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By Paul W. Johnson, Ralph C. Kirby, Frank A. Peters

Alumina can be recovered from clay , using 30 percent nitric acid for digestion . Calcined clay is crushed and then digested at 325 ° F and 85 psig pressure with less than stoichiometric nitric acid required to form normal aluminum nitrate . In this way , a solution containing both normal aluminum nitrate , Al ( NO3 ) 3 , and basic aluminum nitrate , assumed to be Al ( OH ) ( NO3 ) 2 , is formed , and in which iron is virtually insoluble . The solution is filtered and then concentrated in vacuum evaporators to crystallize normal aluminum nonahydrate . The crystals are washed with 50 percent nitric acid and then decomposed to alumina and nitrogen oxides . The design that has been developed for this process is based on published work . For a plant producing 1,000 tons of alumina a day , the estimated operating cost is $60.69 per ton of alumina , and the estimated fixed capital cost is $ 76 million using a Marshall and Stevens chemical equipment index basis of 240.0 . This process is not competitive under current economic conditions with the production of alumina from bauxite via the Bayer process . For lowering costs , future research should include study of leaching at lower temperatures under atmospheric pressure and alternate aluminum nitrate decomposition methods .

Jan 1, 1964

By G. L. Anderson

The U.S. Bureau of Mines (USBM) has conducted research to improve the nondestructive testing (NDT) of wire hoist ropes. Losses in the diameter of a wire hoist rope are used as one criterion for judging when a rope should be replaced. Losses are determined by periodically measuring the rope diameter and comparing this measurement with the original measured diameter; when the diameter reaches a specified minimum at any point along its length, the rope must be retired. Generally, these measurements are made at randomly selected locations along the length of the rope, using a hand caliper. To provide more accurate measurements and to allow measurements to be taken continuously along the length of a hoist rope, an optical diameter-monitoring system was built for the USBM under contract. Continuous measurements are preferable because, when combined with continuous electro-magnetic NDT results, they can indicate whether losses in metallic cross-sectional area originate from external wear or internal wear and corrosion. Tests of the system showed that the instrument met specifications when measuring wire rope at low rope speeds but was inaccurate at speeds over about 30 m/min (100 ft/min). This report describes the prototype system, presents the results of the test program, and describes the capabilities of the system.

Jan 1, 2010

By Carlton E. Brown

[The purpose of this report is to present results of tests on the effectiveness of a spray of water mist, commonly called compressed-air water blast or water blast, in reducing the concentration of dust present in the air shortly after blasting and during mucking of the blasted material. Many observations have been male on the effectiveness of such ,sprays, but published quantitative information on comparative dust concentrations with and without their use, obtained by dust-sampling methods in use in this country, is rare if not absent. Tests conducted. in South Africa about 19164/ and more recently in England5/,6/ have shown that such sprays reduce the dust concentration to very low values within a fen minutes after blasting.]

Jan 1, 1938

By R. P. Walters, M. J. Lynch, D. R. Flinn

The Bureau of Mines evaluated tthhee feasibility of substituting platinum- coated metals for bulk platinum shapes as a means for conserving platinum . Platinum coatings were prepared using four different methods of electrodeposition , then tested and evaluated . In order for platinum coatings to be useful in process environments , they must be thick , adherent , stress - free , and pore - free . The Bureau evaluated direct - current , current reversal , cathode shielding , and pulsed- current plating techniques for producing a pore-free platinum electrodeposit from a molten cyanide bath . Aqueous corrosion tests of Fe - 10Cr substrates coated with approximately 25 μm of platinum showed that pulse plating yielded the most corrosion- resistant and , hence , the most pore -free coatings . The morphology of coating cross sections was in all cases columnar . The average grain size of pulse -plated deposits was independent of thickness , while all other plating techniques produced grains that increased in size as the coatings became thicker . It is believed that the constant grain size in the pulse - plated deposits resulted from better mass transport during the electrodeposition .

Jan 1, 1965

By Michael Sokaski, M. R. Geer, H. F. Yancey

This report is one of a series describing investigations by the Federal Bureau of Mines of the performance of various types of coal - cleaning equipment ; other reports in the series are listed in the bibliography . The information in these reports is useful to the coal industry and the manufacturers of coal - cleaning equipment in several ways : First , it assists the coalpreparation engineer who is planning a new plant to select the type of process best suited to the requirements by enabling him to forecast the yield and quality of clean coal obtainable with each type of equipment . Second , the information serves as a yardstick by which the performance of a plant can be judged and thus helps determine whether it is operating at satisfactory efficiency . Both these functions promote better coal - preparation practice ; that is , they help provide coal of more suitable quality for the market and likewise minimize the waste of good coal . This serves the interest of conservation with which the Bureau is vitally concerned . The present report deals with three plants using the Tromp dense - medium process , named after its inventor , K. F. Tromp , who developed the process in the Netherlands in 1936.5/ Selection of this particular dense -medium process for investigation was entirely a matter of convenience , and reports dealing with other dense -medium systems are planned for the future . Two baths are employed in one of the plants investigated . The first of these , handling 6- to 3 - inch coal , exhibited an exceptionally sharp separation between coal and impurity . This was characterized by an error area of 12 and a probable error of 0.023 . In the second bath , treating refuse from the

Jul 1, 1960

By Ludwig Schmidt

This report, the second of a series, presents the results of laboratory corrosion studies which were made in connection with a one-year test on aluminum lease tanks conducted by the United States Bureau of Mines. Part I of the report contains the results of the field teats.5 The studies were made on an oil lease in a so-called "sour district," near Borger, Tag., where free hydrogen sulphide accompanied the production of oil, gas, and salt water. Steel tanks previously used on the lease had suffered severe corrosion, because steel is inherently susceptible to attack by hydrogen sulphide. Because of the high resistivity of aluminum to the action of hydrogen sulphide, it Was believed that this metal had promising possibilities as a material for the construction of lease tanks in "sour districts." The results of the one-year field teat proved that aluminum lease tanks will withstand corrosion by hydrogen sulphide, but it was found that aluminum was susceptible to attack by salt water, which was invariably present in certain portions of the tanks, and that hydrogen sulphide accelerated this salt-water corrosion in an indirect manner, as will be explained hereinafter. In order to study corrosion conditions encountered in the tanks during the test period, a laboratory was maintained at the site of the aluminum lease tanks.

Jan 1, 1931

By J. Fletcher Smoak

Consumption of abrasive materials in the United States decreased 23% in value from that of 1981 to $262 million, of which 53% was manufactured abrasive, 39% was industrial diamond (natural and synthetic), and 8% was natural abrasive. Production of natural abrasives, excluding industrial diamond, appeared to be stable when compared with that of 1981. Production of tripoli, a porous siliceous rock, increased slightly after decreasing steadily over the three previous years. The production increase of garnet, an abundant iron-aluminum silicate, was attributed to increased output from one plant that had completed an expansion program in late

Jan 1, 1983

By T. A. Clancy

Since many new mineral processing systems under development can impose severe corrosive conditions on construction materials, the Bureau of Mines reviewed and assessed the literature on corrosion resistance of ceramic materials. Corrosive conditions were categorized as: (1) acids and aqueous solutions, (2) glass and slag/metal melts, and (3) gases. Information on the corrosion resistance of ceramic materials, generally, is disseminated by many sources, each of which is interested in specific corrosive environments. Based on this survey, it was noted that (I) the development of standardized tests is needed to study solution-type corrosion of ceramics, (2) slag/melt corrosion data are the most comprehensive of the available data, and (3) better definition of corrosion mechanisms In gaseous environments is needed.

Jan 1, 1980

In 2005, a total of 2,063 coal mining operations reported employment to the Mine Safety and Health Administration (MSHA). Coal mines comprised 14.1% of all mining operations. ? Bituminous mines comprised 92.6% (n=1,911) and anthracite mines 7.4% (n=152) of coal mining operations. ? Approximately 70% of all coal mines were located in three states: Kentucky (28.0%), West Virginia (21.8%), and Pennsylvania (20.6%).

Jan 1, 2008

By Ernest W. Johnson

Diamond, drilling of some blast holes in stoning operations is practised in at least two iron mines in the Lake Superior district - the Soudan mine of the Oliver Iron Mining Co., on the Vermilion range at Soudan, Minn., and the Anvil-Palms mine, operated by Pickands, Bather & Co., on the Gogebic range at Bessemer, Mich. Diamond drilling, at the Soudan nine has partly replaced percussion drilling because of the extreme hardness of the ore and of the lean formation. According to Wolff,4/ the jasper or lean formation in this mine is the hardest rock regularly drilled in any commercial operation.

Jan 1, 1945

By H. C. Young

This paper deals with roof bolting in Alabama coal mines and iron-ore mines from the time it was introduced in early May 1948 to May 1, 1953, a 5-year period. The Tennessee Coal & Iron Division of the United States Steel Corp. began systematic roof bolting in early May 1948 in a coal mine and in an iron-ore mine, which had some of the poorest roof conditions in the Alabama mines. After the efficiency of roof bolting had been proved by the Tennessee Co. it was gradually adopted by other companies throughout the State, until in May 1953 approximately 53 percent of Alabama's total coal production and 100 percent of Alabama's total iron-ore production, mined underground, was being produced from roof-bolted areas. Statistics in this report will show the advancement made in roof bolting in the 5 years and also the amount of roof bolting that was being done as of May 1, 1953. Significant progress has been made in the coal and iron-ore mines of Alabama in reducing the roof-fall fatality rates during the past several years by adopting systematic roof bolting. The groundwork was laid through successful experiments early in 1948 by the Tennessee Coal & Iron Division of the United States Steel Corp. in cooperation with the Federal Bureau of Mines. This experimental work was based upon the previous experience of the St. Joseph Lead Co.2/ in its Southeastern Missouri mines.

Jan 1, 1954

By David Schlain

IN 1942 the Bureau of Mines began to develop the Kroll process for use in the large-scale production of titanium. Titanium and titanium alloys are now commercial metals. These metals are relatively expensive, but It is now evident that they will have important industrial uses and that in many instances these will be related to their remarkable corrosion resistance. This bulletin presents the known corrosion properties of titanium and its alloys in useful form. In marine environments titanium is highly resistant to corrosion and does not pit, or undergo crevice corrosion, stress corrosion, or corrosion fatigue. Titanium is also highly resistant in many salt solutions, including most chlorides. It is very resistant to corrosion in nitric acid solutions. It is also resistant to white fuming nitric acid. However, it may react violently with red fuming nitric acid. In phosphoric acid solutions titanium has rela¬tively good resistance to corrosion, but it has less resistance to sulfuric acid and still less to hydrochloric acid solutions. Titanium corrodes very rapidly in hydrofluoric acid Solutions. It is very resistant to corrosion in many organic chemicals. However, it has only moderate resistance to formic acid solutions and poor resistance inn oxalic acid solutions. Titanium does not corrode in dichloroaretic acid but, corrodes rapidly in 100 percent trichloroacetic acid at 100° C. Titanium is resistant to barium, calcium, magnesium, ammonium, and sodium hydroxides. Titanium is inert in wet chlorine, bromine, or iodine gases. However, in dry chlorine gas titanium reacts rapidly enough to ignite. It also reacts rapidly with dry bromine gas, but, it is resistant to dry iodine gas. When titanium is exposed to red fuming nitric acid solutions with high nitrogen dioxide content and low water content, it corrodes, undergoes stress-corrosion cracking, and becomes pyrophoric. This occurs more readily with some titanium alleys, such as titanium-8 percent manganese. A fresh titanium surface immersed in water or in an aqueous solution and in contact with an oxygen-rich atmosphere under sufficientt pressure is unstable and will ignite spontaneously. Inherently an active metal, titanium has a tendency to become less active in environments containing oxidizing agents such as air, oxygen, chlorine, or ferric, cupric, or platinic ions. Titanium is more noble than most structural metals in roost, environments and its excellent corrosion resistance is generally not, affected by contact with these metals. However, some of the other metals corrode faster because of contact with titanium. Titanium undergoes anodic polarization readily, so that even when it is the less noble member of a galvanic couple it may corrode less because of the contact. Titanium alloys often have corrosion properties and electrochemical characteristics similar to those of commercially pure titanium. Titanium alloys containing noble metals, zirconium, molybdenum, vanadium, tantalum, or copper sometimes have better corrosion resistance than pure titanium.

Jan 1, 1964

By George Quackenbos

The principal objective of this Program is the design, fabrication and testing of an Environmental System for operation in underground mines, to assess the effect of various mining systems on the contaminant levels near the mine face and within return airways. In order to determine the effect on airborne contamination in mines resulting from the development of new mining techniques, equipment and control systems, a Comprehensive Monitoring System is required to assess such contamination levels at critical and strategic locations and relate this information with ventilation parameters. The three variables to be sensed on a continuous basis are airborne dust concentration, methane concentration and ventilation air velocity. Each Monitoring Station will consist of a self-contained unit containing a power source and sensors to monitor the three above mentioned parameters. Ruggedness, reliability, ease 'of operation and intrinsic safety are important design objectives. Data gathered by each Monitoring Station will be fed to a Central Data Acquisition System by means of a portable transfer unit.

Jan 1, 1982

By Kenneth P. V. Lei

The Bureau of Mines investigated a silver-catalyzed oxidative procedure for leaching an arsenical copper sulfide concentrate containing 10 pct As and 32 pct Cu_ Currently, there are no environmentally safe means to treat arsenical copper concentrates in the United States. Leaching was conducted in a 2-L autoclave reactor. The effects of catalyst concentration, O2 pressure, temperature, and H2S04, Cu, As, and Fe concentrations in the leaching solution on extractions of metals from the concentrate were determined. The best leaching conditions for extracting 95 pet eu and As and less than 21 pct Fe were 260 g/L concentrate, 0.007 mol/L (1.0 g/L) AgCI, 3.0 mol/L (294 gIL) H2S04, 1000 C, 60 psig 02, and 6 h. Copper as CuS04-5H20 was recovered by crystallization from the pregnant solution. Arsenic, as AS203, was recovered from the copper mother liquor by solvent extraction, with tributyl phosphate, S02 reduction of As5+ to As3+ in the strip solution, and crystallization of the As3+. The silver catalyst was recovered by contacting the leached residue with a brine solution. A conceptual scheme is proposed for treating arsenical copper sulfide concentrates.

Jan 1, 1987

By C. M. Flynn

The solubilities of sideronatrite [Na2Fe(OH)(SO4)2?3H20] and ferrinatrite [Na3Fe(SO4),&apos;3H2O] were determined by the Bureau of Mines in the Na2SO4-Fe2O3-H2SO4-H20 system at 25°, 40°, 60°, and 90° C. The solution compositions investigated ranged from Na+-Fe&apos;+ mol ratios of 0.5 to >100 (Na2SO4 saturation) and H+ -SO4 2-mol ratios of 0 to 1. O. The results are presented in the form of contour plots. The solubilities were determined by seeding supersaturated solutions of known composition with the specified solid phase to precipitate a substantial amount of solid. Water was then added in small portions to the solution until the last portion of the solid dissolved. Equilibration times at 25°, 40°, 60°, and 90° C were 2 days, 1 day, 8 to 16 h, and 2 to 4 h, respectively. The accuracy of the solubility data is estimated to be 1 to 2 pet. Low iron solubilities of <0.36 pct Fe2(SO4)&apos;, or 1 g Fe/kg solution, were obtained in solutions containing at least 8 pet Na2SO4 in the absence of H2SO4 or a total of at least 36 to 38 pet Na2SO4 + H2SO4 at high acidity. The filterability and density of sideronatrite and ferrinatrite in comparison with other iron compounds are reported. These compounds are suitable vehicles for iron removal in Na2SO4-rieh solutions. Additional solubility data on the Na2SO4-H2SO4-H20 system were also obtained.

Jan 1, 1987

By Raja V. Ramani, Sachin Shankar

"Re-entrainment refers to dislodgement of particles deposited by both atmospheric and nonatmospheric processes and their subsequent insertion into a flowing field. Formation of sand dunes, snow drifts, soil erosion and fugitive dust emissions are a few examples of the natural occurrence of re-entrainment. Re-entrainment studies have been done for the estimation of potential hazards from nuclear fallouts. The phenomenon of re-entrainment has been utilized for the cleaning of wafers and filters. Re-entrainment is associated with both surface and underground mining activities. However, studies on dust re-entrainment in mine atmospheres are limited. Understanding the re-entrainment phenomenon is important because dust particles lying seemingly harmless on the ground and adhering to numerous surfaces can get re-entrained and become a health and safety hazard.There are significant differences in the kind of re-entrainment encountered in underground mines and those in other fields of interest. These major differences are air velocity, direction of air flow, particle size, amount of particles, and time of exposure. While numerous studies have been done in other fields to identify the role of interacting variables and their contribution to the mechanisms of re-entrainment, no similar reported work is available for dust in mine atmospheres.In this paper, recent research efforts on re-entrainment are reviewed. The most suitable form of representing re-entrainment in underground coal mine atmosphere is presented. Various approaches to studying re-entrainment phenomenon in mines are also outlined.In the mineral industries, formation of dust particles of widely varying sizes is a natural outcome of the fragmentation required in mining the solid resources. Fine particles in mine atmospheres, particularly in the respirable size range, are a threat to the health and safety of the miners when present in high concentrations. In 1980 the National Academy of Sciences (NAS) Committee on the Measurement and Control of Respirable Dust in Mines recommended that the spatial and temporal characteristics (of fragments produced in coal mining) need to be understood so that the exposure of workers to the dust can be controlled. Recently several studies have been performed to understand the fundamental behavior of the airborne respirable dust in mine airways (Bhaskar, 1987; Qin, 1988; Polat, 1989; Bode, 1990)."

Mar 1, 1992

By Forrest T. Moyer

To keep the mineral and allied industries informed of trends in the causes of accidents and to point out the need for corrective measures, the Bureau of Mines collects, analyzes, and periodically publishes health and safety statistics. This report includes data for 1962 on injury experience, with related employment statistics, at coal mines in the United States. These data are presented in tabular form under the following: General Injury Experience Tables 1 to 6: Current data on number of injuries, degree of injury, frequency and severity rates, average severity, and related employment and production data by work location.

Jan 1, 1964

By Forrest T. Moyer

To keep the mineral and allied industries informed of trends in the causes of accidents and to point, out the need for corrective measures, the Bureau of Mines collects, analyzes, and periodically publishes health and safety statistics. This report includes data for 1962 on injury experience, with related employment statistics, at coal mines in the United States. These data are presented in tabular form under the following: General Injury Experience Tables 1 to 6: Current data on number of injuries, degree of injury, frequency and severity rates, average severity, and related employment and production data by work location.

Jan 1, 1964

By P. L. Swanson

Over a recent 20-month observation period, the U.S. Bureau of Mines obtained seismogram records from a single vertical-component, short-period seismometer installed at the surface of a metal mine in northern Idaho. The seismic events were analyzed for local (Richter) magnitude (M), time of occurrence, location, and relation to rock bursting and production blasting. Approximately 150 seismic events with -0.5 = M = 2.9 were located within the mine, yielding a b value (slope of the logarithm of the number of events with magnitude greater than M versus M) of 0.5. Event locations were constrained using a dense underground array of high-frequency accelerometers. Twenty of the surface-recorded events, with 0.5 = M = 2.9, were associated with rock bursts that produced damage requiring at least 1/2 day of cleanup and/or repair. Other possibly hazardous rock bursts, with magnitudes as small as -1.1, were numerous but were not associated with significant structural damage. Approximately 60 pct of the seismic events with M > -0.5 and 75 pct of damaging rock bursts occurred within 45 min of blasting. Estimates of characteristic rupture dimensions for rock bursts with -1.1 = M = 2.9, based on a conventional dislocation shear-slip model of failure, range from 3 to 300 m.

Jan 1, 2010

By James Paone

This report on the state of the art of horizontal boring technology for underground power transmission installations was prepared by the Bureau of Mines at the request of the Department of the Interior. This paper describes the different machines and methods used in augering, impacting, pushing, drilling, and machine tunneling horizontal holes through soil and rock. A review of the borehole survey and guidance tools and techniques applicable to these methods is also given. Nonboring methods used for emplacement of power distribution and transmission lines are briefly discussed. The paper ends with a brief technical forecast, an analytical summary of the state of the art, and recommendations based on power industry needs. Horizontal boring techniques for power distribution lines installation are adequate to meet the requirements of the power industry, particularly where such burial involves relatively short distances in soil or soft rock. For burying power transmission lines, particularly in the harder rocks and over relatively long distances, horizontal boring methods are not as well advanced. Research and development as well as economic incentives to equipment manufacturers could substantially improve the state of the art. Obstacle detection and guidance systems for directing boreholes to specified targets need major improvements to meet the requirements of the power industry for underground burial of distribution and transmission lines

Jan 1, 1968