Search Documents

By J Zhang, L Klemettinen, A Jokilaakso, J Biswas, J Partinen, H O’Brien, A Klemettinen

Waste lithium-ion batteries (LIBs) are important secondary sources of many valuable materials, including Critical Raw Materials (CRMs) defined by the European Union (EU): lithium, cobalt, manganese, and graphite. Additionally, LIBs typically contain nickel and copper, which are classified as Strategic Raw Materials for EU since 2023. In recent years, great effort has been made to develop efficient recycling processes for waste LIBs. Pyrometallurgical processes have been essential in industrial production of metals for many decades. These technologies are relatively mature, with high adaptability for different raw materials. Pyrometallurgical treatment in LIB recycling typically involves the use of smelting processes, in which waste batteries are heated above their melting points and metals are separated through a reduction reaction in the liquid phase. Through this recycling route, cobalt, copper, and nickel can be efficiently recovered in the form of a metal alloy, whereas lithium and manganese are lost in the slag phase. The goal of this work was to increase the recoveries of valuable battery metals through a combination of hydro- and pyrometallurgical unit operations. First, industrial Li-ion battery scrap underwent a selective sulfation roasting stage, where the aim was to transform LiCoO2 and Mn-oxides into Li, Co and Mn sulfates. After roasting, the battery scrap was leached in distilled water with a solid to liquid ratio of 100 g/L at 60°C and recovered 95 per cent of Li, 61 per cent of Mn and 35 per cent of Co. After leaching, the solid leach residue was mixed with industrial Ni-slag and biochar, followed by reduction at 1350°C in argon atmosphere. The high-temperature smelting experiments were conducted as a function of time (5–60 mins) to investigate the reduction behaviour of battery metals. The results show that Co and Ni from the slag and leach residue can be efficiently recovered in the slag cleaning stage.

Jun 19, 2024

By A D. Strand

The Coeur dÆAlene mining district in northern Idaho, USA is the second largest producer of silver in the world. The Proterozoic Revett Formation hosts most of the mesothermal Ag-Pb-Zn vein ore in the district; it consists of informally designated lower, middle, and upper members. All three members show up to an order of magnitude of southward thickening across the regionally significant Osburn fault. Changes in thickness of the Revett Formation across the Osburn fault reflect a major, down-to-the-south, crustal-scale fault that:was active during sedimentation, was periodically reactivated during the structural and metallogenic history of the district, and likely provided first-order control over regional fluid flow during mineralization events. Where vein structures intersect favourable strata, they produce rich ore; where vein structures cross unfavourable strata, they are poorly mineralised or barren. The most favourable host rock in the district is quartzite, which accounts for the large production from the quartzite-rich Revett Formation.The district has five main types of hydrothermal alteration:feldspar destruction, hydrothermal bleaching, carbonatisation, sulfidation, and silicification. Feldspar destruction is the most extensive and pervasive type of alteration, involving the district-wide absence of feldspar from Belt Supergroup rocks. Hydrothermal bleaching results from the destruction of hematite; it forms alteration envelopes that extend for tens to hundreds of metres into the wall rocks around many of the mineralised veins. Siderite alteration is most diagnostic of mineralisation, forming alteration envelopes that extend for tens to hundreds of metres into the wall rocks around all mineralised veins. Fine-grained arsenopyrite and/or fine-grained pyrite commonly form alteration zones adjacent to high-grade ore shoots that extend for metres to tens of metres into the wall rocks. Widespread silicification is most easily recognised by the presence of numerous quartz veins.

Jan 1, 2002

By D L. Decker, G C. Miller, C Papelis

Arsenic, often associated with precious metals ore deposits, is a major contaminant released during large-scale gold mining. Because of the complex oxidation/reduction and sorption behaviour of As, prediction of the long-term mobility of As in pit lakes is uncertain. The behaviour of As in pit lakes is investigated in this paper by conducting a series of laboratory experiments where As is allowed to adsorb onto pit lakes sediments. Experiments were conducted over a range of pH with both As(III) and As(V) allowed to adsorb onto sediments collected from existing pit lakes found in the three main orebody types in Nevada, USA; porphyry copper, quartz-adularia gold, and Carlin Trend type gold deposits. Results from adsorption experiments show that As(V) and As(III) adsorption is strongly pH dependent with higher uptake at pH 5 and lower uptake at pH 9 for As(V) and higher uptake at pH 9 and lower uptake at pH 5 for As(III). This behaviour, as expected for oxyanions, has been described previously for agricultural soils, iron oxides, and Carlin Trend heap materials. Maximum adsorption of As(V) for the Carlin Trend type gold sediment was 3.0 g/kg at pH 5, 2.0 g/kg for the quartz-adularia sediment, and 0.9 g/kg for the copper porphyry sediment. Maximum adsorption of As(III) for Carlin Trend type gold sediment was 2.5 g/kg at pH 9, 2.2 g/kg for the quartz-adularia sediment, and 2.1 for the copper porphyry sediment. Adsorption isotherms are non-linear and show Freundlich isotherm behaviour. Variations in sorption between the different pit lake sediments under similar conditions can be explained by differences in the elemental composition of the sediment. Most rock forming elements from XRF analysis are similar in quantity except for Fe. The Fe content is highest in the Carlin Trend type gold deposit sediments and lowest in porphyry copper deposit sediments and is the third most abundant element in all three sediments. The Fe content of the sediments correlates well with the amount of As sorption seen in the laboratory experiments.

Jan 1, 2003

By Akerkar D. D, Dey M. L, Mathur S. B, Chowdhury S. K R

The extraction of gold and silver from chalcopyrite concentrates has been investigated. In view of the recent interest in non-cyanide leachants for gold and silver, one such alternative reagent, namely thiourea, has been employed in the present work. Precious metal leaching was attempted from received copper concentrates as well as pre-oxidised concentrates. Pre-oxidation of the concentrates was carried out by three different methods, namely roasting, pressure oxidation and biological oxidation. After pre-oxidation and leaching of the base metals, the leach residues were subjected to further leaching for precious metal extraction. The results obtained on the extraction of gold and silver from received concentrates as well as pre-oxidised concentrates are presented and the effectiveness of the three pre-oxidation routes employed is compared.

Jan 1, 1992

By J Ferreira

To speed up multivariate geostatistical simulation it is common to transform the set of attributes into spatially uncorrelated factors that can be simulated independently. One decorrelation method is the method of minimum/maximum autocorrelation factors (MAF), where a two structure linear model of coregionalisation is assumed. The transformation decorrelates the theoretical model exactly, but the actual data are only approximately decorrelated. The MAF transformation can therefore be seen as a special case of a non-orthogonal approximate diagonaliser of a set of symmetric matrices. A more general approach for approximate joint diagonalisation (AJD) has been developed in the context of blind source separation. For these AJD algorithms no assumptions are made beyond symmetry of the individual matrices and so they can be applied to a family of experimental semivariogram matrices. In their application there are no restrictions on the number of structures in the linear model of coregionalisation (LMC) thus removing one of the conditions placed on the subsequent modelling of the spatial structure of the factors. In this paper the general background for the U-WEDGE AJD method is presented. It is shown that the U-WEDGE method achieves better spatial decorrelation than the MAF method. The factors derived from U-WEDGE are simulated using conditional turning bands simulation and then backtransformed to attribute space.

Sep 26, 2011

By S Paciornik, G Schinazi, M H. de Pinho Maur-cio, M B. Vieira, O da Fonseca Martins Gomes, D T. Wagner

Vale (previously CVRD û Companhia Vale do Rio Doce) evaluates the microstructure of sinters in order to understand their characteristics and behaviour in the agglomeration process, and the correlation with conventional quality parameters. Efforts on image analysis development are in progress between Vale and PUC-Rio in order to improve both the qualitative and quantitative evaluation of a representative portion of material. In the present work, digital microscopy techniques were developed allowing this kind of assessment. Employing a motorised and computer controlled optical microscope, low magnification mosaic images covering complete sinter samples were automatically obtained. The mosaics provide a powerful qualitative overview of the whole sample while allowing low resolution quantitative evaluation of the major phases. In addition, quantitative results for phase fractions were compared for the same sample regions at three magnifications (5x, 10x and 20x objective lenses). A single field (1 x 1) at the lowest magnification corresponds to mosaics of 2 x 2 and 4 x 4 images at the higher magnifications. The automated system allows perfect registration between the mosaics and the single image. Changes in phase discrimination were evaluated as a function of optical resolution, and phase fractions obtained by interactive segmentation of the image histograms were compared. While finer dark phases, eg silicates, were only visible with the best optical resolution, coarser phases such as haematite and pores were measured at all resolutions. For haematite, magnetite, ferrite and pores, the largest relative error in area fraction, between the images obtained with the 5x and 20x lenses, was 12 per cent. The results for silicate were less accurate with a relative error of 44 per cent. The results indicate that digital microscopy provides a flexible method for qualitative and quantitative evaluation of these materials.

Jan 1, 2008

By P K. Wong, D A. F Oliveira, F M. Azad

In situations where foundation piles are located in proximity to existing or future tunnels, it is typical for the tunnel owner to require that sleeving of the piles be carried out to at least the invert of the tunnels to minimise any load transfer to the tunnel lining. In competent rock, this practice may be sometimes unnecessary, thus uneconomical. This paper presents an assessment of the effect of pile loading from one of the multi-storey buildings at Barangaroo South in Sydney on the adjacent future Sydney Metro tunnels. It was originally required by Transport for NSW (TfNSW) that the piles be sleeved below the tunnel invert level; however, the building developer wanted to reduce the pile sleeving depth to achieve a more economical solution due to the large number of load transfer piles being required for the project. To assess this feasibility, a full 3D commercial numerical code, FLAC3D, was used to carry out this complex soil-structure interaction analyses. Based on these assessments, it was demonstrated successfully to the TfNSW that the pile sleeving may be terminated at 2 m above the tunnel invert level. For this arrangement, the investigations found that the loading on the piles should have negligible adverse impact on the tunnel lining design. As a result of such an assessment, the proposed pile sleeving level was approved by TfNSW, thus offering an economical foundation solution for the project.CITATION:Azad, F M, Oliveira, D A F and Wong, P K, 2014. The impact of pile loading on adjacent metro tunnels – Barangaroo South, Australia, in Proceedings 15th Australasian Tunnelling Conference 2014 , pp 355–360 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 17, 2014

By H Benzer, N A. Aydogan

It is well known that the high pressure grinding rolls (HPGR) can only be operated efficiently under choke feeding conditions in which a material bed is built up between the rollers to ensure interparticle breakage. By increasing the fines amount in the material bed up to a specific level with the recycling load, a uniform material bed is created and higher pressure gradient along the roller width is obtained which results in compact flakes including more fines. Extensive test work has been carried out with an industrial HPGR unit grinding cement clinker in a cement plant in Turkey. During the test work the recycling load of the circuit was changed to achieve different ratios to the fresh feed rate in order to identify the effect of the recycling load on the circuit performance. Six different tests were performed with the circuit at steady state. For each test, samples were collected from HPGR fresh feed and discharge, and total feed, then the particle size distributions of the samples were determined and mass balances around the circuit were calculated. The conclusion was that the reduction ratio of the HPGR increased with increase in recycling load. The flake densities showed the same trend with more compacted flakes being produced for higher recycling loads.

Jan 1, 2009

By Collins DN, Hollick CT

Conventional processing of heavy mineral deposits containing radioactive rare earth minerals such as monazite and xenotime may cause industrial hygiene problems through atmospheric dust and contamination of product concentrates. An alternative procedure has been developed in which such minerals are removed from bulk heavy mineral concentrates by flotation with little loss of other economic minerals. With fine ores, recoveries of over 95% have been achieved and with coarse ores over 80%,in both cases at high grade. Several flotation regimes have proven effective. The potential for generation of radioactive dust or product contamination is subsequent processing -is correspondingly reduced.

Jan 1, 1990

By Nag D. K

King Island Scheelite is a wholely owned subsidiary of Peko-Wallsend Ltd. The company works two underground mines near the southern end of King Island at the western approach to lass Strait, 240 km south of Melbourne. (See ^igure 1).

Jan 1, 1981

By D J. Williams, S Islam

Fine-grained coal tailings slurry undergoes only limited settling and self-weight consolidation, and tends to remain slurry-like and unsuitable for conventional laboratory consolidation testing. In addition, constant rate of loading consolidation testing is more representative of the continuous disposal of tailings slurry into a tailings storage facility (TSF) than conventional step loading. The laboratory consolidation testing of coal tailings slurry under a constant rate of loading has been carried out in a purpose-built, large-scale, slurry consolidometer, instrumented with load cells and pore water pressure (PWP) transducers. In the slurry consolidometer, the rate of loading may be varied to represent the actual rate of rise of the tailings in the TSF. A slow rate of loading increases the test duration, while too fast a rate of loading may build up very high excess PWP, without achieving significant consolidation. For the particular fine-grained coal tailings slurry tested, the rate of loading in the slurry consolidometer is varied to access its effect on the development and dissipation of excess PWP. The resulting consolidation parameters are evaluated and explained using the recorded settlement and PWP data.CITATION:Islam, S and Williams, D J, 2018. Optimisation of constant rate of loading slurry consolidometer testing of fine-grained coal tailings, in Proceedings Mine Waste and Tailings Stewardship Conference 2018, pp 72–80 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 23, 2018

By Bowra N

Working capital is best described as money that must be supplied from a company's treasury to buy inventories for raw materials and finished products and to provide credit to customers who have not yet paid for delivered products. Working Capital requirements for resource projects are to a large extent, dependent on specific characteristics of the projects concerned. Important variables are the nature of the project and speed with which sales can be realised. The project's location is also important as this will influence inventory levels. Working capital requirements have a time profile, the present value of which can represent a significant portion of a projects overall capital needs. A significant component of a project's working capital is not readily recoverable or able to be reassigned should the project fail or be deferred.

Jan 1, 1986

By T Raynlyn, S Hapugoda, V Nunna

The predominant phase in most Marra Mamba, channel iron deposits and detrital iron ore deposits is goethite. Goethite abundant iron ore fines tend to have complex mineralogical associations and fine dissemination of gangue material. These ores are typically challenging to process using conventional beneficiation methods. With declining ore grades, there is a need to develop new processing routes for low-grade goethitic ores/fines.Comparative process amenability studies were carried out using two different processing options to recover iron with low alumina and silica content from a low-grade goethite-abundant iron ore fines (-2 mm) sample from the Pilbara region of Western Australia. The first option involved dehydroxylation at 350°C and 400°C, followed by grinding dehydroxylated samples to 100 per cent passing 106 µm and magnetic separation. The second option was processing raw sample by gravity separation using a Floatex density separator. The performances of the two processes are discussed in terms of the iron grade-recovery responses, and an optimal processing route is proposed based on the findings from these tests.CITATION:Nunna, V, Hapugoda, S and Raynlyn, T, 2015. Process amenability studies on goethite-abundant iron ore fines, in Proceedings Iron Ore 2015, pp 165–174 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 13, 2015

By BTrubT M

In the roast-leach-electrolysis process for the production of zinc, iron contained in zinc concentrates is converted to zinc ferrite during roasting. At Canadian Electrolytic Zinc (CEZinc), the Outokumpu Conversion process is used to simultaneously leach zinc ferrite and precipitate the iron as jarosite. These simultaneous reactions, while providing good process stability, require a compromise between optimum conditions for maximum zinc extraction and efficient iron precipitation. An improved conversion process has been identified which can achieve >99 per cent zinc extraction and more efficient jarosite precipitation to residual iron concentrations of

Jan 1, 1993

By M J. Saynor, J B. C Lowry

The Ranger Uranium Mine is located in the wet-dry monsoonal tropics approximately 250 km east of Darwin in the Northern Territory of Australia (Figure 1). Mining of open-cut ore bodies commenced in 1980 (Pit 1) and ceased in 2012 (Pit 3) and milling and production are scheduled to cease by 2021. At the conclusion of mining and milling operations, mine tailings will be returned to the mined out pits 1 and 3, which must then be physically isolated from the environment for at least 10,000 years (Australian Government 1999). The final landform also needs to have sufficient mitigation measures in place to ensure that areas downstream are not impacted by erosion products from the mine site. The proposed post-mining rehabilitated landform will cover approximately 847 hectares (8.5 km2) which represents an area that has the potential to supply sediment to catchments and streams downstream. One method of reducing runoff and associated sediment is the construction of rip lines along the contour to slow down the runoff velocity and to also trap fine sediment and nutrients in the depressions to assist vegetation growth.CITATION:Saynor, M J and Lowry, J B C, 2018. The impact of rip lines on erosion at the Ranger Mine Site, in Proceedings Life-of-Mine 2018, pp 150–154 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 25, 2018

By H Bao, M Nehring, M Kizil, P Knights

The mining sector, a notably energy-intensive industry worldwide, is a major consumer of fossil fuels, leading to significant carbon emissions globally. The move towards electrification, coupled with advancements in battery technology, has redirected focus from traditional diesel-powered solutions to battery-powered alternatives. This paper introduces a novel mining haulage system, termed the Battery Trolley system, and examines its theoretical foundations, configurations, and operational processes. It offers a comprehensive analysis of the system’s characteristics and limitations. Through a hypothetical road simulation, the study analyses various battery mining trucks, calculating energy consumption based on force parameters and tailoring battery sizes to contemporary materials and technology. When assessing various battery truck alternatives—considering aspects such as battery size, effective payload, duty cycle, energy efficiency, productivity, and single-shift production—a range of performance outcomes and characters become apparent within the mining context. The findings indicate that Battery Trolley configurations, requiring smaller battery capacities, entail lesser compromises on effective payload. Consequently, these configurations achieve a higher duty cycle, reduced energy consumption per tonne, heightened productivity, and enhanced singleshift production capabilities compared to Battery-only alternatives. The comparative analysis of Battery Trolley with stationary charging (BT-S) and Battery Trolley – dynamic charging (BT-D) underlines that battery Trolley systems are capable of overcoming the challenges associated with battery size, thus successfully fulfilling the production demands of large truck applications in mining. This positions Battery Trolley systems as a more advantageous option for the decarbonisation of mining fleets, underscoring their potential in contributing to the sector’s sustainable evolution.

Sep 1, 2024

By C M. Côte, S Worden, K Svobodova

Mines in Queensland are transitioning to the progressive rehabilitation and closure plan (PRCP) framework. Mine operators are required to select and justify appropriate and viable post-mining land uses (PMLUs) following consideration of the surrounding landscape, community views and the objectives of local and regional planning strategies. The new approach offers opportunities for considering innovative PMLU options and collaborative use of post-closure mine assets, such as infrastructure (power, road/rail, buildings), dams and residual voids. Consideration of regional planning strategies will require a shift in thinking as mine closure is regulated and planned on an individual site basis and selection of PMLUs are commonly considered from this perspective. Planning at regional rather than site-specific scale offers strategic advantages, including the ability to align PMLU selection with the regional context and stakeholder aspirations (which could foster sustainable outcomes); address cumulative environmental and socio-economic impacts; consider options that are only viable at scale (ie across larger geographic areas); establish more extensive and connected ecological habitat corridors; reinstate larger expanses of functional agricultural land; and optimise regional resources (Hattingh, Williams and Corder, 2019). This paper presents the findings from a multidisciplinary project that identified PMLU options within Queensland’s four mining regions: the North-west Minerals Province, North Queensland, Bowen Basin and Clarence-Moreton and Surat Basin (Figure 1). To enable spatial analysis at the appropriate scale and to accommodate geographic diversity, North Queensland was divided into three geographical ‘focus areas’ – Weipa, Charters Towers and Tablelands. Delineation of the areas captured most of the mines within the wider region as well as regional characteristics and features.

Aug 2, 2023

By S Doudle

The Iluka Resources Ltd Jacinth-Ambrosia heavy mineral sand mine (South Australia) is located in an undisturbed semi-arid landscape consisting of sparse trees, shrubs and grasses. The soil interspaces are covered with biocrusts, a living soil cover also found worldwide in arid regions. Biocrusts are composed of lichens, cyanobacteria, algae, mosses, liverworts, fungi and bacteria, and live on and within the first few millimetres of the soil surface. Biocrust organisms bind soil particles, sequester carbon and many fix atmospheric nitrogen making them important structural and functional components of ecosystems. Despite their important role in ecological processes, biocrusts are susceptible to disturbance; nevertheless they can recover provided sufficient inoculum is present. Cyanobacteria are the early colonisers and they capture atmospheric and landscape resources and establish conditions that subsequent successional seres can capitalise on. Research conducted in countries including China, Spain and South Africa has been focused on methods to either encourage rapid regeneration of cyanobacterial remnants or to introduce new material from cultured cyanobacteria. We have been investigating the extent and diversity of biocrusts across the 4500 ha mine lease and their potential to improve mining rehabilitation outcomes. Approximately 46 per cent of the soil surfaces are colonised with biocrusts and 33 taxa have been identified. Laboratory experiments were designed to mimic massive soil disturbance and treated with a range of water qualities. Within 22 days, treatments irrigated with fresh water were colonised by new cyanobacterial filaments with a mean surface coverage of 65 per cent. Secondary tests revealed that differences in the photosynthetic yield of the crust were dependent on the salinity levels of the irrigation water used. In 2011 this program is expanding from the laboratory into field scale trials designed to assess both the potential and practicalities of up scaling these techniques to provide crushed biocrusts and cyanobacterial bio-inoculum for use in mine rehabilitation.

Oct 5, 2011

By Gibbons S. L, Ritchie I. M, Murr D. M

Fundamental studies on the transformations of iron oxides have been carried out and related to the solution conditions in the Becher process. The results show that a number of iron oxide interconversion reactions occur in the aeration reactor with the products depending on the pH, temperature and oxidation potential of the aeration liquor. It is concluded that the lack of process control in the aeration reactor of the Becher process significantly hinders the ability to predict and produce high quality single phase iron oxides of a consistent colour.

Jan 1, 1990

By Mine F. J, Woods P. H

Waste waters from mine sites may be screened for all constituents of significance as a first step in establishing water quality criteria for protection of aquatic ecosystems. Inductively-coupled plasma mass spectrometry (ICP-MS) offers the capability to screen water samples and digest solutions for virtually all elements in the periodic table. This technique is therefore able to identify elements whose concentrations are elevated in waste waters and may be rarely present in background surface or ground waters. Such elements may be present in waters at only a few ¦g/L. ICP-MS has sufficient sensitivity to detect sub-¦g/L or even ng/L levels of many elements. Waste waters from most mining activities in the Northern Territory have been examined by ICP-MS. The concentration data provide the basis of a contaminant data base. The data can show specific tracers in the ore or mineral itself, subsequently found in waste water. An example is the presence of rhenium in uranium ore. Such trace elements may be present in soluble or insoluble chemical forms and are more useful as indicators when soluble and exemplifying conservative chemical behaviour. The approach described, based on ICP-MS screening of mine site waste waters, together with general physico-chemical variables, provides the most comprehensive means yet available of selecting variables for monitoring programs and ensures that key elements and/or their chemical species are not excluded from monitoring programs.

Jan 1, 1994