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By D. Shishin

Continuous integrated experimental and thermodynamic modelling work is conducted in Pyrometallurgy Innovation Center (PYROSEARCH). The target is to develop a tool, which is capable to predict the compositions of phases, phase equilibria and enthalpy balance for pyrometallugical processes with higher accuracy. All these can be achieved by thermodynamic calculations based on Gibbs energy minimization algorithm. Recent developments made it possible to predict important factors, such as the chemical solubility of Cu in slag as a function of matte grade, temperature, P(SO2), Fe/SiO2 ratio in slag, wt% Al2O3, CaO and MgO in slag. In industrial practice, it is not only chemical solubility, but the overall amount of slag, which affects the recovery of copper and other valuable metals. It will also impact the energy balance. The presence of solids in the slag matrix influences the physical entrainment of matte in slag. Oxygen enrichment which is sometimes used to control the temperature of the furnace, may also affect the volatilization of minor elements into the gas phase. Same is true if additional fuel is used to compensate for heat balance. In other words, all key process parameters mentioned above are interrelated. Present study demonstrates the ways thermodynamic modelling can be used to link those process parameters on the example of copper smelting. INTRODUCTION Research methodology involving integrated thermodynamic modelling and experimental approach has been recently reported by the authors (Shishin, Hayes, & Jak, 2018 Shishin, Hidayat, Jak, Decterov, & Belov, 2016). Present paper reviews the updates and discusses challenges in the development of a large self- consistent thermodynamic database. The database covers the Al-Ca-Cu-Fe-Mg-O-Pb-S-Si-Zn-(Ag, As, Au, Bi, Ni, Sb, Sn) chemical system. The database works in the environment of FactSage software Bale et al., 2016 and related family of products: ChemApp (Petersen & Hack, 2007), ChemSheet and SimuSage. A list of phases, and thermodynamic models is shown in Table 1. For the copper industry, most important phases are Gas, Slag, Spinel and Liquid matte/metal/speiss. Black-colored elements represent the base system, elements in green can be considered as slag modifiers (slagging elements), and elements in red are minor. Ni is highlighted because it was included recently, in 2019, and currently under development. In addition to copper, the database covers the conditions typical for lead and zinc pyrometallurgical extraction. It is developed in consistency with the experimental results for high concentrations of Pb and Zn. Examples of applications in the present study include the thermodynamic analysis of fluxing for an agitated copper reactor to show the effect of Fe/SiO2, and calculations of copper slag cleaning using reductant.

Jan 1, 2019

By Y. Duna

The reliability of mine ventilation systems is critical to normal and safe production in a mine and includes reliability of the following parts: ventilation system branch (or passage), ventilation structures, ventilation network, and the fan. Among these, the reliability of a ventilation branch may be considered the foundation of the whole ventilation system. The branch ventilation flow includes four parameters: air volume; toxic and hazardous gas concentrations; temperature, and dust concentration. The calculation model for the reliability of a branch was established based on the analysis of normal distribution of flows in any one branch. Then, the efficiency of the ventilation structures and fire risk compromising the reliability of branch was studied. The results obtained were as follows: if the air volume, toxic and hazardous gas concentrations, temperature and coal dust concentrations of the branch are within reasonable limits, set at any stable state and at the same time, then this branch is reliable.

Aug 1, 2013

By Roy S. Celland, K. H. Singh

The introduction of 'post' pillar mining at the Strathcona mine represents a new approach to ground support in cut-and-fill applications. The method has also shown significant economic advantages. It is believed that the development of this concept is one of the few examples where rock mechanics principles have successfully been applied in the development of a stoping method. The paper describes the evolution of this method and contains discussions on the theoretical analysis of the technical, operational and economics aspects of the system. Pillar design procedures and field observations on the practical application of theoretical analysis are also outlined.

Jan 1, 1973

By E. Haccuria

Due to the growing share of electrical cars, the use of lithium ion batteries significantly increased. Recycling of these batteries is essential to safely dispose hazardous materials as well as to recover valuables (Cu, Ni, Co, etc.). In order to optimise the recycling process, accurate information is required on the slag phase equilibria for battery smelting. The slag is a multi-component system containing alumina from the battery cases, silica and lime from fluxes, and manganese and lithium from the electrode materials. The present study accurately determined the phase equilibria in the "MnO"-Al2O3-SiO2 sub-ternary system at metal alloy saturation. Particular attention was given to the accuracy and reliability of the final results by highlighting the different reaction pathways, mass transfer- and reaction mechanisms taking place in the system during experiments. This attention enabled improved experimental methodology and measurements. Based on the present study, further measurements will be undertaken in the quaternary "MnO"-Al2O3-CaO-SiO2 system at low "MnO" concentrations, which closely represents the future recycling industrial slags.

Jan 1, 2014

By J. S. Godard

The mining developments in western Quebec have shown the ores of this district to be more complex in character than was at first expected. When the initial discoveries were made it was thought that the ores would be similar in character to those of Kirkland Lake and Porcupine areas. Developments have since shown that although the ores along the southern margin of the belt are somewhat similar, those within the belt, constituting by far the greater proportion, are vastly different, being complex mixtures of base-metal sulphides carrying values in the precious metals. These mixtures of base-metal sulphides of copper, zinc, and iron, present several problems to the metallurgist, especially in their concentration into marketable products. For the purpose .of this paper the following classification may be made of the ores of the district. Group I. - Milling Ores: (a) Ores in which~ arsenopyrite is the predominating sulphide. In this class of ore the gold occurs in fractures in the quartz and is associated to a lesser extent with the arsenopyrite and pyrite. Examples of this class of ore are the Granada, south of Pelletier lake, and the O'Brien and the Thompson in Cadillac township. (b) Ores in which iron pyrite is the predominating sulphide and gold is the valuable constituent. This may also be classed as a concentrating ore-Group III.

Jan 1, 1928

By J. Kalejta

Ever increasing depth of mineral extraction presents a challenging environment for hard rock underground mines. High in-situ stresses and associated seismicity with potential rockburst hazards are the major decisive factors contributing to the choice of a ground support regime. Conventional ground support systems, designed primarily for static loads, are not always capable of providing safe working conditions for underground personnel in seismically active mines. Systems specifically developed to resist dynamic loading and allowing for larger deformations are therefore preferred alternatives. High-tensile chain-link mesh has a proven record of successful use in open cut operations in various rockfall barrier installations due to its high energy absorption capacity. It has also been used in underground operations in various parts of the world. This paper describes a method of mechanized installation of a chain-link mesh evaluated at the Kiruna mine in Sweden and South Deep Mine in South Africa. A purpose-built mechanized roll mesh handler was used in this evaluation. The handler is compatible with all standard multi-boom underground drill rigs and is operated utilizing the hydraulic circuit normally used for the feed arrangement. A number of key performance indicators have been identified as success criteria: ??A 30-50% faster installation compared to the conventional methodology ??The mesh should sustain any blast damage when applied to the blasting face ??No unraveling of the mesh when cut ??No failure of mesh under normal conditions Although the energy-absorbing mesh combined with yielding rock bolts is a ground support system of choice for rockburst prone conditions, the operational upsides recognized during the evaluation imply that this product can also be competitively used in less demanding ground conditions where customarily weld mesh or shotcrete are used as a primary surface support. The main conclusion: a fast, safe and fully mechanized installation.

Aug 1, 2013

By Jacek Paraszczak

Possibility to move human workers away from dangerous places ?enhanced safety and improved working environment; ? Increase of actual operational time: ? Less losses due to shift changes, regulatory breaks, blasting periods, ventilation after blasting, etc.; ? Possibility to work in extremely dangerous conditions where man-operated machine could not be used (for example: ST-14 loader in backfilling operations in the Kemimine, following roof collapse). Reduction of the production cost through: ? Lower maintenance cost (less damage due to operator?s mistakes and no machine abuse); ? Higher productivity and effectiveness of the equipment (less machines to meet production targets, less operators required, lesser maintenance cost...). ? Although personnel health and safety are key drivers behind autonomous operation of mobile equipment in U/G mines, with significant capital and operation costs one expects to achieve: ? Productivity higher, or at least equal to that offered by man-operated equipment and systems; ? Lower production cost. Therefore, high effectiveness of the autonomous equipment is crucial to succeed.

May 1, 2010

By V. G. Papangelakis, G. A. Moldoveanu

"One of the major commercially viable secondary sources of rare earths elements (REE) are the ion-adsorption ores, containing 0.05-0.3 wt% rare earth oxides physically adsorbed on the surface of clay minerals formed during weathering of lanthanide-rich rocks. Although ion-adsorption deposits are substantially lower grade than other types of rare earth sources, this is offset by the easier mining and processing costs and the low content of radioactive elements. The conventional extraction route involves ion exchange leaching with monovalent cation solutions (usually ammonium sulphate) under ambient conditions; during the process, the lanthanides are desorbed and transferred into solution, being replaced by the exchange cation. While ammonium ions are known to perform best, there is increased environmental motivation to investigate alternative lixiviants in order to minimize ammonium sulphate impact via reducing its use without considerable loss in rare earth recovery.The objective of the present research was to screen various cations salts (alkaline and alkalineearth metals present as sulphates, chlorides and acetates, respectively) in order to comparatively evaluate lanthanide desorption levels and provide a theoretical base of the observed behaviour. The overall aim is to gain a better understanding of how both cation and anion may affect the overall REE recovery from ores in order to provide alternative processing routes. The distinct exchange capabilities of cations were explained in terms of differences in cation hydration enthalpy within the same group, i.e. Cs+ > NH4 + > K+ > Na+ > Li+ and Ba2+ > Ca2+ > Mg2+. For the same cation, it was determined that REE extraction efficiency follows the order sulphate > acetate > chloride, based on dissimilarities in constants of formation values. Various process implications scenarios will be described based on using mixed cations and anion matrices."

Jan 1, 2016

By S. Pauly, U. Kühn, J. Eckert, I. Kaban, G. Wiehl, F. Silze

In the present work, the effect of Ga on the wetting behavior of the Cu-rich braze filler CuGa10 (wt.%) on the steel 304L was investigated. For this, the macroscopic and microscopic effects governing the wetting of pure Ga, pure Cu and CuGa10 alloy (wt.%) on the austenitic steel were analyzed and compared. Contact angle and surface tension measurements were carried out by means of the sessile drop technique and, in addition, the phase formation at the interface was determined. Pure liquid Ga spreads on 304L, which supposedly is related to the formation of intermetallic Fe-Ga phases growing into the liquid Ga. Depending on the annealing time, FeGa3 and Fe14.5Ga12 were identified. In contrast, CuGa10 as well as pure Cu show secondary wetting on the steel surface. Especially, liquid Cu prefers to spread laterally and vertically along the grain boundaries of the steel substrate. In spite of rather similar mechanisms, CuGa10 wets 304L steel at lower rate than pure Cu above the liquidus temperature.

Jan 1, 2014

Since 2008 rapid advances have been made in technologies for the sensing and sorting of ores, particularly copper, and copper-related ores. Advances include significant increases in the sensitivity and throughput, specifically in the area of bulk sorting. Such advances were not possible without contemporaneous advances in the understanding of copper orebodies, in particular the understanding and quantification of the heterogeneity required within an orebody to support an effective sort, regardless of the technology deployed to do this. This paper covers fundamental knowledge in the characterization of orebodies and their ores for sorting; relationships between measures of heterogeneity and sorting response; the design of bulk sorting systems that can exploit this heterogeneity to add value to copper operations; and, a quantification of the value that can be generated from bulk sorting at a case study mine. INTRODUCTION Society currently puts increasing pressure on industries to move towards cleaner and more efficient means of production, and the mining industry is no exception. Mining additionally faces other factors increasing the pressure to be more efficient: high-grade and easily accessible reserves have become largely depleted, therefore the mined grade at operations across most commodities, including and in particular copper, is decreasing. Additionally, the grade of new discoveries in the sector continues to decrease (Schodde, 2011). Factor in the high capital cost of processing facilities and the low levels of efficiency of current grinding circuits, and the situation for such mines becomes dire. Sorting, by maximizing the amount of ore extracted while simultaneously reducing the waste content in ore delivered to downstream processes (whether simply transport and crushing, or more sophisticated circuits such as grinding and flotation or leaching) has long been of interest to mining operations and projects struggling with low margins (Bamber, 2012). However, until recently sorting technologies that are both cost effective and effective at such high throughputs have not been commercially available.

Jan 1, 2019

By M. Sahoo, P. Burke, Y. Fasoyinu, J. P. Thomson

The effects of grain refinement, mold temperature and chemical composition on the hot tearing resistance of aluminum alloys 535.0 and 206.0 has been studied by pouring constrained rod castings in metal molds. In addition, two prototype components that could be used in automotive applications were also poured from both alloys by gravity tilt-pour and low pressure permanent mold casting processes. This paper summarizes the results and issues encountered during the casting trials. It was shown that grain refinement and mold temperature ::::: 400°C reduced, and sometimes eliminated hot tear cracks in both alloys. The two prototype engineering components could be cast successfully from both alloys in metal molds. The metallurgical issues related to molten metal treatment and processing temperatures were well controlled. However, issues related to the control of hot tearing, casting and mold design must be addressed in future studies to guarantee the production of defect free castings.

Jan 1, 2006

This paper describes basic parameters, such as surface forces and film elasticity, affecting the stability of foams (two-phase froths). We used the thin film pressure balance (TFPB) technique to measure the surface forces in foam films stabilized with various frothers such as pentanol, octanol, methyl isobutyl carbinol (MIBC), and polypropylene glycol (PPG). The results were compared with the foam stabilities measured experimentally and the film elasticities calculated using a new model developed by Wang and Yoon (2006). It was found that at low electrolyte (NaCI) concentrations foam stability is controlled by both film elasticity and surface forces (or disjoining pressure), the relative contributions from each changing with frother type and concentration. Further, the kinetics of film thinning was studied at a high electrolyte concentration. The results obtained in the present work showed that the major role of a frother is to decrease the hydrophobic force rather than to increase the film elasticity. This conclusion is drawn from the observation that at the typical frother (MIBC) concentrations employed in flotation, frother additions cause sharp decreases in hydrophobic force while causing relatively little changes in film elasticity.

Jan 1, 2006

By A. Roy, T. LeBel, P. Coursol, P. Lind

At the early stage of a mining project, small amounts of concentrates are available for testwork. For gold concentrate or ores containing significant arsenic levels, batch bench scale roasting is often unreliable, leading to highly variable gold recoveries to be used in the project’s financial justifications. With an appropriate bench scale unit using continuous feeding and residence time control for solid and gas phases, reliable numbers can be obtained at small scale with only a few hundred grams per test condition. This paper describes the development of a pilot fluid bed roasting unit by Kingston Process Metallurgy Inc. (KPM) to perform representative trials on gold concentrates containing arsenopyrite, arsenian pyrite and carbonaceous components. Calcines produced under different conditions were characterised by chemical analysis and electron microprobe; the calcine microstructure obtained is described. The most important parameter affecting gold recovery is oxygen content in the roasting atmosphere, with the lowest controlled oxygen level giving the highest gold recoveries. Higher local temperatures in the bed may cause the formation of molten glassy phases which can also reduce the gold recoveries significantly. The impact of roasting conditions in the two inch fluid bed is compared with commercial results obtained in full scale operation.

Jan 1, 2014

By Rénard Chaigneau

Quality during induration Drying ??40% of energy ??Drying velocity = f(1/radius2) ??Size versus risk of condensation ??Flow is important (minimise fines)Oxidation ??IOC Fe2+ typically 0.04% ??Important to minimise Fe2+forLow Temperature Disintegration ??Tight size distribution is key13

May 1, 2011

By N. Valkanov

This paper presents results of an investigation into the connection between minerals liberation management and flotation, responding to lead-zinc concentrator ?Erma reka?, in Bulgaria. Monitoring of a Zn flotation circuit was carried out. The causes for the high silica content in the final Zn concentrate were established. Quartz is present mainly as liberated particles (> 60?80 %) in the fine fractions of the products; therefore the selectivity of the flotation process is not effective. Two approaches were tested to reduce the quartz content of Zn concentrate: froth washing in Zn cleaner flotation and new gangue depressants in the Zn circuit. Experimental results from bench-scale flotation and industrial tests show that it is possibile to reduce the silica content of final Zn concentrate more than 2 times without the need for extensive regrinding. The depression of liberated quartz particles on all operations of Zn circuit using stage depressant addition is the right solution to produce high-grade Zn concentrate that meets the metallurgical requirements.

Aug 1, 2013

By E. H. Dudgeon

In order to make increased use of automation in copper smelting, it is evident that a useful first step .world be the accurate determination of the copper end point in the converter operation. After laboratory tests, the copper end points in a copper converter at Gaspe Copper Mmes Ltd. were determined without reference to melt samples or other observations. The results indicated that the rapid measurement of the S02 level in the gas released from the converter has potential as a new and independent method of determining the copper end point in converter operation.

Jan 1, 1966

By R. Stach, S. Gola, P. Zgrzebski, K. Soroko

"The future of Polish copper mines KGHM Polish Miedz S.A. will be associated with mining at depth. At present, technologically advanced measures are being introduced to minimize the adverse influence of the environmental hazards on people working underground. Polkowice-Sieroszowice mine is the only mine in Poland where mining takes place in copper and salt deposits. On the basis of the current and anticipated methods of ventilation of a selected ore deposits the paper will analynze a number of solutions enabling planned mining of copper ore deposit, while minimizing the impact of natural aerological hazards in working areas. INTRODUCTION The future of copper ore mining, carried out by KGHM Polska Miedz S.A., will be based on mining from continuously greater depths (Butra, 2015). It is forecast that this will be accompanied by an increasing climatic hazard, resulting from an increase in the original temperature of rocks of more than 45°C as well as gas and geodynamic hazards (Soroko, 2015; Andrusikiewicz, 2015). Due to the safety of underground teams, a need arises to develop methods eliminating the adverse impact of the natural hazards, down to a level enabling the mining activity to be carried out on an industrial scale while maintaining favourable economic parameters. Current depths of the copper ore deposit being developed are effectively verifying the technical methods and measures employed to date for eliminating the natural aerological hazards. Amounts of air supplied to mining areas, with lengthy transport routes, are becoming insufficient for miners’ temperature safety, whereas increasing the power of cooling air-conditioning stations for cooling the air undermines the economic legitimacy. However, along with the temperature hazard, a significant problem at the current depths is an increase in gaseous occurrences in the headings’ areas. The concentrations of natural harmful gases found, even with the values below the permissible concentrations, in the case of limited amounts of air and/or low airflow rates, may pose a considerable danger to the workers. The hazards referred to are currently the major factors determining the advance of headings, above all in mining sections, being the outcome of geological structure and depth of lying of a deposit. However, at the current depths of mining minerals from deposits, room-and-pillar mining systems employed also have a decisive impact on the increase in natural aerological hazards."

Jan 1, 2019

By G. J. Arseneau

Mineral resource statements are reported as tonnage and grades. While great care is placed on generating a reliable estimation of grade, the determination of bulk density for resource estimation is often overlooked. Often mineral resource statements are prepared using a simple average value of bulk density. While a simple average estimate of bulk density can be appropriate for some deposit types, an over simplistic estimation of bulk density can result in serious errors in tonnage estimates and consequently to an over or under estimation of metal content. The construction of a reliable bulk density model requires an adequate bulk density database in order to develop a good understanding of the variability of bulk density with grade and geology. A reliable bulk density database is also essential in determining the appropriate modeling technique to minimize the errors in mineral resource statements caused by incorrect bulk density determinations. This paper summarizes bulk density measuring techniques and draws on examples from various deposit types examining the basic principles of bulk density modeling and domain construction for each deposit type. Examples are presented of simple bulk density domains and more complex grade variable bulk density domains with a discussion of best approaches for minimizing errors in density estimation.

Aug 1, 2013

By J. Cayouette, C. Bolduc, P. Blatter

"The LaRonde mill was commissioned in 1988 and began treating ore from the Penna shaft in 2000. The mill has been expanded to accommodate 7,500 t/day, but ramped down to 6,000 t/day since the deep extension began. The process recovers gold, silver, and base metals. In 2008, the Goldex plant began trucking gold-pyrite concentrate to a treatment plant feeding pulp to the LaRonde mill, increasing gold output by 40,000 oz. In 2009, the high-grade Lapa ore processing facilities were annexed to the LaRonde plant, increasing gold output by 120,000 oz. This paper outlines the metallurgical considerations related to the treatment of different ore types.RÉSUMÉ Le concentrateur de la mine LaRonde a été mis en service en 1988 et a commencé à traiter le minerai du puits Penna en 2000. La capacité du concentrateur a augmenté afin de permettre le traitement de 7 500 tonnes de minerai par jour, capacité qui est retombée à 6 000 tonnes par jour (tpj) depuis le début de l’extension en profondeur de la mine. Ce procédé permet de récupérer de l’or, de l’argent et des métaux communs. En 2008, l’usine de traitement Goldex a commencé à transporter par camion du concentré de pyrite et d’or vers une usine de traitement alimentant en pulpe le concentrateur de LaRonde, augmentant ainsi la production d’or de 40 000 onces. En 2009, les installations de traitement du minerai à haute teneur de Lapa ont été annexées à l’usine de traitement de LaRonde, augmentant la production d’or de 120 000 onces. Cet article passe en revue les considérations métallurgiques liées au traitement de différents types de minerai."

Jan 1, 2017

By J. Zhang, T. Oleniuk

It is well-known that Saskatchewan has the world’s richest uranium deposits and advanced processing technologies. Unlike the Saskatchewan deposits, complicated mineralogy is common for other places in the world. Mineralogy dictates the process. Mineral Processing at the Saskatchewan Research Council has been working with the uranium industry worldwide since its inception to develop effective processing technologies to suit the unique mineralogy of each deposit. This paper reviews the research and development of uranium processing technologies in the current major uranium production areas such as Canada, as well as the potential development regions like Argentina and Sweden. Acidic and alkaline leaching processes, as well as by-product recovery technologies are discussed based on mineralogy.

Jan 1, 2020