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By R. P. King

"A model of the flotation process can be used effectively for design and control. For design purposes it can be used to predict the performance of a large plant from laboratory and pilot plant data. It can be used for control purposes to assess the utility of any proposed operating modification to an existing plant, and it can also be used to determine optimal control settings for best operating performance.A model has been developed that will allow for variations in feed properties and for variations in fineness of grind. The model can be used to assess the effects of reagent addition rate, aeration rate and pulp level on plant performance and these are the control variables that are used individually or together in all operating flotation plants. The model provides for a distribution in the values for flotation rate constants, particle size and mineral fraction, and, because of its complexity, requires a large computer when it is to be applied to a typical plant configuration. The computational method that is used to apply this model to such configurations is described in this paper, and particular attention is paid to the problem of allowing for feedback of tailings from cleaners and recleaners."

Jan 1, 2014

By M. Kerr

Background- History The most significant change in mining since the late 1970?s has been the emergence of very large scale mining operations , which have been developed to ensure profitability with relatively low grade ores. These large tonnage operations have resulted in the development of larger unit sized machines in all operations of beneficiation, solid-liquid separation and dewatering. Often only a few flotation lines are installed and tonnages up to 25 ktpd and beyond are not uncommon. The increased throughputs have led to the development of circular, reactor type tank designs. The reactor cell system is the most up to date flotation cell design to utilise the principles of circular cell design. The Svedala DV mechanism was specially developed to suit the RCS machine giving good solids handling characteristics and excellent metallurgical performance. Development of UG2 ore type flotation equipment The equipment was developed and optimised by Svedala process from 1995. A higher energy specification was requested by industry. This amounted to 3kW/m3 for installed volume. Existing designs were at 1.5kW/m3. Hence various modifications were required to achieve the required power input. The first 50m3 machines were installed and developed at Impala Platinum?s UG2 circuit over a one year period. Once reliability and performance was achieved, over 300 large volume flotation cells were installed at Anglo Platinum and Lonmin operations as well. Pilot Plant Development The Impala Platinum High Energy pilot plant was commissioned in 2002 and had an installed power exceeding 5kW/m3. It was operated for over a year at the tailings dam booster station and was fundamental to the large scale scavenging plant design. All experience in overcoming mechanical and operational problems was applied in scale up design principles. A very robust mechanism was designed to accommodate the additional power input from installed motors, as well as the high SG (>1.5) of the feed source. The pilot plant flowsheet is shown in the figure below.

Jan 1, 2007

By J. P. Gous, M. Tangstad, J. D. Steenkamp

In April of 2013 a 48 MVA submerged arc furnace producing silicomanganese was excavated in South Africa. One of the areas excavated systematically was the furnace taphole. The aim was to obtain a refractory wear profile of the tap-hole area, together with affected hearth and sidewall refractory. Subsequently, thermodynamic modelling was applied to quantify the potential for chemical reaction between refractory and slag and refractory and metal in the tap-hole area.

Jan 1, 2014

By N. V. Moraka

In dealing with transformational aspects, the South African Constitution aspires for a balance between attempts to broadly represent the country’s demographics in the way in which organizations are structured and the need to maintain the necessary skills to ensure continual retention of skills for optimum and efficient organizational performance. Through the Mining Charter, government aimed to redress gender and racial imbalances in the mining industry as part of transforming the demographic representation of mining companies to include black people, women, and people living with disabilities in all job levels up to top management. While the Constitution calls for an appropriate balance between demographic representation and competency, this aspiration for mining poses challenges for companies due to the proficient and competent skills needed in this industry. To this end, the South African mining industry has been subjected to substantial criticism from government regarding the slow progress of transformation. The mining industry justifies its slow pace of transformation by pointing at inconsistent, varying legislation and definitions governing transformation, limited skills available from historically disadvantaged groups, and cautioning not to compromise the sustainability of mining companies by marginalizing white males and white youth with the objective of addressing racial imbalances. This lack of understanding between industry and the government has led to considerable confusion regarding the accountability of stakeholders in transforming the industry. This article presents the perspectives of ten mining executives on transformation in the South African mining industry. The theoretical description of transformation, as well as other mining stakeholders’ interpretations of transformation. is presented. Qualitative data from interviews with mining executives demonstrates their understanding of transformation through rich descriptions, interpretations, and implications in their contexts. The findings demonstrate that transformation in the mining industry is not simply about race and gender, but about cultural change, a change in mind-sets, embracing diversity, equalizing rights and opportunities, and attaining social justice. Moreover, transformation is clearly a gradual process. The article concludes with a recommendation for the definition of transformation to be corroborated with the views of mining executives and that of the Constitution of South Africa. This will create an overarching, simplified definition of transformation that can be accepted and interpreted by all stakeholders.

Jan 1, 2016

By M. Tangstad, J. D. Steenkamp

In April 2013 a 48 MVA submerged arc furnace producing silicomanganese was excavated in South Africa. Since the high shell temperatures recorded in the tap-hole area resulted in the furnace being switched out for relining, the tap-hole area was excavated systematically. A refractory wear profile of the tap-hole area with affected hearth and sidewall refractory was obtained in elevation. The carbon ramming paste in front of, above, andbelow the tap-hole was worn, as was the SiC with which the tap-hole was built. A clay mushroom formed but was detached from the refractories. Thermodynamic and mass-transfer calculations were conducted to quantify the potential for wear by chemical reaction between refractory and slag and refractory and metal in the tap-hole area. It was found that chemical reaction between refractory and slag or metal could offer only a partial explanation for the wear observed; erosion is expected to contribute significantly to wear.

Jan 1, 2015

By L. A. Cornish

Pt-based alloys for high-temperature applications in aggressive environments have been under development for over 10 years, and are targeted to be used as either as bulk, or as coatings. The alloys comprise Pt, Al, Cr, and Ru, and the microstructure has been improved by composition to a best possible analogue of the nickel-based superalloys, which these alloys could partially replace. This was necessary because the previous best alloy had a strengthening precipitate volume proportion of only approximately 40 vol.%, whereas the nickel-based superalloys have around 70 per cent, and a lower volume would mean that the strength would not be the best that could be obtained. The microstructures were assessed using electron microscopy, and have been related to the alloys? hardness values. The current microstructures are much more like those of NBSAs, with a high proportion of the strengthening ~Pt3Al precipitates. Since the samples have to be small (platinum is expensive), hardness has been used as an indication of strength. Nano-indentation studies showed that the hardness and Young?s modulus were higher for ~Pt3Al than the (Pt) matrix. More extensive oxidation studies have been undertaken on the previous optimum sample, and the effect of cooling rate after heat treatment has also been ascertained. In addition, the samples were studied after different heat treatment times, and cross-sections were made in order to characterize the alumina scale that formed. The oxide scales of Pt-11Al-3Cr-2Ru (at.%) up to 100 h exposure did not spall, and were at least as good as those of the ternary alloys. There was no discernable Al depletion zone in the substrate, although it could have been at a greater depth than thickness of the samples studied. Further additions to the Pt-Al-Cr-Ru alloys have been studied, to increase the melting temperature as well as to reduce the platinum content without compromising the properties. Reduced platinum content would have the benefits of reduced density and cost. The target elements include vanadium and niobium, of which vanadium is of special interest, since it is a South African product. Before these additions could be made, phase equilibria studies were undertaken so that the maximum addition could be ascertained, and also to check any possible ternary phases, which could be deleterious. Work on the Pt-Al-V system revealed a ternary phase, ~V27Pt54Al19 (at.%), which has a eutectic reaction with (Pt). The maximum V addition is likely to be around 15 at.%, otherwise ~Pt3V or the ternary phase will form, and not the required (Pt)/~Pt3Al phases.

Jan 1, 2012

By D. Stone, M. Le Roux, Q. P. Campbell, M. Fofana

Float-and-sink analysis is widely used in the coal industry to obtain washability data, yielding important information about beneficiation potential and performance. This method is associated with health and environmental problems, and research into alternative densimetric methods is important. The RhoVol is a new technology developed by De Beers Group Technology South Africa (DebTech) for the image-based generation of densimetric data from ores. The analysis is done on a per-particle basis, within a size range of +3 mm –8 mm. In this paper we compare the established methods used for the float-and-sink analysis of coal with a new method using RhoVol. The aim of the study was to determine the validity of the information obtained from the RhoVol analyser by performing comparative densimetric analysis on three different coal samples. The results showed that the RhoVol method was more rapid, safe, and precise, but tended to consistently underestimate the density of the coal sample, probably due to varying coal porosity.

Oct 3, 2023

By R. Uwaoma, A. Goosen, R. Matjie, K. Mphahlele, J. Bunt

Coal properties that are associated with wear and damage of grinding equipment during pulverization prior to combustion were investigated. A South African Highveld feed coal and its beneficiated fractions were crushed to <1 >0.25 mm particles for the grindability tests. These particles were milled and screened into <75 μm and >75 μm fractions, which were analysed by different techniques to establish a correlation with the conventional Hardgrove Grindability Index (HGI). The <1.5 g.cm-3 float fraction, which contained 93 vol.% (mineral matter free) total -macerals,9% kaolinite, and had the lowest HGI (57) (hardest to grind) was pulverized for 15, 30, 60, and 120 minutes for particle size distribution analysis. This analysis indicated that the content of <75 μm particles increases with increased grinding time. The >1.9 g.cm-3 sink fraction, with the highest HGI (76), 44% kaolinite, and 20 vol.% total macerals, was ground easily to generate the highest proportion of <75 μm particles. Based on higher correlation coefficients (R2 = 0.77–0.91), the ash yield, mineral matter, petrographic composition, and fixed-carbon have significant effects on the HGI. Conversely, the inherent moisture and total sulphur (R2 = 0.48–0.62) have only minor effects on the HGI. Results from this investigation could be implemented in the preparation of a suitable pulverized fuel with little equipment wear, as well as utilizing mineralogical and petrographic compositions. Finally, the effect of microlithotypes and maceral types in South African feed coals on the HGI should be investigated in further pulverization and grindability studies.

Jul 5, 2023

By M. Kumral, S. Li, M. Balci, Z. Shao

Main haulage roads play an important role in the performance of underground mines because of the cost of transportation of the extracted ore, equipment, and workers. During mine development, these roads are designed through manual tools or CAD-based software. However, the optimisation of these roads is still a complex problem due to some constraints such as minimum turning radius and maximum gradient. By utilising Dubins path theory, three elevation cases; namely low, medium and high are defined, considering gradient constraint as well as the minimum turning radius in a three-dimensional space. The shortest path between two points can then be found by the three-dimensional Dubins path algorithm with elevation constraint. As a further step, a three-dimensional Dubins path algorithm with elevation constraint for multiple points is also developed for multi-point cases. The effectiveness of these algorithms is tested through case studies in order to determine the optimal path between different points.

Sep 1, 2021

By P. R. Jochens

South Africa depends to a considerable measure on the exploitation of mineral reserves and the processing of these minerals. One of the prime requirements for the mining and metallurgical industry to continue in this vital role is access to sufficient energy in a suitable form. Hence, four important questions are discussed: Does South Africa have sufficient energy for the processing of its minerals and metals! Will the cost of energy allow South Africa&apos;s minerals and metals to compete on world markets? Can mining and metallurgical processes become more energy-efficiency Can mining and metallurgical processes be adapted to the various forms of energy that may have to be utilized in the future? It is concluded that about 26 per cent of the extractable reserves of coal would be required in the mining and processing of 50 per cent of South Africa&apos;s reserves of gold, platinum-group metals, copper, iron, ferrochromium, and ferromanganese. However, the reducing agents required exceed the extractable reserves but not the total estimates of mineable in situ resources of metallurgical coal and anthracitic coal. Even under the severe constraint that coal could become virtually the sole source of energy, only about three-quarters of the extractable reserves of coal would have been consumed by the year 2025. The reasonably assured resources of uranium metal that can be recovered at less than $80 per kilogram are considerable and, at current conversion efficiencies to electricity, are equivalent to one-fifth of the extractable reserves of coal. The rate of exportation of energy in the form of U30. was about five times that of coal in 1978. It is pointed out that the price of energy has a direct effect on the competitiveness of metals, and, although constituting only a small proportion of the selling price of precious metals, it represents a significant proportion of the selling price of copper and metals recovered from oxide ores. The scope for the conservation of energy appears to be greater in the extraction and conversion of primary energy-carriers to electrical energy than in other mining or metallurgical fields. Provided that alternative sources of energy can be converted to electrical energy, they can be applied to the mining and metallurgical industries. The decision as to which type of energy should be used in specific mining and metallurgical situations is complicated, and is likely to be subjected to closer scrutiny than in the past. The hope is expressed that the tentative conclusions reached will give rise to more-quantitative analyses from those qualified to undertake such an exercise. Inevitably, the questions asked at the outset give rise to more questions, and the more interesting ones are posed in the context of each conclusion.

Jan 1, 1980

By S. T. L. Harrison, M. Smart, C. J. Edward

Biooxidation, a biohydrometallurgical process, utilizes a mixed microbial consortium to mediate the dissolution of refractory gold-bearing ores to enhance gold recovery during cyanidation. Recognition of water as a critical resource has prompted improved water management strategies within mining and minerals processing. Bioremediated wastewater from the cyanidation tailings provides a potential water source to supplement the water required for the biooxidation circuit, reducing freshwater extraction. Gold biomining operations have typically been reluctant to recycle this wastewater due to the potential inhibitory effects of cyanide and thiocyanate (SCN-) on the microbial population. Historical process upsets suggest that the microorganisms are sensitive to SCN- concentrations as low as 1 mg/L. However, effective bioremediation processes resulting in effluents with low or negligible SCN- concentrations may allow gold biomining plants the opportunity to recycle available water. Microbial activity as well as alteration in community structure were monitored as a function of increasing SCN- concentration over the range of 0 mg/L to 5 mg/L to investigate the response of the biooxidation community to potential SCN- spikes resulting from upsets in the remediation process. Appropriate microbial growth and ferrous iron oxidation activity with a nominal shift in community structure were observed at SCN- concentrations up to 1 mg/L. Thiocyanate concentrations above 1 mg/L resulted in the complete inhibition of ferrous iron oxidation activity. This was attributed to Leptospirillum ferriphilum’s sensitivity to SCN-. Exposure to a SCN- concentration of 5 mg/L resulted in a lower cell concentration and a significant increase in growth lag time, and the absence of L. ferriphilum from the microbial population. At. caldus and Ap. cupricumulans were still present at 5 mg/L SCN-, although Ap. cupricumulans was unable to oxidise ferrous iron at this SCN- concentration. It was concluded that recycling bioremediated cyanidation tailings wastewater within the biooxidation circuit is feasible; however, to retain process performance, SCN- concentrations should not exceed 1 mg/L. Keywords: Biooxidation, thiocyanate, water recycling, community structure

Jan 1, 2020

By L. Cheng, Y. Liu, Z. Shen, H. Shang, Y. Li

The pre-concentration process of magnetic coarse particles can discharge waste rock or liberated gangue before milling, which is an effective means to reduce cost and increase the efficiency of the concentrator, but the weakly magnetic ore doesn’t have the effective separation method of coarse particle such as hematite, limonite, ilmenite and so on, Because the composite iron minerals contain both strong and weak magnetic elements, the pre-concentration process cannot be applied, or the existing pre-concentration process has problems of complicated configuration and high operation cost. By researching a new type of external magnetic separation technology, the pre-concentration process of composite iron ore was realised by single equipment, which can have a good recovery rate with simple arrangement. In this paper, the separation principle and structure characteristics of the external magnetic separator were researched, and the magnetic circuit characteristics of the external magnet were analysed. The laboratory tests of vanadium titanium magnetite were conducted, and the test results proved that the external magnetic separator can be applied for the pre-concentration process. The industrial application shows that a product of TFe 24.76% with 90.08% recovery, TiO2 10.10% with 91.78% recovery can be achieved from the feed of TFe 20.67%, TiO2 8.33%. Keywords: Coarse particle pre-concentration, composite iron ore, external magnet, magnetic separator

Jan 1, 2020

By V. Borissenkob, L. D. Ropera, M. J. Danielc

Eccentric High Pressure Centrifugal Comminution (eHPCC) is a novel comminution device that provides a single step to achieve a desired target grind size. The mechanisms within the unit mirror particle breakage that is akin to high-pressure-grinding rolls (HPGR) and high-intensity-attrition with air classification. eHPCC receives lump and can produce a product P80 such that the progeny are at or less than natural grain size of the feed. The unit operates in either closed or open-circuit. The grinding zone is dry and free of steel grinding media. This paper presents evidence of eHPCC-2 capable of selective and preferential mineral liberation. A recent test campaign on a blend of underground quartzgold- vein ore was completed. The feed to eHPCC-2 trial was SAG mill trommel oversize (low-grade pebble rejects). eHPCC-2 operated open-circuit with air-fluidisation in the rotating-grinding-chamber, classifying particles based on terminal velocity of the air-swept product particles, displaying size and mineral composition classification taking place at the same time. There is an opportunity for future industrial research targeting eHPCC as an advanced integrated comminution and classification technology. Keywords: High pressure, high intensity, compression, attrition, comminution, classification

Jan 1, 2020

1. Mintek publications The folowing are available from Mintek (Private Bag X3015, Randburg, 2125 South Africa) at R35 (including GST) per copy to purchasers in South Africa and US$30 (including airmail postage) to purchasers elsewhere. Report M402 The preparation of synthetic fusion standards for use in the X-ray-fluorescence analysis of rocks and minerals, by RT. Eddy and J.J. Jacobs. Apr. 1990. 19 pp. Report M405 Slag-metal equilibria in the system Fe-Cr-Si-C-Ca-Mg-AI-O, by R.H. Eric and M. Akyizli. Aug. 1990. 29pp. Application Report no. 8 The development of a process for the recovery of gold from gold-bearing solutions by means of activated carbon or resin in a NIMCIX column. 1990. 19 pp. 2. New publications from Trans Tech The folowing are available from Trans Tech Publications Ltd, Old Post Road, Brookfield VT05036, USA. Efect of iron and silicon in aluminium and its aloys, edited by I. Kovacs. 1990. 450 pp. $124. Martensitic transformations, edited by B&apos;.C. Muddle. 1990. 714 pp. $190. Ferites, edited by C.M. Srivastava. 1989. 2 vols. 1280 pp. $254. Properties and characterization of amorphous carbon films, edited by J.J. Pouch and S.A. Alterovitz. 1990. 714 pp. $152. Synthesis and properties of boron nitride, edited by J.J. Pouch and S.A. Alterovitz. 1990.426 pp. $192. Electronic structure and latice defects in aloys, edited by R. W. Siegel and F .E. Fujita. 1989. 320 pp. $78. 3. A new edition Tomorow&apos;s materials, by K.E. Easterling. London, The Institute of Metals (1 Carlton House Terace, London SWIY 5DB, England), 1990. 2nd ed. 170pp. US$29. 4. Books for exploration geologists The folowing books are obtainable from Elsevier Science Publishers, P .0. Box 211, 1000 AE Amsterdam, The Netherlands. Lateritic bauxites, by G. Bardossy and G.J.J. Aleva. 1990. 624 pp. DFL. 295. Platinum-group element exploration, by D.L. Buchanan. 1988. 186pp. DFL 150. Lead isotopes in mineral exploration, by B.L. Gulson. 1986. 246 pp. Dfl. 160. Prospecting and exploration of mineral deposits, by M. Kuzvart and M. B6hmer. DFL. 285. 5. Journal for earth scientists . Ore Geology Reviews, published by Elsevier Science Publishers, P.O. Box 211, 1000 AE Amsterdam, Netherlands. 6 issues per year. Annual subscription DFL 453 including postage.

Jan 1, 1990

By N. Hamlef

In this study, the effects of heat treatment on phase formation and surface morphology of the Cr-Pt coated system are investigated using X-ray diffraction and electron microscopy techniques. The CrPt andCr4Pt (Cr3Pt - A15 type) phases were formed after heat treatment of the coated samples. Heat treating at 1000°C renders a distinct island coating morphology that is non-continuous in nature. A diffusional model is proposed for this coated system with regards to the surface morphology formation after heat treatment.

Jan 1, 2014

By D. Minson, G. Lindner, S. Miskovic

Thickening is an essential process in the mining industry and currently one of the most costeffective technologies for recovering water from tailings streams. Improved performance of thickeners can lead to significant energy savings, and increased recovery of water close to the mill. Its performance is directly affected by the rheological properties of slurry at the raking zone. To further understand the dynamics of slurry inside thickeners, a multiphase particle-in-cell method (MP-PIC), is used to investigate its behaviour on a sliding channel. Parameters like particle-size distribution (PSD), rheological properties, and domain discretisation were benchmarked to study its influence on highly dense flows. The slurry concentration by weight of the samples ranged between 60 to 70% of solids by mass, under which conditions it is known to behave like a non-newtonian fluid. An experimental flume, 0.2 m wide and 2 m long, was used for validation under different angles and slurry composition. Visual analysis of the slurry height and shape, as well as velocity measurements, were compared with numerical data. The preliminary results show the ability of MP-PIC method to represent different types of highly dense flows, while still being computationally affordable and practical for industrial use. Keywords: High density thickener, CFD, MP-PIC, multiphase-flow

Jan 1, 2020

By R. Altındag, D. Akbay

The point load index is a simple, fast, and inexpensive method for determining rock strength and can be applied both in the field and in the laboratory. There are, however, some disadvantages and limitations to the method, and the test results can be affected by the person carrying out the test, the rock characteristics, or the test device. In this study we describe an investigation into how the point load index value is affected by the shape of the conical platens used in the test. Point load index tests were carried out using different devices fitted with conical platens of different spherical radii, and on a modified device which circumvented the limitations/disadvantages. It was seen that the point load index value increased as the platen radius increased, as expected. In the case of testing using non-standard conical platens, an equation is proposed to normalize the point load index value with respect to the standard spherical radius value.

Nov 1, 2021

By P. de A. Barbosa, M. G. Bergerman, E. da Fonseca

Located in the state of Pará, Brazil, the Sossego copper and gold mine consists of a heterogeneous geological deposit. Its complexity derives from the hydrothermal alteration, the ore-forming event, which modified the host rocks, such as granite, and metamorphosed volcanic rocks into several mineral assemblages. Different mineral assemblages have led to differences in abrasiveness. A few Bond abrasion tests conducted during the mine feasibility study did not provide a robust abrasiveness database, thus the variation of physical properties for some mineralisation host rocks was not possible. Although several test methods may be used to determine ore abrasiveness, the Bond method is the one most commonly used in the mining industry. Despite being simple to carry out, this test method has certain limitations as to particle size and the amount of ore sample required, which often makes it difficult or even impossible to apply in the early stages of a project and in geometallurgical studies. The Laboratoire Central des Ponts et Chaussées (LCPC) test may provide an alternative, as it requires a smaller amount of fine-grained material. This study aimed to provide data on wear properties of various ore types from Sossego mine using the LCPC method. It included validation for 40 different ore samples using the Bond test as a benchmark. The results showed good correlation, indicating it may be possible to use the LCPC test as an alternative to the Bond abrasion test. A high abrasiveness index was found for acid metavolcanic rock, confirming the results observed in Sossego mill’s operating database, pointing to a mineralogical drive to amorphous quartz. Keywords: Abrasiveness, geometallurgy, copper ore, Bond abrasion test, LCPC

Jan 1, 2020

By A. F. Lee

Dr E. C. Hanekom (Visitor): Two years ago we used the bubble pick-up technique as developed at Anglo American Corporation for screening candidate flotation agents prepared in our laboratories. It was obviously necessary to know to what extent the technique gave reproducible results and a statistical evaluation of the test method was made using a mineral sample provided by Anglo American Corporation. A bubble of 2.0 mm diameter was used and the measuring graticule was divided into squares (units) with sides of 5.0 mm at 25 X magnification. The mineral granules had diameters from 53 to 74 mm. The bubble was loaded by depressing it against a layer of mineral grains to give an arbitrary but constant compression of 0.4-0.5 mm. It was rolled five times through 2 mm horizontal displacement. The bubble was then lifted, its load compacted by gently stirring and the projected area measured in squares (units) on the grid. Each substance was tested at 5 ppm concentration in distilled water at five points in the pH range 3-6. With these standardized conditions of operation the reproducibility of the test was studied. Four materials were tested and at each pH value the procedure of forming a bubble, picking up granules and counting the units was repeated ten times. From these results the standard deviation for a single count at any pH value was calculated for each material (Table 1. The coefficient of variation of approximately 3 per cent was relatively low and it was decided that further refinements in the counting procedure would be of doubtful benefit with the present apparatus. Similar experiments were carried out with 12 sample materials. In this case the bubble formation and pick-up were repeated four times at each pH value, the mean value was calculated for each set of four observations and final pick-up values for the materials were obtained by selecting the highest mean count. Each test was completely repeated a number of times as indicated in Table 2 and the standard deviation calculated. The results allowed the selection of the more promising materials and the rejection of poor performers at the 95 per cent confidence level. All tests were carried out by one operator. Some evidence was obtained that the method is sensitive to operator bias. In conclusion it can be said that from all the results analyzed it would appear that once operation conditions are fixed (viz operator, pH control) the precision of the method is adequate. The author wishes to thank Messrs African Explosives and Chemical Industries Limited for permission to publish these data. G. S. Stander and C. J. Kooij (Visitors): We must congratulate Mr Lee for this most interesting and useful development of the pick-up experimental method. It certainly provides research workers with an instrument which makes flotation more of a science and less of an art. We visited Mr Lee at his laboratory where he gave us a demonstration of the bubble pick-up instrument and technique as developed and improved by him.

Jan 12, 1969

By Z. Tshentu, M. Ngayek, P. Moleko-Boyce

This paper is focused on the development of iridium(IV)-specific quaternary diammonium cations containing electron-donating substituents in the benzyl group of methyl and electron-withdrawing substituents such as triflouromethyl and nitro groups. Quaternary diammonium cations used were tetra- 4-methylbenzyl-1,10-diammonium decane chloride (QuatDMDAMeBnz), tetrabenzyl-1,10- diammoniumdecane chloride (QuatDMDABnz), tetra-3-trifluoromethylbenzyl-1,10- diammoniumdecane chloride (QuatDMDACF3Bnz) and tetra-4-nitrobenzyl-1,10-diammoniumdecane chloride (QuatDMDANO2Bnz). Polyvinylbenzylchloride (PVBC) nanofibres were used as support material, and the functionalised nanofibres were used for separation of Ir(IV) from Rh(III). The sorbent materials were characterised by FTIR and elemental analysis. The efficiency of the quaternary diammonium cations was investigated in a column study under dynamic flow adsorption conditions. Column sorption of [IrCl6]2- and [RhCl5(H2O)]2- on nanofibres functionalised with diammonium cations showed [RhCl5(H2O)]2- was not adsorbed by the sorbent materials while [IrCl6]2- was loaded onto the column. The loading capacities of [IrCl6]2- on the quaternary diammonium sorbent materials increased in the order of F-QuatDMDAMeBnz (3.08 mg/g) < F-QuatDMDABnz (3.39 mg/g) < FQuatDMDACF3Bnz (5.46 mg/g) < F-QuatDMDANO2Bnz (7.10 mg/g). The loading capacity for Ir(IV) with quaternary diammonium cationic nanofibres increased with an increase in the electron-withdrawing nature of the substituent on the quaternising group. The charge delocalising ability of the 4-nitrobenzyl group resulted in the best interaction of the decamethylene diammonium cation with [IrCl6]2-. Keywords: Iridium(IV), rhodium(III), quaternary diammonium, polymer nanofibres, separation

Jan 1, 2020