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By K. Thuro, L. Wilfing, H. Kasling

"In mechanized tunneling, performance prediction is a crucial issue for estimating excavation costs and construction time of a tunnel project. The aim of this work is to compare the calculated parameters by penetration prediction models with the results of penetration tests during excavation by a Tunnel Boring Machine (TBM) at actual tunnel projects. This comparison helps to improve the existing prediction models (Gehring, 1995 and Rostami (Colorado School of Mines), 1997.) and to develop a new, so-called “Alpine Model” (research group ABROCK; Schneider et al., 2012).On-site penetration tests are a common tool to determine performance of a TBM in certain geological environments. During a test, the TBM is operated under defined conditions that allow comparing the results of different projects and machine types. There are two different types of penetration tests in use. The more common type, described by Bruland (1998a), is based on test drives at different thrust levels. The tests in this study are performed as start-stop-tests, meaning that the TBM starts from zero to the maximum possible thrust and reverse with slowly increasing respectively decreasing steps (Frenzel et al., 2012). To gain information about the interaction between TBM and rock mass, a detailed geological documentation including an analysis of the discontinuity pattern and laboratory testing for rock strength characterization are mandatory.Within the last year 16 penetration tests have been performed. The results are thrust- penetration curves (Figure 2) showing that up to a certain penetration rate only crushing occurs (subcritical penetration). From there the desired rock fragmentation process called chipping takes place (Frenzel et al., 2012). These two different fragmentation processes can be described best by a bilinear function as seen in Figure 3. Both, CSM- and Gehring-model, do not fit to the trend of the penetration rates determined during the excavation process as they are using potential or simple linear functions.Another parameter that has to be implemented into the new prediction model is the influence of discontinuities. In case of favorable orientation and spacing, discontinuities reduce the required thrust at same penetration rates. In contrast, unfavorable discontinuity systems can cause blocky faces and hence worse performance than predicted. Besides discontinuities, the toughness of rocks has to be taken into account when predicting the penetration as tough rocks need more energy to obtain complete failure than brittle rocks.Key advantage of these tests in comparison to existing are more data points in less time. By improving respectively extending the existing penetration prediction models with the stated parameters, the penetration prediction for TBMs can be more accurate and also wear calculation can benefit from this approach."

Jan 1, 2015

By Anne-Marie Dagenais

Un recouvrement de type couverture à effets de barrière capillaire (CEBC) a été mis en place en 1988-1999 sur le parc à résidus de l?ancien site minier Lorraine situé au Témiscamingue. Depuis sa construction, la CEBC fait l?objet d?un programme d?auscultation et de suivi qui vise à évaluer son comportement hydrique et sa capacité à limiter le DMA. Des essais de consommation d?oxygène ponctuels ont également été réalisés sur le site afin de mesurer directement le flux d?oxygène traversant la couverture. Les résultats provenant des relevés de teneur en eau volumique et de succion, pour les années 1999 à 2001, montrent que les effets de barrière capillaire sont présents et que la couche de rétention d?eau demeure dans un état près de la saturation pour l?ensemble de la couverture. Les flux d?oxygène calculés à partir des mesures mensuelles sont en général inférieurs à 10 g/m2an, soit en deçà des valeurs de design de 20 à 40 g/m2an. Les essais de consommation d?oxygène réalisés sur la CEBC donnent également des flux d?oxygène du même ordre de grandeur. Les résultats obtenus de ces différentes méthodes d?évaluation concordent, et ils confirment l?efficacité de la CEBC à inhiber le flux d?oxygène et à contrôler le DMA.

Nov 1, 2002

By J. W. M. Porritt, M. P. Brameld, R. H. McCorkell

"Soil-gas Rn was measured by two types of alpha-particle-track detectors, by emanometry and by counting alpha-activity on Rn-decay-product collectors. Soil samples were analyzed for V by fluorimetric and fission-track methods, their Rn-emanation by decay-product collectors and their total alpha activities with track detectors. The same uranium anomalies were revealed by each method. Fission-track analysis of leaves for V showed only random variations with sampling site, and the Rn emanation of trees and leaves removed from them was barely detectable . The agreement among the other methods is significant, total alpha and collector methods are simple, rapid and useful, and a combination of methods at a site would reveal disequilibrium in the U-decay series if present. Track-Rn measurements are highly reproducible and insensitive to apparatus design and their sensitivity is not enhanced by covering the detectors with thin foil or placing them in large containers.IntroductionIn the past two years , a number of methods of geochemical exploration for uranium have been tested by the authors over the known copper-uranium occurrence at South March, Ontario. This was done partly to compare methods and partly to develop and test new ones. The South march deposit has been described a number of times by others(1,2,3,4). The methods included in this study were the following.Emanometry, Radon in soil gas is measured by pumping the gas into the cell of a scintillation counter or emanometer(5,6). Alpha particles from radon (222Rn) and its decay products (218Po and 214Po) produce scintillations of light in the silver-activated zinc sunphide (ZnS(Ag) covering the walls of the cell. These are counted by a photomultiplier tube and scaler, the count ra sulphide (ZnS(Ag) covering the walls of the cell. These are counted by a photomultiplier tube and scaler, the count rate being proportional to the concentration of radon in the soil gas."

Jan 1, 1981

By A. G. Ballachey

Introduction This paper will describe the mining plant and underground operations at Quemont. Details of geology and milling are beyond its scope. Papers on these subjects will be prepared and presented separately. A detailed account of the exploration and development, 1944 to 1947, has been given by W. L. Brown (1). Location The mining concessions of Quemont Mining Corporation, Limited, are in Rouyn township, Rouyn-Noranda county, northwestern Quebec. These concessions total about 640 acres in area. They lie within the limits of the City of Noranda, contiguous to, and directly north of, the Horne mine of Noranda Mines, Limited. A large area in the southern part of the property is covered by the north arm of Osisko lake. Production The present operating rate is about 2,100 tons per day. Three flotation concentrates are produced: copper, containing a large proportion of the gold and silver in the ore; zinc; and pyrite, which carries an appreciable additional proportion of gold. The copper and zinc concentrates are shipped to smelters as produced. The pyrite concentrate is cyanided to recover additional gold, after which it is filtered, dried, and shipped for the manufacture of sulphuric acid. The principal revenue metals are copper, gold, and zinc. Silver and pyrite are important by-products.

Jan 1, 1952

By K. Krishnapisharody, S. Clark, M. Barati

Different gas purging methods to metallurgical baths have been applied to date, among which are top lancing and bottom blowing through tuyeres or porous plugs. Among these, the porous plug bottom blowing technique has shown higher efficiency in gas utilization than tuyeres and top blowing, due to smaller bubble size and lower liquid velocity. However, the studies related to bottom stirring of metallurgical baths are limited to slag-less or thin slag-covered melts. In particular, there is no examination of stirring ability in conditions similar to Falconbridge's Slag Make Converter, where the bath is covered with a thick slag layer and a stream of solids is charged on the bath from top. This study was undertaken to investigate the application of gas purging through a porous plug in stirring in and melting of the solid feeds. The spreading behaviour and melting time of a solid layer forming on a plume created by stirring were calculated using the existing models. The results show that formation of a thick solid layer, specifically in areas beyond the plume region is very likely. Nevertheless, the thickness of the layer and melting time do not appear unreasonably high. It is predicted that by proper controlling of gas flowrate and plug configurations, successful solid charging through the mouth can be practiced.

Jan 1, 2007

By M. Dotto, T. G. Joseph, M. Curley

"Equipment selection is a key decision in mine planning. Equipment size affects decisions from pit size to the total operation cost. Particularly when replacing haulage fleets for long-life surface mining operations, mining operations focus solely on haulage productivity. Road width and specifically ramp width are significantly affected by an increase in hauler size in terms of overall strip ratio through required highwall set-backs or sterilizing of lower ore access due to required overlying ramp fill structures. In addition, in light of ever increasing regulatory and reporting emissions requirements, bigger equipment may not translate into lower emissions per tonne moved. This study analyzes hauler-scale impacts on aspects not currently incorporated into conventional mine planning, including expansion of roads to accommodate larger equipment, road layer thickness variation depending on hauler size, and fuel consumption and emissions. Results indicate that such relationships have a large impact on cost. Therefore, an expanded consideration of the capacities of increasing equipment size in mine planning is highly recommended. ¦ KEYWORDS Equipment selection, Grade resistance (GR), Haul road, Haul truck, Mine planning, Payload, Rolling resistance (RR), Total resistance (TR) RÉSUMÉ La sélection du matériel est une décision importante dans l’aménagement des mines. La taille de l’équipement a une incidence sur la prise de décisions, depuis la taille de la fosse jusqu’aux coûts totaux des activités. L’exploitation minière se concentre uniquement sur la productivité des moyens de transport, particulièrement lorsqu’il s’agit de remplacer les parcs de camions de transport dans les exploitations à ciel ouvert à longue durée de vie. La largeur des routes, et spécifiquement la largeur des descenderies sont considérablement affectées par une augmentation de la taille des camions de transport en termes du coefficient global de recouvrement qui dépend de la taille requise des parois (si les descenderies sont agrandies, les parois devront être creusées de haut en bas afin d’agrandir la taille du fond de la fosse). Il faut aussi pouvoir procéder à l’excavation des gradins les plus profonds de la mine et ainsi préserver l’accès à cette zone, ce qui pourrait devenir difficile si la quantité de stériles utilisés pour la structure des descenderies augmente et s’ils occupent une trop grande partie du fond de la fosse. En outre, au vu des exigences de plus en plus strictes en matière de réglementation et de déclaration des émissions, un équipement plus volumineux ne sera pas nécessairement synonyme d’une réduction des émissions par tonne déplacée. Cette étude analyse l’incidence de la taille des camions de transport sur des aspects actuellement non intégrés dans l’aménagement classique des mines, notamment la création de routes permettant le passage d’un équipement plus volumineux, la variation de l’épaisseur de la couche d’asphalte des routes en fonction de la taille des camions de transport, ainsi que la consommation de carburant et les émissions. Les résultats indiquent que ces relations ont des répercussions importantes sur les coûts. Ainsi, on recommande d’accorder une attention accrue aux capacités d’augmentation de la taille de l’équipement dans l’aménagement des mines. ¦ MOTS CLÉS aménagement des mines, camion de transport, charge utile, résistance au roulement, résistance due aux rampes, résistance totale, route de transport, sélection du materielINTRODUCTION Over the past five decades, the mining industry has progressively attempted to increase production rates through the use of larger haulage equipment. Each new generation of mine is designed to operate with the most recent and often bigger equipment iteration, while older mines are re-evaluated to keep pace with upgraded mixed fleets. Whereas production gains are often realized with larger equipment, there are additional aspects to consider when evaluating the feasibility of mo"

Jan 1, 2019

By Ainul Akhtar, Steve Cockcroft, Jixiang Xu, Daan Maijer, Lu Yao

"Nitrogen rich Ti-N inclusions are one of the more difficult inclusions to remove during liquid metal refining of titanium. If present in the final component, they can significantly decrease the mechanical performance of titanium and its alloys in applications involving cyclic loading. Understanding the kinetics of dissolution of Ti-N particles during consolidation/melting of titanium can help us better operate and design the melting processes to minimize their occurrence in Premium Quality Titanium production. A numerical model based on finite difference method has been developed to calculate the dissolution of a spherical Ti-N particles in molten titanium. Analytical solutions were used to verify the finite difference code for calculation of concentration profile and the dissolution of spherical solids. Taking into account the limitations in these approaches for the different cases examined, the invariant field approximation showed good agreement with the results from the numerical analysis. Evolution of the size of a spherical Ti-N particle during dissolution was predicted by the numerical model and the particle dissolves in 163 s.INTRODUCTION Properties like low density, high specific strength and excellent corrosion resistance make titanium attractive for a variety of applications. Key characteristics in the processing of titanium and its alloys include its high sensitivity to impurities, especially atmospheric oxygen and nitrogen and its high reactivity in the molten state. Nitrogen rich inclusions Ti-N, also known as Type ? or hard alpha defects, usually have substantially higher hardness and lower ductility than the surrounding material. Because they can act as fatigue initiation sites, Ti-N inclusions can significantly decrease the mechanical performance of titanium and its alloys in applications involving cyclic loading, even in minor amounts (tenth of a percent) (Lampman, 1990; Moiseyev, 2005; Lütjering & Williams, 2007). Ti-N encompasses as a broad range of nitrogen contents from a few wt% up to stoichiometric TiN. The liquidus temperature of Ti-N titanium increases substantially with increasing nitrogen content. Consequently, depending on the concentration of nitrogen, the melting point of Ti-N inclusions can be above bulk liquid metal temperatures during melt processing. Thus, removal of Ti-N defects hinges on dissolution and not melting."

Jan 1, 2017

By M. B. Greyver

The results of laboratory tests on iron precipitation from non-decopperized nickel anolyte are discussed. The parameters (pH, oxygen consumption and stirring speed) for iron precipitation from the anolyte, using the oxygen in the air, were determined. In the experiments conducted under optimized conditions, the residual concentration of iron in the anolyte after precipitation was 0.7-2.7 mg/L, and the copper and nickel losses to the solid phase were 0.05-0.07% and 0.05-0.16%, respectively. The filtration ability of the iron slurry obtained was 2 to 5 times higher as compared to that after chlorine oxidation and oxyhydrolysis. The leaching of the non-ferrous metals from the iron cake made using the separate nickel anolyte purification process was possible by dissolution in sulphuric acid. It was established that after cobalt precipitation from the copper- and iron-depleted anolyte, the precipitates obtained had lower ratios of Fe:Co and Ni:Co.

Jan 1, 2006

By J. D. Christian

WHEN mining development began in the Kirkland Lake camp, twenty-five years ago, there was very little information obtainable from surface showings as to the nature of the ore deposits. A length of almost a mile of the main 'break' lay under the south arm of the lake, and elsewhere most of the outcrops were covered with glacial drift. Shafts were sunk on ore-bodies of uncertain value, either on the outcrop of the veins or-because of the lake to the north-in the south or hanging-wall. In the second year of the camp's development, the Great War broke out and retarded progress for its duration. He would have been a real optimist who, in those early years, could have foreseen mining at depths of more than a mile.

Jan 1, 1939

By A. Lopez-Valdivieso

Particle size enlargement processes play an important role in solid/liquid separation, and in beneficiation unit operations. In the latter, not only the size of the formed aggregates but also their surface properties are very important. Oil agglomeration has a special place among such processes: it is a selective process in which hydrophobic particles are agglomerated into hydrophobic agglomerates which can be recovered by flotation. This explains the broad applications of oil-assisted beneficiation processes not only in the beneficiation of fine coal, but also in agglomerate flotation of many different types of ores, and in coal/gold agglomeration.

Jan 1, 2004

By Sunil S. Gandhi

Magmatic-hydrothermal deposits rich in magnetite and/or hematite form a broad group that includes monometallic Fe deposits and polymetallic (mainly Cu and Au) deposits. They show a considerable variation in deposit characteristics, but share the genetic processes of magmatic differentiation and related hydrothermal activity in intermediate to felsic melts, and in some cases involve brines and/or meteoric waters during mineralization. They include several world-class deposits. They range in age from Proterozoic to Recent, and form important metallogenic districts in Scandinavian, Canadian, Brazilian and Australian Shields, Circum-Pacific regions, and in China, Iran and Turkey. Monometallic deposits have been important sources of iron in the past and still contain significant resources of the metal, e.g., the Kiirunavaara deposit in Sweden. The giant Olympic Dam Cu-Au-Ag-U-REE deposit was discovered in 1975, and since then explorationists have focussed on search for analogues worldwide. This has brought to light a number of economically important new deposits and prospects, including examples in Canada. The discoveries have in turn prompted considerable research on individual deposits and the group as a whole. This short paper is an attempt to summarize the main aspects of the group from the literature cited in Gandhi and Bell (1996), and from the papers published recently in two milestone volumes on these deposits, edited by Porter (2000 and 2002).

May 1, 2003

By N. Ahern, L. Manoukian

"Cyanide is a leaching agent for precious metals commonly used in gold ore processing. Cyanide exists in various forms (including free, complexed as weak or strong complexes, and as ions such as cyanate and thiocyanate), so its detection, speciation and analysis in processing or environmental samples can be complex. This paper will review best practices for cyanide sampling and preservation in the field, interferences and pretreatment methods required prior to sample analysis and analytical methods that are used for cyanide species. Titrimetric, flow injection ligand exchange, spectrophotometric, colorimetric, potentiometric, amperometric, and chromatography techniques will be discussed and their chemistries, detection limits, advantages and limitations will be described.INTRODUCTION Cyanide is well known to be an extremely toxic species. Accurate cyanide measurement in effluent from mines is critical from an environmental perspective. Its measurement is also an important control parameter in the recovery of gold using cyanidation. Cyanide chemistry is diverse and complex, and cyanide analysis can be challenging as a result of and because of limitations in understanding of analytical methods. Various chemical mechanisms can form or destroy cyanide, and the sample matrix or preservation chemicals can also affect analytical results. These interferences make the collection of reliable cyanide measurements challenging and can start as soon as the sample is collected, during laboratory pre-treatment and during analysis. This paper reviews different methods of cyanide measurement. The basic chemistry of cyanide, best practices for sampling and preservation, as well as various methods of analysis will be discussed.CHEMISTRY The complexity of cyanide chemistry is well known (Beck, 1987; Delgado, Botz, Bucknam, Milasovljevic, & Staley, 2008; Botz, Milosavljevic, & Ward, 2013) and is attributed to the ability of cyanide to undergo: •,Volatilization •,Precipitation •,Adsorption •,Complexation with metals •,Oxidation to cyanate, ammonia, or cyanogen chloride •,Reaction with sulfur or sulfide minerals to form thiocyanate •,Redox reactions leading to the formation of cyanogen and cyanate •,Redox reactions (of some cyano complexes) •,Photochemical reactions (of some cyano complexes)"

Jan 1, 2017

By J. J. Fitzpatrick

"This paper deals with the methods used by Quebec Cartier Mining Company in the evaluation and selection of new haulage equipment and in increasing the productivity of the existing fleet.Selection of new equipment is based upon the comparison, for each model under consideration, of the capital investment required and the estimated operating costs and production rate. The calculation of the production rate is based on a widely used estimating procedure. Actual operating conditions considered in the method include: payload, haul distance, road grade, rolling resistance, loading and dumping times, and operational efficiency. A digital computer is used to handle the large volume of repetitive calculations required. Where a fleet of haulage equipment includes trucks of different size and performance characteristics, the problem exists of assigning each truck type to the different working locations to minimize total cost. Linear programming can be used in the solution of this problem."

Jan 1, 1967

Despite the claims of energy efficiency and the considerable development that has gone into dramatically extending rolls? life and facilitating rolls? change-out, in the six years since the last SAG conference, only a few HPGR operations have entered the realm of mineral processing. Risk barriers to the take-up of new equipment or processes are: a massive increase in materials handling issues as well as in the number of pieces of equipment required, low total circuit potential energy savings, and similar or higher capital costs. An alternative route is to make use of the complementary strengths of the HPGR and SAG in hybrid circuits. Minimising materials handling issues, providing an ideal balanced feed to the AG or SAG mill, and improving controllability through shifting grinding load as the RoM feed changes, are all potential major advantages to this approach. Conceptual circuit layouts, based on real measured ore and equipment data, are presented here to illustrate the potential production upside, the reduction in operating costs and the reduction in the physical and energy footprints.

Jan 1, 2012

By C. S. Parsons

Custom milling-plants have been operated successfully for a great many years on this continent. One of the outstanding examples in the United States is the Golden Cycle mill at Colorado Springs, which mills the gold-telluride ores from the Cripple Creek district. In eastern Canada, the Northern Custom Concentrators, Limited, at Cobalt, successfully treated the cobalt-silver ores of that area for a number of years. Flotation plants have entered the custom field in the past few years. The building of flotation concentrators to treat ores on a custom basis indicates the advance which has been made in flotation. In fact, three years ago it was considered almost impossible to treat successfully a mixture of miscellaneous ores by flotation. The methods used at that time were considered so delicate that any change, even in a single ore, would usually result in decreasing the effectiveness of the separation. Today we find four large custom flotation plants in the United States and one in Canada for treating complex lead-zinc ores from many different localities. The advent of these mills was brought about by the serious problem confronting the lead-smelting plants due to increasing amounts of zinc in the ores presented for treatment. It was necessary to penalize the mines shipping high-zinc ores. The penalty is justified, because high zinc in the lead blast-furnace charge not only decreases the tonnage of the furnace but increases the amount of flux necessary, as well as increasing the metal loss in the slag. It has been estimated that in the Salt Lake valley alone, 75,000,000 pounds of zinc was lost in the slag-dumps from the operations of three large lead blast-furnace plants. It has also been estimated that $150,000 worth of additional flux was required to slag this zinc. It was to avoid at least a part of this wste and to help maintain an ore supply that custom flotation concentrators were built by the smelters.

Jan 1, 1928

By P. Leo

Al-Mg-Si alloys are widely used as medium-strength structural materials; extrusion is the most common processing route. In the present hot deformation investigation of a 6060 alloy, the microstructure of the alloy has been analyzed in the as-cast state, after homogenization heat treatment and after hot deformation by tensile tests in the range 400-490°C and 10-4 to 10-2s-1 on both as cast and homogenized alloys. After deformation the microstructure of the as-cast alloy exhibited cavitation. The flow curves at the lowest test temperature T show a gradual softening after a stress peak, being more evident for the alloy deformed in the homogenized state in association with a high yield stress; at higher T a plateau is attained which is lower as T rises and strain rates decrease. For each fixed T, the ductility decreases as strain rate increases for the homogenized alloy whereas, for the as cast alloy, it rises with strain rate. Constitutive analysis gives Q = 240kJ1mol for the homogenized alloy in agreement with published values; this indicates a more rapid strength decline with rising T than Al, suitable for good hot workability along with the lack of cavitation.

Jan 1, 2011

By L. C. S. Dharmasiri, S. M. Shin, A. Senaputra, J. S. Sohn, K. H. Park, J. Avraamides

Reducing agents can be applied to leach metal values from natural and secondary resources such as laterite ores and deep sea manganese nodules and recycled materials such as spent batteries / catalysts which contain high-valent metal oxides of manganese, cobalt and iron. Selective leaching of some metals can be achieved by selecting conditions to control the saturated solubility and dissolution rates of metals from oxides or mixed metal/oxide matrices. The leaching results are rationalized on the basis of chemical species, Eh-pH diagrams and heterogeneous kinetic models. The role of reducing agents such as hydrogen peroxide, sulfur dioxide and iron(II) sulphate, in acid, alkali and in the presence of complexing ligands such as ammonia for the improvement of the leaching of metal oxides and metals is discussed. Previous studies on acid leaching of metals from nickel laterites, manganese nodules and spent catalysts/batteries in the absence or presence of reducing agents show that the rate controlling step involves the diffusion of protons through a thickening product layer on the particle being leached. It is shown that the leaching of nickel and cobalt from manganese nodules and zinc-carbon batteries in ammoniacal sulphur dioxide solutions also obey shrinking core kinetics.

Jan 1, 2014

By L. Gonzalez-Sardi, W. McCombe, M. Pearson

Pressure oxidation is increasingly being used for processing refractory sulphide ores and concentrates because it offers highly effective base metal and precious metal extraction while minimizing elemental sulphur, arsenic & mercury emissions. Yet pressure oxidation processes introduce new safety concerns and process risks as demonstrated by a number of safety incidents over the last 20 years, including overfilling, oxygen-metal fires, nozzle/sparger failures, and uncontrolled pressure relief events. Chemical Process Safety regulations in the United States and Canada mandate that companies constructing or operating chemical process facilities perform a rigorous hazard and risk analysis based on either ANSI/ISA-84.00.01 or IEC 61511 safety standards to determine the level of protection required for each hazard in the plant. This paper describes the application and implementation of three (3) unique safety instrumented systems developed by Hatch for ensuring the safe operation of three different pressure oxidation processes.

Jan 1, 2014

By M. Krasowska, K. Malysa, M. Krzan

The paper presents fascinating, in our opinion, observations on mechanism and course of processes occurring during bubble collision with hydrophobic and hydrophilic solid surface. Hydrophobicity of particle surface is a necessary condition for the particle attachment to bubble. We have observed that even in the case of such hydrophobic solid surface as Teflon, the bubble attachment didn't occur at first collision. In distilled water the bubble bounced a few times without attachment. Influence of a-terpineol and n¬pentanol on bubble local and terminal velocity and the phenomena occurring during bubble collisions with hydrophobic and hydrophilic solid surfaces was studied. Bubble collisions with the solid surfaces were monitored and recorded using the high-speed (1182 frames per second) camera. It was found that in distilled water the velocity variations of the "approach-bounce" cycles were identical for Teflon and glass. Four distinct "approach-bounce" cycles were detected both at Teflon and glass surfaces. Moreover, the amplitude and frequency of the velocity variations were identical on collisions with the hydrophobic (polished) and hydrophilic surface. There was no immediate three phase contact formation, with the hydrophobic Teflon surface, what we found really astonishing. Roughness of Teflon surface seems to be important parameter, which affects probability of the bubble attachment as a result of a presence of micro-and/or nano-bubbles at the surface. It was detected that the presence of the micro-bubble affected attachment of the colliding bubble even in distilled water. Presence of a small amount of a-terpineol or n-pentanol affects dramatically the bubble velocity, but their role in mechanism of the bubble attachment needs further study.

Jan 1, 2004

By A. Pawelczyk, D. Hreniak, E. Zych, W. Strek, K. Grabas, A. Ostrowski

"Nowadays recycling became an important rare earth elements (REE) source, which allows to reduce their demand for extraction from natural deposits. At present, the used fluorescent lamps and old type TV or computer monitors kinescopes are selectively collected and undergo processing in the system of recycling. It has been estimated, that utilization of such waste would be sufficient to cover the REE demand for the next 5-8 years. In the developed process, the luminophores were separated from the electronic and electronic waste materials, and processed by hydrometallurgical methods to obtain concentrated REE in form of oxides. INTRODUCTIONInternational Union of Pure and Applied Chemistry (IUPAC) defines the rare earths as a set of seventeen chemical elements, specifically the fifteen lanthanides plus scandium and yttrium. They are considered the most important indicators of the developed technologies and techniques. Rare earths are used, amongst others, for the production of magnetic and superconducting materials, ceramics, lighting, catalytic converters, advanced electronics and alloys. The demand for RE continually increases, similarly to many other primary raw materials. Globalization, the growing demand for limited resources of raw materials, the policy of the countries controlling the raw material market and the economic crisis became a spur for new programs of socio-economic development of the European Union (EU), with particular regard to EU safety for commodities in intermediary as well as long-term horizons (COM 2008), COM 2011).EU countries import most of metallic and chemical raw materials important for their economy. In 2008 a detailed program named Raw Material Initiative was announced. The increase in demand for most raw materials having special importance for the development of technology, and access to of raw materials security of supply affect the future economies of the UE member states and other developed countries."

Jan 1, 2012