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By R. C. Reed, A. Akhtar

Oxidation of the third generation cast single crystal, nickel-base superalloy CMSX-10 is examined using isothermal tests at 900°C and 1000°C for times ranging from 20 hours to 100 hours. X-ray diffraction, scanning electron microscopy and energy dispersive secondary X-ray analysis were used to characterize the microstructure. It was found that the external scale formed at 1000°C is made up of (Ni,Co)O and the spinel NiCo2O4. The (? + ? ') microstructure of the superalloy transforms into the intermetallic (3 phase prior to the onset of internal oxidation. Internal oxidation results in the formation of (Ni,Co)Ta2O6 and (Ni,Co)WO4. No evidence was found for the formation of alumina (Al203), and the spinels NiCr2O4 and NiAl2O4 in this third generation superalloy. Results of the laboratory investigation are compared with those of an aero-engine turbine blade removed from service and examined earlier.

Jan 1, 2004

By Kenta Suzuki, Toshiya Anami, Daisuke Shimosaka

"In an Al-Mn alloy heat exchanger fin stock, the effect of annealing conditions for as-cast and 0.1%Zr addition on recrystallization behavior is investigated using metallurgical analysis. Refinement of post-brazed recrystallized grains in fin stocks with Zr addition are suppressed for long-time annealing. In 0.1%Zr fin stocks, there was a decrease in the number of fine a-Al(Mn,Fe)Si dispersoids for pinning of sub grain and grain boundary. In addition, relatively homogeneous distribution of Al3Zr dispersoids was observed with increasing annealing time in as-cast. Homogeneous distribution of Al3Zr dispersoids can have a major effect on pinning of sub grain and grain boundary during brazing heat treatment. The homogenous distribution of fine dispersoids prior to brazing heat treatment is effective in causing the suppression of refinement of post-brazed recrystallized grain structure in aluminum alloy fin stocks.INTRODUCTIONAl-Mn based alloys are widely used as fin stocks in automotive heat exchangers because of their superior mechanical properties, braze ability, sagging and so on. In particular, coarsening of recrystallized grain structure is beneficial to avoid erosion, and achieve excellent sagging resistance (Lee, Yoon, Kim & Jung, 2002). For resisting grain coarsening, the alloys should contain a dense and homogeneous distribution of fine dispersoids to retarder crystallization (Humphyreys& Hatherly, 2004). It has been demonstrated that addition of Zr to Al-Mn alloys can shift recrystallization to higher temperatures because of the distribution of fine Al3Zr dispersoids in matrix(Pokoba, Cieslar& Lacaze,2012). According to Tohma, Asanoand Takeuchi (1987), coarsely recrystallized grain structure was obtained in 3003alloy with Zr addition after heat treatment. However, fine Al3Zr dispersoids are usually heterogeneously distributed because of segregation during casting and low diffusion rate of Zr in aluminum. Therefore, a homogeneous distribution of Al3Zr dispersoids can be achieved through long-time precipitation annealing(Jia, Hu, Forbord& Solberg, 2008)."

Jan 1, 2018

By M. Reza Bateni, M. Zandrahimi, J. A. Szpunar

Titanium aluminides and nickel aluminides offer the potentials, as coating materials, for high temperature and aerospace applications. In this research, attempt has been made to develop Al-Ti and Ni-Al intermetallic compound coatings on the surface of Inconel 738. The coatings applied through pack cementation and simultaneous diffusion annealing processes. Scanning-electron microscopy (SEM), energy-dispersive X-ray spectrometry (EDAX) and grazing angle X-ray diffraction were used for evaluating of coating structure. It was demonstrated that the pack cementation technique could be used to develop TiAl3 and AlNi intermetallic compounds coating on Inconel 738 substrate. When pack cementation technique is based on a halide-activated pack with aluminum and titanium powders, the coating consists of TiAl3 intermetallic compound phase. Whereas, by pack aluminization of Inconel 738, the coating consists of AlNi intermetallic compound phase.

Jan 1, 2004

By Michael J. Rosko

Methods have been developed for processing and analyzing reflected solar radiation data obtained by Landsat 5 Thematic Mapper multispectral scanner. Spatial resolution for the Landsat series satellites is 30 meters per side per pixel. Materials on the Earth?s surface absorb or reflect different parts of the electromagnetic spectrum depending on their physical and chemical properties and, therefore, typically have characteristic spectral ?signatures?. Using these signatures, environmental parameters such as surface water and vegetation may be identified and analyzed. Principal advantages of the satellite image method for environmental monitoring include: a relatively long historic period beginning in 1985 for which information is available, the reliable numerical basis for the results, and the ability to assemble a historic environmental baseline and provide on-going monitoring for large or remote areas where standard monitoring methods may not be practical. However, because the long-term continued operation of Landsat 5 is problematic due to the age of the equipment, QuickBird and IKONOS satellite images were processed to determine if the two systems are sufficiently similar in their results to allow continuing monitoring using QuickBird data. The QuickBird satellite was launched in 2001 and collects the same visible and near infrared spectral bandwidths as Landsat 5, allowing for equivalent process algorithms for QuickBird, IKONOS, and Landsat 5 data. Spatial resolution for the QuickBird images is 2.4 meter per side, allowing for more detailed characterization of the land surface; spatial resolution for the IKONOS images is 4 meter per side. Because of several differences between the satellite systems, including degradation of the Landsat 5 sensor, it is necessary to calibrate QuickBird and IKONOS results to the Landsat results to verify similarity. Recent images from the satellite systems have been processed and results have been compared to determine the validity of comparing Landsat 5 and QuickBird/IKONOS images so that these newer data can be used reliably in the future instead of Landsat 5 data. Results from this comparison are presented in this paper and suggest that analyses for vegetation using the two satellite systems are comparable, and that little calibration is required. Results from comparison of surface water results from the two systems are less comparable and is currently being investigated by the authors.

Oct 1, 2009

By Patty Simpson, Sarah Benson

In an effort to improve consistency across the nuclear industry, over the past 10 years the Canadian Standards Association has developed a series of standards related to environmental management at Class 1 nuclear facilities and uranium mines and mills. Canadian uranium mines have been required by the Canadian Nuclear Safety Commission to align their existing monitoring programs with these standards. Orano’s McClean Lake Operation’s monitoring program, which was originally presented in the Environmental Impact Statement in 1991, has evolved through regulatory change, new scientific understanding, additional projects, and experience into a comprehensive set of monitoring requirements for effluent, groundwater, air emissions, and the receiving environment. The exercise of aligning the existing practices with the standards provided an opportunity to review and rationalize the entire program. To document the process the original “Environmental Monitoring Program Design Document” was restructured and developed as both a repository for historical information and monitoring rationalization, and also to be a living document describing on-going studies and supplementary work that are outside of the regular environmental monitoring program and may justify future changes to the program.

Jan 1, 2020

By M. J. Young, C. A. Aird

"The Gem molybdenum prospect is situated at the head-waters of Clear creek, between the Fraser river and Harrison lake, about 30 miles north of• Harrison Hot Springs, B.C. Clear creek follows a deeply eroded fault zone southwesterly through the center of the claim group. Elevations range from 2,000 feet in the creek bed up the steep slopes flanking the creek to a height of 5,500 feet. The property lies within an area underlain by schists and gneisses which strike from north to west in a broad fold plunging steeply to the northeast. This metamorphic complex has been invaded by numerous bodies of grano-diorite, much of which is gneissic. A granite plug, roughly 2,400 by 4,000 feet in size, has intruded this broad fold just west of Clear creek and encloses a circular breccia pipe 1,500 feet in diameter. In the breccia pipe, fragments of metamorphic rocks, granite and quartz monzonite porphyry are firmly cemented in a matrix of quartz monzonite porphyry. All the above rocks are cut by numerous fractures filled by vuggy quartz veins, many of which contain molybdenite. Attentien was first drawn to the area by a quartz vein, 18 inches in width, known as the Gem vein, which consists of several laminated bands of quartz and molybdenite. Since 1964, exploration efforts have been directed toward attempting to outline a large, low-grade type of molybdenum deposit."

Jan 1, 1969

By M. U. Oko

"Monitoring of all the waste streams from Falconbridge's Sudbury Operations to determine whether they meet the required standards, has been performed for many years. By 1969, however, the number of samples being collected had become so large that a complete revision of the existing systemwas necessary. Sites previously designated by name only, were numbered, clearly marked on the ground and on maps which were circulated to all concerned. The types of pollutants analyzed were determined and specified for each sampling location and a chemical analysis report form was designed. The sampling schedule has been computerized to produce a periodic listing of the samples to be taken and the analyses required.An area map showing sampling sites, chemical analysis report form, spill report and a computer print-out example are shown and explained.EVOLUTION OF FALCONBRIDGE'S WASTEWATER. MANAGMENT SYSTEMFalconbridge Nickel Mines employs some 4500 people, operates nine mines, four mills and a smelter in the Sudbury basin. The operations are geographically fragmented into four widely separated locations, the Falconbridge operations east of Sudbury and the Onaping operations in Levack Township being the two largest of the four. The Lockerby area located to the west and the Lindsley Mine just north of Sudbury are now under development. The magnitude, the diversity and nature of the operations are such that constant vigilance is needed to prevent inadvertent damage to the environment. The purpose of this paper is to describe the information system used to monitor and control waste-water disposal on Falconbridge's properties to help ensure the maintenance of effluent standards satisfactory to the Ontario Water Resources Commission (OWRC) and to the Ontario Department of Health."

Jan 1, 1971

By R. C. Lo, M. D. Scott

"This paper reviews tailings management at Highland Valley Copper, and outlines main features of its tailings storage facility enclosed between the H-H and L-L dams. Key management focusses are: energy efficiency, cost effectiveness, safety and integrity of the tailings impoundment, environmental protection, and reclamation after decommissioning. Main features of the tailings facility include: high international standards for seismic and flood design criteria, water management and water quality monitoring, operations and construction optimization, reclamation and decommissioning plan, and geotechnical challenges associated with the complex geology of the L-L tailings dam foundation.IntroductionHighland Valley Copper stores its tailings mainly in the Highland Valley tailings facility (ultimate capacity: 1.8 billion tonnes). Smaller tailings storage facilities were operated by predecessor companies: the Number One Pond, the Trojan Pond at Bethlehem and the Highmont Pond at the Highmont operation as well as backfilling the Heustis and Jersey lona Pits at Bethlehem. These areas are currently not in use, and are in the reclamation phase prior to decommissioning. This paper focusses on tailings management in the main facility. As indicated in Figure I, the facility includes three tailings dams: these are, going from east to west, the H-H, J-J and L-L Dam, named after the alignment alternatives in the initial feasibility studies. From 1970 to 1977 Canadian Bechtel Ltd. advised Highland Valley Copper's predecessor company Lornex, on tailings storage at the H-H and J-J Dams and on the L-L Dam. Since the completion of the L-L Starter Dam in 1977, Klohn Leonoff Ltd. has provided ongoing consultation and construction monitoring of the raising of the L-L and the H-H Dams. The J-J Dams is currently buried by deposited tailings. This paper reviews key tailings management focusses and main features of the tailings facility."

Jan 1, 1992

By R. Baker

A novel electrochemical half-cell and corresponding working electrode were designed to evaluate the electro-catalytic activities of catalysts in an environment close to that of an operating proton exchange or polymer electrolyte fuel cell (PEMFC). Cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) techniques were employed using the novel cell to characterize various methanol electro-oxidation parameters that contribute to the overall reaction on a fuel cell anode. The effect of temperature on methanol oxidation kinetics was examined in the potential range of 0.31 to 0.65V (vs. NHE). The data was collected in the temperature range of 20 to 80°C. Based on the experimental analysis and literature data, an equivalent circuit model (ECM) for methanol oxidation was proposed and was used to fit the EIS experimental data. The experimental data and ECM electrochemical data was used to extract electrochemical kinetic parameters for methanol oxidation such as the exchange current density, Tafel slope, and energy of activation for the reaction. Kinetic data, especially at different temperatures, is very limited in the literature.

Jan 1, 2005

By E. Goodwin

"Maclaren Forest Products Inc.Lime is commonly used for the neutralization of acid, and the removal of heavy metals in mine waste waters. However, the precipitation of heavy metals as hydroxides must take place under conditions of controlled pH, to produce minimum concentrations of dissolved metals. An account is presented explaining the concepts applied to lime-treatment processes at Bell Mine during the period of a supernatant discharge to Babine Lake; October 18, 1982to January 25, 1983. IntroductionBell Mine of Maclaren Forest Products Inc., Babine Mining Division, an open-pit copper mine, is located on Newman Peninsula, Babine Lake approximately 65 kilometres northeast of the town of Smithers, British Columbia (Fig. 1).A depressed market for copper metal in 1982 forced a management decision to suspend operations at the mine for an indefinite period from October 3 I, 1982. For some time prior to the mine closing date, mine management was concerned about the increasing level of supernatant in the tailings pond , and its possible effects on the stability of the dam when cycloning of mill tailings ceased. Consideration of these potential hazards led to an application being filed with the Provincial Waste Management for a permit to discharge the excess water to Babine Lake. This large lake, an important link with several significant salmon spawning sites, is a major contributor to the British Columbia commercial fishing industry. Jurisdiction for the environmental affairs in the area is shared by the Department of Fisheries and Oceans, the Environmental Protection Service, and the Provincial Waste Management Branch. These agencies were directly concerned in the formulation of discharge permit following joint consultation, and exchange of information with the company on environmental concerns. An approval was finally granted to discharge approximately 1,000,000 cubic metres of supernatant from the tailings impoundment at Bell Mine into Hagan Arm, Babine Lake from October 18, 1982 with a daily discharge not to exceed 9000 cubic metres. Provisions were made that a particular discharge procedure be followed, and that the company would be responsible for setting up a sampling and monitoring program to safeguard the quality of the effluent."

Jan 1, 1986

Red Chris Project Project Status ? Tahltan, Iskut First Nations MOU ? Bankable Feasibility Study ? BC Environmental Assessment Certificate ? CEAA (Federal Environmental) ? EPCM contracts LOI?s ? US$110 million Project Debt Financing(credit approval pending) ? 1st5 years concentrate production sold ? 99,150 m of drilling in 371 holes First Nations Participation Agreement ?Advanced stage negotiations

May 1, 2006

By W. J. Adams

It is recognized that within life cycle assessment that the eco-toxicity potentials (TPs) derived for metals require additional research to improve their reliability. Current models used to develop TPs do not include important fate process for metals such as speciation and bioavailability. Toxicity potentials are standard values used in LCA to enable a comparison of potential toxic impacts between substances. Huijbrechts (2001) calculated toxicity potentials for 181 substances utilizing the USES model for six impact categories, i.e. freshwater aquatic ecotoxicity, marine aquatic ecotoxicity, freshwater sediment ecotoxicity, marine sediment ecotoxicity, terrestrial ecotoxicity and human toxicity (not considered here). Marine ecotox potential for metals is typically high using this approach, whereas most open ocean metal concentrations are very low. A sensitivity analysis of the USES-LCA model was undertaken using copper as an example. Results indicate: fate processes on the global scale are driving the marine water and sediment TPs for copper most; the second most important fate parameter is sedimentation from the water and burial in deep sediment layers; inclusion of speciation and bio-availability processes would be very beneficial; more accurate estimates of input parameters should be used, and the PNECwater and PNECsediment and all partition coefficients for metals should be updated in the model.

Jan 1, 2007

By A. J. R. Smith

"CANADA'S ECONOMY TODAY is about two-fifths larger than it was six years ago, as measured by the total volume of production of goods and services. Such an achievement has been a rare phenomenon in Canada's first one hundred years. Excluding the forced-draft expansions which took place under war-time conditions, perhaps only the first decade of this century recorded a performance of greater dimensions, when, with massive immigration, the opening up of the West and a powerful array of well-de-signed development policies, the country was looking forward confidently to a great future of nation-building in the twentieth century.What makes Canada's over-all economic advance since 1961 all the more remarkable is that six years ago there was virtually no one in this country who anticipated an expansion of such dimensions. Back in the buoyant conditions of 1956-57, perhaps such an achievement would not have seemed beyond our grasp. After 1957, however, Canada stumbled through an extended period of slow economic growth, high unemployment and substantial and widespread under-utilization of its productive capacity. By the early 1960's, conditioned by the emergence of substantial, persistent and pervasive slack in the economy, t h e r e were few Canadians bold enough to anticipate that their economy was about to embark on a Great Expansion. However, this •is, in fact, what occurred. Beginning early in 1961, Canada moved forward into a sweeping advance which grew into the longest and largest peacetime business expansion in Canada's first century as a nation -a truly great expansion by any standard of measurement. This strong thrust has moved Canada into the front ranks of over-all economic expansion among the industrially advanced nations in the 1960's."

Jan 1, 1970

In this study, flotation of fine galena, chalcopyrite and pyrite was performed after grinding with different extent of oxidation-reduction condition adjusted by grinding media. Sodium dithionite and iron ions were added in mill to simulate pulp potentials and iron oxidation species produced by grinding media, respectively. The types and quantities of the metal oxidation species on mineral surfaces were determined by EDTA extractions, while the surface electrical properties of minerals and interaction of different types of metal oxidation species were studied by zeta potential measurements. It was found that the nature and concentration of the absorbed metal oxidation species were dependent on oxidation atmosphere controlled by the iron amount of grinding media. These species interacted with each other and had an important role in determining flotation of fine galena and chalcopyrite as well as activation of fine pyrite by lead and copper.

Jan 1, 2006

By Marke Wong

? Vietnam?s economy is growing so fast that gross domestic product (GDP) growth remained above 8% in 2005 and exports are rising steadily at 25% per year. ? Demand for electricity is expected to increase 18% per year through 2010 requiring an additional estimated 7,547 MW before 2010 ? Domestic coal demand is expected to be over 45 Mt by 2010. ? The Quang Ninhcoal deposits are estimated at 6.5-7 billion tons (350m) Vietnam News Agency. Saturday, May, 6, 2006. ? National resources are now estimated at 10 billion tonnes; not including a relative new coal bed discovery estimated at 210 billion tonnesin the Red River Basin.

May 1, 2006

1.Overview of the Ministry of Energy, Mines and Petroleum Resources (MEMPR) 2.First Nations Perspective 3.Revenue Sharing Framework 4.Economic and Community Development Agreements (ECDA?s ) 5.Questions? The Ministry of Energy, Mines and Petroleum Resources (MEMPR) MEMPR manages the responsible development of British Columbia?s energy, mining and petroleum resource sectors. Through the promotion of teamwork and positive working relationships with our clients, MEMPR facilitates a climate for thriving, safe, environmentally responsible and competitive energy, mining and petroleum resource sectors. Works closely with others in Government (e.g.. Integrated Land Management Bureau) to engage First Nations in consultation processes as well as revenue sharing negotiations.

May 1, 2010

By D. Adiguzel

In this research, providing the sustainability of production quality was aimed for a quarry which is located in Istanbul western part of Turkey and producing concrete aggregates with different types of rock. First, research field was divided in 3 different areas in accordance with the geological differences and parameters that control their product quality, limit values of standards and effect levels were determined. Concrete aggregate conformity tests which are stated in international standards were applied on samples which were taken from these 3 different areas and physical, geometric and chemical properties of each rock type were revealed. The properties of the 3 different types of rock which were produced in the quary were determined and the binary blends were composed. Blending studies were conducted with linear programming technique. In the linear programming model, the cost of aggregate production was aimed to be minimal. The limit values that meet literature and national standards for usability of aggregates in concrete were defined as constraints in the linear programming model and evaluated with objective functions, thus the most suitable aggregate blends were composed. In conclusion, to provide the sustainability of product quality, the most appropriate product blends were composed for the research field and the usability of this model for those quarries were revealed.

Aug 1, 2013

By J. Currie, J. McManus, R. Chenier

"Cominco Copper Division's Valley Mine is located in the Highland Valley of British Columbia, approximately 275 km by air northeast of Vancouver. The nearest towns are Logan Lake, located IS km to the east and Ashcroft, located about 50 km to the northwest.Preproduction stripping of rock and overburden at the Valley Mine's Lake Zone Pit began in mid-1982 following a decision to discontinue mining in the adjacent Jersey Pit. Equipment and mining methods were carried over from the Bethlehem Copper operations which, with Valley Copper Mines, were merged into Cominco in December 1982.Blasting practices, as carried over from the Bethlehem pits, were designed to provide the fine fragmentation required to meet production requirements using the Bethlehem crusher. However, after mining the first few benches of the Lake Zone Pit, it became apparent that overblasting at the pit limits was causing a number of bench failures, as well as contributing to an over-all reduction of the material strength of the rock mass forming the southwest wall of the pit.With present ultimate pit plans calling for the southwest wall to be as high as 300 m, Valley staff realized that potential slope stability problems should be dealt with as early as possible. This philosophy would enable experimentation on phase pit walls in order to attain the optimum slope angle on the ultimate pit wall.As part of an over-a ll slope stability program, a controlled blasting program was initiated at the Lake Zone Pit in March 1983. In this program, Valley engineering and production staff worked together with Golder Associates in establishing design criteria and evaluating the results. This program resulted in a marked improvement in the soundness of pit walls while maintaining the required degree of fragmentation."

Jan 1, 1985

By K. Adham, C. Lee

The demand for nickel is continuing to exceed inventories, and producers are working vigorously to increase capacity. Many nickel processes utilize the fluidized bed technology for its fast heat and mass transfer, excellent temperature control and low maintenance. The following four nickel applications of the fluidized bed technology have been commercialized: I) Sulfide ore roasting; II) Nickel sulfide (matte) roasting; III) Nickel oxide reduction; IV) Nickel chloride pyrohydrolysis. This paper examines the issues surrounding the application of fluidization technology to the above processes, from the stand point of the engineer modeling the process and designing the key equipment, based on the historical success stories and the fundamental principles of flow sheet synthesis. Using the available data in open literature, typical flow diagrams (with convenient bases of 1 t/h feed or product) are developed to illustrate the relative flow rates and to highlight the key features of each application. In addition, some historical background information is provided for each process with supplemental notes with regards to our company's involvements.

Jan 1, 2005

Building block cave operations involves significant commitments to capital and time before arriving at completion or full scale production. The focus of the mine planners is habitually to minimize the upfront capital and achieve target development rates and construction dates. However, management of the construction of block cave projects requires understanding of the strategic/tactical decisions that the project planners can take to increase the value of the project and cope with schedule risks. As block cave projects involve development of vertical and lateral access to the underground footprint and ore body, more attention to uncertainties is required as most of those projects need to confront delays leading to a decrease in value. The standard process of development and construction scheduling is often not planned with provisions to realise uncertainties in the construction phase. Uncertainties and risks such as poor ground conditions and equipment breakdowns are the primary reasons for schedule slippage. As a result most of these projects experience delays. In order to mitigate risk to the project schedule, we centre our attention on increasing the value of the project by spending more money upfront and improving the schedule rather than focus on minimizing the upfront capital. Scenario-based simulations along with project appraisal methods hold great promise to address those challenges and enable mine planners to make better decision and enhancing project value. This paper will present a hybrid simulation based approach to model the process of development and construction based on discrete event (DES) and continuous based simulations (CBS). Such simulations will be conducted for scheduling multiple development headings (Apex, undercut, extraction, and haulage levels). Two scenarios are utilized to investigate the impact of risks on schedule and how flexibility in construction can be incorporated to minimize delays: (1) The bench mark scenario is created based on actual data from an existing case study. (2) The flexible scenario is an alternative way to use primary production infrastructure (Ore Handling System) including conveyer drifts, conveyer belt, and a gyratory crusher in the construction process and that requires the system to be in place before starting lateral development in the footprint. As a result, a truck-load system versus a conveying system will be studied to observe the gain in construction speed and to estimate the premium cost for mucking rock from headings and drawbells and transporting it to surface. Such strategic flexibility would be part of the original budget to make the tactical flexibility available during construction. Continuous cash flow models are used to evaluate and compare the scenarios. This study is an example of how new techniques in planning can be used to support decision-making processes in block cave design.

Aug 1, 2013