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By P. Condori

Palabora Mining Copper (PMC) has two autogenous mills that have been in operation since 1976. The mills were originally designed to treat 30 000 t/d of open cast copper ore in a closed circuit with cyclones. As the ore body went deeper the open cast method of mining was changed to block caving, a consequence of this was the dolerite content (hardest barren material) increased significantly, increasing the production rate of pebbles and thus reducing the milling capacity. In order to cope with the increased ore hardness and to increase mill capacity, a second ball milling stage and pebble crushing were incorporated to the circuit. The above actions created new challenges to the circuit operation and bottlenecks in different areas of the milling circuit. This paper reports the holistic work performed on the Palabora autogenous milling circuit including the implementation of a mill constraint control scheme, the implementation of a pebble removal system from the circuit and a new circuit configuration. The achieved plant stability and increment of ore throughput are also reported in this paper.

Jan 1, 2012

By V. A. G. Preto, W. H. White, J. E. Harakal

Potassium-argon age dating performed recently on intrusive rocks from Copper Mountain indicates that the satellite Smelter Lakes and Voigt stocks have radio-metric ages which are indistinguishable from that of the Copper Mountain stock, as determined by Sinclair and White (1967). The complex of intrusive rocks known as the Lost Horse Intrusions also yields essentially the same radiometric age, as do biotite-sulphide-pegmatite veins on Copper Mountain.

Jan 1, 1971

By Roger Davieds

FACT: a company?s profitability (or loss) is directly related to the efficiency and effectiveness of its maintenance operation. Fact: in order to contribute in a positive manner, maintenance must understand what its true purpose is in the organization. It is easy to say our main purpose is to increase: ?equipment uptime ?OEE ?asset life cycle We all understand this; so does management.

May 1, 2010

By V. Vakiloroaya

The paper aims at developing a hybrid solar-assisted air conditioner system for performance enhancement and energy efficiency improvement. To increase sub-cooling of the refrigerant at partial loads, we propose a new discharge bypass line together with an inline solenoid valve, installed after the compressor to regulate the mass flow rate of the refrigerant vapour passing through a hot water storage tank. For control design, a lumped parameter model is first developed to describe the dynamics of the system in an explicit form of input-output relationship. The system has been fully-instrumented to examine its performance under different operation conditions. The system model is then validated by extensive experimental tests. The predictions from the models exhibit a good coincidence with experimental results, judging by an RMS error less than 15%. Based on the obtained dynamic model, a linear quadratic regulator (LQR) is applied to optimize a cost function of the output errors and control efforts. The key challenge is to regulate the refrigerant temperature entering the condenser by controlling the valve opening. The design approach is then tested in a transient simulation tool to predict the system performance in transient conditions. The experimental results obtained from implementation with PLC demonstrate that the proposed system delivers higher system efficiency owing to the higher refrigeration effect in the direct expansion evaporator. Thus, the novel development is promising for improvement of energy efficiency, enhancement of the system performance while fulfilling the cooling demand. Consequently, between 25 and 43% of monthly electricity can be saved on average.

Aug 1, 2013

By R. J. Traill

Introduction Following the discovery of high-grade deposits of pitchblende in the Great Bear Lake area of the Northwest Territories by Mr. Gilbert LaBine in May, 1930, samples were submitted to the Mines Branch for examination and investigation as to suitable methods of treatment (1). The purpose of this paper is to present, briefly, the results of the investigative work conducted on the ores and an outline of the methods developed for the extraction of the radium content and recovery of the by-products. The paper is presented in two parts. Part I gives a review of the history of radium production and of the principal processes used in other countries. Part II describes the work and gives the results of the Mines Branch investigation. Part 1-Radium Production In Other Countries Historical Outline Uranium was discovered in 1789, and more than a century later Madame Curie, while studying the physical properties of this element, observed that the ore of uranium exhibited greater activity than the pure uranium com-pounds she had prepared and traced the cause to the presence of a new element which she named radium. Eventually, research proved radium to be a disintegration product of uranium, and always present in uranium ores.

Jan 1, 1933

By Harry V. Warren

THE Dolly Varden Mine is situated in the Kitsault River valley, eighteen miles from the head of Alice arm, in the Nass River mining division of British Columbia. During the years 1919-21 it was operated by the Taylor Engineering Company, Limited, and produced 1,300,000 oz. silver from about 36,000 tons of ore. The ore was transported by narrow-gauge railway to Alice arm, and shipped to the smelter at Anyox for treatment. During recent years, a small quantity of high-grade ore has been extracted by leasers and shipped to the smelter at Tacoma, Wash. Unfortunately, the bonanza ores which occurred near the surface did nor persist to depth, and two hundred feet below the exposures only rare and unimportant patches of ridi ore have been found. Two opinions exist as to the origin of this rich silver ore. One, advanced by V. Delmage (1, 2), is that the ores are hypogene, and the other, by G. Hanson(3, 4, S), is that the ores are the result of supergene enrichment. It is true that Dolmage first advanced his view that the ores are primary because they appeared to be analagous to Premier ore, which he had studied in detail and which he considered to be primary. The present authors have had access to excellent suites of material from both mines and consider the comparison well taken, the only essential mineralogical difference being the presence at the Premier mine, in addition to the silver minerals, of gold and electrum. Although the arguments put forward by Delmage have, in the opinion of the authors, never been refuted, nevertheless R. P. D. Graham(6), in a reference to the mine published in 1924, describes the ore as of supergene origin, and since then nobody appears to have challenged this statement. Indeed, in 1935, Hanson re-affirmed his earlier conclusion(5).

Jan 1, 1942

By S. Esfahani, M. Barati, Y. Kauwachi

"Heat recovery from slag has gained attention due to its high potential in lowering energy intensity of metal extraction processes. A direct method to recover the thermal energy of slag is to use countercurrent air flow that extracts the heat from falling droplets. Often, the solidified slag is aimed to be used as a substitute for Portland cement, thus high cooling rates are required to form an amorphous slag with sufficiently strong hydaulicity. Rapid cooling however involves using large gas flow rates that in turn lower the thermal efficiency of the process. This article presents a mathematical model that was developed to determine the optimum conditions in the heat recovery process and to investigate the effect of the air flow and granule diameter on the cooling rate of the droplets as well as the thermal efficiency of the heat recovery system. INTRODUCTIONMetallurgical slags are the largest by-product of high temperature materials refining and extraction processes. The total amount of metallurgical slag produced in the year 2008 has been estimated at up to 422 million tonnes containing up to 222 TWh/y (Barati and Esfahani, 2011) of thermal energy. Over the past four decades attempts have been made to recover this substantial amount of energy as heat, electricity, or fuel, while none of the proposed method has been commercialized yet.During slow cooling the slag tends to crystallize the constituents (CaO, SiO2, Al2O3, etc.) into a hard, heavy solid. In the past, over 90% (Bengt, 1983) of the molten waste was discharged onto heaps and allowed to cool slowly, then crushed and used in road construction or land filling or as coarse aggregate for concrete. However, later it was found if cooled rapidly, the slag can be used as a substitute for Portland cement. As a result, processes such as wet granulation were created in which molten slag is fragmented with water, forming amorphous (glassy) phases. Despite its effectiveness in producing a suitable material, heat would not be recovered through this process. Thus, dry granulation was introduced in 1930’s and was developed further in 1970 – 1980’s."

Jan 1, 2012

By A. J. Williams

"IntroductionAN EXCELLENT paper entitled Potash Discoveries in Western Canada (l) was presented to the 1948 Annual Meeting of the C.l.M. by L. Heber Cole, of the Department of Mines and Resources, Ottawa. In the intervening three and a half years, the search for oil and gas in Saskatchewan has added considerably to the information available on the occurrence of potash. It is the purpose of this paper to summarize the additional data. For greater clarity, it may be useful, first, to recapitulate some of the highlights of Mr. Cole's paper.Underlying the western plains of Canada there is a large deposit of sodium chloride, believed to be of early Devonian age. Associated with the sodium chloride are certain potash salts, primarily 'sylvinite,' a mechanical mixture of sodium chloride (halite) and potassium chloride (sylvite) crystals. The potash salts, when present, are usually near the top of the salt formation, though in at least one well they were found near the central part of the deposit. Cole reported on some seven wells in Saskatchewan which had encountered appreciable amounts of potash; these were the Ogema, Radville, Davidson Nos. 1 and 2, Prairie Salt Nos. 1 and 2, and Verbata wells. Depth of potash from surface ranged from 7,653 feet in the Radville well to a minimum of 3,466 feet in the Verbata well. Such depths do not compare favourably with those at which the potash is found in mines in the United States, France, and Germany, where about 1,000 feet is the average. The greatest concentration of sylvite encountered was in the Verbata well, where a bed 11 feet thick carried the equivalent of 21.64 per cent K20."

Jan 1, 1952

By Zihe Ren, Edouard Asselin, Marcus Tomlinson, Tianbi Zhang, Jing Liu

"Raman spectroscopy is used to quantify the extent of disorder in the carbonaceous matter associated with preg-robbing ores. Previous studies of Goldstrike ores showed that the height and width of the peaks for the “D” (disordered) and “G” (graphite) bands, the so-called “Raman ratio” had a strong correlation to the preg-robbing value (PRV) measured for various ore samples. A brief literature review on Raman spectroscopy as it applies to preg-robbing ores is presented. Further, recent studies, presented here, have shown no correlation between the Raman ratio and the PRV for a wide variety of ores. This suggests that the extent of organic carbon crystal disorder is not the main factor in determining preg-robbing characteristics.INTRODUCTION Valuable base metals, such as nickel, cobalt, molybdenum, vanadium and tungsten, are used in a wide range of important technological applications. The demand for many of these metals has increased significantly over the last few decades, driven especially by economic expansion in Asia generally and China in particular. This has led in turn to a large growth in the output of mines in order to satisfy this increasing demand, as shown by the data in Table 1 (USGS, 1994, 2014). These data reflect an even longer trend of growth of these metals, with nickel, for example, showing an average rate of 5.3% per year from 1980 until 2015 (International Nickel Study Group, 2017). This rapid and sustained rate of growth means that annual mine outputs for nickel, tungsten, molybdenum and vanadium have had to double roughly every 11 to 14 years, whilst cobalt mine output has had to double roughly every 7 years, over the period from 1994 until 2014. With the average working life of a nickel mine being between 17 and 22 years (Statista, 2017), this means that from the time a nickel mine opens until it closes, the industry needs to find the equivalent of another three or four mines of a similar output to satisfy this relentless growth in demand for the metal."

Jan 1, 2017

By Y. M. Zhao, C. L. Duan, Z. F. Luo, X. L. Yang

"Fine coal beneficiation in a dry way is considerably imperative for the efficient utilization and conservation of coal resource in drought regions, especially for China. In this study, a continuous vibrated gas-fluidized bed separator was established and developed based on the results of laboratory batch separation results. The fluidization behavior and the effects of several main parameters including superficial air velocity, vibrational parameters, bed height and separating time were systematically investigated. The results showed that the bed expansion increased linearly with the superficial air velocity and theoretically, higher bed expansion benefited the hindered settling process of fine coal particles. However, larger superficial air velocity would induce intense fluctuation in bed surface and a poor performance of density segregation. The conveying velocity of particles was mainly determined by the vibration angle and a predicted model was established by the nonlinear regression analysis. A theoretical model of bed height distribution was established and this model fitted the measured value well. The beneficiation performance of this separator was evaluated by separating -3+1 mm Wuhai fine coal. The results showed that the probable error, E, is 0.225, indicating a continuous vibrated gas-fluidized bed separator could achieve a satisfactory performance.INTRODUCTIONFine coal beneficiation in a dry way is considerably imperative for the efficient utilization and conservation of coal resource in drought regions, especially for China. Meanwhile, it is also conducive to environment protect and low-carbon, green development of coal sector. In recent years, the increasing academic interest in the field of fine coal dry beneficiation has been aroused in most of big coal countries. In summary, recent processes of fine coal dry beneficiation are, according to their processing principles, mainly classified into two categories: dense medium beneficiation (Dong et al., 2015; Fan, Chen, Zhao, & Luo, 2001; Luo et al., 2008; Macpherson, Iveson, & Galvin, 2011) and improved pneumatic beneficiation (Patil & Parekh, 2011; Yang, Zhao, Luo, Song, & Chen, 2013; Yang, Zhao, Luo, Song, Duan, et al., 2013; Zhao, Zhao, Chen, & Luo, 2015). The former deploys artificial dense medium, such as magnetite powder and fine sand, to form a stable gas-solid suspension with certain density under the function of the upward fluidizing air flow and in some case, the external force field like vibration and magnetic field. Generally, it is believed that the process of air dense medium fluidized bed (ADMFB) is suitable for separation of coarse coal (-50+6 mm) and can't obtain a satisfactory result for fine coal separation (Luo, Chen, & Zhao, 2002; Luo et al., 2008). However, some recent laboratory efforts (Patil & Parekh, 2011; Zhang et al., 2014) attempt to find an improved performance for fine coal beneficiation in ADMFB with some modifications. The point of these works is to use a comparatively shallow bed and finer magnetite powder with appropriate size distribution. It is known that fluidization of finer magnetite powder is prone to arouse adverse fluidization properties such as channeling and slugging. Thus, the external force is introduced to an ADMFB in order to improve the fluidization quality of a magnetite powder bed. Some recent literature on air dense medium magnetically stabilized fluidized beds (Fan et al., 2001; Luo, Zhao, Chen, Fan, & Tao, 2002; Song, Zhao, Luo, & Tang, 2012), air dense medium vibrated fluidized beds (Luo et al., 2008) and Reflux Classifier (Macpherson, Iveson, & Galvin, 2010) reports that the separation efficiency, namely the probably error E value, of dense medium separation of fine coal ranges from 0.066 to 0.07, indicating a good separation performance. But, the main unresolved problems of dense medium beneficiation are located in the processes of product purification and medium recovery and are urgent to be solved befor"

Jan 1, 2016

By Lawrence Melis

Fission Uranium Corp.’s Triple R Uranium Deposit at its Patterson Lake South Project is located in northwest Saskatchewan in Canada’s Athabasca Basin. As part of pre-feasibility studies for the project a detailed metallurgical test program was completed to provide process design criteria. The testwork program encompassed preparation and analysis of test composites, comminution testing, uranium acid leaching, liquid-solid separation, solvent extraction of uranium, precipitation of uranium yellowcake products, tailings and effluent treatment, tailings physical and chemical characterization, and environmental testing of prepared tailings, as well as investigations of gold and silver recovery from the mineralization. The paper provides mineralogical information, testwork methodologies and test results which were used to arrive at process design criteria and the selection of the process flowsheet for the project.

Jan 1, 2020

By S. Mathieu, R. Mennillod-Blondin, P. Cousin, N. Valle, H. Bouzahzah, P. Marion

The gold deposit of the Lapa mine has a complex mineralogical gold state with coarse and fine native gold, aurostibite and submicroscopic gold within arsenopyrite. A specific mineralogical characterization of the refractory fraction was conducted combining various techniques such as optical microscopy, electron microscopy, electron microprobe and secondary ion mass spectrometry. In parallel, the mineral processing behaviour and the recovery of the refractory gold were studied by pressure oxidation and cyanide leaching. This paper presents the mineralogical methodology developed to characterize the refractory gold distribution within arsenopyrite. These results are presented and interpreted in order to plot gold recovery versus sulphide oxidation. The comparison of the metallurgical behaviour yields predicted from the mineralogical data and the one calculated from leaching tests shows a good agreement and allows mineralogical explanations of the gold metallurgical behaviour.

Jan 1, 2011

By Carlos Alberto Spier

The Águas Claras and Pico mines are two world-class, iron-ore mines hosted within Lower- Proterozoic banded iron-formations (locally known as itabirites) of the Minas Supergroup located in the Quadrilátero Ferrífero District, Minas Gerais, Brazil. The Águas Claras orebody consists of a 2,500 m long roughly tabular-shaped lens hosted within the dolomitic itabirite of the Cauê Formation. Dolomitic itabirite is the protore of the soft high-grade iron ore, which is the main ore type of the Águas Claras orebody, and represents more than 85% of the 284 Mt mined since 1973. Hematite is the main constituent of the iron ores. It occurs as martite, granular hematite and, locally, as specularite. Magnetite appears subordinately as relicts within martite and hematite crystals. Gangue minerals are very rare. These consist of dolomite, chlorite, talc and apatite and are especially common close to the contact with the protore. This virtual absence of gangue minerals is reflected in the chemistry of ores which are characterized by very high Fe contents (an average of 68.2% Fe). The Pico orebody is a continuous ~3,000 m long body of lenticular shape hosted within quartz itabirite, which is the protore of the soft high- and low-grade ores at the Pico mine. The soft high-grade ores, together with the low-grade ores, called iron-rich itabirite, are the main types of ores at the Pico mine, respectively representing approximately 51 % and 29 % of the reserves within the pit. The iron oxide mineralogy is the same as that of the Águas Claras mine, but in different proportions. Gangue minerals are very rare in the high-grade ores, but are slightly more common in the iron-rich itabirite. Quartz is the dominant gangue mineral, and is found with minor quantities of chlorite. The chemistry of the high-grade ores is characterized by high Fe contents (an average of 67.0 %) and low P, Al2O3, and SiO2 which are concentrated in the fines. Iron rich itabirites average 58.6% Fe and 13.5% SiO2.

May 1, 2003

By L. R. Wilkinson, W. J. Howarth, G. J. Wenk

Over a period of three years, a cooperative program in Australia has resulted in the development of radioisotope immersion probes for the on-stream analysis of mineral slurries. Two basic probe types are now available on a commercial basis - fluorescence and absorption probes - and within each type there are a number of variations so that optimum sensitivities can be obtained for elements with atomic number greater than titanium (22), thus covering most metals of interest to modern metallurgy.

Jan 1, 1973

By Henry C. Knight

A number of improvements in the techniques of budgetary control have been developed in the 1970's. The most significant of these is zero-base budgeting. This procedure is a marked improvement, because it overcomes some of the key weaknesses inherent in most traditional approaches to budgeting. It incorporates techniques and disciplines which improve the quality of both the budgeting effort itself and the documents that most senior managers will need to evaluate. The end result is a budget that establishes and improves cost effectiveness. This budget is based on resource allocations using cost-benefit criteria and on a system of prioritization for making funding choices. Zero-base budgeting is applied only to costs and expenses that are not conducive to control using industrial engineered standards. Therefore, the benefits attributed to zero-base budgeting will only hold true for administrative, selling, exploration, safety, fire protection and overhead, and other indirect types of costs and expenses. It is in this context that the question of its attractiveness for the mining industry is dealt with.

Jan 1, 1978

By L. M. Pidgeon

Introduction The production of magnesium by direct reduction of the oxide has far passed the experimental stage and was responsible for 30 per cent of the recent wartime production of 246,000 tons per annum. This paper describes the small-scale experiments which culminated in a number of the wartime plants. The paper traces the author's early experiments on various direct reduction reactions leading to his choice of the ferrosilicon reduction of dolomite and the realization that this reaction would proceed at a satisfactory rate at temperatures obtainable in metal apparatus. MgO has a standard heat of formation of 146,100 cal. and is therefore one of the most difficult oxides to reduce. However, if advantage is taken of the relative volatility of magnesium metal, thermally unfavourable reactions may be utilized. In reaction MgO + X = XO+ Mg . . . . . . . . . . . . . (1) the removal of Mg as a gas at high temperatures displaces the equilibrium to the right in the face of the unfavourable thermo-chemistry which is inevitable with any X other than calcium metal. If X is carbon, not only is the reaction highly endothermic, but CO is gaseous. A temperature of l,864°C. is required to produce a pressure of one atmosphere of Mg. Between l,900°C. and perhaps 400°C., the back reaction takes place readily and special shock cooling devices are required to recover magnesium from the gaseous mixture. This reaction does not lend itself to small-scale experiments and was not examined by the author. If, in reaction, carbon is replaced by a relatively pan-volatile metal, the oxide of which is also non-volatile and possesses a fairly high heat of formation, a reduction reaction is offered which is free from the difficulties associated with carbon. The typical case of silicon will serve as an example: 2MgO + Si = SiO2 + 2Mg (g) . . . . . . . . . . . . . . . . . . . . . . (2) At temperatures above l,000°C., a positive pressure of magnesium will exist over the system. Removal of the magnesium vapour will displace the reaction to the right in the face .of an unfavourable thermal balance. Since magnesium is the only volatile component at this temperature, it may be evolved and condensed, using attractively simple distillation technique.

Jan 1, 1946

By M. E. Holter

"Five main lignite seams occur in the Tertiary Ravenscrag Formation in the Eastevan area, at depths of 100 feet or less. They are named, in ascending order: the Boundary, Estevan, Souris, Roche Percee and Short Creek seams. A total sequence of approximately 250 feet is represented by the coal beds and interstratified clays, silts and sands. Strata dip to the southeast at 25 feet per mile or less and trike northeast. Large areas underlain by coal seams at shallow depths are delineated. Reserve calculations are dependent on detailed information on seam thicknesses and feasible stripmining depths. The stratigraphically higher seams are thinner on the average than lower seams and this, together with the increase in elastic size fractions in higher strata, suggests a retreat of a Tertiary marine margin to the south during the closing depositional history of coal seams and associated strata."

Jan 1, 1972

By G. F. Doggett

In describing accounting methods at Lake Shore Mines, it is the intention of the writer to limit the discussion to the principal features of the system used in securing cost figures and other statistics. The subject can be conveniently treated under the following divisions: (1) Time-keeping and Labour Distribution (2) Supplies: Handling and Distribution (3) Method of Assembling Data for Cost Purposes (4) Details of Operating Costs Time-Keeping and Labour Distribution After a new employee has gone through the routine of being 'hired on', he is assigned an employment number corresponding with the group applying to his occupation. This is for identification purposes in the plant and time office. He is also given an individual serial number, the use of which will be refer-red to later. On entering and leaving the plant, each employee passes through the clock room adjoining the time office, where he registers the time in and out on time recorders, on the clock card (Figure 1) bearing his name and number. It is the duty each morning of the time clerk to extend the hours worked by each employee, as indicated by the clock for the previous day, and at the end of the half-month period the total hours are multiplied by the rate and entered in the space provided for total wages at the bottom of the card.

Jan 1, 1935

By A. Bois-Brochu, G. Morin, G. Marin, M. C. Parr, J. Carignan

The presence of an alpha case on titanium parts produced by investment casting is problematic and has to be eliminated. The traditional techniques for the evaluation of its thickness are metallographic measurements and micro-hardness profiles. To obtain a better understanding of how the alpha case is formed with the underlying objective of limiting its depth, the present study proposes to characterize the microstructure and the chemical composition of the alpha case. Electron microprobe analyzer (EMPA) linescans were used to quantify the oxygen and substitutional elements that come from the mould and promote the alpha case formation. The chemical profiles were correlated with metallographic and microhardness measurements. For microstructure, optical microscopy (etched and polarized light analysis) was used. For phase analysis, samples were mechanically polished step by step and analysed using X-ray diffraction and optical microscopy. Furthermore, surface analysis techniques such as XPS and Auger Microscopy were evaluated but results were found to be inconclusive because the formation of the oxide layer was faster than its ablation and the matrix could thus not be analysed. The alpha case was observed on a Ti-6Al-4V step block casting.

Jan 1, 2014

By H. Aaltonen, T. G. Robinson, M. Morimitsu

"The energy required to plate pure zinc can be the most significant operating cost for an operator in the production of electrolytic zinc. This paper reports on developments on low energy Outotec coated titanium anode process technology with fully amorphous coatings, MSA®, and its application to brownfield zinc electrowinning operations around the world. This technology aims to reduce the operating cost and increase productivity for zinc producers.INTRODUCTIONZinc electrowinning is an energy-intensive process using more than 3,000 kWh/t of electric energy [1-4], and the reduction of the energy consumption is one of the key issues. The high energy consumption is due to a high cell voltage during electrolysis, which is mainly caused by a high overpotential of oxygen evolution reaction on lead alloy anodes which have been widely used in commercial zinc electrowinning processes. The overpotential of oxygen evolution is 0.6 V or more and which is approximately 4 times higher on average than that of the cathodic reaction (zinc deposition) [3,4]. Therefore, the reduction of oxygen overpotential is significant to reduce the electric energy consumption, and this will become more significant with increasing demand in metal production and rising energy costs.Oxide coated titanium anodes have been widely investigated for the oxygen evolution anodes in order to replace the lead alloy anodes [5-9], because it is known that the oxygen overpotential strongly depends on the material and structure of the anode. The most typical example of such anodes is an IrO2-Ta2O5 coated titanium anode, which is usually prepared at thermal decomposition of a precursor solution containing metal salts at 450 oC or more and obtained mixed oxide coating consists of crystalline IrO2 and amorphous Ta2O5. On the other hand, one of the authors of this paper, Professor Morimitsu, Doshisha University in Japan, has developed a novel oxide coated titanium anode, MSA® [10-25]. The most specialized point of MSA® is that the catalytic coatings are prepared at low thermal decomposition temperature and amorphous IrO2 or RuO2 is contained as the components in the coatings. Such amorphous coatings have high catalytic activity for oxygen evolution compared to lead alloy or crystalline coatings. Outotec acquired the international specialized MSA® patent licensing rights from Doshisha University and has produced and commercialized the amorphous oxide coated titanium anodes. These anodes have already been utilized mainly in copper electrowinning plants worldwide and have demonstrated a significant voltage reduction, a cost-efficiency, and a long lifetime. This novel technology is also effective to zinc electrowinning process, thus this paper presents the characterization and performance of amorphous IrO2-Ta2O5 coated titanium anodes and amorphous RuO2-Ta2O5 coated titanium anodes for oxygen evolution in zinc electrowinning."

Jan 1, 2016