western Tehama County, CA. Petrography has demonstrated unequivocal evidence of migrated PGE deposited in peridotite and chromite of hypabyssal nature. Active diapirism (due probably to serpentine buoyancy) above a reactivated mantle to surface conduit marks the position of the conduit. Young explosion breccia cemented loosely by volcanic glass and tuff demonstrates the significance of the conduit as the prime source of the various emissions. Deep drilling could result in major metals discoveries as well as shedding light on the grand questions of platinum group mineralization. What role water has played in this occurrence is not yet certain; but chlorine and asphaltite have been detected in and adjacent to native PGM, suggesting a major role for water. The explosion breccia suggests that this excellent site could overlie entrapped geothermal steam.

Jan 1, 1988

By R. Hogg

A standard procedure for determining size-specific gravity distributions of fine coal (including the -400 mesh fractions) by sieving and centrifugal sink-float separation is described. The significance of using a centrifugal sink-float technique and the effect of the magnitude of the centrifugal force on the separation of fine coal are confirmed in the present study. The relative merits of cumulative versus incremental sink-float are discussed. The procedure is evaluated quantitatively using data obtained for the products of froth flotation of -100 mesh coal.

Jan 1, 1994

By Jeff Schwoebel, Arcy, D&apos Horner

The Deep Coal Seam Project is a multi- year, large-scale research and development effort between the Gas Research Institute (GRI) and Resource Enterprises, Inc. (REI). The project is being conducted at the Red Mountain Site, a multi-well test site located in the southeastern portion of the Piceance Basin near Collbran in Mesa County, Colorado. The project objective is to develop the drilling, reservoir evaluation, completion and production technology required to produce gas from a thick, deeply buried coal seam. To understand the parameters controlling gas production, project efforts are focused on the Cameo "D" coal reservoir which lies at a depth of about 1707 m (5,600 ft) at the test site. This paper overviews the drilling, testing, completion, and production techniques used on the 1, 2 and 3 Deep Seam wells and implications for resource development.

Jan 1, 1987

By John J. Stetler

Introduction Samarco Mineracao S.A. is a Brazilian corporation jointly owned by S.A. Mineracao da Trindade (SAMITRI) and Utah International Inc., with 51% and 49% interests respectively. Headquartered in Belo Horizonte in the state of Minas Gerais, Samarco owns and operates an open-pit mine capable of producing 10 Mt/a (11 million stpy) of iron ore; a concentrator rated at 7 Mt (7.7 million st); a 12-Mt (13.2-million st) capacity pipeline transportation system; a 7 Mt (7.7 million st) filtering and pelletizing plant; and a harbor facility. The mine, concentrator, and initial pipeline pump station are located at Germano, near the town of Mariana, about 300 km (186 mi) north of Rio de Janeiro by air. The pipeline terminal, pellet plant, and harbor are at Point Ubu, 70 km (43 mi) south of Vitória the capital city of Espirito Santo State, and about 300 km (186 mi) by air east of the mine. The 396-km (246-mi) pipeline uses 508-mm (20-in.) pipe except for a 53-km (33-mi) section where 457-mm (18-in.) pipe is used to absorb and control slack flow through increased velocity in one of the areas along the route. Iron Ore Slurry The hematite iron ore concentrate produced at the Germano plant is processed by grinding the average 53% run-of-mine itabirite iron ore to -150 µm (100 mesh) for gangue liberation. It is treated further by cyclones to remove the 10 µm (1250 mesh) slimes to prepare the ore for flotation. During the multistage cationic flotation operation, the silica is reduced to make low silica (-0.9%) concentrate for the direct reduction (DR) iron-making process or to make normal silica (-3.5% +2.5%) concentrate for the blast furnace (BF) iron-making process. The concentrate then is reground further to meet the particle size requirements for pelletizing. The reground hematite concentrate is screened in closed circuit with the regrind mills for close control of the maximum particle size, not to exceed 3.5% +75 µm (200 mesh) for pipeline wear protection. Thickened concentrates at 70% solids are pumped to four 5-kt (5,510-st)(dry) agitated slurry storage tanks that hold the feed before it goes to the first pipeline system pumping station. Pipeline Capacity The pipeline system was designed to transport 12 Mt/a (13.2 million stpy) at 65% solids with an average minimum safe operating velocity of 1.5 m/s (5 fps). The pipeline will transport 5 Mt (5.5 million st) in 1982. The system, therefore, is moving the slurry in 13-kt (14,330-st) batches, dispatched at intervals to move 20 kt/d (22,050 stpd). In operation, the pipeline has exceeded its 93% availability design factor. Pipeline Facilities Pump station No. 1 is located at the Germano minesite 1 km (3,330 ft) above sea level. It has the following principal equipment: • four 5 kt (5,510-st) (dry) agitate slurry storage tanks; • two centrifugal charge pumps (one stand-by); • a 217-m (712-ft) safety loop; • seven mainline positive displacement triplex plunger pumps (189 m3/h, or 832 gpm, at 14.9 MPa, or 2,162 psi, maximum output pressure); • four corrosion-erosion spools; • a control and command center. Operation The output at pump station No. 1, with 66% solids, is pumped 151

Jan 10, 1982

By R. J. Sweigard, R. V. Ramani

Productive and beneficial use of reclaimed surface-mined land is a concern of industry, government, and the general public. A process has been developed that will aid mine planners and public planners in the evaluation of postmining land use potential. This process involves the application of site planning principles to surface-mined land in a way that ensures productive end use of reclaimed land. The process consists of 10 basic components and is iterative in nature. Termination of the process depends on the amount of data collected and the evaluation requirements of each mining site. The analysis centers around the economic, environmental, and social impacts of the alternative land use plans.

Jan 1, 1987

By C. A. Born

AMAX Inc. climax's mine-mill complex at Climax, Colorado is best known for its molybdenite production: 50,000 TPY of molybdenite flotation concentrate (95% MoS2) from mill heads containing 0.35% molybdenite. Less recognized are the byproducts that are concentrated from the tails generated in the rougher flotation circuit (see Figure 1). Climax recovers a heavy mineral concentrate by passing the rougher tailings from molybdenite flotation over Humphrey spirals (Figure 2a). This concentrate is floated using xanthate at pH 4 to remove sulfides, principally pyrite. The tails from the pyrite float are then cleaned of quartz, feldspar and light minerals by tabling (Figure 2b). Amine flotation follows at pH 1.5 and 75°C to float monazite (Figure 2c). The present circuit at Climax dries the monazite flotation tailings and utilizes high intensity cross-belt magnetic separation Figure 2d) to generate a high grade wolframite concentrate and a low-grade cassiterite product, both of which are contaminated with the mineral brannerite, (UO, TiO, UO2)TiO3. The uranium specifications have recently become difficult to meet due to the increasing percentage of brannerite reporting in the mill feed. A plant is being built utilizing hot sulfuric acid and sodium chlorate to leach this uranium from the monazite flotation tailings prior to their being fed to the wolframite- cassiterite magnetic separators. This modification is the subject of our paper.

Jan 1, 1975

By R. E. Anderson

Canada encompasses an area of approximately 9,976,000 kilometres. It is comparable in size to the United States, but because of climatic conditions and limited transportation facilities, much of the area is unsuitable for agricultural or industrial development. We have a population of 22,000,000 - most of whom reside within a hundred mile belt paralleling the Canadian-U.S. border. Our principal cities in order of size are Montreal, Toronto, Vancouver, and Winnipeg. We have a total of 10 provinces, each of which elects its own - government. The Yukon Territory and Northwest Territories covering the northern half of the country, are administered by federal government agencies. The mining industry employs approximately 9% of the labour force and accounts for more than 40% of all tonnage shipped on Canadian railroads and inland waterways. In 1974 it produced $4,800 million in mineral wealth. Canada ranks first in world production of asbestos, nickel, zinc, and silver and has significant production of copper, iron, molybdenum, lead and other mineral commodities. During the past decade Canada, like many other western countries, has undergone dramatic economic and social change. This trend is continuing, and its effect on the Canadian mining industry has produced conflicting results. From the industry's point of view, some of the more negative aspects include a steadily increasing involvement by government at municipal, provincial and federal levels through the imposition of Stricter controls, regulations and taxation policies, a rising tide of nationalism, which advocates public ownership of all natural resources, the spectre of inflation (currently increasing at the rate of 8% per year) and unsettled labour conditions.

Jan 1, 1976

By D. Malhotra

The number of variables which can effect flotation of molybdenite is very large. This paper discusses the effect of two operating variables, namely, the degree of aeration and agitation, on the grade and recovery of molybdenite. A series of factorially designed flotation tests were carried out in a "Leeds Automatic Laboratory Flotation Cell." The analysis of flotation results indicate that molybdenite can be characterized into fast-floating and slow-floating components. The rates of fast-floating components, which do not create a problem in flotation, could be varied by changing agitation of airflow rates. However, the rate of slow-floating components was stable and was only a function of residence time in the float machine. The degree of aeration has a significant effect on the grade of MoS2 with only a slight effect on the recovery of MoS2. The degree of agitation has a slight effect on the grade, but does not effect the recovery of molybdenite. The implications of the results on the design of flotation cells and control and optimization of the existing circuits is subsequently discussed.

Jan 1, 1977

By Garry W. Warren

The electrochemical oxidation of chalcopyrite in the absence of-a chemical oxidant was studied in ammonia/ammonium sulfate solutions by anodically polarizing electrodes prepared from massive chalcopyrite. The effects of pH, cupric and ammonia ion concentration were systematically evaluated. Kinetic parameters were obtained from the anodic charge-transfer regions of the anodic polarization curves. Increasing ammonia and hydroxyl ion concentrations increased the rate of oxidation. A mechanism is proposed which explains the first order dependence of (NH3) and (OR) associated with a single electron transfer process. An empirical relationship which accurately describes the dependence of the rest potential (i.e. zero current potential) on solution composition is also given.

Jan 1, 1978

By Thomas F. Evans

Niagara Mohawk, like other northern coal users, has long experienced increased costs during winter months as a consequence of handling frozen coal. These costs include operating labor, maintenance labor and materials, equipment rental, fuel for thawing, demurrage, carrying costs for excess coal inventory and substitution of higher cost electrical generation for lost production capacity. In the winter of 1978-79, limited trials of several coal freeze conditioning agents were made to determine whether these would provide a cost-effective means of reducing the problems of handling frozen coal. Since these trials were generally effective, the Coal Purchasing Department arranged that all rail coal received during the 1979-80 winter from early December to mid March would be treated at the mines during loading. Inasmuch as the treatment costs are themselves appreciable and our various coal suppliers made a variety of choices of chemical supplier and equipment for application, an attempt was made to evaluate the unloading performance of each train received at the two generating stations which use coal as an aid in the future optimization of the use of freeze conditioning agents. These stations also receive coal by truck but this coal is not treated because of the short hauling time. The C.R. Huntley Station in Tonawanda, NY has a capacity of 800MW and burns about 5000 tons of coal per day during the winter months. The coal is primarily from central and western Pennsylvania but one source in southern Kentucky is also used regularly. Most of the Pennsylvania coal is washed and the fines are thermally dried. The coal is delivered in unit trains made up of mixed cars of 60, 75, and 90 ton capacity. Time between loading and arrival at the station averaged five days and ranged from three to eleven during the 1979-80 winter season.

Jan 1, 1980

By A. D. Hammond

Vanadium is a transition metal, ductile, silver-gray metal. It is harder than most metals and steels and it has a good resistance to corrosion, it is stable against alkalis, sulfuric and hydrochloric acids. Vanadium is oxidized in air about 660 °C, although an oxide layer forms even at room temperature. The chemistry of vanadium is noteworthy for the accessibility of the four adjacent oxidation states 2-5. In aqueous solution the colors are lilac V2+, green V3+, blue VO2+ and, at high pH, yellow VO42-. Considered to be as abundant as zinc, metallic vanadium is not found in nature, but it is known to exist in about 65 different minerals. Economically significant examples include patronite (VS4), vanadinite (Pb5(VO4)3Cl), associated to the uranium mineral carnotite (K2(UO2)2(VO4)2?3H2O) and in a vanadium mica called, roscoelite K(V3+,Al,Mg)[(Si,Al)4O10](OH)2. Other important vanadium ore oxides are montroseite (V,Fe)O(OH) and corvusite (Na,Ca,K)V8O2.4H2O. Much of the world's vanadium mine production comes from magnetite-hosted deposit and to a lesser extent, in sedimentary-hosted sandstone. Vanadium is also present in bauxite and in fossil fuel deposits such as crude oil, coal, oil shale and tar sands. In crude oil, concentrations up to 1,200 ppm have been reported. A significant vanadium production comes from the processing of petroleum residues, fly ash and recycling spent catalysts. In 2011, metallurgical applications accounted for 93% of the use of vanadium. Here, an alloy called ferrovanadium is utilized to strengthen steel to be used as rebar in the construction industry, in the manufacturing of axles, crankshafts, gears and chassis in the automotive and transportation industries and in the manufacturing of high-speed tools. In the aerospace industry, vanadium is utilized as a titanium alloy in the manufacturing of airframes and jet engines. The reason for the wide use of vanadium as alloy is its high strength-to-weight ratio, the highest of any engineered material on earth. The major non-metallurgical use of vanadium is in the production of catalysts for the chemical industry. The most commercially important compound is vanadium pentoxide (V2O5), which is used as catalyst in the production of sulfuric acid.

Feb 23, 2014

By M. Kaya

This paper presents an experimental method to determine the degree of gangue entrainment in mechanical flotation cells and proposes new and inexpensive methods to lessen it. The applicability of froth washing and vibration was studied in laboratory, pilot plant, and plant scales. The effect of wash water on metallurgical performance was tested with various streams from the Falconbridge Strathcona mill at laboratory, pilot, and plant scales, with the 2nd cleaner at the Eastmaque Kirkland Lake mill, and with the 2nd and 3rd zinc and 3rd and 4th copper cleaners at Les Mines Selbaie mill. It was found that gangue recovery was closely related to water recovery in all systems. Wash water at an optimum superficial rate from 0.03 to 0.07 cm/s reduced entrainment by anywhere from 30X to 70X. Wash water can be further assisted by mechanical and ultrasonic vibration of the froth. A further rejection of 10 to 20X becomes possible. As a result of this work, a number of plants in Canada and in the United States have evaluated and/or are now using froth washing.

Jan 1, 1990