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By Y. Mudryk, D. Paudyal, K. A. Gschneidner, V. K. Pecharsky, M. Khan

"Rare earth intermetallic compounds are utilized commercially as magnetic and battery materials, electron gun electrodes, etc. Several of these intermetallics will be briefly discussed. There are many other rare earth intermetallic compounds which are not utilized industrially but have unusual properties which are of fundamental interest and may have future technological applications. Several of these materials are discussed as well.INTRODUCTIONTens of thousands of rare earth intermetallic compounds exist, but physical properties (primarily their magnetic behaviors), other than their crystal structures have been measured for only a small percentage of these materials. Among these are the commercially important compounds: Nd2Fe14B, and the SmCo5 – Sm2Co17 family – well known high strength permanent magnets; (Tb0.3Dy0.7)Fe2, Terfenol-D, a giant magnetostrictive material; LaNi5Hx a critical component of the rechargeable Ni metal hydride batteries; and LaB6 an electron emitter. There are, however, many other intermetallic compounds which are not utilized industrially, but none-the-less, exhibit interesting, and sometimes, exotic physical properties which are of fundamental interest and may have some future technological significance. These include: the giant magnetocaloric effect compounds Gd5Si2Ge2 and La(Fe13-xSix)Hy; the RCu and RAg families of ductile intermetallics; the mixed intra-lanthanide (R,R')Al2 compounds in which magnetic transitions disappear and reappear as one R is substituted for by R'; and GdNi which exhibits large dilations along two crystallographic directions and a larger contraction in the third direction at the Curie temperature resulting in zero volume change as GdNi orders magnetically via a second order phase transition.COMMERCIALLY IMPORTANT INTERMETALLICSNdFeB Permanent MagnetsThe Nd2Fe14B permanent magnets were discovered in 1984 independently in the USA and Japan. It is a ferromagnet and with proper heat treatment and processing Nd2Fe14B is the strongest near room temperature permanent magnetic material known today. This intermetallic compound is utilized as a permanent magnet in many applications, such as electric motors (e.g. the modern automobile contains up to 35 electric motors), spindles for computer hard disc drives, microphones and speaker magnets for cell phones and other audio equipment, direct drive wind turbines, actuators, and Magnetic Resonance Imaging (MRI) units. There are two kinds of NdFeB permanent magnets – bonded and sintered. The bonded magnets have a lower magnetic strength than the sintered magnet. The highest strength magnets are obtained by small substitutions of Dy (up to a maximum of 10%) for Nd, because Dy can significantly increase the coercivity and thus the energy product (a measure of the magnetic strength or hardness). The bonded magnets account for about 12% of the NdFeB market (~82 metric kt per year, containing ~20 kt/a of Nd). The NdFeB permanent magnet market is growing at a rate of about 15% per year. (Burzo & Kirchmayr, 1989; Kobayashi & Hirosawa, 2001; Coey, 2011)."

Jan 1, 2012

By J. J. O?Neill

Introduction The Beattie mine is the first of its character to be exploited in Quebec. It is primarily a large low-grade gold deposit containing values which a few years ago would not have been considered as ore. Much interest is attached to this development as its success may mean a greatly enlarged scope to gold mining in Canada on deposits which have formerly been considered worthless. Because of its potential importance as a pioneer in low-grade gold mining, the Quebec Bureau of Mines decided to make a careful detailed study of the Beattie in the hope not only of assisting in its development, but of stimulating the search for similar essential geological conditions in other parts of the Province. This paper is a summary of the results obtained during two months on the property in 1932, supplemented by a few trips underground in 1933. The full report will appear in the Annual Report of the Quebec Bureau of Mines for 1932, Part C. Location and Means of Access: The Beattie ore-body is situated two miles west and one half mile north of the centre of Duparquet township, and approximately 22 miles north 28° west of the town of Noranda. Until the fall of 1932, access to the property was from LaSarre, on the Canadian National railway, over a thirty-mile water route with one portage 600 feet long; about 2,000 tons of machinery and supplies were taken in by that route. An automobile road, nine miles long, now connects the property with the Makamik highway, and a narrow-gauge railway, without ballast, gives outlet for concentrates from the mill to the C.N.R. tracks of the Rouyn-Taschereau line, nineteen miles distant.

Jan 1, 1934

By J. E. Nesset

"As an alternative to conventional dewatering by vacuum filtration and oil-fired rotary dryers, Brunswick Mining conducted extensive pilot-scale testwork on its copper, lead, zinc and bulk concentrates using a Larox Oy (Finland) automatic pressure filter. The results showed that pressure filtration readily produced final cake moistures of 6-8.5 per cent on this very fine sulphide material.An in-depth analysis examines pressure filtration in terms of metallurgical performance and projects energy savings of 78 per cent for pressure filters over the current dewatering operation. Potential energy and operating cost reductions are also estimated.IntroductionVacuum filters followed by oil-fired rotary dryers are one of the most common means of dewatering mineral concentrates. They represent, however, a level of technology which is exceedingly wasteful in terms of manpower, space utilization equipment and fossil fuel dependence. In addition, the use of thermal dryers is leading to increased environmental concerns both in plant and out.These were the primary factors which prompted Brunswick Mining to consider alternative dewatering methods as the existing equipment came up for replacement and upgrading. In late 1979, company engineers were encouraged by automatic Larox pressure filters seen at several Scandinavian operations. Subsequent laboratory tests by the manufacturer (Larox Oy of Finland) on several concentrate samples were sufficiently promising for Brunswick and Noranda to lease a trailer mounted filter-lab unit and a technician from Larox for a five-week period. Extensive on-site testwork on all four Brunswick concentrates (zinc, lead, copper and 'bulk' lead-zinc) confirmed the potential of pressure filtration."

Jan 1, 1982

By Chen Feng

Compared to widespread successful deployment of robotic manipulators for repetitive and hazardous tasks in related industries such as manufacturing, the construction industry has achieved relatively limited benefits from robotics and soft automation. Unlike manufacturing, where robotic solutions benefit from the structured layout of the environment (e.g., factory assembly line), construction robots face unique challenges that arise from the rugged, dynamic, and unstructured environment of the work site, as well as the uncertainty and evolving sequence of occurring on-site events. This challenges any intended construction robots to not only replicate basic human motion, but also be capable of sensing and adapting to environmental changes, and making decisions based on the evolving state of the environment. Building upon recent advancements in robotic mapping, computer vision, and object recognition, the authors propose to introduce autonomous behavior at the basic task level for on-site construction robots to address these challenges in a flexible and extensible manner. This paper reports the outcome of the first phase of this research - a structured methodology for improved design and development of basic task automations - and focuses on algorithms developed for mobile robot navigation and relative pose estimation. The algorithms are implemented on a prototype mobile robotic platform, and evaluated in several experimental scenarios.

Aug 1, 2013

By Weiren Lin

The Mw 9.0 Tohoku-Oki, Japan earthquake occurred on 11 March 2011 produced a maximum coseismic slip of >50 m near the Japan Trench. To investigate why the plate boundary fault between the subducting Pacific Plate and overriding North American Plate which caused the earthquake had such unprecedented large coseismic displacement and slipped to the trench, Integrated Ocean Drilling Program Expedition 343 called Japan Trench Fast Drilling Project (JFAST) drilled three boreholes at Site C0019 through the earthquake fault about one year after the earthquake. Borehole C0019B dedicated to loggingwhile- drilling (LWD) penetrated ~850 meters below seafloor (mbsf) at a water depth of approximately 6890 m. The plate boundary fault is located at ~820 mbsf in the borehole and has been identified as the slip zone during the Tohoku-Oki earthquake. Borehole wall resistivity images obtained from LWD show that drilling induced borehole breakouts are available in a wide depth range above the fault but are not available below the fault. Breakouts are reliable indicators of the orientations of current maximum and minimum horizontal stresses and can also be used to constrain the horizontal maximum and minimum stress magnitudes. As results of breakout analyses, the maximum horizontal stress orientation highly varied in the upper part of the borehole, but has a clear preferred orientation in a northwest – southeast direction in the deeper part just above the fault. This orientation is approximately parallel to the direction of the Pacific Plate subduction. Stress magnitude constraints indicate that the post-earthquake stress states in the hanging wall are either in or close to the normal faulting stress regime. By inferring the pre-earthquake stress state and comparing with the constrained post-earthquake stress state, a significant coseismic stress change was interpreted. The stress change suggests an active slip of the frontal plate-interface consistent with coseismic fault weakening and a nearly total stress drop.

Jan 1, 2015

By Richard Murphy

"The general geology of the Great Bear Lake area has been described by; D. F. Kidd in the Summary Report of the Geological Survey for 1932. A brief description of the Eldorado mine was prepared by C. S. Lord for Memoir 230; Mineral Industry of the Northwest Territories; published by the Geological Survey in 1941. Recently; a detailed geological examination of the mine area has been initiated by the Geological Survey and; under A. W. Jolliffe's leadershif; J. D. Bateman; H. B. Thurber; and M. Feniak have prepared a number of maps and reports; as yet unpublished. Detailed mapping of the mine has been carried out since August; 1943; by A. W. Esty.Kidd has shown that, in the largely granitic country along the east side of Great Bear lake, the Echo Bay district is one of several underlain by older rocks . These he has divided into the Echo Bay and Cameron Bay groups. The former are strongly altered sediments, .porphyries, and lavas; the latter and younger group is predominantly sedimentary and far less altered. Associated with the granite, which everywhere intrudes the sediments and volcanics, are earlier differentiates. Later than all these rocks are various basic intrusives, collectively termed diabase. All the rocks are of Precambrian age."

Jan 1, 1954

By S. Leong

This paper reports on research examining disclosures from mining companies regarding their water usage in the Macquarie and Lachlan catchment areas, both parts of the Murray-Darling Basin in New South Wales, Australia. The objective of the research was to assess whether this disclosure is sufficient to allow communities to determine whether mining companies are complying with mining conditions of consent and abiding by the requirements of their water licencing agreements. These requirements are then compared to the water reporting requirements of the Global Reporting Initiative (GRI) and the Water Accounting Framework for the Minerals Industry (WAFMI). Communities are concerned about whether the mining industry?s use of water will have impacts on their livelihoods and lifestyle and thus require information concerning the quantity of water that will be extracted, how much water will be left for other stakeholders and whether the mining will affect water quality. This is an archival study. It has involved examining relevant publically available information released by mining companies and government regulators and determining if this is sufficient to meet the needs of the local communities. Additionally, it has involved looking at information indirectly provided by mining companies, via the use of intermediaries. Further, information availability concerning basic water accounting and regulatory breeches and whether such information is available at the mine site level has been considered. It is found that while NSW legislation places very little reporting requirements on mining companies, the development consent conditions for new projects and extensions to existing projects are quite significant and should be sufficient to meet the needs of local catchment residents though such information is not always easily accessible for the layperson.

Aug 1, 2013

In-Situ Leaching (ISL) process plants are low cost producers for uranium deposits where the geology is suitable. In the 1970s, a three-year pilot ISL program occurred on gold ore from the Ajax Mine, Cripple Creek District, Colorado, using a chloride and iodide solution [1]. The test was halted due to poor results. With gold and silver the international ISL progress has been slow; however the potential for low capital expenditure (CAPEX) and operating expenditure (OPEX) with large low grade deposits is real. Unless the metallurgy has been demonstrated there are significant risks which could be fatal flaws to an ISL gold or silver project. The metallurgy of gold ISL projects is far from simple and it is early days with project development.

Jan 1, 2011

By Li Qihou, Li Yuhu, Liu Zhihong, Liu Zhiyong, Yang Xiaofeng

Scorodite samples were synthesized, in adding or without crystal seed respectively by using Atmospheric Scorodite Process (ASP), Hydrothermal Scorodite Process (HSP), and Improved Atmospheric Scorodite Process (IASP) individually; and their crystal structure, crystallinity, morphology, particle size, specific surface area, Fe/As mole ratio, as well as the leaching stability were characterized, aimed to reveal the relationships among the synthesis methods, the compositional and structural properties, and the leaching stabilities of scorodite. The results show that synthesis methods have significant effects on the compositional and structural properties of scorodite. Scorodite samples of high crystallinity, small specific surface area, and low Fe/As mole ratio, possess high leaching stability. The order in the leaching stability of scorodite samples synthesized in this study is as follow: ASP<HSP<IASP. Scorodite particles in the sample synthesized by IASP without crystal seed are in large sizes and of pyramidal morphology enclosed mainly by crystal planes of {111}; and the sample possesses the crystallinity of 84.5%, the particle size (D50) of 28.2 m, the BET specific surface area of 3.72 m2/g, and the Fe/As mole ratio of 1.05; after leaching this sample by using acetate buffer solution of pH 4.95 for 10 days, the total arsenic concentration in the leaching solution is merely 1.14 mg/L.

Jan 1, 2015

By Renato Macciotta

The argillaceous formation known as the Opalinus Clay is host to the Mont Terri Underground Research Laboratory. The URL was developed to investigate the hydrogeological, geochemical and geotechnical properties of the formation. Underground excavations at the site are characterized by non-elastic and time-dependent deformations. Excavations trending perpendicular to the strike of the bedding presented relatively minor deformations, however, tunnels parallel to the strike of the bedding showed much larger non-elastic deformations. This paper presents an analysis of the measured response of a tunnel trending parallel to the strike of the bedding in Opalinus Clay. The measured convergence is compared to tunnel experience in weak rocks to assess the tunnel stability.

Jun 1, 2012

By S. Aram

Concrete reinforcing requires coordination among many roles: structural engineer, estimator, detailer, fabricator, installer and others. The methods used to define and represent concrete reinforcement elements and assemblies in building information models is crucial in determining the efficiency of sharing data among BIM platforms and the effectiveness of using the carried data in production planning, fabrication and site work activities. Starting from the information items that are required to be provided by BIM platforms, as defined in earlier work, we have developed the Industry Foundation Classes (IFC) bound Concepts and Model View Definitions (MVDs) for concrete reinforcement. Furthermore, in coordination with software developers, we propose guidelines for best practices for concrete reinforcement modeling. Implementing these guidelines by software providers will improve reinforcement modeling with regard to various aspects of reinforcement products like geometric representation, placement, and property specifications. The proposed approach is selected as a way to improve functionality of the shared data for production planning, fabrication, project management, and site activities. Guidelines for assigning information to rebar type and instance definitions as well as to rebar elements and assemblies are provided. An efficient method of sharing geometry and property sets among rebar instances of a rebar array is also defined.

Aug 1, 2013

By T. Abu Leil

A new class of ternary Mg-Sn-Ca alloys is being developed to address the dual demands of corrosion and creep resistance at service temperatures. While tin has proven to enhance the corrosion resistance, calcium is expected to significantly increase their creep resistance of binary magnesium alloys. Their effects in ternary magnesium alloys are not yet known. The series of alloys studied has Sn and Ca in the ranges 3-6% and 1¬2%, respectively. The results indicate that these alloys have two-phase structures with CaMgSn phase dispersed in a matrix that is predominantly a solid solution of magnesium. The corrosion behavior of these alloys has been investigated by means of salt spray tests and potentio-dynamic measurements. Creep behavior of these alloys was measured at a temperature of 135 C under an applied compressive stress of 85 MPa. Scanning Electron Microscopy with Energy Dispersive X-ray facility and X-ray Diffraction techniques were used to characterize the microstructures. The results indicate the prospect of designing alloys that can provide optimum combinations of corrosion and creep resistance by adjusting the relative compositions of Sn and Ca in the system.

Jan 1, 2006

"An atmospheric process for the synthesis of scorodite(DMSP®)has beendeveloped,in which ferrous ions were oxidized by oxygen gas in the presence of pentavalent arsenic ions. Under optimum conditions, the synthesized scorodite (FeAsO4?2H2O) was well crystallizedand the crystals were faceted; the particle sizes were as large as 15 to 20 µm. In thisstudy, iron (II) sulfate heptahydrate (FeSO4·7H2O), arsenic (V) acid (60mass%H3AsO4) solution, and distilled water were used to prepare the original experimental solution (700 ml), in which the contents of Fe(II) and As(V) were 55.9 g/L and 50.0 g/L, respectively. The effects of various synthesis conditions, such as the type of oxidizing gas (oxygen or air), gas injectionrate, temperature, and the initial pH of the solution, on the size and shape of the scorodite particles wereinvestigated. From the experimental results, the changes in the shape of the scorodite particles wereclarified for each synthesis condition.INTRODUCTIONDOWA has developed a processfor synthesizing well-crystallized scorodite (FeAsO4•2H2O). Theprocess is named andtrademarked as DMSP® (Fujita et al., 2008; Fujita et al., 2008; Fujita et al., 2009; Fujita et al., 2009; Fujita et al., 2009, Kubo et al., 2010). In this process, oxygen gas is injectedinto a sulfuric acid solution containing large amountsof As(V) and Fe(II). Facetedscorodite crystals as large as 15–20 µm weregeneratedthrough the pre-formation of a gel-like precursor. However, it is known that the synthesized scorodite particles become smaller and more aggregatedwhen the synthesis conditionsdeviate from the optimumconditions.In this study, the effects of various synthesis conditions, such as the type of oxidizing gas (oxygen or air), gas flowrate, temperature, and initial pH of the solution, on the size and shape of the scorodite particles were investigated. The experimental resultsclarified the changes in the shape of the scorodite particles for each synthesis condition."

Jan 1, 2016

By P. Van Marcke, X. Sillen, G. J. Chen, I. Troullinos, A. Dizier, J. Leysens, X. L. Li, J. Verstricht

"In Belgium, Boom Clay is considered as one of the potential host formations for the disposal of the High Level radioactive Waste (HLW). The URL HADES at 223 m depth at Mol site was constructed in order to study the feasibility of HLW disposal in Boom Clay. Since 1995, the URL R&D programme has focused on large scale demonstration tests like the PRACLAY experiment.The PRACLAY in-situ experiments include a set of three tests: The gallery and crossing test, PRACLAY Heater test and PRACLAY seal test. The main aim of the Heater test is to study at a large scale the thermal impact of a HLW repository on the host rock. The test is housed in the PRACLAY gallery. A hydraulic seal, made of compacted swelling and low permeable bentonite annular ring was installed at the intersection between the heated and the non-heated part of the gallery. The primary objective of the seal is to provide undrained hydraulic boundary conditions for the Heater Test.The PRACLAY gallery was constructed in 2007 and the hydraulic seal was installed in 2010. The bentonite is hydrated by natural and artificial process. The swelling, total pressure and pore pressure of the bentonite are continuously measured and analysed by numerical simulations to get a better understanding of this hydration processes. The performance of the seal is tested systematically by means of gas injection breakthrough tests and permeability tests at interface bentonite / Boom Clay and in the Boom Clay around the seal.The PRACLAY Heater will be turned on at the end of Oct. 2014, since a sufficient seal swelling has been attained to fulfill its role for the PRACLAY Heater test. This paper will focus on the PRACLAY Seal test: How we understand the process behind the hydration of the bentonite and how we test the performance of the bentonite seal."

Jan 1, 2015

By Frank Martonhegyi

"The objective of this paper is to review the coal basins in the Canadian part of the Western Cordillera to aid their understanding, and to aid in finding and proving places of economic coal mining potential. Coal occurs in eugeosynclinal basins in the Western Cordillera which evolved through three stages: -from systems of volcanic arcs in the Late Jurassic to mid-Cretaceous; -through an intermediate stage with deposition in increasingly restricted successor basins in Jurassic to Early Tertiary; -to a continental stage by the Eocene. Minor coal seams occur usually in late volcanic arc stage sediments bur they can be locally thick as they are on Queen Charlotte Islands. Successor basins usually show a marine-paralic-limnic evolurion. Signijicanr coal deposits occur in the tarter two sequences in the Whirehorse (Tantalus) and Bowser (SkeenaSusrur) basins. Currenr activities are intensive in the more accessible Bowser Basin, for example at Telkwa, Susrut River and on the Groundhog coal field. On Vancouver Island major coal seams occur in cyclic sediments, but the more accessible deposits are mined our. Exploration renewed recently in the less accessible northern part of the Island, for example Quinsam, for surface mineable coal. The Western Cordillera is a mosaic of allochtonous tectonic blocks. They originated from the south and were displaced northward by several hundred kilometres. Many Tertiary coal basins are related to strikeslip transcurrent faults along which the later part of displacement took place, for example the Dawson coal area in the Tintina Trench. Tensional and dipslip normal faulting also created or enhanced sites for thick peat accumulation. For example at Hat Creek 280 m of coal occur in a 550 m section. Secondary structures are often better exploration targets than the main fault zones. Pluvial and alluvial fan environments away from the main drainage are usually the favourable sites for thicker and cleaner coal deposition."

Jan 1, 1985

By D. L. Mckay

"Texasgulf&apos;s 25-foot-diameter Kidd Creek No. 2 Shaft is situated next to the company&apos;s No .1 Shaft, so that both shafts can share common surface and underground facilities. Shaft construction, covering a span of five years from collaring to commissioning , started by freezing the 50 feet of grey varved clay covering the bedrock. After first completing the concrete headframe, sinking to the 5/00-foot horizon utilized two different shaft construction methods. The top 2800 feet was excavated by slashing a 6-foot-diameter borehole and hoisting the broken material up the 3OO0-foot-deep No.1 Shaft; the remaining 2300 feet was excavated by conventional benching methods. Prior to installing the 5100 tons of galvanized shaft steel on the completion of the sinking operation, the sinker was able to install all thirteen armoured electrical cables in one pass with his modified galloway stage. All loading and lip pockets were installed along with the steel guides and bun tons during the equipping operation.IntroductionOn November 21,1978, Texasgulf completed the No.2 Shaft at Kidd Creek Mine. This shaft is the largest shaft (volumewise) in North America and is unique in many respects . The purpose of this paper is to outline some of the unique features of this shaft as well as to record how this facility was constructed.Soon after sinking No.1 Shaft, Texasgulf started a program of exploratory diamond drilling from the 2800 level in No. 1 Mine. The drilling outlined sufficient ore below that level to justify a second mine. Feasibility studies demonstrated that production could be increased by one-third exclusively from this deep ore . The study called for a 25-foot-diameter shaft to the 5100-foot horizon to service a mine producing 5,000 tons of ore per working day.The site chosen for No.2 Shaft and head frame is 350 feet southwest of No.1 Shaft. This, along with No.1 Shaft, will be away from the influence of ground subsidence when mining at depth. The collar and head frame foundations are located on a flat rock ledge some 70 feet below surface. This flat ledge was found by test holing through the overburden by diamond drilling. It is fortunate that this location best satisfied the surface layout and logistics for both surface and underground ore and waste handling."

Jan 1, 1981

By G. A. Maki, P. J. Fullman, R. G. Roden

"In October 1984, Rocanville Division began using a stacking system to handle potash mill tailings. Previous to this date, mill tailings were slurried to the top of the tailings pile and allowed to debrine while flowing down the pile. With the new stacking system, slurried tailings are fed to mobile stackers. The stackers consist of cyclone packs to debrine the tailings and drag conveyors with screw discharges to deposit the tailings onto the existing pile. This paper deals with the various aspects of the project from conception to its present state.IntroductionPrevious to 1984, when the stacking project was first implemented, potash mill tailings were handled as follows. Mill tailings were first debrined to approximately 65010 solids using a cyclone cluster. The cyclone underflows were then introduced onto a vacuum scroll filter table. Here the tailings were further debrined and discharged into the disposal tank where the tailings were reslurried with reclaim brine and pumped to the tailings disposal site. At the disposal site the slurry was discharged onto the tailings pile and by a natural settling process the tailings were debrined with the brine ultimately collected in the reclaim brine ponds. The shape and profile of the tailings pile was controlled by building salt dykes to control the flow of the discharged tailings slurry. As the tailings pile grew in height, booster pumps were added to the disposal system."

Jan 1, 1990

By T. Gerritsen, C. Martinez, F. Stober, T Ma, J. R. Frias, M. Sedighy, J. Janzen

Electrode control systems regulate power by physically positioning electrodes. Due to the weight and inertia of the electrodes and hoist equipment, this is a relatively slow process where power fluctuations of less than a few seconds are not fully corrected. Nickel laterite AC furnaces operating in high voltage, shielded arc mode typically incur frequent power variations of approximately +/- 20% or more around the power set point. To provide enhanced power control, Hatch has recently supplied, at commercial scale, a thyristor-switched reactance system called an SPLC. The SPLC incorporates predictive control software to operate furnaces at the maximum transformer rating by reducing the large power swings experienced without the SPLC. The resulting higher average power enables higher production, without increasing transformer or power plant capacity. A 60 MW production version of the SPLC has been commissioned on Falconbridge Dominicana&apos;s laterite nickel furnace, yielding excellent results with a 3 to 1 reduction in power fluctuations.

Jan 1, 2005

By Lassi Klemettinen, Ari Jokilaakso, Dmitry Sukhomlinov, Pekka Taskinen

The solubilities and distributions of molybdenum and iridium in iron silicate slag and copper-iron mattes were studied using an equilibration-quenching technique and subsequent direct phase composition analyses by EPMA (Electron Probe X-ray Microanalysis) and LA-ICP-MS (Laser Ablation-Inductively Coupled Plasma-Mass Spectrometry). The equilibrations were carried out on a wide matte grade interval, ranging from 55 wt-% Cu to 75 wt-% Cu, in pSO2 = 0.1 atm at 1300°C. The results in equilibrium with a solid iridium-molybdenum alloy indicated an iridium solubility of 150–500 ppmw in the sulphide matte, depending on the matte grade, and a molybdenum solubility of 100–600 ppmw. Iridium was distributing predominantly in the sulphide matte with the distribution coefficient of 10+3 - +4 but molybdenum deported predominantly in the slag with Lm/s(Mo) = 0.02–0.1. The effects of alumina and lime additions in the smelting slag were also examined. INTRODUCTION Iridium is a highly siderophile element (HSE), which means that it is incompatible with the sulphide forming elements and possesses a small solubility in mattes, such as copper- and nickel-iron sulphide melts. Molybdenum behaves only modestly in that way (Walker & Li, 2008; Righter et al., 2017). They both are known to be trace elements accompanying copper and nickel sulphide ores. No solubility data, however, are available for them in copper-rich sulphide mattes. Geochemical data on the behaviour of Ir and Mo deal mostly with low-iron silicate systems, e.g. basaltic melts, and high-sulphur sulphide solutions and mattes (Ertel et al., 2008; Fonseca et al., 2007). They also indicate that Ir and Mo dissolve in silicate melts primarily as oxides and not as electrically neutral metal species. Most geological data of iridium focus on high-sulphur systems of the monosulphide composition and typically Fe-Ni mattes where copper is a trace element (Fleet et al., 1996; Sattari et al., 2002). Direct solubility measurements for mattes and iron-lean silicates have also been made using pure Ir or an Ir alloy as the saturation phase (Borisov & Palme, 2000; O’Neill & Eggins, 2002; Makovicky & Karup-Møller, 1999; Ertel et al., 2008; Mungall & Brenan, 2014). A recent summary about the solubilities of HSE’s in iron- and sulphur free silicates is available in Laurenz (2012). The thermodynamics of molybdenum partitioning between oxides and Fe-S-O melts was studied by Mengason et al. (2011). Their results indicate strong accumulation in the iron-rich sulphide in reducing conditions (pO2 = 10-9.6 atm in Ni-NiO equilibrium at 1050°C). Molybdenum dissolves in iron-lean silicate melts as MoO3 species in oxygen pressures above the Fe-FeO equilibrium and as MoO2 in more reducing conditions (Farges et al., 2006; Righter et al., 2017).

Jan 1, 2019

By Y. Héroux, A. Chagnon, M. M. Savard

"Résumé - Le gite de Pb-Zn de Gays River s&apos;accompagne d&apos;anomalies des propriétés de la matière organique (MO) et des assemblages de minéraux d&apos;argile (AMA). L&apos;association entre la minéralisation, la distribution de la réflectance de la MO et des AMA suggère que ces traceurs peuvent servir à I ‘exploration des sulfures de métaux de base dans cette région.A I ‘emplacement du gîte, la réflectance varie considérablement (0,8% à 1,88%), pouvant même afficher une baisse avec I ‘enfouissement, ce qui est interprète comme une altération chimique de la MO. Les valeurs les plus élevées s&apos;accompagnent localement de quelques textures en mosaïque et délimitent une anomalie thermique au centre sud de la région. Parmi les minéraux des argiles identifies, I ‘illite et la chlorite sont terrigènes alors que la smectite, la kaolinite et la corrensite sont authigènes et, à l&apos; instar de I ‘altération de la MO, résultent des nouveaux équilibres chimiques créés suite à la précipitation des sulfures.Abstract - The Gays River Pb-Zn ore deposit is associated with anomalies defmed from the characters of the organic matter (OM) and from the clay minerals assemblages. The relationships between these anomalies and the mineralization at the mine suggest that these parameters can be used as new guides for the exploration for base-metal sulfides in this area.The vitrinite reflectance (RJ shows a wide range of values (0.8% to 1.88%) and exhibits an anomalous suppressive effect with depth of burial at the mine site, suggesting a chemical alteration of the OM. The highest R"" values are associated with mosaic textures and outline a therrnal anomaly at the south-center of the studied area. Among the identified clay minerals, illite and chlorite are terrigenous, whereas smectite, kaolinite and corrensite are authigenous and, like the alteration of the OM, are due to the new chemical equilibria resulting from the precipitation of the sulfides."

Jan 1, 1994