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By G. Viramontes-Gamboa, A. Encinas-Oropesa, S. Velázquez-Roque, L. A. Ibarra-Bracamontes

Some industrially relevant applications for pyrite nano/micro-particles have been proposed in the literature, such as the catalysis of chalcopyrite leaching, the removal of As(III), As(V) and Cr(VI) from solution, as photovoltaic devices, and others. Even though pyrite can be recovered from solution by flotation, for some applications it may be beneficial to provide pyrite with magnetic properties. In this work, a methodology to synthesize magnetic shell/core composites made of pyrite as the shell and either natural or synthetic magnetite as the core is presented. The size of the magnetic composite may range from tenths to hundreds of microns. The synthesis is basically made by stoichiometrically mixing iron nano/micro-particles with sulfur microparticles with magnetite particles, and bringing the mixture in an oxygen free atmosphere from 200 to 300 °C for 4 h. The composites were characterized by optical microscopy, Scanning Electron Microscopy and X-Ray diffraction.

Jan 1, 2014

By J. Güntner

A significant portion of Outotec's business relates to the application of fluidized bed for processing a wide range of industrial materials, including gold ore and gold concentrate. As part of the former Lurgi and Boliden organization, our division constructed the first industrial reactor for roasting sulphur-bearing materials in 1950, based on the principles of fluidized bed technology. This process, when combined with efficient heat recovery and off-gas treatment and its conversion to sulphuric acid, became the standard for processing sulphur-bearing ores. In the last 60 years we have delivered more than 265 plants and developed (in addition to the standard fluidized bed solution) variants of the fluidization technology, such as the circulating fluidized bed and the bubbling fluidized bed. This paper describes the different options of the fluidized bed technology for gold roasting reflecting on main process design criteria.

Jan 1, 2011

By J. Awmack, M. A. Tomlinson, P. J. Lind

"Peñasquito is a complex polymetallic deposit containing gold, silver, lead, zinc, and copper and is one of the largest producers of gold in Mexico. Mining activity is currently transitioning to a second open pit, Chile Colorado, which will be mined concurrently with the existing open pit, Peñasco. The ore bodies are located within diatreme pipes and into the surrounding sediment formation. In the coming years, mining will be carried out in more sedimentary zones, which are significantly higher in organic carbon content. Organic carbon in the feed influences both flotation and leaching operations. Several changes are being implemented to the Peñasquito flowsheet to mitigate the effects of increased organic carbon in the plant feed. These include the use of alternate reagent schemes, construction of a carbon pre-flotation circuit, implementation of a pre-leach flotation circuit ahead of pyrite leach, and evaluation of a tertiary process for separation of carbon and precious metal minerals.INTRODUCTION Goldcorp’s Peñasquito operation is located in the Mexican state of Zacatecas, approximately 200 km from the city of Zacatecas in the Mazapil municipality (Figure 1). Peñasquito has been in operation since 2009, with mining carried out by open-pit methods. Oxide ore has been processed in a heap leach facility and sulfide ore is treated in the sulfide processing plant. The processing capacity of the sulfide plant is 130,000 tonnes of ore per day and in 2016 production amounted to 465,000 ounces of gold, 17.6 million ounces of silver, 109 million lb of contained lead in lead concentrate, and 263 million lb of contained zinc in zinc concentrate (Goldcorp Inc., 2017). To recover more of the contained gold and silver and to mitigate the impact of increasing organic carbon content in the ore, a number of significant changes are being made to the operation."

Jan 1, 2018

By E. Swartzman

"DURING 1951, experimental cleaning studies on both fines and larger sizes of certain Canadian coals were conducted on a relatively large scale in two pilot plants in the United States, large enough to be considered as small commercial units, and in one commercial plant in Canada.One of the pilot plants was a wet washer of a type which apparently has never been .used in Canada, nor has any Canadian coal been tested in it before. In the other pilot plant and in the commercial plant, dry cleaning equipment was used. The commercial plant is the first of its kind to be employed in Canada, and this type is used only to a limited extent in the United States.Fine-Coal Cleaning ExperimentsTest PlantsHydrotator and Hydrotator-Classifier combination pilot-plant with a capacity of about twenty tons per hour. This is a classifier type washer adapted for cleaning fine coal as well as certain intermediate sizes. The Hydrotator deals with that portion of a coal retained on approximately a 24-mesh Tyler sieve, whereas the Hydrotator-Classifier deals with the minus 24-mesh fines."

Jan 1, 1952

By Joey R. Kish, Shooka Mahboubi, Hatem S. Zurob, Gianluigi A. Botton

The kinetics of the Cr2O3-based scale oxidation and volatilization were studied in the presence of water vapour (H2O). A commercial Cr2O3-based scale forming Type 310S stainless steel was examined at the ambient pressure (0.1 MPa) and 550ºC in relatively low and high H2O containing environments of air- 10% H2O and air- 70% H2O, respectively. The increase in the partial pressure of H2O (pH2O) from 10% to 70% resulted in transition of the oxidation and volatilization kinetics from the parabolic rate law for air-10% H2O to the paralinear rate law for air-70% H2O. The kinetics transition was attributed to the increase in the Cr loss rate from the base scale after coupons exposure in air- 70% H2O. The significant role of the Mn alloying element in the base scale protectiveness was also discussed in the context of the Cr2O3-based scale stability.

Jan 1, 2017

By L. Van Wyk, J. Fernandez, J. Suarez, L. J. Diaz, A. Uria, D. Breeuwer

"Ventilation is an essential component of any underground mine, playing a vital role in ensuring the health and safety of workers, and a mine’s continuous operation. At a time when mining companies are increasingly having to move to deeper underground operations in pursuit of high-grade ore-bodies, the search is on for more efficient ventilation systems that will allow mining to be carried out at even deeper levels whilst ensuring the protection of workers and the maximisation of productivity through temperature management and the lowering of energy costs. Mining companies today are looking for innovative ways to deliver new technologies and procedures to enhance their mine’s profitability. Energy consumption by mine ventilation systems is higher than ever due to stringent specifications of underground equipment (primarily combustion engine emissions), air quality standards and mining at deeper levels which all require more powerful ventilation systems. With energy costs associated with operating ventilation systems being a mine’s second-highest cost of production after labour, finding the optimal ventilation solution is critical to a mine’s performance. Proper fan design remains a major factor in reducing capital expenditures (CAPEX) and operational expenditures (OPEX), which means that there are compelling reasons for making use of comprehensive factory testing at full power before fans are dispatched to site to simulate the mine’s current and future design requirements, and thus verify the fan’s effectiveness in ‘real’ conditions.INTRODUCTION A primary mine fan is considered the heartbeat of the entire mine ventilation system, drawing fresh air from the surface and providing a safe environment for miners. A ventilation system’s lack of performance often leads to a reduction in acceptable air quality levels for underground working operations and can potentially have an adverse impact on production rates."

Jan 1, 2019

By T. Feldmann, G. P. Demopoulos

The feasibility of chloride leaching processes depends on interfacing them with cost-effective HCl regeneration technologies. This paper summarizes the most important findings of research conducted in the past 3 years concerned with a novel process to regenerate high-strength HCl from concentrated CaCl2 solutions at temperatures below 100°C, via reaction of CaCl2 with H2SO4 resulting in the formation of calcium sulfate phases (gypsum, a-hemihydrate or anhydrite). From constant supersaturation semi-batch experiments in pure solution it was found that the crystal growth rate of hemihydrate, and hence the particle size, was influenced by the rate of reagent (Ca2+, SO4 2-) supply to the reactor. Additionally, growth studies of DH in presence of impurities (K+, Mg2+, Sr2+, Ba2+, Fe2+/3+, Al3+, La3+, Y3+, F- and PO4 3-) showed that specifically Sr2+ and PO4 3- are taken up during crystal growth. Furthermore, it was found that decreasing water activity (via different HCl/CaCl2 concentrations) and increasing temperature reduce the metastable life-time of DH and HH by increasing the phase transformation speed. The DH/HH transformation was identified to be dissolution-precipitation based, while HH to AH is a topochemical process. Finally, continuous experiments on bench scale are underway to confirm the feasibility of the process to obtain super-azeotropic strength HCl with up to 9 mol/L (~30wt.%) from 5 mol/L CaCl2 (~40wt.%) solution.

Jan 1, 2014

By George C. Bateman

WHAT I would like to do is to talk for a while tonight about the Canadian mining industry in wartime-at least, the Canadian mining industry as viewed through the eyes of the Metals Controller. There is nothing quite like the Canadian system in the system of controls in the United States, because the Canadian Controller combines the functions of a good many of the organizations here. I think the nearest counterpart would be the Divisional Chiefs of the WPB-although they have perhaps less authority and operate in a somewhat narrower field. My own field, as you know, is the metals and minerals-all of them, as a matter of fact, with the exception of steel and iron and coal and oil. And as I am responsible for supplies not only from domestic sources but also from foreign sources, I exercise most of the functions of the WPB and some of the functions of the Board of Economic Warfare. As my department is also responsible for stock-piling and for the financing of new operations, I therefore exercise some of the functions of the Metals Reserve and also of the Defense Plants Corporation. Being an administrator under the Wartime Prices and Trade Board, I also have the same function in relation w the price of metals as the OP A. The Canadian system of controls is compact, relatively simple, and I believe reasonably efficient. I think two of the reasons for that are that both the Controllers and the Directors of production are clothed with very wide authority, and also the fact that all the buying for the three arms of the service is done through the Department of Munitions and Supply, of which we are a part.

Jan 1, 1943

By R. V. Fox, L. K. Sinclair, D. L. Baek

"In this study, rare earth elements were recovered from bastnasite concentrate and waste fluorescent lamp phosphors using supercritical carbon dioxide extraction with a nitric acid/tributyl phosphate adduct. Several pretreatment methods were used to alter the crystal structure of the source materials, and thus improve rare earth element recovery. Pretreatment methods included 1) dry roasting of the source material at 730oC, 2) decomposition with 50% sodium hydroxide solution at 150oC for 4 hours, and 3) decomposition with 12 M sulfuric acid at 300oC for 4 hours. Treated and untreated samples underwent supercritical extraction at 24 MPa and 65oC for 1 hour. Untreated bastnasite and phosphor samples showed <10% rare earth element recovery, but sodium hydroxide digestion resulted in >60% recovery for most rare earth elements. Dry roasting of the bastnasite concentrate was also effective, resulting in >60% recovery for cerium.INTRODUCTIONRare earth elements (REEs) consist of the 15 lanthanides, scandium, and yttrium. Scandium and yttrium are included because they are in the same group as lanthanum, appear in many of the same ore deposits as the rest of the lanthanides, and exhibit many similar chemical properties. REEs are used in a wide array of applications including electronics, magnets, catalysts, glass, and solid-state lighting (Xie, Zhang, Dreisinger, & Doyle, 2014). Because of China’s continued dominance of worldwide REE production, the United States Department of Energy has sought to diversify domestic supplies of REEs (United States Department of Energy, 2011). A key part of this strategy is the development of improved extraction methods for both ores and recycled sources.Supercritical fluid extraction (SFE) is a promising technology for extraction and separation of rare earth elements. Contact with an acid adduct dissolved in supercritical carbon dioxide allows for the rapid extraction of REEs from solid matrices. Supercritical CO2 has several potentially useful properties as a solvent, including high diffusivity and the ability to tune solvation properties by adjusting pressure. Such tunability may have applications in separating the REEs once they have been extracted from the solid phase. Tributyl phosphate/nitric acid adducts (TBP:HNO3) are a particularly promising class of adducts for SFE extraction of rare earth elements. Using TBP:HNO3 adducts in supercritical CO2, several researchers have successfully extracted REEs from their oxides (Wuhua, Pijia, & Yongjun, 2010; Zhu, Duan, Xu, & Zhu, 2009). However, there is a complication in applying this technique to many types of ores and recycled sources: REEs are often locked in refractory minerals which are resistant to acid attack, resulting in limited recovery in supercritical extraction."

Jan 1, 2016

By E. Kordzadeh, M. Reza Bateni, M. Karaminezhaad, A. Moeini

A series of austenitic heat resistant Fe-Ni-Cr-Al alloys with different nickel contents have been investigated at 1100 ° C and 25, 50, 50,100 hours in S/0 bearing atmospheres. Before sulphidation test, the specimens were annealed in argon at 1250 °C for 8 hrs. Weight changes were measured using an automatic thermo gravimetric analyzer and corrosion products were analyzed by scanning electro microscope (SEM), energy dispersive X-ray spectrometry (EDAX), X-ray diffraction and optical microscope. The results showed that sulphidation resistance decreased with increasing nickel content. Internal sulphidation controlled by gaseous transport through cracks and pores and the formation of internal sulphide increased when liquid sulphides formed on the surface.

Jan 1, 2004

THE Michipicoten area, one of numerous iron-bearing "Archean" segments in the Shield, contains two main types of iron formation, a normal Keewatin-type, consisting of interbanded chert, siliceous magnetite and jasper, and, gradational to this, a carbonate-sulphide type which contains large de-posits of siderite and pyrite. The carbonate-sulphide type of iron formation bears a direct and intimate relationship to the volcanic development of the area; it there-by affords some insight into genetic problems of Archeanron formation in general. The purpose of this pa-per is to summarize the geological setting of Michipicoten iron formations and to briefly review genetic aspects of recent work in the area. GENERAL GEOLOGY in largely by assorted volcanics and sediments of the Michipicoten series and younger, regional granite masses. (Fig. 1). The Michipicoten series comprises a thick assemblage of mixed flows and pyroclastics together with elastic sediments and banded iron formations. The volcanics belong to the Andesite-Rhyolite Association, and characters-

Jan 1, 1961

By J. B. Kwon

For improvement in the productivity of tall building projects, table formwork is one of the main methods that have been adopted for slab formwork. Because the table formwork method is an equipment-oriented construction method, the type of lifting equipment and method of operation considerably affects the productivity and cost of the table formwork. It is also important to make an equipment input plan for completing the table formwork within the time given, according to the structural construction cycle. For performing the table formwork, a tower crane or an independent lifting system, and shifting trolleys, are required. However, if an inefficient equipment input plan is made, exorbitant cost may be incurred. Therefore, the purpose of this study is to analyze the productivity of a table formwork, considering the type and number of lifting equipment and the number of trolleys inputted, and to suggest quantitative data for making a cost-efficient equipment input plan within the construction duration given. It is expected that the results of this research will be utilized as a basis for cost-efficient equipment input planning.

Aug 1, 2013

By G. S. Hume

"THERE HAS BEEN a marked growth in the petroleum industry in Canada since the end of the war. The rate of growth in the demand for oil products has exceeded that in United States, although the per capita consumption is still less. Estimates of the consumption of petroleum and petroleum products in Canada in 1951 are approximately 154,000,000 barrels, which is slightly more than 11 •barrels per capita, whereas the estimated consumption in United States for the same period, according to World Petroleum, is placed at 2,619,- 970,000 barrels. This, on the basis of a population of 154,000,000, would be equivalent to 17 barrels per capita. The increase in consumption of the petroleum and products is world wide. World production in 1951 has been estimated (Oil and Gas Journal) at 11,700,000 barrels a day or more than 41;4, billion barrels for the year. United States production increased 13.7 per cent to 6,143,000 •barrels a day and Canada'.s ,, total production increased about 65 per cent from a total of 29,091,235 •barrels in 1950 to an estimated (Dominion Bureau of Statistics) 48,096,800 barrels in 1951.The trend to use increased amounts of petroleum and petroleum products, particularly in the United States and Canada, has also been supplemented by increased use of natural gas. The rate of expansion of the consumption of natural gas in United States in the past few years has been very rapid, increasing from 2,600 billion cubic feet in 1940 to 5,975 billion in 1950, with the proven reserves in the same period increasing from 85,000 billion to 186,000 billion cubic feet."

Jan 1, 1952

By E. Peters

Roasting processes are divided into several elementary mechanisms, any of which could be significant or pre-dominant in a particular roast. The elementary processes considered in-elude beat transfer, gas-solid inter-actions with accompanying mass transfer between the bed and furnace atmosphere, vapor phase transport processes in solid-solid interactions, and solid phase diffusion processes. Examples are chosen of processes in which one of these mechanisms pre-dominates and some recently obtained data is presented to support the existence and significance of these mechanisms. Proposals are also made for future research in these areas, and for utilizing the information in the improvement of roaster capacities’ OASTING of ores as a preparative treatment for smelting or leaching has been practiced for so long that its origin has been lost in antiquity, but little has been under-stood of its basic nature until fair-ly recent times. The nominal chemistry of roasting processes is now understood; that is, the initial chemical com-pounds present in the ores or con-

Jan 1, 1961

By G. H. K. Pearse, R. P. Taylor

The Big Whopper, one of only four giant economic rare metal pegmatites worldwide, is set to become a producer of the highly valued lithium mineral petalite (LiAlSi4O10) used in glass, ceramics and the specialty glass-ceramics familiar as Corningware® and the new ceramic stovetops. The deposit has a strike length of 1.5 km, a width of up to 80 m and a resource, open in all directions, of 11.6 Mt, grading 25% petalite. It is amenable to open pit mining and Avalon Ventures Ltd. holds a patent on a flotation process that produces an exceptional quality petalite product. The project will also produce: superb quality Na-feldspar which, too, finds use in glass and ceramics; the unusual Rb- K-feldspar for high voltage porcelain insulators; tantalum, in high demand for electronics; lepidolite, an ore of rubidium; and mica and tin. A positive prefeasibility study has been completed and it remains only to undertake bulk sampling and a full feasibility study.

Jan 1, 2001

By E. O. Chisholm

Synopsis The colour changes effected in a solution of dithizone by trace amounts of copper, lead, and zinc mineralization provide a sensitive field test for these metals. The method has been used with success by the United States Geological Survey to trace zinc orebodies under residual soils. The dithizone test is used here on samples of non-residual soil overlying a gold-bearing zone in which the gold is associated with disseminated sphalerite, galena, and chalco-pyrite. A gold-bearing zone was successfully traced under overburden ranging from a few inches to five feet in depth by means of this method. The method may prove useful in guiding preliminary trenching through light overburden, by outlining the extent of copper, lead, and zinc mineralization. Introduction The dithizone test affords a rapid, simple, and delicate test for the presence of zinc in soil and water and is suitable for use under field conditions. It has recently been used with success by the United States Geological Survey to outline a zinc-rich area in the residual soil over a primary zinc deposit in Tennessee. The purpose of the present study was to ascertain whether the method could be used to trace a gold-bearing zone, containing associated zinc mineralization, under shallow, non-residual, glacial overburden. The results obtained indicate that the method can be used to guide preliminary trenching in overburden up to six feet in depth. Tests made of the water near lake-shore outcrops also indicate that favourable prospecting zones may be located from the water, within five feet of the shore. It is felt that this simple field test should find a wider use in prospecting, because, under certain conditions, it can outline favourable zones and thereby reduce the amount of blind trenching necessary. The following pages describe the type of deposit tested, the method used, the .results obtained, and the difficulties encountered by a novice in the use of this chemical procedure. The author is indebted to the officials of Nor-Penn Mines, Limited, for their co-operation while the tests were being made; to the late Richard Bouska, Kenora prospector, for helpful suggestions; and to F. W. McCamus, University of Toronto undergraduate student, who ably assisted with the work.

Jan 1, 1950

By Rhual L. Guerguerian

MINING has been practised by mankind for over sixty centuries (1). In 1876, the "ball mill" was patented, and during the century that followed rotary grinding developed to the state where individual machines are treating tens of thousands of tons of ore per day. This paper gives a brief description of design practices prior to the availability of advanced facilities, followed by modern analytical design development at Dominion over the past ten years.

Jan 1, 1978

By R. A. Parra, Fuentes, C. Godoy, L. E. Arias, C. A. Toro, M. Marin, E. Balladares, V. Parra, G. Reyes, S. N. Torres, D. Sbarbaro

In this paper, we report on the detection of spectral molecular emission of iron oxide (FeO) and copper oxide (CuxO) emitted by reactions occurring in a laboratory scale flash smelting process of pyrite (FeS2) as well as copper concentrate. The novelty of the technique is that, the molecular spectral emission sensing is achieved by using a low spectral resolution and low sensitive radiometer, enhanced with signal processing and matrix factorization techniques. The method was validated using a highly sensitive spectrometer, with a high spectral resolution; achieving a similar FeO spectral pattern as the one obtained after signal processing techniques over low resolution spectral signals. INTRODUCTION Visible-near infrared (VIS-NIR) spectroscopy is an optical contactless sensing technique commonly used to capture information about the emitted, absorbed, transmitted or scattered radiation in a physical or chemical process, with the presence or absence of an excitation light source such as a laser or a broad spectral band source. These techniques coupled with signal processing and machine learning algorithms, sometimes referred as chemometrics (Pisapia et al., 2018), can be found in processes such as: pharmaceutical (Kandpal et al., 2016); food (Coelho et al., 2016); combustion (Ballester & García-Armingol, 2010); siderurgy (Strakowski et al., 2014) industry, among others. In the extractive copper industry there are several technological developments using optical sensing techniques aimed to retrieve information about copper ore and concentrate mineralogical composition such as X-Ray Fluorescence, Qemscan® (Quantitative Evaluation of Minerals by Scanning Electron Microscopy) and X Ray Diffraction (XRD) analysis, however, because of the manual procedures to analyze the samples with these laboratory instrumentation, only discrete information during a daily based operation can be retrieved, making impossible for the operators to take decisions over the involved processes in real time. The aim of our research work presented here is to contribute with sensing and data analysis procedures based on VIS-NIR spectroscopy for the flash smelting process characterization, particularly in this paper, with the detection of FeO and CuxO molecular emissions in a laboratory scale setup.

Jan 1, 2019

By C. Pichler, S. Luidold, C. Wagner, C. Sagadin, D. Kreuzer

Engineers and scientists have been combating the attack upon refractory materials of molten metals/matte and slags for hundreds of years. The details in many cases are still questionable or at least debatable. The corrosion is a major concern for furnace operators as refractory wear or failures inevitably results in reduced production efficiency and furnace reliability. Also the cost to industry is considerable and only a thorough understanding of all the complexities of the process will help to minimize that cost. One of the critical questions to overcome is the correct selection of refractories for the individual process steps to provide long and predictable refractory life together with high furnace availability. To understand the nature of the reactions involved in refractory corrosion, it is crucial to determine the complex thermo- chemical equilibria of the reactions occurring between the refractory materials and the process phases. A simulation model coupled with commercial software like FactSageTM is demonstrated aiming to understand the corrosion mechanisms between refractories and the molten process phases and draw implications for improving the performance of refractories and refractory lifetime. INTRODUCTION The extraction or recycling of valuable materials, e.g. metals, can be done by two main routes, pyro- and/or hydrometallurgical processing, depending on the chemical behavior of the used ore, scrap or pre-treated concentrate. Sometimes it is also necessary to use both process routes for the extraction or the recycling of valuable materials. In the case of a pyrometallurgical treatment, the usage of refractory materials is inevitable. This is mainly caused by high temperatures, prevailing during processing. The interaction between refractory material and slag, metal or matte leads to different reactions and interactions. As a main result corrosion of the furnace lining (refractory material) takes place. Hence, recurring furnace shutdowns occur for renewing the refractories. This leads to reduced production efficiency. Such refractory lifetimes are between some hours and decades, depending on the processes.

Jan 1, 2019

By David A. Orava, Richard C. Swider

"The technical knowledge and practical experience accumulated by industry and others in abating acid mine drainage (AMD) is being proactively applied at every phase of the mine life cycle. This paper traces the mine life cycle from exploration to post closure monitoring and maintenance, and reviews AMD abatement measures that have become an integral component of exploration and mining activities.Attention is increasingly being given to evaluating AMD potential as part of exploration work, and studies related to project feasibility and design. Mining, mineral processing, and waste management options are selected taking into consideration their suitability to inhibit AMD. These inhibition measures are typically committed to in closure plans submit-ted at the permitting stage. Mines are operated and decommissioned, often progressively, as planned and in accordance with environ-mental protection policies."

Jan 1, 1996