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By Raymond B. Ladoo

Silica , or silicon dioxide , ( Si0, ) , occurs in a free state chiefly as quartz , but hydrous silica ( amorphous silica carrying a variable amount of combined water , 2 to 13 per cent ) , occurs as opal , flint , diatomaceous earth , tripoli and so on . Quartz is found in many forms , the most important of which are ; As vein quartz; quartzite ; sandstone ; silica sand and gravel ; as crystals or crystalline grains , masses or aggregates in igneous rocks such as granites , dicrites and pegmatites . Commercially silica is used in many ways , but ordinary uses of sand and gravel are so well known that they will not be considered here .

Jan 1, 1922

By Rudolf Kudlich

"SUMMARYThe Ringelmann Smoke Chart fulfills an important need in smoke abatement work and certain problems in the combustion of fuels. A knowledge of its history and method of preparation is, therefore, of interest to many. Since instructions on its use are not shown on the recent edition of the chart, those included in this revision of the previous information circular, by Rudolf Kudlich, now are a necessary complement to the chart. More detail regarding the use of the chart is included than was given in the earlier manuscript.INTRODUCTIONThe Ringelmann Smoke Chart, giving shades of gray by which the density of columns of smoke rising from stacks may be compared, was developed by a Professor Ringelmann of Paris. Maximilian Ringelmann, born in 1861, was professor of agricultural engineering at l'Institute National Agronomique and Director de la Station d'Essais de Machines in Paris in 1888, and held those positions for many years thereafter.The chart apparently was introduced into the United States by William Kent in an article published in ""Engineering News"" of November 11, 1897, with a comment that he had learned of it in a private communication from a Bryan Donkin of London. It was said to have come into somewhat extensive use in Europe by that time. Kent proposed in 1899 that it be accepted as the standard measure of smoke density in the standard code for power-plant testing that was being formulated by the American Society of Mechanical Engineers.The Ringelmann Chart was used by the engineers of the Technologic Branch of the Federal Geological Survey (which later formed the nucleus of the present Bureau of Mines) in their studies of smokeless combustion beginning at St. Louis in 1904, and by 1910 had been recognized officially in the smoke ordinance for Boston passed by the Massachusetts Legislature."

Apr 1, 1955

By Isaac A. Zlochower

This paper presents data on the limiting (minimum) oxygen concentration (LOC), in the presence of added N2, of methane (CH4), propane (C3H8), ethylene (C2H4), carbon monoxide (CO), and hydrogen (H2), and some of their binary mixtures. It also addresses the issue of the flammable concentration (flammability) limits of these pure gases in air. The study is based on spark ignited explosions in large, spherical laboratory vessels (120-L and 20-L) using a 7% pressure-rise criterion for explosion propagation. The results of the study are compared with the older values which used long flammability tubes with a diameter >5 cm together with visual evidence of substantial upward propagation. They are also compared to results reported recently using a 12-L spherical flask with a visual flame propagation criterion. Finally, they are compared to results reported in Europe using more modest flammability criteria and smaller chambers. The findings reported here show excellent agreement between the 120-L and 12-L results, good agreement with the 20-L results, and reasonable agreement with the earlier flammability tube values for the lower flammability limits. They disagree, however, with the more conservative European values. These results and those from the 12-L experiments also feature lower LOCs than are given by traditional flammability tubes. A model for the LOCs of such fuel mixtures based on the Le Chatelier mixture rule for lower flammable limits is seen to reasonably fit the observed results on binary mixtures and can accommodate more complex mixtures as well. One such set of ternary mixtures containing CH4 and 1:1 CO:H2 is well fitted by the model.

Jan 1, 2009

By RV. Ramanl, KV. K. Prasad, M. Swaminathan

The objective of the research in this project is to develop a knowledge based expert system for aiding the planning of mine ventilation systems. This system focuses on mine ventilation system design from a coal mine dust control standpoint. It is recognized that mine ventilation system design is an engineering problem involving not only rote numerical calculations to solve the pressure quantity problem but also substantial judgement and expertise to analyze a problem situation and Interpret the results of an algorithmic program. The thrust of this project is to i) extract this knowledge from public domain sources and recognized experts in industry, government and academia, 11) represent this knowledge in the form of IF ... TI-IEN rules in an expert system (ES) and 111) interface the developed expert system with a mine ventilation network analysis program vis. PSUMVS (Pensylvania State University Mine Ventilation Simulator). By providing the numerical computing and qualitative reasoning aspects of mine ventilation system design in a single Integrated system, better quality decision support will be made available to apprentice users.

Jan 1, 1988

By J. M. Stuve

This Bureau of Mines investigation measured the low-temperature heat capacities of FeOC1(c) and FeC13(c) in the temperature ranges of 6 to 305 K and 4.6 to 300 K, respectively. The standard entropies (S°, 298.15 K) of FeOCl(c) and FeC13(c) were derived as 19.73±0.03 cal/deg-mole and 35.33±0.07 cal/deg-mole. A large lambda transition was observed in the heat capacity of FeC13(c) at 8.4 K. The standard enthalpy of formation (?H°f, 298.15 K) of FeOC1(c) was determined to be -98.23±0.22 kcal/mole by HC1 solution calorimetry. High-temperature enthalpy measurements (H-H298.15) of FeOC1(c) were determined to 700 K by precision drop calorimetry. Standard thermodynamic formation data and related functions were tabulated at various temperatures for FeOC1(c) and FeC13(c).

Jan 1, 1980

By Terry J. Close

In 1992, as part of the U.S. Bureau of Mines Idaho Land Assessment Program, the Western Field Operations Center investigated the mineral resources of the 30,300-hectare Elk Summit study area. The area is in the Clearwater National Forest, adjoining the Selway-Bitterroot Wilderness in Idaho County. Idaho. The study area is underlain by granitic and metasedimentary rocks. Associated with these rocks are road metal (stone) resources, black sand mineral placer resources, and thermal water resources. Also present are abundant sand and gravel. Two of the five sites examined during the Bureau study have road metal (stone) resources, one has black sand mineral resources, one has thermal water resources. The fifth site is a black sand mineral placer occurrence. There is no evidence of petroleum or coal resources. Idaho County records indicate that 38 mining claims, mostly black-sand placer, have been located in the study area, Twenty-three of the claims are current. Workings consist of a few pits and trenches at the placer, and two borrow pits. The only mineral commodity produced from the area was about 1,500 tonnes of stone excavated from the Savage Pass and Swamp Creek borrow pits along the Elk Summit road, north of Hoodoo Lake. The stone was used to surface the road; these stone resources will continue to be used as needed.

Jan 1, 1993

By D. Eugene Rannels, Yu-Chen Lee, John W. Swisher

"Inhaled dust particles of appropriate size contact cells of the alveolar region.' The acute response to coal dust appears to involve a variety of cell types, including alveolar epithelial cells, interstitial fibroblasts, both resident and recruited macrophages, and cells of the immune system. Direct and indirect effects of dust, which may be mediated by soluble factors,'' can initiate acute and long-term lung injury. While it appears that epithelial cell growth and differentiation, along with integrity of the epithelial basement membrane, may play a role in the long-term response to dust exposure, little is known of the role the alveolar epithelium may play in the progression of injury. The broad hypothesis that underlies these experiments is that short- and long-term consequences of coal dust exposure involve changes in structure and function of the alveolar epithelium and the underlying extracellular matrix. Recent studies show that coal dusts exert direct effects to modify pulmonary epithelial cell-extracellular matrix interactions in vitro.3EXPERIMENTAL PROCEDURESType II cells isolated on day 0 by density centrifugation and differential attachment4 were plated overnight in D MEM containing 10% fetal calf serum before exposure to anthracite dust PSOC 867 sonicated into culture medium (750 ug/mL).3 Synthesis of extracellular matrix proteins was determined on day 3 of primary culture, as detailed elsewhere. 5 Cells were removed from extracellular matrix by extraction with NH4OH and high salt. Extracellular matrix synthesis and fibronectin content were evaluated based on radiolabeling with 3 H-leucine and on Western blot analysis, respectively. Additional analytical methods and calculations are detailed elsewhere.3-5"

Jan 1, 1998

By J. D. Spagnola

The Bureau of Mines conducted research to obtain comparative data on the extent of reduction of galena and sphalerite with molecular hydrogen and with hydrogen from the thermal cracking of ammonia and methane at various time intervals. Galena reductions of 95 to 99 percent were obtained with H2 and with decomposed NH3 while reductions of 70 to 80 percent were obtained with cracked CH4? Sphalerite reductions of 99 percent were obtained at 1,000° C with Hz and with decomposed NBs; however, complete volatilization of the free zinc from the remaining concentrate and the subsequent recombination of zinc and sulfur vapors resulted. A promoted iron catalyst brought about a decrease of 100° C in the temperature required for complete decomposition of ammonia. It was found that H2S retards NB3 decomposition and that nitrogen retards the reduction of galena by H2? A mixture of N2 and He in about the same ratio as that obtained by the thermal cracking of NBs gave about 15 percent less reduction of galena than was obtained with decomposed NB3; this indicates that a portion of the hydrogen obtained by NBs decomposition is in an active form.

Jan 1, 1965

By Mary H. Brown

The heats of formation of oxalic acid and sodium, potassium oxalates, and lithium oxalates were related by solution calorimetry to the heat of formation of (COOH)2.2H20, a value believed to be reliable as reported in the literature. The following heats of formation were determined: (COOH)2(a), -198.1±0.1; (COOH)2(ß), -197.8±0.1; UAW,, -328.7±0.4; Na2C204 -316.2±0.1; K2C204, -321.9±0.2; and K2C204-H20, -393.5±0.2 kcal/mole. The heat of the crystalline transformation (COOH)2(a) ? (COOH)2(ß) was determined to be 0.30±0.02 kcal/mole at 298.15° K.

Jan 1, 1970

By K. D. Plants, J. H. Holden, L. F. Willmott

Pulverized high- volatile A bituminous coal was gasified with oxygen and superheated steam in a pressure - gasification pilot plant equipped for steampickup feeding . The pilot plant operated satisfactorily at relatively high steam- to - coal ratios , but steam- to - coal ratios could not be reduced much below 0.5 lb / lb without condensation of steam or softening of the coal . Carbon gasified , gas composition , and coal and oxygen requirements were essentially the same as for a pilot plant equipped with a fluidized coal feeder . Average results from the pilot plant equipped for steam- pickup feeding were coal requirement , 37.3 lb/M ( 1,000 ) scf of CO + H₂ produced ; oxygen requirement , 358 scf /M scf CO + H₂ produced ; and carbon gasified , 87.7 percent .

Jan 1, 1964

By W. A. Jacob, E. W. Dean

The Pittsburgh petroleum laboratory of the Bureau of lines has recently developed an improved method for the determination of water in pctroleum emulsions. It has been described in detail in an article entitled "A convenient method for the determination of water in petroloum and other organic emulsions" by E. W. Dean and D. D. Stark (Jour. Ind., and Enc. Chem. Vol. 12, ſay, 1920, page 436). It is essentially a modification of the familiar procedure of "distillation with an iniscible solvent", the improvement consisting in the use of apparatus that is rºck more convenient than any previously employed. The method has been used with marked success in the Bureau's laboratories for a period of about a year and has also been tried with equal satisfaction by a number of other laboratories. It has been most extensively employed for determining the water content of heavy fuel oils but has been applied also to several other types of emulsions, including shale oils, tars derived from coal, greases, and mixtures of powdered coal, oil and water. The Bureau has received a number of requests for information regarding commercial sources for the apparatus used, and having been assured of the value of the method, has taken steps to render it available for general use. - The equipment is, with the exception of two items, made of parts that are obtainable from the ordinary stock of chemical supply houses. The two exceptions are (1) the so-called "distilling tube receiver" and (2) the electric heater. The former is an essential part of the equipment; the latter is a convenient ac cessory but it can if necessary be roplaced by a gas burner. Efforts on the part of the Bureau staff to ronder these two items of apparatus available for purchase from supply houses, or for production by the user are hero described.

Sep 1, 1920

By Ronald D. Hill, Elmore C. Grim

The removal of overburden often exposes pyritic materials (iron disulfide). As shown in equations 1 and 2, the oxidation of this material results in the production of ferrous iron and sulfuric acid. The reaction then proceeds to form ferric hydroxide and more acid, as shown in equations 2 and 4. [ ] Consequently a low pH water is produced (pH 2-4.5). At these pH levels, the heavy metals such as iron, manganese, copper, and zinc are more soluble and enter into the solution to further pollute the water. Water of this type supports only limited water flora, such as acid-tolerant molds and algae; it will not support fish life, destroys and corrodes metal piers, culverts, barges, etc., increases the cost of water treatment for power plants and municipal water supplies, and leaves the water unacceptable for recreational uses. The amount, and rate of acid formation, and the quality of water discharged are a function of the amount and type of pyrite in the overburden and coal, time of exposure, characteristics of the overburden, and amount of available water(l). Crystalline forms of pyritic material are less subject to weathering and oxidation than amorphic forms. Since oxidation by oxygen is the primary reaction during early acid formation, the less time pyritic material is exposed to air, the less acid is formed. Thus, a positive preventative method is to cover pyritic materials as soon as possible with earth, which serves as an oxygen barrier. In terms of mining, this step is accomplished by current reclamation techniques and small open pits.

Jan 1, 1974

By F. W. Davis

For some years this subject has been of interest to metallurgists. Previous to the War some work was done in :Belgium. on the enrich.ntSnt of the blast with oxygen i.."'l. connection with the smelting of iron orei.; in the blast furnace. In the United States, the late .J. E. ,Joh."lson, .Jr., \ve.s :interested in the possible use of 0J1.:ygen for metallurgical operations ar.:i cerried on some experic:.ental work along these lines pre..,,-ious to his de.e.hft Dr. F. G. Cottrell, formerly Director of the :Bureau of Mines, De7?,H''(;:,-of,,:a:t: of the Interior, and now Direc'cor of the Fixed lifi trogen Itesearc:l-1 La -:c r;a.-o='Y, Depart­ment of .Agriculture, first directed. the Eurec:ru 1 s attention to this subject. When it first began this work, the Director of the Burea.t1. of Mines, beca11se of his interest in this investigatio:::i, asked :Mr. M. H. Roberts: Vice-President of the FraU:din Railway Supply Company to select an Advisory Corr:nittee to work with the BJ::eau on tl1is subject; it also asked Mx-. Robez·ts to act as Cha.irman of this C<)1.,_1l!lHtce. T!le personneJ. of the Comrnitee which was selected. by r. Roberts is as follows:

Jul 1, 1923

By Gary L. Mowrey, William D. Monaghan, George F. Persetic, Gregory M. Molinda

Ground penetrating radar (GPR) has been investigated by the U.S. Bureau of Mines Pittsburgh Research Center for its potential to determine rod hazards in underground mines. GPR surveys were conducted at four field sites with accompanying ground truth to determine the value of GPR for roof hazard detection. The resolution of the current systems allows detection of gross roof fractures (>6A mm (>0.25 in) zone) or rider beds in coal measure roof. Data quality is not yet sufficient to detect small bed separations or subtle lithologics changes in the roof. Differences in data quality are discussed, as well as suggestion for collecting improved data.

Jan 1, 1996

By Ε. P. YoUNGMAN

This paper presents one of a series of digests of foreign mining legis- lation and court docisions that is being prepared in advance of a general report relative to the right of American citizens to explore for minerals and to own and operate mines in vericis foreign countries. This interpretation of the laws - of Italy has been prepared, in part, from an aclysis made by John W. Frey, for merly associate mineral economist, U. S. Bureau of Mines. It incorporates addi- tional data and comments offered by Enrico Giobbe Della Pitta, a well-known Italian lawyer, in response to a questionnaire. These comments were forwarded by Harold H. Tittmann, American chargé d'affaires ad interim, at Rome, and trans- mitted to the Bureau of Mines through the courtesy of the Department of State.

Oct 1, 1930

By R. L. Hopkins, H. T. Rall

A continuous method has been developed for preparing thiolacetic acid . Acetic anhydride and hydrogen sulfide are passed concurrently over an amine ion- exchange resin , under 20 - psi pressure . The thiolacetic acid , a product of the reaction , is flashed continuously from the crude reaction mixture and is purified by fractional distillation . The yield of thiolacetic acid is in excess of 80 percent based on the acetic anhydride charged . INTRODUCTION In the synthesis of reference compounds needed in the identification of sulfur compounds in petroleum , thiolacetic acid has become an important reagent because of its use in the synthesis of thiols by addition to appropriate olefins : R - CH = CH₂ + CH3 - COSH R- CH2 - CH2 - S - COCH R - CH2 - CH₂ - SH + CH3COONa NaOH (1 ) The commonly used procedures for its preparation , as described by Clark and Hartman (1 )4 and by Ellingboe (2 ) , are based on the batchwise reaction of acetic anhydride with hydrogen sulfide :

Jan 1, 1964

By M. J. Ferrante

Low-temperature heat capacities and high-temperature enthalpies were determined calorimetrically for Na2Cr04, A reversible transition was found at 700° K with an isothermal heat of transition of 2,263 cal/mole. High-temperature X-ray diffraction analysis showed that the transition was a crystal change from the low-temperature orthorhombic form to the high-temperature hexagonal form. At 795° K the hexagonal form had the parameters a, = 5.691 and co = 7.478 A. Powder diffraction data for the high-temperature form are given and possible structures discussed. The melting point was determined to be 1,065° K with a heat of fusion of 5,810 cal/mole. Enthalpy and entropy increments from this investigation were combined with other data from the literature to calculate enthalpies of formation, free energies of formation, and equilibrium constants of formation from 298° to 1,400° K. Equations that represent enthalpies above 298° K are given.

Jan 1, 1972

By Thomas V. Falkie, R. Venkataramani

Anderson, L. B., 1963, "Multiple Regression Techniques Correlate Experimental Data," Chemical Engineering, V. 70, N. 12, pp. 223-228. Aubert, E. J., Lund, I. A., and Thomasell, A. J., 1959, "Some Objective Six-Hour Predictions Prepared by Statistical Methods," Journal of Meteorology, V. 16, pp. 436-46. Barrett, A. L., 1958, "Alternating Current in Continuous Mining," Mechanization, V. 22, N. 9, pp. 83-86. Bower, A. B., Jr., 1970, "Bit Design: Key to Coal Cutting," Coal Age, V. 75, N. 7, pp. 70-72. Bower, A. B., Jr., 1971, Personal Communication dated April 29, 1971; General Electric Company, Mining and Metallurgical Products Department, Detroit, Michigan. Burt, C., 1950, "Group Factor Analysis", British Journal of Statistical Psychology, V. 3, pp. 40-75. Cady, L., Gertler, M., Gottsch, L., and Woodbury, M., 1961, "The Factor Structure of Variables Concerned with Coronary Artery Disease", Behavioral Science, V. 6, pp. 37-41. Cattell, R. B., 1965, "Factor Analysis: An Introduction to Essentials I. The Purpose and Underlying Models," Biometrics, V. 21, N. 1, pp. 190-215. Christensen, R. W., Heins, R. W., Babcock, W., and Tonn, R., 1971, "The Effect of Material Properties on Materials Handling Processes," Six Month Technical Report, (August 1971) to Advanced Research Projects Agency, U. S. Department of Defense; The University of Wisconsin. Collins, G., 1961, "Factor Analysis," Journal of Advertising Research, V. 1, N. 5, pp. 28-37. Cooley, W. W., and Lohnes, P. R., 1962, Multivariate Procedures for the Behavioral Sciences, New York: John Wiley and Sons, Inc. Cree, J. 0., 1956, "Power for Continuous Mining," Mining Congress Journal, V. 42, N. 10, pp. 49-52. Draper, N. R., and Smith, H., 1966, Applied Regression Analysis, New York, John Wiley & Sons, Inc. Griffiths, J. C., 1966, "A Genetic Model for the Interpretive Petrology of Detrital Sediments," The Journal of Geology, V. 74, N. 5, pp. 655-672.

Jan 1, 1972

By D. Harrington, F. E. Cash

For a number of years the efforts of the coal -mining industry , as well as of the Bureau of Mines , have been directed largely towards the limitation and prevention of explosions in coal mines . The origin of most explosions is ignition of methane or marsh gas , but the extent and violence of these explosions depend chiefly on the combustible dust present . The Bureau of Mines has conducted a large number of tests on the use of incombustible materials in limiting or preventing widespread explosions . The result of these tests , published in Bulletins 167 and 268 and Technical Paper 386 , proves that incombustible dust can be so applied and maintained in coal mines that the ignition of the mixture of incombustible and combustible dusts , or the propagation of flame by the dust mixture , is impossible ; on the other hand , experience and experiment indicate that watering methods are not reliable as a preventive of general or widespread coal-mine explosions . This report describes the use of " mudite , " a mixture of water and finely divided incombustible soil or dirt applied in some coal mines as a means of attempting to limit or prevent widespread explosions .

Jan 1, 1929

By Robin B. McCulloch

No producing mines are in the study area. Sample results indicate the only resources in the study area are low grade phosphate deposits associated with Cuyama Phosphate Mine (fig. 1). Within the study area, are more than 21.4 million tons of inferred subeconomic phosphate rock resources which would be reserves at an 80 percent higher phosphoric acid price; weighted average grade is 4.84 percent phosphorous pentoxide (P205). About 17.6 million tons of similar grade are outside the area to the northwest. The South Cuyama Oil Field, adjacent to the study area (fig. 1), produces petroleum from the Vaqueros Formation which underlies parts of the study area. Oil and gas potential was evaluated by U.S. Geological Survey. INTRODUCTION Location, Size, and Geographic Setting The U.S. Bureau of Mines conducted a mineral survey of the Fox Mountain RARE II area (No. 5120) during the summer of 1981. The area was examined to determine the presence or absence of mineral resources and reserves, and to estimate tonnage and grade where possible.

Jan 1, 1982