Search Documents

By David Lewin

The journey toward cleaner coal-fired power generation is driven by technological improvements, more stringent regulations around greenhouse gas and other air emissions, and the potential of one of Canada?s most abundant resources. Within this context, EPCOR is leading efforts to commercialize gasification technology to produce electricity with near-zero emissions. By turning coal, oxygen, and water into synthesis gas through a gasification process ? and then capturing CO2 ? it is possible to dramatically reduce greenhouse gas and smog-related emissions. EPCOR is conducting front-end engineering and design work on an Integrated Gasification Combined Cycle technology (IGCC) utility-scale plant ? in conjunction with the Canadian Clean Power Coalition ? at its Genesee site, west of Edmonton. EPCOR, the Alberta Energy Research Institute, and Natural Resources Canada have each contributed $11 million to the $33 million project. A critical element of the project features the capture of CO2, which would be piped underground for long-term sequestration, or for use in enhanced oil recovery (EOR). The combination of IGCC and CO2 sequestration, at this scale, has not been used anywhere else in the world.

May 1, 2008

By M. Fairclough, B. Moldovan

Insights into uranium mining projects of the future can be gained by a careful statistical analysis of past and present deposits, as well as an examination of recent trends for uranium resource evaluation and primary uranium production. The International Atomic Energy Agency (IAEA) provides the necessary data and corresponding mechanisms as inputs for methodologies that enable strategic and scientific evaluations of long-term security of supply uranium required to sustain the demand for nuclear fuel. Sustainability of the uranium mining industry and subsequently new uranium mines of the future requires innovation and expertise to lower operating costs, maintain or improve uranium recovery while meeting the requirements of stakeholders in regard to protection of the environment and safety of the workers and general public.

Jan 1, 2020

By A. Otsuki

"This paper discusses the primary collector adsorption onto a sulphide mineral in mixed collector systems to understand its adsorption mechanism. UV-vis measurements were performed to identify the primary collector concentration adsorbed on pyrite, and the adsorption kinetics under different conditions were compared to distinguish their difference between single and mixed collector systems. Small amount of secondary collector addition prior to the primary collector addition significantly improved the adsorption kinetics of primary one. The result was explained by the combination of two previously proposed mechanisms (i.e., different adsorption site mechanism and multi-layer product mechanism). This study showed UV-vis measurement as an effective tool to study mixed collector adsorption behaviour.INTRODUCTIONCollectors are surfactants composed of heteropolar molecules with a non-polar and a polar group (Lotter & Bradshaw, 2010). In a froth flotation process, the function of collector is to improve the hydrophobicity of target minerals and selectively float them with the aid of gas bubbles. Because of the chemical or physical attraction between the polar group and the mineral surfaces sites, collector molecules adsorb on the particle surface with the non-polar group assigned towards the bulk solution (i.e., water), thus the mineral particle surface becomes hydrophobic (Wills & Napier-Munn, 2006).Thiol collectors are major collectors widely used in sulphide mineral flotation. Potassium amyl xanthate (PAX), dithiocarbamate (DTC), dithiophosphate (DTP), mecaptobenzothiazole (MBT) are some common thiol collectors. Previous studies reported that some mixed collectors systems enhanced the flotation performance (e.g., Bradshaw, 1997; Bradshaw et al., 1998; Rao & Forssberg, 1997). Thiol collector mixtures are often used in the flotation of sulphide ores, and discussed with the synergistic benefits (Bradshaw et al., 1998) which include lowering the total collector dosage requirements, improving the sulphide recovery and the rate of flotation as well as the improving the froth characteristics. The current paper mainly considered the mixture between two thiol collectors (PAX and DTC, considered as a weaker and selective collector, and stronger and less selective collector, respectively (Bradshaw, 1997)) to further understand their adsorption mechanism that should assist in improving the flotation performance of refractory gold ore."

Jan 1, 2016

By D. Mark Richards

Highland Valley Copper is a large open pit copper mine in the southern interior of British Columbia. Machine guidance technology using the Global Positioning System (GPS), was first implemented at the mine in late 1996 for blast hole drill navigation. The purchase of a third BE49R drill in 1998 completed the change to GPS navigation for all the mine?s drilling. The acceptance of this technology was almost immediate at both the operator and management levels. With the purchase of a new P&H 2800 shovel in 1997, the opportunity was taken to extend GPS navigation to a shovel. Due to communication restrictions, this was not as successful as envisaged. In late 1999, following a cost benefit analysis, a three-shovel trial of Caterpillar?s Computer Aided Earthmoving System (CAES), was initiated. The trial was successfully concluded in June 2000 and a further two shovels were equipped. Acceptance of this system has been very good at all levels, which has undoubtedly contributed to its success. In September 2000, CAES was extended to the dozer fleet with the purchase of a new track dozer. The CAES equipped dozer is used for pit production and project work. It is planned to extend CAES to the rest of the shovel fleet in 2001, along with a production front-end loader and one or two more track dozers.

May 1, 2001

By Jack F. McQuat, Ross D. Lawrence

"Most geologists and mining engineers, in the course of their professional careers, frequently become involved with the appraisal of metalliferous mineral deposits and develop a familiarity with and standard approach to the evaluation of these deposits. When the same individuals approach the industrial mineral field, however, their usual approach pattern can be rudely disturbed.This paper highlights the difference in appraisal approach and outlines the factors common to both but which have entirely different emphasis. These comprise geological appraisal, analytical requirements, the importance of transportation, marketing requirements and standards, including appropriate allowances for product development, and marketing penetration.Out of these ""different"" considerations, however, a pat-tern or standard approach emerges which is as common to the industrial mineral field as that used either consciously or subconsciously in the metallic field.The paper reviews the different factors and points of emphasis and offers an outline of the common pattern of appraisal for industrial minerals."

Jan 1, 1971

By B. Dyck, C. Rodgers

ABSTRACT Cameco Corporation is revitalizing its Key Lake Operation uranium mill in northern Saskatchewan. The mill currently uses ammonia stripping in solvent extraction (SX) and ammonia yellowcake precipitation. As part of the revitalization, the company considered installing strong acid stripping in solvent extraction (used at its Rabbit Lake Operation), which would lead to using hydrogen peroxide for uranium precipitation. As part of the process evaluation, tests were carried out to study how the drying temperature in indirect fired dryers would affect the uranium peroxide yellowcake precipitate properties. This paper discusses the test work results, including the relationships between drying temperature and product reactivity with water, product colour, product grade, and energy input requirements.

Jan 1, 2012

By G. A. Gamble

"The inlet air velocity profile of any surface mine ventilation fan is an important factor when designing the connecting ductwork from the mine shaft collar to the fan. Deficient fan performance can be the result of ductwork that adds unnecessary pressure loss and/or adversely influences the fan inlet air conditions (velocity profile). The need for optimized inlet air conditions begins with discussing the process of performance testing during the development of the fan performance curve. Additional discussions include design of the shaft collar connection and the connecting ductwork. A preferred design of ductwork for parallel fan installations will be illustrated.INTRODUCTIONThe inlet air velocity profile of any surface installed mine ventilation fan is one of the most important factors to consider when designing the connecting ductwork from the mine shaft collar to the fan. Oftentimes deficient fan performance can be traced to poorly designed ductwork that adds unnecessary pressure loss and/or adversely influences the fan inlet air conditions (velocity profile). Such designs may lead to added power requirement, excessive vibration and noise, and reduced fan performance.Understanding the need for optimized inlet air conditions begins with discussing the process utilized when factory testing takes place during the development of the fan performance curve.Additional discussions include design considerations for the shaft collar connection, the connecting ductwork, and fan inlet. Illustrations of cost savings and pressure losses will be included for audience consideration. The design of ductwork for parallel fan installations on the surface is another issue that requires consideration. A preferred method will be illustrated.The selection of accessory components, such as self-closing doors, can also add to the potential for reduced fan performance. Several components will be discussed.An elementary presentation of the Air Movement and Control Association (AMCA) Standard 201 “Fans and Systems” will be included to provide background for those audience members that want additional technical explanations of the need for a uniform inlet air velocity profile at the fan inlet."

Jan 1, 2019

By G. A. Young

THE Geological Survey was created in 1842 to aid the development of Canada's mineral resources. Although the institution has been in existence for nearly 100 years and has accomplished an immense amount of work, the need for its services remains as great as ever and, indeed, it is difficult to imagine a time when the country will no longer require a Geological Survey. This is so because of the tremendous effort required to make an adequate geological examination of so large an area as is embraced by Canada and partly because what today may seem an adequate geological examination proves, later on, to be inadequate. The ultimate objective of the Geological Survey is to complete the study of all phases of the geology of Canada, that is, to determine how and when the physical features originated, how and when the soils and other unconsolidated deposits were formed, and how and when the solid rocks and associated deposits were produced and assumed their present conditions. When the study has been completed, any only then, will it be possible to make a reliable estimate of the country's mineral resources. This appraisal embraces more than determining the value of already discovered deposits: it also involves attempting to establish what kinds of undiscovered deposits may be present and where they may occur. The estimating of the potential mineral wealth can be clone only after the geology of the country is known. Not until then will it be possible to forecast what types of valued deposits may occur in a district and what types will almost certainly be lacking. A thorough knowledge of the geology of the country is desirable not only to permit estimating the potential mineral resources but also as an aid in locating and developing mineral deposits whether these are of the nature of a bed of limestone, a seam of coal, a reservoir of petroleum, a vein, an irregular body of sulphides, or any other type of deposit.

Jan 1, 1940

By Asanga S. Nanayakkara

The surface deformations induced by reservoir dilations can be measured using tiltmeters and these measurements can be used to infer reservoir level volume changes by solving an inverse problem. Preferred approach to solve such an inverse problem is to consider more tiltmeter measurements than the number of unknown variables considered in the inverse problem. However, sufficient number of measurement points is not always available due to economical and practical issues. This paper proposes a new approach to circumvent this problem. The new approach entails generation of pseudo surface deformation data by curve fitting tiltmeter measurements using a mathematical function, which delineates three-dimensional characteristics of surface deformation profiles. Then a three-dimensional inverse problem is solved using pseudo surface deformation data. This method is useful in inferring reservoir volume changes with high areal resolution when the number of available measurements is not sufficient to acquire the desired areal resolution.

Jun 1, 2012

By J. Qi

Based on the commercial steel 42CrMo (4140, SCM440), a new generation of CrMo steel was developed by increasing the content of Mo, adding the alloy element of V and Nb, and decreasing the content of P and S. This new CrMo steel has higher strength of 1500MPa and better delayed failure property. TEM and EDS were used to study the distribution and function of the alloying elements in this steel. A new EELS technique was developed to study the bonding strength of the grain boundary in the steel. The mechanism of strengthening of the new steel has been studied.

Jan 1, 2004

By Sigmund J. Andersen, Eva A. Mørtsell, Jostein Røyset, Randi Holmestad, Oddvin Reiso, Yanjun Li, Øyvind Paulsen, Calin D. Marioara

"With the purpose of increasing the extrudability of lean alloys, we reduce levels of the alloying elements Mg and Si in a 6xxx extrusion alloy. To avoid sacrificing strength, we investigate the compensating effect of smaller amounts of lithium and germanium, alone and in combination. Recent studies by atomically resolved high angle annular dark-field scanning transmission electron microscopy (HAADF-STEM) together with density functional theory (DFT) calculations have demonstrated that while Li replaces Mg, Ge substitutes Si in the columns in the hardening ß’’-phase. Several studies have shown that Ge replaces Si in other precipitates as well, and that both Li and Ge promote precipitation and can improve macroscopic properties, like strength and thermal stability. The scope of the current work has been to investigate and document the combined effect of the two alloying elements. Of the investigated alloys, the one containing both elements displayed highest hardness, corresponding with a significant increase in precipitate number density. We used HAADF-STEM to determine the extent of Li and Ge in the precipitate structures.INTRODUCTION The two most important alloying agents, with respect to age hardening of the 6xxx alloy series, are Mg and Si. In general, 6xxx alloys are formed into their final shapes by rolling or extrusion, before being age-hardened at elevated temperatures around 180°C. The hardening effect during this stage is due to the formation of metastable, semi-coherent, precipitate needles along the three < 001>Al directions generally following the precipitation sequence (Marioara, Nordmark, Andersen, & Holmestad, 2006): Supersaturated solid solution ? atomic clusters ? Guinier-Preston-zones (pre-ß”) (Edwards, Stiller, Dunlop, & Couper, 1998) (Marioara, Andersen, Jansen, & Zandbergen, 2001) ? ß” (Andersen, et al., 1998) (Hasting, et al., 2009) ? ß’ (Vissers, Huis, Jansen, & H. W. Zandbergen, 2007), U1 (Andersen, Marioara, Vissers, Frøseth, & Zandbergen, 2007), U2 (Andersen, Marioara, Frøseth, Vissers, & Zandbergen, 2005), B’ (Vissers, Marioara, Andersen, & Holmestad, 2008) ? ß, Si (stable)"

Jan 1, 2018

By L. Avramovic, B. Han, R. Jonovic, Z. Stevanovic, K. Haga, S. Dimitrijevic, A. Shibayama, L. Godirilwe, Y. Takasaki

Pyrite (FeS2) and chalcopyrite (CuFeS2) which could not be recovered, are present in mine tailings discharged from Bor copper mine. About 0.3% of copper (Cu) is contained in these tailings, therefore it can be considered as a useful copper resource. At the same time, pyrite is known to promote acid mine drainage, therefore it is necessary to detoxify the tailings. An efficient method has been proposed to recover copper and reduce the environmental impacts of tailings by a combined hydrometallurgical process of high pressure leaching (HPL), solvent extraction (SX) and electrowinning (EW) process. HPL process yielded high copper leaching rate (>95%) when water (H2O) was used as a leaching media. On the other hand, pyrite contained in the tailings was converted to iron oxide by high pressure leaching. Stability evaluation of the residue obtained from high pressure leaching, confirmed almost no elution of metal ions. The percentage of copper extracted and stripped from the Cu-loaded organic phase reached 97.4%. Moreover, it was confirmed that a low iron concentration in the electrolyte of copper electrowinning, resulted in the improvement of current efficiency of copper electrodeposition. INTRODUCTION Mine tailings are a by-product obtained from the flotation process and there are billions of tons of already existing tailings all over the world. Moreover, several billion tons of additional copper tailings will inevitably be produced in the coming years (Onuaguluchi & Eren, 2012). With the declining average copper ore grade, alternative sources of copper are highly sought, mine tailings have a comparable copper grade to that of low-grade ores (0.2–0.3%) therefore, it can be said that copper mine tailings present a very important source of secondary raw material for copper production (Antonijevi´c et. al., 2008). Consequently, it is necessary to confirm the possibility of the valuable metals (such as copper) recovery from mine tailing in which copper content is about 0.2–0.3%. Our group investigates the flotation and high pressure leaching processes for recovering of copper from mine tailings. Previous work on related samples include copper and nickel flotation tailings from Botswana, and a low–grade copper ore sample from Chile. Impurities, which are associated metals in mine tailing such as iron (Fe) and aluminum (Al) co-dissolve into the solution during the HPL treatment process. Therefore, separation of copper from impurities is necessary for selective extraction of copper from mine tailings and upgrading the copper concentration in the leachate to enable further purifying of Cu by electrowinning. Thus, it is important to investigate the possibility of applying solvent extraction for concentration of copper from leachate solutions of mine tailings (Onuaguluchi & Eren, 2012; Antonijevi´c et. al., 2008). In this study, LIX-84I was used as an extractant of copper from the leachate of high pressure leaching of mine tailing. As a fundamental solvent extraction investigation, the extraction behavior of copper was studied using a simulated solution of the leachate from the high-pressure oxidative leaching of mine tailing. The effects of; solution pH, extraction time, extractant concentration and phase ratio on copper extraction and sulfuric acid (H2SO4) concentration on stripping were investigated.

Jan 1, 2019

By Todd S. Harris

"IntroductionThe western region of North America has long been considered a dynamic market supporting such diversified industries as lumber, agriculture, cement, and electronics. In recent years however, the region has also been the focus of a great deal of activity in the extender and filler mineral s business from companies seeking to position themselves to take advantage of the large demand for these materials both here and abroad.Extender and Filler MineralsExtender and filler mineral s include 15different products used in numerous end uses. The nine most important extenders and fillers are listed in Table I. These products range in price from under $50 a ton to over $4,000 a ton and basically represent the following three different types of minerals:Particulate products-Calcium carbonate; Kaolin; Silica.Platy minerals-Talc (Montana, Canada); Mica.Fibrous minerals-Talc (California, Eastern U.S .A.);Wollastonite.What distinguishes these products from other industrial minerals? For one thing, an important feature of extender and filler minerals is that they are used primarily in such consumer non-durable good s as paper, paint, plastics, sealants, and rubber which traditionally do not react as violently to swings in the economic cycle. In addition, these minerals are sold principally on key physical properties, usually brightness, particle size and shape, oil absorption, and hardness. As part of the physical minerals segment of industrial minerals, extenders and fillers are traditionally the most stable group and typically the most profitable. Studies by C.H. Kline over the past decade on extender and filler minerals has revealed historic average profitability (expressed as a percentage on sales) nearly double that of most other industrial mineral s.The demand for these minerals in the western region (Fig. 1), closely follow s the areas of greatest population concentration. These markets include pulp and paper, mainly in the Pacific Northwest, and paint, around Los Angeles and San Fran cisco. Other significant markets for extender and filler minerals in western North America include joint cements, carpet backing, and plastics, mainly PVC pipe."

Jan 1, 1986

By A. Mykytiuk, I. E. Puddington, W. D. Macleod, F. W. Meadus

"A laboratory-scale continuous procedure for the up-grading of naturally occurring tin ores, based on the principle of spherical agglomeration, is described. High recoveries are indicated. A proposed second stage suggests useful fractionation steps.IntroductionA LABORATORY-SCALE batch process for the upgrading of a tin ore using the principles of spherical agglomeration has already been described (1). This procedure consisted of milling, for about an hour, a precrushed ore with at least 200 per cent water, 0.2 per cent of a reagent such as tall oil (to render the de-sired ore particles hydrophobic) and about 3 per cent of a viscous petroleum oil. The feed material passed an 8-mesh Tyler sieve, and the percentages of re-agents are based on the dry weight of the feed. Du-ring the grinding, the hydrophobic particles transfer into the oil phase to produce coherent semi-solid bodies while the gangue stays preferentially in the aqueous phase. The concentrate can be separated from the gangue easily by a mechanical operation. Using an ore containing about 0.3 -0.5 per cent tin, grades of from 1.5 to 7.0 per cent were obtained by varying the pH of the system. Recoveries fell from about 80 per cent to as low as 50 per cent as the grade in-creased."

Jan 1, 1966

By Jan E. Nesset, L. Paul Staples

"High Gradient Magnetic Separation (HGMS) technology, although developed over 2 decades ago, has not been widely applied to the separation of sulphide minerals. Under conditions of strong magnetic field gradients, weakly magnetic minerals such as chalcopyrite (CuFeS2) and marmatite (Zn(Fe)S, sphalerite with iron in solid solution) behave paramagnetically and can be effectively separated from diamagnetic minerals such as galena (PbS). The application of this technology to the separation of Cu-Pb and Zn-Pb bearing streams in the treatment of fine grained complex sulphides may in some cases be more effective than separation by flotation. A 2 TPH Sala HGMS pilot plant was operated at Brunswick for a nine month period, ending in March 1995. The testing demonstrated the mechanical reliability of the technology, the consistency of operating results and the scale up from laboratory testing. HGMS is seen as a complimentary technology to flotation, best suited to performing those separations of galena (and other diamagnetics) which flotation does not do as well.IntroductionBackgroundSince the turn of the century, the magnetic character or magnetic susceptibilities of minerals have been determined with increasing precision and accuracy. Figure 1 illustrates specific magnetic susceptibilities of some common minerals. As long as susceptibility ranges do not overlap, separation is possible.In 1937, the principle of using a magnetizable matrix material in a magnetic field to increase both magnetic flux density gradients and number of capture sites for susceptible minerals was first applied (Frantz). It was not until the 1970's, however, that the genuine development of wet high gradient magnetic separation began with the introduction of very fine matrix materials to the magnetized volume of large solenoid magnets. Today, dozens of HGMS units purify, filter and separate minerals, primarily for the removal of iron stained minerals from clays used in the paper coating and china clay industries and for the recovery of fine titanium and iron oxides in the iron ore industry. Only the Garpenburg mill in Sweden is currently applying a continuous HGMS machine to separate complex sulphide minerals; upgrading a lead concentrate since 1988."

Jan 1, 1996

By F. Kapeller, G. Herget

"The need for monitoring the effect of changes in ground stresses due to mining in hard rock has existed for many years. The Mining Research Laboratories of CANMET, EMR have developed a new tool which monitors with high precision the radial deformation in boreholes. The result is the Mining Research Laboratories strain monitoring system (MSMS) which uses the highly stable and very sensitive vibrating wire principle to monitor deformations in relatively large boreholes, e.g. 76 mm to 153 mm diameter.The vibrating wire is strung across a relatively large proving ring and operates at a frequency between 600 to 1800 Hz. The read-out system is based on continuous vibration.The ring is installed with a hydraulic tool and brought into contact with the surrounding rock through precisely machined and guided wedges. The resolution of the system is in the neighbourhood of 4 x 10-4 min/ Hz. The data collection can be carried out with a portable read-out unit and provisions are available for automatic data collection. Stresses may be calculated from strain readings.The system was tested in cooperation with the Centre de recherches minérales at the Niobec Mine in Quebec for the purpose of monitoring the effects of drill drift development and slope mining on surrounding ground stresses.After access was available to the site, 153 mm diameter holes were drilled for the determination of in situ ground stresses. These holes were then used to install the strain monitoring system. The effect of drill drift development and production blasting in stopes C-203-13 and C-203-15 on ground stress distribution could be observed clearly.The horizontal relaxation in the core of a pillar which occurred during mining of adjacent rooms was between 0.082 mm to 0.111 mm. Calculations of stresses from these deformations indicate that the rock material is still in an elastic condition.Roctest of Montreal has obtained a license on the manufacturing and distribution rights. A patent has been registered and CANMET will assist in installation of the MRL strain monitoring system and the interpretation of records."

Jan 1, 1989

An optimized long-term mine planning determines the best order of material extraction, so that the Net Present Value (NPV) becomes maximum. In the case of oil sands surface mining, one of the key constraints in NPV maximization is the volume of tailings slurry that will be generated downstream. Specifications of tailings slurry are also important from environmental perspective. Moreover, most of the material that will be used for the reclamation of tailings ponds in later periods is generated in extraction and processing of oil sands. In this paper, an integrated optimization framework is proposed to maximize the NPV of the produced oil sands, with respect to tailings capacity constraints and reclamation material requirements. A mixed integer linear programming (MILP) model is developed to find the optimal solution for long-term mine planning problem. The proposed model is coded in Matlab and has been run using CPLEX for verification. The results for real-case oil sands dataset show that the optimal production schedule meets material requirements for reclamation, tailings volume is within tailings capacity range in all periods and the production schedule follows the predetermined horizontal direction.

Aug 1, 2013

By G. K. Rutherford, G. W. Van Loon

"Tailings in the mining and smelting industry are reject products of the refining process which are deemed too deficient in native are to warrant smelting. They are essentially finely ground rock materials which have been moved by alluvial suspension from the site of crushing to a deposit site. It is realized that components of flotation chemicals used in specific gravity separation may become part of the tailings and also that sewage sludge or other materials may be added at some stage to the tailing deposits.It would seem, then, that as tailings have a similar parent material to soils, namely rocks, and that they have also been comminuted to similar size fractions, they would react in similar ways to soils. There is an increasing body of evidence and experience which both supports and negates this supposition. It is the object of this paper to point out similarities and contrasts between these two materials which may influence the vegetation and rehabilitation of tailings.Soil-Formlnq FactorsThere are considered to be six soil-forming factors which impart the particular and unique properties harboured by a soil at any site. It is .relevant to consider each of these in turn, as each provides an historically based parameter with which to judge tailing properties.Parent MaterialsAlthough all mineral soils have originally come from rocks, for most soils the route has been rather circuitous. Soils may be formed directly from underlying rocks, as in some parts of tropical and semitropical regions today; these are sedentary soils. However, most soils of the world have been formed by materials which were transported to their present site by ice, water or wind, or as volcanic ash. Virtually all soils in Canada have been transported by ice or water and deposited on an extraneous rock surface during the last glacial retreat. Ice-deposited materials are extraordinarily heterogeneous in their size components and may range from very bouldery and gravelly to predominantly clay-sized materials. Water deposited sediments are usually homogeneous, but nevertheless these also show considerable level variations. In many parts of Canada, clay-sized materials deposited in ephemeral post-glacial lakes form the parent material for soils."

Jan 1, 1982

By Fazel G. Jahromi, Ahmad Ghahreman

"Several studies were performed on the atmospheric leaching of copper sulfide minerals in the presence of activated carbon and a new catalyst, AF 5. AF 5 is a carbon based catalyst with similar properties to those of activated carbon however much better mechanical properties. The activated carbon surface chemistry has been investigated in various studies; however the connection of the surface chemistry of activated carbon and AF 5 with the sulfide minerals during the atmospheric leaching process is not well-understood yet. Based on the surface analysis, AF 5 showed higher surface area than activated carbon (AC). Adsorption and oxidation of copper, arsenic and iron ions in the presence of different activated carbon were investigated. Adsorption properties of both catalysts were similar and 18-24% of iron, 12-18% of copper and 10% of arsenic adsorbed on the catalysts surface form 5 g/L Fe(III) and Cu(II) and 2 g/L As(III) at 80°C. In oxidation experiments, both catalysts reduced Fe(III) and Cu(II) ions and re-oxidized the reduced species in the presence of oxygen and oxidized As(III) ions. The addition of oxidizing ions can enhance the oxidation process kinetics and increase the catalytic capability of carbon.INTRODUCTION Hydrometallurgical processes of copper sulfide concentrates are under development and various different methods have been proposed to increase the atmospheric leaching rate of copper sulfide minerals. These methods include using different media, reagents, and catalysts. Among different methods, leaching of the copper sulfide minerals in the chloride media has some advantages over sulfate media. Smaller scale of operation, increased leaching rates, and lower sulfate formation are some of the benefits of the chloride leaching media over other similar media. Moreover, using ferric and cupric ions as oxidants and utilizing activated carbon as a catalyst has been proven to enhance the leaching rate of copper sulfide minerals effectively. Activated carbon (AC) and AF 5 (micro porous carbon based catalyst) are two of the most efficient and practical catalysts in copper sulfide leaching processes. AC can enhance the copper recovery of enargite in chloride media from 69% to 92% after 96 hours of leaching under the similar conditions (Jahromi & Ghahreman, 2016). It has been shown that AC at acidic pH can generate hydrogen peroxide in the presence of oxygen which can leach copper minerals (Ahmumada et al., 2002)."

Jan 1, 2017

By H. Sipilä, H. Vartiainen, H. Paarma

"The carbonatite massif of Sokli includes several low-grade Nb showings composed of ores and wastes as identified by routine analyses. More detailed lithologic proportions were determined in two orebodies in the Kaulusrova Nb-mineralized area by a careful geological study and by thorium radiation measurement on 10 cm-long drill core cuttings with a total length of 460 metres. The distribution of Nb in eight X-ray spectrometrically analyzed drill core sample intervals (totalling 35.8 m) was determined by analyzing the intervals semi-continuously by an X -MET analyzer. The geological studies suggest that Nb-mineralized bodies are feasible fo r the sorting of are and waste. This was confirmed by the semi-continuous determination of Nb on the X-MET analyzer.IntroductionThe Sokli carbonatite complex is located in eastern Finnish Lapland. The main ore of the carbonatite massif is a regolithic phosphorus ore in the weathered crust. Large-scale geophysical measurements and diamond drillings have also established several niobium showings within the magmatic carbonatites. Owing to the complicated geology of the massif, the niobium showings occur as irregular zones o r areas displaying complicated structure, texture, mineralogy and geochemistry (Vartiainen and Paarma , 1979; Vartiainen , 1980). The tonnages in areas such as this are large but the grades in-situ are low . The most intensely studied niobium showing is the Kaulusrova area.The exploitation of these showings depends on the feasibility of applying a sorting technique to upgrade the feed and to minimize the amount of material to be treated in the concentration plant. These possibilities o n the Kaulusrova area have been viewed by a detailed geological and X-MET an analyzing study."

Jan 1, 1985