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By F. R. Lee

This publication lists permissible equipment approved by the Bureau of Mines during 1965 and 1966 (calendar years), except for breathing apparatus and explosives. The purpose of this publication is to inform the public about approved equipment for safe use in underground mines.

Jan 1, 1968

By C. A. Komar

The Bureau of Mines has undertaken an investigation to determine possible applications of acoustic energy at sonic and ultrasonic frequencies to improve ultimate recovery from oil reservoirs. A literature search was conducted to provide background information for initiating laboratory research. The purpose of the literature search was to review the uses that have been made of acoustic energy in the petroleum industry and to select procedures and techniques that could be applied to the solution of petroleum production problems. The characteristics (68)3 of ultrasonic energy make it potentially useful to a variety of industrial and experimental applications. Pulse techniques (99) are common in the testing of materials where inspection is accomplished by propagating an ultrasonic pulse through the material. Viscosity measurements (45) are made by interpreting changes in the absorption of sound as it is propagated through a flowing liquid. Cavitation phenomena (93) produced by high-intensity ultrasound in liquids have been used extensively in industrial cleaning, machining, impact grinding, and aluminum soldering operations.

Jan 1, 1963

By Walter Kawa

The hydrogenation of phenyl ether, benzyl ether, and phenyl sulfide in the presence of iron catalysts was studied by the Bureau of Mines to gain a better understanding of the role of iron catalysts in the hydrogenation of coal. The carbon-oxygen and carbon-sulfur bonds in these compounds may be similar to some of the carbon-oxygen and carbon-sulfur bonds in coal which react during the early stages of liquefaction by hydrogenation. Experiments were made in batch autoclaves for 4 hours; hydrogen was at a pressure of about 540 atmospheres. In the hydrogenation of phenyl ether at 400° C, metallic iron catalyzed both hydrogenolysis (splitting-hydrogenation) and nuclear hydrogenation (addition of hydrogen to aromatic rings) reactions, Products were principally benzene and cyclohexane. The activity of metallic iron was decreased by adding carbon monoxide or a reactive sulfur-containing organic compound. Ferrous sulfide catalyzed the conversion of phenyl ether to benzene, phenol, and small amounts of cyclohexane. Hydrogenolysis of benzyl ether was catalyzed by metallic iron and to a lesser extent, by ferrous sulfide at 250° C. No nuclear hydrogenation was observed with either catalyst. Conversion of phenyl sulfide to benzene was nearly quantitative in experiments made at 250° C with equimolar quantities of phenyl sulfide and metallic iron or iron as ferric oxide. Conversions of metallic iron and ferric oxide to ferrous sulfide were nearly stoichiometric. No reaction of phenyl sulfide occurred in the presence of ferric oxide and water, and very little occurred in the presence of metallic iron and water. Ferrous sulfide also catalyzed the hydrogenolysis of phenyl sulfide to benzene, but conversion was lower than in experiments with metallic iron or ferric oxide. The activity of ferrous sulfide was increased by adding water and decreased by adding hydrogen sulfide. The results of this study suggest that ferrous sulfide is an active form of iron when iron is used as a catalyst for the hydrogenation of coal.

Jan 1, 1963

By E. O. Wagner, Manuel Gomez, W. S. Landers

The Bureau of Mines studied coking rates of a special Columbia - Geneva six - coal blend to establish the effect of the coking rate on coke properties . The tests were conducted in a 500 - lb , 14 - in experimental slot oven at essentially constant conditions of blend composition , size distribution , surface moisture content , and bulk density . The coking rate was varied as a function of oven flue temperature . Coking rates within the range of 0.56 to 1.35 in/hr were achieved . Increase in the coking rate decreased the size of the coke . The stability factor of the coke showed no significant change with coking rate until coking rates greater than 1.0 in/hr were reached , after which a decrease in the stability factor was observed . The apparent specific gravity increased to a maximum value at coking rates approaching 1.1 in/hr and decreased sharply with further increase in the coking rate . Coke parameters correlated well with the coking rate .

Jan 1, 1963

By G. S. Scott, G. W. Jones

"INTRODUCTION An important phase of the accident-preventing program of the Bureau Mines is the determination of the explosion hazards of various combustible gases, vapors, and liquids encountered in mining and allied industries and the development of methods of eliminating or mitigating them.Recently, isobutane has become a commercially important raw material in the production of aviation gasoline by the alkylation process. 4/ in which isoparaffins are combined with olefins to give higher molecular weight compounds of branched-chain structure.Because of the anticipated commercial importance of isobutane in industry, it has been deemed necessary to study and determine its general explosion haz¬ards. This report gives its limits of inflammability, minimum ignition temper¬atures, and the amounts of nitrogen and carbon dioxide required to render isobutane-air mixtures noninflammable."

Jun 1, 1947

By W. H. Young

The thickness of the coal seam is one of the more important items influencing the productivity and general overall efficiency of operation 1 of a coal mine. The average thickness of coal seams mined in the United States decreased 2 inches between 1950 and 1955 to an average of 62 inches, which also is 3 inches less than the 65 inches in 1945. The decrease in thickness is due partly to the increased production from strip mines with thinner seams and partly to the increased percentage of total production at underground mines in certain States having thinner seams. The thickness of seams at auger mines was measured for the first time in 1955 and was 53 inches. Though bituminous coal and lignite is mined today from seams of exceedingly variable thickness -less than 2 feet to ore than 50 feet -a large majority of the production, 65 percent in 1955, came from seams 3 to 6 feet thick. This is not surprising since the coal seam of moderate thickness presents the least mining difficulties.

Jan 1, 1957

By Tell Ertl, Ernest E. Burgh, John R. Wagner

The principal goal of the Oil-Shale Mining Division is to develop the most economical methods and practices for mining oil shale. Experimental work in the mine has not progressed far enough to conduct full-scale breaking tests; therefore, mining season - to October 31, 1945, has been confined largely to problems connected with drilling cost oil shale. Calculations have indicated that commercial production will result in breaking the oil shale; the largest individual turn will be for drilling. This paper is a report on the progress of phase two of drilling research to date; it outlines the development of a successful hard-surfaced rock bit for drilling oil shale.

Dec 1, 1948

By E. G. Davis

A research program to evaluate the use of ceramic die inserts for ferrous diecasting was initiated by the Bureau of Mines at its Tuscaloosa Research Center. Data were compiled from the literature to characterize selected ceramic materials with respect to thermal properties, thermal-shock resistance factors, chemical reactions with molten metals, and processes required to form die components. With this information and a computer model developed for predicting temperature and stress patterns induced in ceramic materials during simulated ferrous diecasting operations, 27 candidate materials were evaluated. After evaluation, only 15 were considered for testing in an apparatus constructed to immerse the ceramic specimens in molten cast iron. Of these, 13 were tested in a modified testing unit in which cast iron was poured onto the specimens. These tests resulted in the selection of three materials for further testing: boron carbonitride (50 pct B4C:5O pct BN), boron nitride-grade M (BN-M, 40 pct BN, 60 pct Si02), and pyrolytic boron nitride (PBN). Tests in a gravity-flow die unit showed that PBN was thermal-shock resistant and could be used in diecasting of ferrous metals.

Jan 1, 1981

By Andrew B. Cecala

As deeper seams are continually mined, methane liberation will continue to increase and must be monitored effectively. To effectively monitor and develop appropriate control technology, methane-liberation patterns must be known. The Bureau of Mines recently completed a study to identify specific patterns of face methane liberation during long- wall mining. Both of the longwall faces surveyed had high methane liberation rates. At one longwall face, most of the methane was liberated during cutting of coal by the shearer mining machine. At the second face, a significant portion of methane was emitted from the face and floor. An effective methane-monitoring system would be different for each longwall panel because of the differences in how the gas is released along the face.

Jan 1, 1985

By T. F. Mitchell

As a part of the program of investigation of domestic sources of manganese ore, mining engineers of the Bureau of Mines examined and obtained samples of ore from two properties in the vicinity of Bettie Mountain, Lander County, Nev. In addition, samples from three claims in the Carico Lake region, Lander County, Nev., were submitted by private interests. RS the ores were too low in grade to be acceptable for the direct production of ferromanganese, their amenability to concentration by ore dressing was investigated. The Black Bock property is 16 miles south of Valmy, Nev., and is owned by Western Alloys, Inc., Salt Lake City, Utah. The deposit is a replacement of sedimentary rock by manganese oxides. Ore occurs in two main ore bodies designated as the "upper bench" and "lower bench", which could be mined separately. Examining engineers obtained samples from each ore body, and laboratory experiments were made on each sample. The Black Eagle group of claims is in Lander County, Nov., about 43 miles southwest of Battle Mountain. Ore occurs as a replacement of manganese oxides in shale and chert. The 2-ton sample of ore used for laboratory testing was taken by a Bureau of Mines examining engineer from an adit that partly transversed a 28-foot bed of ore. The property is controlled by Western Alloys, Inc.

Jan 1, 1951

By P. E. Churchward

The Bureau of Mines developed a process using amines for recovering tungsten as ammonium paratungstate from alkaline leach liquors without producing synthetic scheelite as an intermediate product. Over 90 pct of the tungsten in low-grade scheelite or ferberite concen-trate was recovered as ammonium paratungstate by (l) autoclave leaching the concentrate with Na2CO3, (2) solvent extraction of the acidified leach liquor with kerosine solutions of either a quaternary amine (Aliquat 336) or a primary amine (Primene JM-T), (3) stripping the tungsten values from the quaternary amine with ammoniacal NH4C1 or from the primary amine with NH4OH, and (4) crystallization of ammonium paratungstate from the strip liquor. Reagent consumption in pounds per pound of W03 recovered was, for the quater¬nary amine, 3 Na2CO3, 3.5 H2SO4 , 2.2 NH4Cl, 1 NH3, and 0.4 glacial acetic acid; for the primary amine, it was 3 Na2CO3, 3.5 H2SO4, .06 NH4Cl, and 0.9 NH3. Both reagents extract molybdenum along with tungsten. Silicate and phosphate are partly extracted and contaminate the product; leach liquors containing these impurities require preliminary purification.

Jan 1, 1966

By George H. Schnakenberg

This Bureau of Mines publication describes a passive personal sampling device for N02 in air, developed by the New York University Medical Center under Bureau Grant G0133066. The sampler has been successfully demonstrated in the field and in the laboratory. In corroborative laboratory trials the agreement with reference method is excellent. The overall accuracy is approximately ±5 pct of reading to a precision of about ±l pct. All evidence indicates that these samplers should indicate the time-weighted-average N02 concentration to the above accuracy and precision equally well in the field since effects of wind velocity and relative humidity are negligible and the effects of temperature are about 0.1 pct per °F. The duration of exposure and the approximate temperature are the only data that need to be collected in the field. A two-step analysis procedure in field or service laboratory is then used to obtain the total cumulated exposure to N02 in parts per million-hours (ppm times hours), which can be converted to the time-weighted-average concentration of N02 in ppm by dividing cumulated exposure by the duration of the exposure.

Jan 1, 1976

By T. J. Ballard

Chromite deposits in the vicinity of Louise, Troup County, Ga., were studied y the Bureau of Mines from September 1, 1942, to March, 15, 1943. They are about three-fourths of a mile southeast of Louise and 8 miles northeast of La Grange, Troup County, Ga. The existence of chromite deposits in that area has been known for more than 75 years, but no active prospecting was done until World War I. Prospecting continued intermittently' until 1928. The Bureau became interested in the deposits in connection with its strategic minerals investigations during World War II. The chromite in these deposits occurs as grains ranging from "pin-head" size to 3/8-inch and occasionally 1 inch. Some of the material is magnetic, indicating the presence of magnetite. Of the 300 samples taken during the course of the project, 266 were analyzed. Tables showing the analyses accompany this report.

Jan 1, 1948

By C. B. Strachan

The Mascot concentrator treats 1,900 tons of zinc ore per day by gravity concentration and flotation. During the year 1929 the heads averaged 2.90 per cent zinc, and the recovery was 90.15 per cent; the concentrates produced contained 60.19 per cent zinc. ACKNOWLEDGMENT Acknowledgment is made to M. H. Newman, geologist, Robert Ammon, chief metallurgist, D. B. Grove, mill superintendent, and W. A. Calhoun, metallurgical clerk for assistance in the preparation of this paper.

Jan 1, 1930

By W. E. Lamont

The Bureau of Mines conducted flotation tests on a mixture of barite waste materials from Nevada in which essentially all of the barite values were finer than 20 micrometers. Flotation variables investigated in these tests were the effects of (1) sodium silicate as a pulp dispersant, (2) sodium hydroxide as a pH modifier, (3) increased amounts of sodium cetyl sulfate, (4) conditioning time and (5) solids content during conditioning. The optimum flotation conditions were achieved by adding 2.5 pounds of sodium silicate and 10 pounds of sodium cetyl sulfate per ton of feed and conditioning the pulp for 20 minutes at a 35-percent solids content. Using these conditions, a concentrate was produced that contained 94.7 percent BaS04, with an attendant recovery of 90.9 percent of the barite in the feed. In addition to the flotation tests, a selective barite flocculation process was developed to treat extremely fine barite. A barite concentrate containing 96.5 percent BaS04 with an attendant recovery of 82.1 percent of the barite was produced by selective flocculation. A process patent application has been filed based on this process.

Jan 1, 1982

By C. B. Manula, R. L. Sanford, R. A. Rivell

PART I. FLOW CHARTS

Jan 1, 1974

By B. W. Jong

As part of the Bureau of Mines program to develop substitutes for critical and strategic materials for metallurgical applications, the Tuscaloosa Research Center has evaluated the effect of additives and starting materials on the sintering and strength properties of sialon (silicon-aluminum-oxynitride) compositions fabricated by conventional pressing and sintering techniques. Sintering and MOR (modulus of rupture) data were developed for sialon compositions produced from three components, Si3N4, A1203, and AIN. When doped with Y203 to aid in sintering, the highest MOR values were obtained with compositions containing between 20 and 30 mole-pet (A1203 + AIN). The effect of the crystalline phase of the Si3N4 and Al203 used in the three-component system on MOR also was investigated. Alpha-Si3N4 and ?-A1203 were found to be the best starting materials. A sialon composed of 67.4 mole-pct a-Si3N4 plus 32.6 mole-pct (?-AI203 + AIN), doped with 5 wt pct Y203, had MOR values at 25°, 1,200°, and 1,400° C of 40,300, 40,300, and 31,100 psi, respectively. Samples of this composition doped with Gd203, MgO, Zr02, and ZrSi04 also were evaluated. The ZrSi04-doped sialon had higher MOR values than Gd203-, MgO-, and Zr02-doped materials but lower MOR values than the Y203-doped sialon. The MOR values of ZrSi04-doped sialons were 25,000 and 25,900 psi, respectively, at 25° and 1,400° C.

Jan 1, 1981

By B. W. Gandrud

In 1927 Coghill5 showed that there is considerable liberation of the iron oxide mineral from gangue when the Alabama red iron ores are ground to a size suitable for classification and tabling, but that there is not sufficient to make possible a high extraction and a high grade of concentrate. Coghill states: High extraction and high grade of concentrate cannot be obtained without grinding to a size comparable with flotation or cyanide practice. If grade of concentrate be sacrificed the grinding need not be so severe.

Jan 1, 1934

By Thomas W. Thompson

The Zebulon manganese deposit has been known for a number of years. It is situated about 3 miles east of Zebulon, Wake County, N. C., on the Avon, Privett property (fig. 1). The deposit outcrops as a vein, or dike averaging-16 to 20 feet in width. Drilling by the Bureau of Mines has shown that this outcrop results from consolidation of a number of small stringers near the surface. The surface width and the Percentage of manganese oxides (resulting from. weathering) diminish with depth. Below 50 to 80 feet, the vein material is mainly quartz and spessartite garnet. The deposit was first examined by W. T. Benson, a Bureau of Mines engineer, in 1941. The Bureau conducted a diamond-drilling exploratory program an the property from November 7, 1944, to January 25, 1945. A. total of 2,508.5 feet was drilled in 14 holes along the strike of the deposit.

Jan 1, 1950

By A. L. Engel

In the period of 1942-1945, medium-grade, oxidized, lead-silver ore was mined and shipped from the Diamond district near Eureka, Nev. An encouraging tonnage of low-grade ore was developed during these operations and partly blocked-out for future mining. If the low-grade ore could be treated profitably, further development of the district would result, and production of an important strategic metal might be increased. A representative sample of Diamond district ore was obtained through the Reno office of the Mining Division for the studies described in this report. The sample consisted of lumps and fines of a highly altered siliceous rock containing much earthy red hematite and some granular black hematite. Examination with the binocular microscope showed the lead carbonate mineral, cerussite, in seams and disseminated in the hematite. No zinc or silver minerals were identified, and no sulfide minerals were present. Analyses of the ore showed:

Jan 1, 1951