Search Documents

By T. Kumaresan

The Bayer process used for refining bauxite to smelting grade Alumina serves as the linchpin of the Aluminum production industry worldwide. Even though the process is well established, the presence of impurities in the liquor affects the quality of product and imposes a major economic cost on the industry. This review article focuses on the issues pertaining to Gibbsitic (Al2O3.3H2O) precipitation circuit. The comprehensive review provides a basic understanding of the aluminum trihydrate precipitation and agglomeration phenomena. Crystal growth rate and agglomeration play a significant role in determining the output PSD of agglomerates. Hence, the effect of certain thermodynamic and hydrodynamic parameters along with the impact of impurities (oxalates, aldols, acids etc.) and additives on hydrate growth has been reviewed.

Sep 1, 2012

By F. M. Zafar Kaifi

Magnesite producing companies rely on high grade purity MgO. The mineralogy of magnesite has a significant impact on the manufacturing of magnesite bricks. The manufacturing process of bricks companies utilizes 90% magnesite from 85%~90% MgO. The main objective of the magnesite bricks was to utilizes the indigenous raw material available in bulk quantity. With better under-standing of chemistry of the mineral species and strict control of bricks manufacturing/processing conditions can be better produce efficiently, a low cost high quality bricks with minimum detrimental environmental impact.

Jan 1, 2014

By R. C. Dunne

As ore grades of existing and new ore deposits continue to decrease there is ever increasing pressure to decrease operating costs to maintain profitabitabitiy at existing mine sites and for new projects. The accepted solution to this dilemma in most cases is to increase treatment rate, leading to a coarser grind, at the expense of marginal decreases in recovery. The recovery loss is usually associated with losses of liberated and composite coarse material. This paper will review the practice of coarse particle flotation, including the reagent chemistry, cell hydrodynamics, froth stability, entrainment and flotation cell design, all parameters important to the recovery of coarse liberated and composite particles. This will provide a better understanding of opportunities to improve the recovery of coarse particles. Some examples will be provided.

Sep 1, 2012

By F. Q. Cheng

Despite the successful industrial practice to recovery KCl by flotation, the adsorption state of collectors at KCl salt surfaces is still not fully understood. In this paper, the captive bubble contact angle measurements at KCl and NaCl crystal surfaces in their saturated solutions are reported. The influence of different collectors and their concentration are considered. The results show that both cationic and anionic collectors produce a hydrophobic state at the structure breaking KCl salt sur-face, with finite contact angle values of between 30o and 40o. In contrast, the contact angle at the structure making NaCl salt surface is zero at all collector concentrations, suggesting that no collec-tor adsorption occurs, a supposition that is supported by results from molecular dynamics simulation (MDS). Further, it appears that the presence of surface defects such as edges and corners promote the adsorption of collectors at the KCl surface, and that the flotation is achieved by bubble attachment at the edges/corners of KCl particles with the formation of aeroflocs.

Jan 1, 2014

By Xiaolu Ye

"Comprehensive utilization of Bi and Sn from the tin-associated polymetallic tailings by “gravity separation – flotation combination process” has been studied, which was verified that the novel process is an effective method to deal with the high content pyrrhotite tin-associated polymetallic tailings. In this investigation, ore property analysis and magnetism analysis of pyrrhotite were conducted to research and develop reasonable beneficiation flowsheet. The results of ore property analysis present that pyrrhotite was not closely related to bismuth and tin minerals. Particle size analysis results indicated that pyrrhotite was mainly in the form of fine particles. The magnetic analysis results show that pyrrhotite was distribution in all the three types of pyrrhotite in a single mining area, which indicated that variable magnetism of with different crystal structure pyrrhotite. The process of “low intensity magnetic separation - high intensity magnetic separation” shown an excellent adaption for the high content pyrrhotite tin-associated polymetallic ore compared with the single flotation process based on the magnetism variable of pyrrhotite. The results of whole process test indicated that a bismuth coarse concentrate assaying 5.63% of Bi at 81.77% recovery was obtained, which treat the conditions for the Bi-S separation flotation. In addition, the content of sulfur in the tin concentrate decreased from 2.5% to 1.5%, which provided a new reference for other tin-associated polymetallic tailings. INTRODUCTION Tin has been applied extensively in catalytic chemistry, gas sensors, tin plating, and plumbing. Tin-bearing polymetallic ores have been the important deposit types to recycle tin with the rapid depletion of mineral resources. The comprehensive utilization of the associated elements has been a preoccupation for the mineral processing researchers."

Jan 1, 2018

By P. Coghill, P. Revell

"Geo-sensing is the ability to routinely measure or infer rock properties at a range of scales using non-destructive scanning devices. These devices can provide information and data flows to support integrated decision making across the minerals value chain. Geo-sensing has been used for many years in minerals exploration using technologies such as satellite imaging and airborne geophysics but to date the use of sensing technologies in between the mine and mill has been very limited. The aim of this research is to develop new mineral sensing technologies that can enable grade engineered ore streams through the rejection of low value gangue or deleterious elements either in the pit or during transfer to the mill. This paper focusses on the research and development being carried out by the Cooperative Research Centre for Optimising Resource Extraction (CRC ORE) and its associated members on new sensing technologies. At the start of their development these technologies were classified on the Technology Readiness Level scale at 3 (TRL3), equivalent to a proof of concept. Laboratory testing and design is aimed at progressing these sensing technologies to TRL5 which is ready for testing at an end users site. New data obtained during the laboratory testing and design phases are presented in the paper demonstrating performance specifications such as detection limits and measurement speed which can be used to infer the pod size of gangue that can be rejected at scale. Grade Engineering® and coarse gangue rejection are considered as key drivers for the mining industry to address the higher mining, processing and environmental costs associated with ore bodies with declining grades. This is an industry wide problem and the development of mineral sensors is seen as key enabling technologies for Grade Engineering® and coarse gangue rejection. The technologies presented in this paper enhance value through early decision making of ore quality and improve the overall resource value case through improved grade and throughput engineering."

Jan 1, 2018

By Alexsandro Berger

Many thickener operations continue to be constrained by their ability to process consolidated underflows with high yield stress and associated rheological characteristics. To maximise separation efficiencies within a thickener operation the use of both engineering and reagents are always considered. BASF is developing a Novel Flocculant Technology (NFT), which combines both of these aspects to enhance the performance of the thickener operation, improving the areas of pumping efficiency, underflow density and throughput. The development progression through stages of laboratory scale batch test work to pilot scale dynamic testing has demonstrated the ability of BASF NFT to maintain effective flocculation performance whilst increasing the rate of underflow consolidation, and significantly reducing the associated underflow yield stress of the treated material. This paper will present application data through full scale dynamic testing conducted on a granite washing circuit to demonstrate the performance benefits that NFT offers to a thickener operation. Compared to the conventional flocculant treatment, within the operation parameters and conditions employed during the full scale trials, the NFT produced a reduction in underflow rheology (yield stress) of around 45 % relative to a given solids and improved the underflow consolidation by providing at least 20% relative higher underflow solids loading than the upper limit of the given typical thickener operation. Keywords: flocculation, thickener operation, rheology, yield stress, underflow density, throughput, slump test

Sep 1, 2012

By Sergey Ulianov, Arkady Senchenko, Alexey Shvets, Arkady Bakotin

"This paper contains description of research results of technology development for copper recovery from weathered tails of iron processing plant. The predominant host mineral that contains valuable component is chalcopyrite occurring in its free form and in associations with ore and rock-forming minerals. Copper grade is 0.26-0.30%. Emulsion inclusions of chalcopyrite in pyrite and sphalerite were noted. Major problem is low copper recovery (30-35%) by flotation. When studying chalcopyrite in primary concentrate it was determined that the surfaces of many chalcopyrite grains are covered with oxide films which prevented collector attachment onto them. Second issue was deep association of chalcopyrite with pyrite and sphalerite. Sulfidizing reagent addition did not help to reach the required level of copper recovery to concentrate. In the result of research performed the technological flowsheet was developed including preliminary treatment of head material in a special unit aiming at oxide films removal, followed by copper rougher flotation on head size tails, crude concentrate regrinding and a number of cleaner flotation operations. After the treatment of weathered tails according to the flowsheet developed, copper recovery to flotation concentrate became 71.53%, at 23.46% copper grade. The suggested technology allows one to solve the issue with treatment of technology-related copper-containing stockpile material, as well as to include the ores where copper is represented by sulfide minerals covered with oxide films into processing."

Jan 1, 2014

By S. Sarioglan

The bleaching of edible oils, industrial oils, and some chemicals may be achieved using natural and acid-activated clays. These materials remove impurities and pigments from the oils. In this work, a bentonite clay from Turkey (Somas bentonite) was activated with different concentration of H2SO4 and HCl at 70~90°C and 5~8 hours. Under these conditions several cations were removed from natural bentonite (Al, Mg, and Fe) and DTA-TGA, FT-IR curves of the solids obtained after acid treatment were examined. Treatment time and acid concentration increased the degree of destruction of the bentonite structure which was determined by ICP. Activated samples were tested in order to verify their capacity to bleach soybean oil and compared to standard commercial bleaching clays. The experimental results indicate that treated samples with H2SO4 have the same efficient in bleaching crude soybean oil with the standards and treated sample with HCl is more efficient in bleaching than the commercial products.

Jan 1, 2014

By R. ?. Shishmarjov, Yu. ?. Davidenko, S. V. Bukhalov, ?. S. Baksheev, M. S. Shkirya, N. ?. Aikasheva, D. V. Bogdanovich, ?. Yu. Faustova

"The goal of prospecting operations in the Republic of Altay was to locate gold-sulfide-quartz mineralization. For this purpose we applied the technology of electromagnetic sounding and induced polarization (EMS-IP). These operations resulted in localizing promising sites with presence of sulfidization. The EMS-IP method proved to be highly efficient amongst other prospecting methods targeted at recognizing zones of sulfide mineralization making up 91%, considering that in more than half cases the ore intervals were the case. In the Yakutian diamondiferous province the EMS-IP technology was approbated during three field seasons to accomplish the assignments on searching for kimberlite bodies under conditions of various geological types. As a result, the reference objects were distinguished, and geoelectric parameters of kimberlite pipes of explosion were defined.INTRODUCTION In the time span 2015-2016 in Gorny Altay the EMS-IP technology was approbated in the Novokuznetsk area. The on-land areal geophysical survey was performed by EMS-IP method applied to identify, outline and locate promising sites with Au-Ag-bearing polymetallic mineralization within surveyed areas. Compared to the hosting rocks, the sulfides contained in polymetallic mineralization are typified by low specific electrical resistivity (SER) and high polarization. The areal survey conducted via EMS-IP method provided spatial characteristics of searched object. From July 2016 to August 2017 our expedition group carried out serial test works and laboratory investigations intending to define performance capabilities of EMS-IP technology in searching for kimberlite bodies under conditions of diverse geological types. The prerequisites for serial work were operations accomplished at the «Listvenichny» site lying 35 km away from Mirny town in the Sakha Republic (Yakutia), where the EMS-IP technology was probed for locating position and measuring geoelectric parameters of tuff pipe «Buardakhsky». After successful completion of operations it was decided to evaluate geoelectric parameters of kimberlite pipes of explosion."

Jan 1, 2018

By Montaser S. EL Salmawy, Takahide Wakamatsu, Eishi Kusaka

"The effect of ethoxylation of long chain alcohols on the quartz and feldspar flotation behaviors was investigated for surfactants of the octylphenol polyoxyethylene family. The tests were carried out with an average of 7.5 (Triton X 114), 9.5 (Triton X 100), 30 (Triton X305), 40 (Triton X 405) and 70 (TritonX 705) oxyethylene units. Electrokinetic and flotation studies on quartz have shown that at low pH values, quartz could be floated with polyoxyethylene octytlphenols. The possible mode of adsorption of these nonionic surfactants may be suggested to be due to hydrogen bonding between the oxygen of ether and hydrogen in the free hydroxyl groups on quartz surface. It was anticipated that the selectivity between quartz and microcline would decrease as oxyethylenic chain length increases.Electrokinetic methods were used to elucidate the mechanism of surfactants adsorption and to correlate these findings with the optimum flotation conditions. The polymeric surfactants would reduce the negative values of zeta potential of quartz while the reverse is true for feldspar. After treatment of microcline with HCl, its electrokinetic behavior in the presence of Tritons X surfactants became similar to that of quartz.The obtained results would suggest that separation of quartz from feldspar using nonionic surfactants of octylphenoletoxylated alcohols having shorter oxyethylenic chain length at low pH could be achieved"

Jan 1, 2003

By Georges Delemontex, Nigel Grigg

"Pre-concentration of precious metal and base metal ore types is becoming more relevant with the discovery, development and operation of many lower grade deposits around the world. The fluctuations in metal prices and currencies expose many mines to risks especially dealing with low and variable ore grades. Pre-concentration, the process of concentrating the valuable metal into a smaller mass yield, effectively results in the introduction of higher feed grades to milling circuits. Gangue rejection, the removal of lower S.G. waste rock from the circuit, not only results in higher downstream grades but also potentially removes harder, non-valuable mineral, providing significant power savings within the circuit. The pre-concentration or ‘gangue rejection’ process offers a number of benefits when considering the treatment of marginal ore deposits, especially if it can be performed at a coarse crush size; these benefits include a reduction of the operating costs and the feed of more metal units to the mill. Gekko Systems has effectively utilized the Inline Pressure Jig (IPJ) to pre-concentrate the valuable metal, achieving high primary recoveries into a range of mass yields resulting in upgrade ratios between 2 and 10 times. This paper explores: the benefits of pre-concentrating ‘marginal’ ore deposits prior to the milling circuit; the selective rejection of ore types that may affect either the recovery or comminution process; and also looks into the potential to effectively reduce the ‘cut-off’ grade when considering the mine planning process. Case studies of projects using the IPJ to pre-concentrate and reject gangue are also included. Pre-concentration and gangue rejection provide the potential to develop marginal ore deposits, thus providing higher grades, less gangue and more metal at a lower operating cost to producers."

Jan 1, 2014

By C. G. Anderson

Industrially proven and applied nitrogen species catalyzed (i.e. NSC) acidic pressure leaching has been utilized to treat a number of ores, concentrates and recycled materials. This versatile technology offers many advantages including low temperatures, low pressures, low capital costs, low operating costs, faster throughput and less costly materials of construction than conventional pressure oxidation. This paper will elucidate the application of this technology for production of gold, silver, palladium, rhodium, zinc, germanium, gallium, cobalt, copper, molybdenum, rhenium and nickel. Recycled material applications will also be elucidated. In addition, details of an application for treatment of a refractory chalcopyrite copper and gold bearing ore will be presented and pertinent economics discussed.

Jan 1, 2014

Low-grade ore bodies, increase in rock competency, finely disseminated valuable minerals in the ore bodies, ore variability and water scarcity are among the technical challenges faced by the mining industry. These challenges have increased the business risk, capital investment and operating cost of the mining projects. Since the last 20 years, many large-scale concentrators have been built to cope with the above-mentioned challenges. Comminution, especially the fine grinding is an energy-intensive process. For example, the ball mill has a limitation in the fine grinding regime where the energy consumption increases exponentially when the product size is below 45 µm. The industry has been seeking for solutions that have a minimum risk and total cost of ownership. The stirred milling technology such as the TowerMill is well accepted by the industry as it has demonstrated the attributes required for fine grinding. TowerMill is a matured technology that has been adopted since the 80s for regrinding duty. Recently, this technology was installed in secondary and tertiary grinding duty to prepare a finer feed to rougher flotation. Four units of TowerMills were installed in a magnetite concentrator in Western Australia in tertiary grinding duty. Recently, Nippon Eirich has conducted process performance evaluation on the TowerMill circuit. The outcome of the exercise had indicated that the circuit is consuming 3.4 kWh/t to reduce from 55 µm to 35 µm with a narrow product size distribution. The effect of operating variables such as the specific energy, grinding media size, mill content % solids and mill feed configuration on the grinding efficiency were evaluated at the plant scale. Furthermore, the scale-up methodology was validated. The scope of this paper includes the performances of TowerMill and the validation of scale-up methodology.

Jan 1, 2018

"The first 90 years of the last century generated a considerable volume of technical literature on the subject of grinding mill power and its prediction. It is therefore surprising that during this time there were no published models for predicting grinding mill power draw which were validated using a wide range of comprehensive industrial scale data.Notwithstanding this lack of data, the majority of models placed limited emphasis on the internal dynamics of mills and relied on simple assumptions which considered the charge to take up a fixed position and shape.Laboratory based studies (Liddell, 1986), and industrial data (Morrell, 1993), showed that these assumptions did not hold over a wide range of operating conditions, and brought into doubt the ability of the (then) existing models to accurately predict grinding mill power draw. Furthermore no model treated AG,SAG and ball mills as a single class of devices whose power draw could be predicted with the same equations.Through a detailed investigation of the charge dynamics, coupled with a large data base of industrial mill power draws, this situation was rectified by the end of the century, by which time a model had been developed and validated, which accurately predicted the power draw of all wet tumbling mills. This paper describes this model and reviews some of the earlier attempts at mill power modelling."

Jan 1, 2003

By F. Q. Dong

According to the principle that should be originated from nature, compatible with nature, used in nature and back to nature and based on conception of designing of eco-material, the author combined the ideas of material, environment, zoology and healthy. Properties of natural mineral materials were used to produce micro-aggregate elements by bionic method, so its components and function could accord with living environment. Eco-mineral functional materials which can adjust, purify and optimize the microclimate were reviewed. The authors pointed out the multifunction, com-pounding, the compound characteristics and integration regularities of micro-aggregates. It was the first time in the world to put forward the ?gene? technique or ?material chip? technique of manufacturing function micro-aggregates and eco-function elementary materials. The results of this re-search supported by the national ?863? Hi-tech Project, mainly including the high-efficient air purifying mineral compound material indoor, the clay elementary antibacterial materials, the masonry cement/coating/putty/compound with preventing radon radiation, environmental friendly composite functional coatings, mosquito repellent and healthcare material and zeolite-based energy-saving composite materials, were introduced. Finally, the foreground of mineral materials in the field of future advanced eco-friendly materials was also discussed.

Jan 1, 2014

By M. Saghaeian, R. Hejazi, R. Barreiro, M. Tavousi, M. Ahadi, O. Asghari

"Banded iron formations are the major iron source for producing high grade concentrate. BIF are generally lower grade and more difficult to extract. In order to know how best to process BIF ore, it require comprehensive knowledge on ore bodies even in the early stages of the mining process. Geometallurgy combines geological and mineral processing information and allows for higher flexibility in response to changes in the plant feed when mining different parts of the ore. This can lead to economic benefits, owing to improved plant operation, yet is time consuming and correspondingly costly. The main focus of this paper work has been to develop a comprehensive geometallurgical testing framework for developing Yogi BIF low grade magnetite deposit located at Western Australia. In order to provide successful geometallurgical mapping, was collected data from several different disciplines (geology, chemistry, mineralogy) and parameters (physical properties, metallurgical response and geotechnical measurements) during drilling activities and test work. The investigation shown magnetic separation behavior of material had high variation and is most important element in the proper design of ore beneficiation plant. This paper provides an improved and efficient magnetic separation test methods used for the investigation of separation behavior and variability of the Yogi Ore deposit and evaluates their applicability and potential in the geometallurgical context. In this paper a small-scale magnetic separation has been developed that allows estimating from single pass separation test using small amounts of sample material. Verification of the evaluation method and validation was done with different mineral systems."

Jan 1, 2018

By Diana Drinkwater

As ore grades decline, ore deposits get harder and mineralogical complexity increases, metallurgical skills are more important than ever to ensure that today?s mining operations are operating efficiently and profitably. Yet specialist undergraduate degree programs have all but disappeared and metallurgical skills training for graduate engineers in the workspace if often haphazard. In response to this situation, specialists at the JK Centre in Queensland, Australia, have put together a professional development program designed to fast-track skills development for early career metallurgical professionals. The program, called ?MetSkill ® ?, is offered as a group training package for young metallurgists in the workplace. It is centred on a meaningful technical investigation negotiated between the JK Centre delivery team and the client company. As well as learning about project management and data collection and analysis, the participants study specialist topics such as comminution, flotation and mineralogy under the tutelage of senior research and consulting professionals. The technical investigation provides an opportunity for immediate practice of these new skills and JK Centre specialists are on hand to provide feedback and support throughout the program. The participants are employed across different operations in Australia and the Asia-Pacific, and although they occasionally come together for group training activities they are often separated by considerable distance. Specialist educational professionals from The University of Queensland have provided an innovative web platform to support collaboration and communication between all participants. This paper will describe the MetSkill ® program in detail, as well as providing a report on its initial roll-out to 2 groups of Australian graduate metallurgists in 2012

Sep 1, 2012

"The first 90 years of the last century generated a considerable volume of technical literature on the subject of grinding mill power and its prediction. It is therefore surprising that during this time there were no published models for predicting grinding mill power draw which were validated using a wide range of comprehensive industrial scale data.Notwithstanding this lack of data, the majority of models placed limited emphasis on the internal dynamics of mills and relied on simple assumptions which considered the charge to take up a fixed position and shape.Laboratory based studies (Liddell, 1986), and industrial data (Morrell, 1993), showed that these assumptions did not hold over a wide range of operating conditions, and brought into doubt the ability of the (then) existing models to accurately predict grinding mill power draw. Furthermore no model treated AG,SAG and ball mills as a single class of devices whose power draw could be predicted with the same equations.Through a detailed investigation of the charge dynamics, coupled with a large data base of industrial mill power draws, this situation was rectified by the end of the century, by which time a model had been developed and validated, which accurately predicted the power draw of all wet tumbling mills. This paper describes this model and reviews some of the earlier attempts at mill power modelling.INTRODUCTIONThe early 1900?s saw the beginnings of published papers which tackled the problem of what influenced the power draw of tumbling mills and what equations (models) were suitable for predicting power draw. This interest continued for the rest of the 20th century and the literature contains many papers that attempted to satisfactorily answer these questions. A common and disappointing theme in the majority of them, however, is the distinct lack of suitable experimentally derived power draw data. This deficiency consequently limited the practical application of many of the attempts at modelling mill power draw. Prior to the early 1990?s some limited data on the power draw of grinding mills in the literature can be found, but as Harris et al (1985) remarked they are ?... too frequently unusable simply because one or more essential variables have been omitted?. The absence of published results, from vigorous experimental testing of the various models, has resulted in a general lack of evaluation of the validity of assumptions and hypotheses that such models contain. Harris et al (1985) however, did make some efforts in attempting to evaluate the performance of various power prediction equations and in so doing further developed a semi-empirical one of their own. However, in using manufacturers? published data, which themselves were undoubtedly generated by proprietary equations of unproven validity, they probably succeeded in generating little more than a consensus of the various errors in these models."

Jan 1, 2003

By Shounak Banerjee, Suresh Babu Dasari, Dharmendr Kumar, Shashank Pardhikar, Beena Rai, Venugopal Tammishetti

Recent increase in steel demand has led to the increased usage of high grade iron ores. During the mining, crushing and washing of ore, huge quantities of fines and slimes (<150 µm) are generated, majority of which is dumped into tailing ponds owing to their high alumina contents (~10-15%). Due to rapid depletion of high grade iron ore, it is the need of the hour to utilize low grade iron ore fines and slimes. These fines and slimes contain high iron values assaying 45-60% Fe. Dumping these valuable resources in ponds locks enormous land space and causes environmental hazards. The constituent minerals present in Indian iron ores comprise of hematite, goethite, gibbsite, kaolinite and quartz. Our research is focused on beneficiation of iron ore slimes through selective flocculation. We use density functional theory simulations to screen the reagents and perform experiments with screened reagents to determine the experimental conditions for effective performance of the reagents. Our studies revealed that reagents like starch, guar gum and carboxymethyl cellulose exhibit excellent selectivity in high alkaline pH range. However, the higher cost of alkali makes the process economically less attractive. In the present study, a commercial reagent from NALCO Water (Hi-Tex 83570) has been explored as selective flocculant for beneficiation of iron ore slimes in wide pH range (4-11). However, the reagent was also found to be the most selective in alkaline pH range only. Full factorial design of experiments was done considering three parameters namely, pulp density, flocculant dosage and settling time. Regression models were developed for yield, iron grade, alumina grade and iron recovery in the concentrate, using experimental results. Further parameter optimization was done to achieve high Fe recoveries and low alumina recoveries. The optimal parameters thus arrived at were validated with the experiments. We were able to achieve a concentrate grade of 60.0% Fe and 5.1% Al2O3 with 68.8% Fe recovery from a feed containing of 53.1% Fe and 8.9% Al2O3. The performance of flocculant Hi-Tex 83570 was also compared with reagents starch and guar gum.

Jan 1, 2018