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By H. C. Brunaugh, James Westfield, R. W. Whittaker

"INTRODUCTION The purpose of this circular is to describe the sealing off of a mine fire and subsequent use of carbon dioxide gas to extinguish it.A fire of electrical origin occurred in the Valier mine of the Valier Coal Co., Valier, Franklin County, I11., on March 29, 1949, at about 1:35 p.m. It was discovered about 3:35 p.m. in 5 south west intake airway inby 1 and 2 west panels. The No. 5 southwest airway had caved, and the fire was in the top coal beneath a large fall of rock. All men, except officials, were ordered from the mine. The mine officials decided to seal the fire, and four temporary seals were erected, which isolated approximately 200 feet of 5 south west entry. The seals were completed on March 30 at 2:45 a.m., but on March 31, at 3;40 a.m,, two of them were blown out by an explosion of gas that was produced by the fire. The two seals were rebuilt, the work being completed on March 31 at 12:00 noon, but they were blown out by another gas explosion at 12:10 a.m. on April 1. It was then decided to extinguish the fire with water if possible.To accomplish this, concrete-block dams were constructed. On April 1, about 4:25 a.m., when the dams were about half completed, water was introduced into the fire area through a 2-inch pipe.On April 4, J. G, Crawford, general manager of the Valier Coal Co., notified James Westfield, chief of the Vincennes (Ind.) Branch, U. S. Bureau of Mines, by telephone of the fire in Valier mine and requested assistance to combat it. Westfield, accompanied by F. J. Smith and H. C. Brumbaugh, Federal coal-mine inspectors, went underground and inspected the seals and dams. Later, during a conference with company officials, it was decided that the concrete-block dams were not strong enough to withstand the hydrostatic pressure that would be produced by flooding the fire area. It was then decided to use carbon dioxide gas to extinguish the fire. Four seals were completed, and 5 tons of carbon dioxide gas was introduced into the fire area, which extinguished the fire."

Apr 1, 1950

By Mark Sheppard

This paper is the second of a series recording the results of tests made at various quarries throughout the United States to determine, (1) the relation between the size gradation of feed to, and product from, primary crushers; (2) the particle shape of crushed product; (3) the differences in gradation and particle shape produced by different tries of primary crushers; and ( 4) the differences in gradation and particle shape caused by crushing different kinds of stone. Primary crushing has received comparatively little attention in the technical literature in spite of tine fact that the design of the whole crushing plant should be correlated to the performance of the primary crusher.

Jan 1, 1938

By E. P. Youngman

By a decree of March 14, 1929,5 the President of the Faitian Repub- lic, considering it to be necessary, until the mining legislation of the Republic shall have been revised, to put into effect the mining law of Decem- Der 4, 1860 (relative to mines, diggings, and quarries), by the authority given in article 55 of the Constitution, declared the law of February 14, 1919, to be abrogated and the provisions of the earlier mining law (December 4, 1050) again to be valid. No concessions were granted under the law of 1919. All citations in this paper, unless otherwise designated, refer to the law of 1930.

Jun 1, 1932

By Donald F. Reed

The bauxite deposits of Tippah and Benton Counties in northeastern Mississippi were developed by drilling as a part of the investigation by the Bureau of Mines of the domestic sources of supply of aluminum. The primary purpose of investigations of this nature was to provide essential information to the war agencies of the United States Government and to assist owners and operators of mining properties in the production of minerals vital to the prosecution of the war. These reports are based upon the field work of the Bureau of Mines and upon data made available to the Department from other

Jan 1, 1948

By F. E. Diebold

The wastewater-treatment system of the Anaconda Mining Co., at its Butte, MT., operation has been physically and chemically characterize modeled on a computer and investigated with respect to alternate systems for economic heavy metal recovery. The system involves lime addition to a mixture of acid underground copper sulfide mine water, acid effluent water from the iron induced precipitation of copper from acid leach solution and basic suspensions of solid effluent from a concentrator plant. Experimental chemical analysis and predictive computer calculations shows that the monosulfllte and disulfllte complexes of transition metals (Iron II being dominant) and alkaline earths are 40% of the total dissolved metal load of both acid streams. The suspended solids (30% by weight) in the basic concentrator slurries are dominated by quartz and pyrite and also contain kaolinite muscovite, biotite and undissolved lime. The mixture of these three streams result's in major reductions in concentrations of Al, Cu, Fe, Mg, Mn, Sir and Zn, and a pH >7 with calcium, sodium, potassium, and sulfate being the major dissolved ions. The treatment system has been simulated in the laboratory and accurately modeled on a computer. The computer program, an altered REDEQL-EPAK, is capable of accurately predicting the amount of lime required to reach a desired effluent water. Preliminary research has indicated the usefulness of electroprecipitation as a means of recovering the valuable metal load and providing an EPA acceptable effluent.

Jan 1, 1982

By A. E. Back

[Several processes for recovering manganese from low-grade ores have been proposed3/4/5/ in which an aqueous slurry of the ore is leached with gas containing nitrogen, oxygen, and sulfur dioxide as obtained from burning sulfur or roasting sulfide ores. The manganese dioxide is dissolved, and most of the sulfur dioxide is oxidized to sulfate, but an appreciable quantity of dithionate is usually formed, together with acid from oxidation of the sulfur dioxide. The over-all reactions may be represented as follows: (1) Mn02 + S02 = Mn++ + S04--. (2) Mn02 + 2S02 = Mn++ +S206--. (3) H20 + So2 + 1/2 02 = 2H+ 5S4--. (4) H20 + 2S02 + 1/2 02 = 2H+ + S206---.]

Jan 1, 1952

By James J. Snodgrass

The Bureau of Mines designed and constructed a series of calibration models for geophysical borehole logging. A nominal hole diameter of 3 inches was selected as representative of typical core holes drilled for mining and engineering purposes, although additional hole diameters of 2, 5, and 8 inches are provided in one of the models for determination of empirical correction factors for variations in hole diameter. The physical properties of the models were determined by laboratory analyses of drill core samples and evaluated statistically for reliability. This report outlines the location of the models, elements of design and construction, and results of the laboratory tests. The models are available at the Denver Federal Center, Denver, Colo., for use by Government agencies and private industry to calibrate logging equipment for measurements of density, sonic velocity, magnetic susceptibility, and electrical resistivity.

Jan 1, 1976

By M. H. Kline

The Great Gossan Lead in Carroll County, Va., is one of the largest undeveloped sulfide ore bodies known in the eastern United States. It extends for 16.7 miles along the western slope of the Blue Ridge Mountains (fig. 1). The various known segments of the deposit, extending from the southwest end to the northeast, are: The Great Outburst or Iron Ridge segment, Chestnut Creek, Copperas Hill, Sarah Ellen, Wild Cat, Cranberry, Dalton Hill and offset segment to the south of the Cranberry, Little Reed Island, Little Vine, and the Betty Baker at the northeast end. All of these segments have been explored or mined to various extents in the past for the iron gossan and secondary copper ore. The Great Outburst or Iron Ridge segment is now being mined by the General Chemical Division of the Allied Chemical & Dye Corp. for the sulfur and iron content of the primary ore. These deposits are becoming increasingly of Interest as a. large potential source of iron and sulfur owing to their proximity to Birmingham, where the burned cinder sells at a premium, and to the acid markets of the region.

Jan 1, 1949

By Ivette E. Torres

World investment 10 all mineral and mining industry sectors is not available. However, partial information available provides some information useful for analysis. Information available in this section covers limited geographic information on investment in the steel industry, limited information for petroleum industry capital spending, and total U.S. foreign investment in comparison to the mineral-related sectors (tables 13, 14, and 15). Annual steel industry investment is available for the European Community, almost all countries within the European Free Trade Association (EFTA), Latin America, and other countries with significant mineral industries, such as Canada, Japan, and the United States. Although information was not available for 1992, data for 1991 indicate that for those countries aforementioned, total investment increased by 8 %. However, investment patterns were very different within the different groups of countries. While the European Community had a net increase of 12 %, dominated by an almost °40 % increase in Germany, EFTA member countries had a 26 % decrease in investment for the same period. Investment in EC countries was almost seven times that of EFT A countries. Japan's investment in the iron and steel industry, by far the largest of those available, almost twice that of the EC and almost four times that of the United States, increased by more than 20 %. In North America, investment in Canada and the United States decreased. Almost all of Latin America decreased investment in the sector. The notable exception was Mexico, with a 60 % increase. Changes in Mexico's investment policies of the recent past, its economic growth, and privatization of its iron and steel industry are some of the reasons for such an increase. The other country covered individually in Latin America, where investment in the iron and steel industry increased, although slightly, was Argentina. This limited information does not allow a comprehensive analysis of global industry trend, which in turn impacts many other mineral commodities, and with the transition in many countries within Europe and Central Eurasia that are now effecting the steel industries of the countries that were members of the U.S.S.R. and its CMEA partners, it is most regrettable that comprehensive and comparable data, both current and historic, on investment in this area are not available.

Jan 1, 1994

By M. C. Irani

This Bureau of Mines survey of methane emissions indicates that total daily emissions have declined from 227 MM ft3 in 1971 to 214.7 MM ft3 in 1973. The highest average daily emissions in million cubic feet per day observed in U.S. bituminous coal mines were, in decreasing order, Monongalia County, W. Va., 40.7; Marion County, W. Va., 23.1; Buchanan County, Va., 22.1; Washington County, Pa. , 12.4; Greene County, Pa. , 11.7; McDowell County, W. Va. , 11.4; Cambria County, Pa., 9.8; Jefferson County, Ala., 9.5; Wyoming County, W. Va., 6.0; Marshall County, W. Va., 4.8; and Indiana County, Pa., 4.8.

Jan 1, 1974

By F. E. Cash

Among petroleum refinery employees and officials throughout the United States there has been marked effort to reduce accident frequency and severity. For the interest and benefit of refineries both in Louisiana and in other petroleum-refining States it has been possible to obtain from five refineries, representing 70 per cent of the production of Louisiana, tae accident experience for the past 3 to 6 years. The companies concerned have requested that their names be not used. For tide reason the four plants listed and discussed are designated as refineries A, E, C, and D. The size of the plant as regards largest to smallest number of employees is indicated by the alphabetical order.

Jan 1, 1933

By Alex C. Smith

This report describes laboratory studies conducted by the Bureau of Mines on the spontaneous combustion of U.S. coals. Approximately 11 pet of U.S. underground coal mine fires are attributed to spontaneous combustion. The relative self-heating tendencies of 24 coal samples were evaluated in an adiabatic heating oven. Minimum self-heating temperatures (SHT's) in the oven ranged from 350 C for a lignite and high-volatile C bituminous (hvCb) coal, to 1350 C for two low-volatile bituminous (lvb) coals. An empirical expression was determined predicting a bituminous coal's minimum SHT in the adiabatic oven based on the coal's dry ash-free oxygen content. Several factors that can affect the self-heating process were also evaluated. The self-~eating tendency of a coal increased when the coal was dried and exposed to humidified air, and was dependent on the particle size and oxygen concentration of the air. A new moderate-scale apparatus is described, in which the self-heating tendencies of larger coal samples, 3 kg, can be evaluated. The minimum SHT's of two coals were determined and the results were in good agreement with those found in the adiabatic oven. Finally, results of a test in the moderate-scale apparatus indicated a strong dependence of the self-heating rate of a low rank coal on the moisture content of the air.

Jan 1, 1987

In this U.S. Bureau of Mines report, in situ vat leach mineral recovery system concepts are described and cost compared with conventional mining and pad and autoclave leach processing systems. In the proposed systems, leachable ores are enclosed in place in reagent-impermeable in situ vat constructions. The ores are then rubbled and flood leached or flood oxidized and leached. The in situ vats are called stope leach or stope autoclave vessels. The report also proposes ore body-adjacent in situ vat constructions containing rechargeable processing stopes. A series of ore body-specific, innovative, and conventional mineral recovery systems case study designs are described and prefeasibility level costed. Based on a comparison of these prefeasibility level cost estimates, the proposed systems are determined to be economically competitive with conventional min¬eral recovery systems. The in situ vat leach mineral recovery systems concepts for leachable and refractory ores are developed around the drill-split narrow-vein and longwall mining methods described in part 1 of this Information Circular series.

Jan 1, 1995

By A. Matzick

In its work under the Synthetic Liquid Fuels Program the Bureau of Mines has developed on a 6-ton-a-day-pilot-plant scale a continuous, gravity-feed retort far distilling oil from oil shale. The development work covered by this report was done from January 27, 1950, to January 26, 1952, at the ail-Shale Experiment Station near Rifle, Colo. Over 300 pilot-plant tests were made during the investigation. The basic retort developed has been named the Gas-Combustion retort. In this process, part of the heat for retorting of the shale is generated by burning recycled product gas in a combustion zone within the descending shale bad in the retort. Additional heat is supplied by combustion of the carbonaceous residue remaining in the spent shale after the oil has been distilled. Air for combustion is admitted through an air distributor in the center of the bed at about the mid-point of the retort. Hot gas rising from the combustion zone heats countercurrently the descending raw shale and liberated shale oil by pyrolysis of the shale. After passing through and exchanging heat with the incoming raw shale, the oil is condensed as a fog or mist in the gas, which is withdrawn at the tip of the retort. The cool gas is then piped to an oil-recovery system where the oil is separated from the gas in centrifugal separators or other types of mechanical or electrostatic separators. The hot, spent shale below the combustion zone is cooled by heat exchange with recycle gas, which is a portion of the effluent gas from the oil-recovery system.

Jan 1, 1955

By George H. Popper

The Bureau of Mines has evaluated the extent of phosphate resources available for recovery by the experimental borehole mining method in the Southeastern Coastal Plain of the United States- Phosphate re- sources at overburden depths greater than 30 m are as a rule currently unsuitable for recovery through conventional mining methods because of economic, environmental, or technical considerations. In the identified deposit areas, borehole mining operations are projected to yield a more favorable rate of return and to be environmentally more desirable than conventional surface mining. Borehole mining resource estimates presented in this study are preliminary and designed to serve as a basis for future resource evaluations, as the current data base is relatively sparse and incomplete. The resulting resources have, therefore, been classified as hypothetical and speculative and are subject to up- dating as additional exploratory data become available. Hypothetical and speculative resources amenable to borehole mining are estimated to total about 385 billion metric tons (rat) of phosphate matrix with a minimum in situ grade of 5 pct P205. With projected borehole mining capabilities and current conventional beneficiation procedures, this resource would make available approximately 64 billion mt of phosphate rock product at an estimated grade of 30 pct P205.

Jan 1, 1985

By E. T. Bowers

Pneumatic conveying of coal underground is not widely used in the United States, although it is becoming increasingly popular in Great Britain, the Federal Republic of Germany, and South Africa. The question of safety has been raised repeatedly: Will the system be prone to dust or gas explosions, and, if so, can it withstand such occurrences safely? The work reported here was done under a Bureau of Mines contract and deals with the safety aspects of pneumatic transport of underground coal, as well as the hazards inherent in more conventional haulage systems. Included are three designs for different applications of pneumatic haulage: off-loading a continuous-mining machine on a room- and-pillar section, vertical hoisting through a 1,200-ft shaft, and off-loading a tunnel-boring machine driving a 2,000-ft tunnel.

Jan 1, 1985

By Lincoln A. Stewart, P. S. Haury

"INTRODUCTION AND RESUME Arizona asbestos mines are the only sources on the American continents of iron-free chrysotile spinning fiber that meets the Navy specifications for asbestos fiber for use in covering electrical cables. Rhodesia normally supplies the bulk of this grade of asbestos at about half the Price of Ari zona spinning fiber. The acute submarine menace in 1942 focused attention on the danger that imports might be cut off and that a sudden demand for greatly expanded production might fall on the Arizona mines to supply the tonnage of this essential material needed for war production.A joint preliminary investigation of Arizona asbestos deposits was made in August 1941 by J. R. Thoenen, senior mining engineer of the Bureau of Mines and A. E. Granger, a geologist of the United States Geological Survey. A more extended investigation of the numerous asbestos mines and prospects, which are scattered over 25 townships of difficult terrain in Gila County, was begun by the senior author in August 1942.The Geological Survey assigned two geologists (Newton Chute and A. F. Shride) a few weeks later to study the geology as an aid in selecting the mines for the Bureau's exploration projects. Six mines were selected for exploratory work because it was desired to prove reserves of ore where production could be started quickly if urgent demand should arise. Acceleration of production is normally slow because of adverse operating conditions. First, the mines are at distances of 35 to 100 miles from Globe, the shipping and supply point, and the roads are few and poor. The mine openings start in steep canyon walls, so that mining supplies usually have to be packed in and the product packed out over 0.5 to 5 miles of burro trail. Second, most of the ore deposits are small, and the ratio of rock broken to spinning fiber recovered is very high, usually exceeding 200."

Aug 1, 1947

By Thomas M. Nasiatka

Tests with a high-pressure water jet were conducted in the steeply pitching Roslyn No. 5 bituminous coalbed in the Roslyn No. 9 mine, Roslyn, Wash., to determine the feasibility of extracting coal from pillars and from a solid coal face in development without drilling and blasting. During pillar mining, using a hand-held monitor, the best results were obtained with a 0.150-inch- diameter nozzle, a water pressure of 3,500 psi, and a flow rate of 38.5 gpm.3 The rate of mining and productivity were 0.74 ton per minute and 16.6 tons per man-shift, respectively. During development mining, using a monitor mounted on a roof jack, the best results were obtained with a 0.148-inch-diameter nozzle, a water pressure of 4,500 psi, and a flow rate of 40.0 gpm. In one section of the mine where the coal was relatively hard, the rate .of mining and productivity were 0.10 ton per minute and 5.7 tons per man-shift, respectively in another section of the mine where the coal was relatively soft, the rate of mining and productivity were 0.51 ton per minute and 8.3 tons per man-shift, respectively. The tests showed that hydraulic mining methods were more productive than conventional mining methods in pillar mining. In development the productivity of hydraulic mining depended primarily upon the coal hardness. Compared with conventional methods, hydraulic mining methods were less productive where the coal was relatively hard and equally as productive where the coal was relatively soft.

Jan 1, 1963

By Michael G. Zabetakis

THIS is a summary of the available limit of flammability, autoignition, and burning-rate data for more than 200 combustible gases and vapors in air and other oxidants, as well as of empirical rules and graphs that can be used to predict similar data for thousands of other combustibles under a variety of environmental conditions. Specific data are presented on the paraffinic, unsaturated, aromatic, and alicyclic hydrocarbons, alcohols, ethers, aldehydes, ketones, and sulfur compounds, and an assortment of fuels, fuel blends, hydraulic fluids, engine oils, and miscellaneous combustible gases and vapors.

Jan 1, 1965

By Lester M. Adams

In 1980, the Bureau of Mines surveyed a group of mine seals in Randolph County, WV, to evaluate their effectiveness for reducing toxic pollutants in mine water discharges. The survey focused on 11 block wet mine seals, but mine seals of several other types were also examined. The seals were installed in 1966 and 1967 in abandoned drift portals by the Federal Water Quality Administration (FWQA), a predecessor of the Environmental Protection Agency (EPA), in cooperation with the Bureau of Mines and other Federal and State agencies, in a project known as Elkins Mine Drainage Pollution Control Demonstration Project. The seals were designed to prevent air from entering the mine portals while allowing mine water to flow out. It was believed that by preventing air from entering inactive or abandoned mines, the formation of toxic pollutants and acid mine drainage (AMD) could be reduced. Evaluation of the seals was based on water flow measurements, water analyses, and visual observations. The Bureau's 1980 data were compared with past data collected by the EPA. Several leaks and failures were observed in the clay seals, as evidenced by apparent blowouts and the absence of vegetation where the mine water surfaced. Analyses of the 1980 data indicated some improvement in the quality of water discharged from many of the wet air seals.

Jan 1, 1984