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The reduction in man's contribution to the Greenhouse effect will only be achieved by a number of small steps. Some steps will absorb carbon dioxide (CO2) from the atmosphere in slightly greater quantities, others will reduce the amount of carbon dioxide generated. This paper deals with the reduction of carbon dioxide by improving the combustion efficiency of petroleum fuels. Until recently most reductions in fuel consumption and air pollution have been brought about through mechanical adjustments to combustion equipment. Since the development of tetraethyl lead, little has been done to chemically modify combustion reactions to improve fuel efficiency or reduce emissions. During the past five years Australian laboratory and field trials with ferrous picrate treatment have demonstrated significant and economic gains in the combustion efficiency of diesel fuels. These studies have revealed that even under ideal conditions in diesel engines, carbon monoxide (CO) momentarily saturates the combustion chamber. This state reduces combustion rates, peak pressure and power and increases the risk of pollution. Theoretical, laboratory and field data are presented which support the mechanism by which the ferrous catalyst accelerates the oxidation of CO to the terminal CO2 thus reducing fuel consumption and the undesirable combustion products accompanying the CO saturation of combustion environments. While this paper deals principally with diesel fuels commonly used in mining operations, the catalytic effect of the ferrous ion is also shown to significantly reduce fuel consumption by petrol engines thereby promising a means to reduce the much larger contributions to the Greenhouse gases by automobiles.

Jan 1, 1989

By Clements R. J, Davey J. M

Development of the process from the pilot stage to the current operation of the Capel, W.A. plant is briefly described. The design criteria for a larger sized plant are discussed together with factors that relate suitable feedstocks and coal types to the capital cost, capacity and product grade of future plants at locations other than Capel. The application of the process to the direct reduction of iron ores is briefly discussed including its commercial application at Rockwood, Tennessee.

Jan 1, 1979

The Chamber of Minerals and Energy of Western Australia Inc (CME) is the peak resources sector representative body in Western Australia. The paper gives a summary of the role and objectives of the CME, including its history, structure and key program areas. Particular attention is given to the role of the CME in the Eastern Goldfields of Western Australia. The paper details the types of CME membership that are currently in existence. The paper argues that a strong and vibrant CME is vital to secure the resources sectorÆs growth and development in future years.

Jan 1, 2006

Perhaps the only thing certain about an address that purports to look into the future of any human endeavour is that time will prove it :.o be inaccurate. In undertaking the dubious, but oft-times necessary business of prediction, thr, historian will base his/her forecasts on tr-ands of the past, the speculator on current events, and the politician on what he/she would dearly like to see happen. The thoughts expressed in this address seem to have arisen through exercising a combination of all three of those philosophies but, hopefully, with a smat- tering of pragmatism.

Jan 1, 1988

By Merry N, Cocks T

The mineral exploration industry is increasingly aware of the importance of the relationship between mineralogical data and geochemical assay results. However, until recently, the cost and time constraints of most techniques for analysing alteration mineralogy have precluded detailed alteration studies. These impediments have been reduced by the development of the Portable Infrared Mineral Analyser (PIMA), a field portable infrared spectrometer that allows rapid (in field) and cost effective analysis of alteration minerals including subtle variations in mineral crystallinity and Composition.

Jan 1, 1995

By Brigden J. F, Birrell

A regional geochemical exploration programme commenced in July 1983, based upon low-density sampling of lateritic duricrust over parts of the Yilgarn Block of Western Australia. This resulted in recognition of an area significantly anomalous in chalcophile elements that progressively led to the discovery of the Johnston Range gold deposits in 1985. The deposits, on the Barlee 1:250,000 map sheet, occur in four mineralized zones, and production is expected to commence during 1988. The programme leading to the Johnston Range discoveries was a collaborative research/ applications study between the AGE Joint Venture (Greenbushes Ltd., St. Joe Minerals, and from 1985, Sons of Gwalia NL) and the CSIRO Laterite Geochemistry Research Group (Smith, 1987). It built upon a precursor project sponsored by Greenbushes Tin Ltd that commenced in 1980 and arose from an orientation laterite research project in the Greenbushes rare metal pegmatite district (Smith et at., 1987). Both were multi-commodity programmes and included the search for gold deposits. Basic methodologies for sampling and data interpretation have been described by Smith and Perdrix (1983) and Smith et at. (1984). Continuous geochemical coverage of designated parts of greenstone belts was sought using a triangular grid of 3-km or 1-km spacing, depending upon the expected prospectivity of the areas and the size and characteristics of the ore deposit targets. First-pass sampling, that resulted in the Johnston Range discoveries, was at 3-km spacing and several samples within a 30-km by 5-km area were

Jan 1, 1988

A critical appraisal of the wide variety of processes used in the pyrometallurgical production of metals and non-metals shows that there is a strong physico-chemical and, in particular thermodynamic, basis for the variety. Based on this, a simple classif- ication scheme has been developed which makes it possible to understand the methods for extracting individual metals and non-metals pyrometallurgically and to assess which are the more attractive routes. The analysis presented shows why there are essentially two broad routes for pyrometallurgical production of metals and non-metals; viz., the reduce- refine and the refine-reduce routes. Halides have the role in pyrometall- urgical processing of producing pure compounds for subsequent reduction. The criteria which determine the selection of reduction method for oxide raw materials and intermediate halides (e.g., use of carbon, hydrogen, a more reactive metal or electrowinning) are examined critically in the paper. The treatment of sulfide raw materials is considered also, particularly the criterion for smelting sulfides directly to the metal.

Jan 1, 1987

The recovery of Copper by solvent extraction was arguably the most significant hydrometallurgical development of the 1960's. However, only dilute solutions at relatively high ph. could be treated effectively. ICVAcorga introduced in the 1970's the much stronger salicylaldoxime based reagents, which resulted in a dramatic change in plant configurations. So for example plants which normally use 3 extraction stages and 3 stripping stages could be reduced to 2 + 2 staging or 2 + 1 staging, even for high copper tenors at low ph. Leach liquors up to 40 g A copper are being treated at some locations so that almost any copper bearing liquor can now be purified by solvent extraction. Following a considerable amount of research and development effort ICI/Acorga have made further significant advances in the application of copper solvent extraction. The first of these is in computerised flowsheeting. In conjunction with ICI's Process Technology Department, Acorga have developed the Minchem Computer program, which uses laboratory generated equilibrium data to facilitate optimisation of metallurgical operating parameters. The program can operate in two modes, prediction and assessment so that given suitable extract and strip isotherms plant performance can be predicted for a given set of conditions. Alternatively existing plant performance can be assessed rapidly and accurately, thus providing a valuable quality control tool. Pilot plant work can now be restricted to evaluation of the physical aspects of the SX circuits, and to looking for the unexpected. Secondly using the patented 5-Nonyl Salicylaldoxime in precise admixture with a number of carefully selected strip modifiers, the Acorga M-range has resulted. Reagent selection from these new extractants can now be based on how the reagent can alleviate the remaining problems such as hydrolytic stability, transfer of iron, and organic losses by entrainment which may be related to particular features of the operating plant. Thus the Acorga M-range has enhanced and significantly extended the use of solvent extraction for copper, whilst refinements in the processing of metallurgical data has considerably simplified circuit design and analysis of results.

Jan 1, 1989

By Toro HCH, Von Borries GH

A brief description of the semi-autogenous grinding (SAG;) facilities of Compania Minera Disputada de Las Condes is given. A data-logging and computer system was connected to the plant inter facing the existing analog control system in a supervisory s, control philosophy. The development of a control straiov,v t,) maintain maximum power of the SAG mill atsubjected to process restrictions is shownThe present control scheme is discussed inalgorithm was designed based on correlations onLween vartaoles. Associated with this, a direct level of control was developed be, on classical control algorithms, process inter-active tuning has been included. Also, an algorithm to prevent overloading of the is discussed. Control scheme tests are presented in comparison t manual operator control under the same conditions. It is shown t the control strategy gives a more stable operation and a higher plant throughput.

Jan 1, 1985

By H Fukaya T Miki, J Gamutan

Molybdenum disilicide (MoSi2) is a promising material for thermal applications due to its excellent heat and oxidation resistance. It can operate at temperatures of up to 1800°C as furnace heating elements and protect refractory metals such as molybdenum from rapidly reacting with air to form volatile molybdenum oxides at elevated temperature. In this work, the feasibility of forming MoSi2 on a molybdenum substrate by hot dipping in a silicon-saturated molten metal bath was investigated. This method is simple, predictable and can be used to coat large components and complex parts. It was found that tetragonal MoSi2 can be successfully synthesised on the surface of the substrate after dipping for 15 mins at 1000°C using molten tin (Sn), bismuth (Bi) and copper (Cu) baths. The growth of the MoSi2 layer was fast within the first 15 mins and then gradually slowed down with time. After dipping for 60 mins at 1000°C, the thickness of the MoSi2 layer were measured as 441.5, 19.5 and 13.1 μm for the copper, tin, and bismuth baths, respectively. The MoSi2 coating synthesised in this study provided oxidation resistance at 1150°C by forming a protective SiO2 layer on the surface. The SiO2 layer prevented the sample from rapidly oxidising by inhibiting direct contact between the molybdenum substrate and oxygen in the atmosphere. Compared to conventional methods, the proposed hot dipping method produces a MoSi2 layer more rapidly and at much lower operating temperatures. This makes it a more attractive option for coating large and complex components, with the potential to enable the use of MoSi2 in a wider range of applications.

Jun 19, 2024

Flotation science and technology are related to three major sub- processes which are organized in a hierarchical structure as shown in Fig. 1. The basic sub-process is the chemical process which affects the attachment of air bubbles to mineral particles. In particular, the chem- ical process is related with the adsorption of surface active sub- stances at the gas-liquid, liquid- solid, and gas-liquid-solid inter- faces. This field has been most intensively explored in flotation research. The second domain in flotation research is concerned with the mineral particle to air bubble attachment sub- process in the system. This sub- process represents the dynamics of particle and bubble encounter where the contact angle and the induction time, determined by the surface chem- istry of the system, are among the most significant parameters. This sub-process can be referred to as the micro-process as against the third sub-process, or the macro-process, which corresponds to the integral behaviour of the system. Two other sub-processes are integrated into the macro-process in which they may not reveal themselves explicitly in the details. The third sub-process does not entail surface-chemical or physi- cal events any more, but it represents them all inclusively. To represent this sub-process we use mathematical equations, called models. Only in some simple or simplified cases can the models be solved exactly to find out the behaviour of the flotation system in which we are interested. Digital

Jan 1, 1984

By K Saito, M Hasegawa

In steelmaking processes, it is known that P2O5 in dephosphorisation slags often exists in solid solutions between Ca2SiO4 and Ca3P2O8, <C2S-C3P>SS, and thus the solid solutions play an important role in the dephosphorisation reaction. Hence, the knowledge of thermochemical properties, ie phase relations and activities of components, in slags containing <C2S-C3P>SS are necessary for the effective removal of phosphorus from hot metal. In this study, the P2O5 activities in <C2S-C3P>SS were measured through the gas equilibrium method. In the present experiment, oxide samples were equilibrated with Cu-P liquid alloys at 1573 K under a stream of Ar + H2 + H2O or Ar + H2 + CO2 gas mixture in which oxygen potential was fixed and then equilibrium phosphorus concentrations in the Cu-P alloys, [mass%P]Cu, were analysed with ICP-OES.

Aug 21, 2024

By M I. Pownceby, N Karimian, J R. Manuel, M J. Peterson

The CSIRO ore classification scheme for Pilbara ores was used as a reference frame to target recognisable ore types/textures with potentially elevated phosphorus content for detailed analysis. Particles of each individual ore texture were separated from a Brockman high-P ore and each class was characterised using methods including XRF, XRD, EPMA and synchrotron-based XAS. Results were then correlated with optical microscopy and hand specimen identification to establish any relevant associated mineralogical phases and/or textures. This represents a more systematic approach to identification of high-P ore components based on particle and goethite type and texture. The information can then provide the basis for more targeted P-removal strategies factoring in the relationship between particle/ore texture and phosphorus deportment

Sep 18, 2023

By Mauk JL, Arehart GB

Quartz veins from the Martha Hill epithermal gold-silver deposit, Waihi, commonly exhibit crustiform banded textures. Visual differences observed between bands are primarily the result of a 1 to 1500 ¦m variation in quartz grain size. Quartz band textures are dominated by anhedral interlocking quartz mosaics, commonly associated with minor adularia and sulfide phases; these textures are interpreted to be products of amorphous silica crystallisation. The occurrence of rhombic adularia suggests that prolonged boiling influenced parent fluids. In contrast, the presence of coarsely crystalline bands, made up of subhedral to euhedral quartz grains, infers primary crystal growth from solution; evidenced by the occurrence of growth-zoned quartz within these bands. There is a narrow range of 3.3%o in 618Oq,,,,,= between maximum and minimum isotopic values for the deposit. Significant overlap in 618Oqu,, values are observed between the Martha and Welcome lodes. However, statistically significant and commonly systematic differences do occur between individual bands analysed in most samples. Temperature fluctuations may be the dominant factor responsible for observed inter-band variation.

Jan 1, 1995

By Q Zhou, J Pan, D Q. Zhu, C C. Yang

Oxidised pellets have become an indispensable high-quality charge for blast furnaces (BF) due to their uniform particle size, high iron grade, high mechanical strength, good metallurgical performance, as well as relatively low energy consumption and gaseous pollutant emissions in pellet production. Nevertheless, due to the rapid development of the global steel industry, highquality pellet feeds are becoming more and more scarce. In order to broaden the source of pellet feeds and reduce the production cost of pellets, more and more steel mills are going to use coarse iron ore fines with relatively low iron grade and low impurities for preparation of desirable pellet feeds through a typical wet grinding-settling-filtering process. In this work, the grinding, settling and filtering behaviour of Brazilian and Australian iron ore fines are studied and compared, aiming at finding out the internal relationship between the mineralogical characteristics of different iron ore types and their grinding-settling-filtering performance. The results show that the grindability is heavily dependent on the hardness of iron ores, which is governed by the mineralogical characteristics of the raw materials. Usually the higher the hardness, the more grinding energy is required. Except for Brazilian specularite, Australian hematite-goethite type iron ore fines and Brazilian hematite ore fines exhibit good grindability with a Bond Work Index of about 10–15 kW•h/t. In addition, the settling and filtering performance of ground iron ores are largely affected by the density, mineralogical characteristics of iron ore fines (eg, quantity of clay minerals and goethite and porosity of ore particles), grinding fineness, etc. Generally, iron ore fines with higher density, lower quantity of soft minerals (clay and goethite) and larger particle size give superior settling and filtering performance. For iron ore fines with inferior grinding, settling and filtering performance, applying more energy-efficient grinding techniques, blending with ore types with good settling and filtering performance can reduce grinding energy consumption and improve settling and filtration rates to maximise the productivity of equipment and lower the operational cost

Sep 18, 2023

The long-term outlook Tor Australla&apos;s traditional mining products is for flat demand and continuing low prices. This has come about because of three far-reaching changes since earlier boom days: 1. Continuing declines in intensity of usage of basic mine products; 2. The failure of newer western and third world developing countries to realise growth expectations; and 3. Continued production pressure from third world countries (and first-world primary producers) in an effort to earn foreign exchange and rectify trade balances. These trends have led to a general situation of excess supply and weak demand. In this environment, the prerequisites for survival in the mining sector are first-class mines, modern and efficient production methods, low unit costs, aggressive marketing, and products with reasonable operating margins. Many of Australia&apos;s mines meet these prerequisites. Following the A$ depreciation and widespread unit cost reductions, most of these mines will be moderately profitable at current depressed commodity prices. They are well placed to benefit from price rises if these eventuate. A new generation of mines is concentrating on a more profitable product range (gold, diamonds, uranium, mineral sands). Australia&apos;s balance of trade remains firmly dependent on the primary mining and agricultural industries (Fig. 1). Despite optimistic talk of high-tech developments, tourism and a resurgence of manufacturing, these will remain a small component of Australia&apos;s export structure.

Jan 1, 1987

By Q Fan

The steelmaking desulfurisation plays an important role in coal-based steelmaking route of blast furnace and BOF converter within the flow sheet of BF-deS-BOF. With the advent of H2-based ironmaking and steelmaking process, the transition flow sheet of DRI-Smelter-BOF has been assessed and developed by the steelmaking industry. What is the role of deS in H2-based route of DRI-smelter-BOF? This paper will present the influence of sulfur-containing iron ore on steelmaking desulfurisation and the leading role of EAF-smelter played in H2-based steelmaking route. The sulfur contents of iron ore vary considerably around the world and lower-grade iron ores with high sulfur are likely to be used for H2-based route, a considerable amount of sulfur that comes from DRI will report to the melt of EAF-smelter and the operating conditions of EAF-smelter also impact the sulfur content of the hot melt for steelmaking deS. The EAF-smelter of H2-based route is the focus of the steelmaking industry at moment, unfortunately, an industrial-scale EAF-smelter has been the missing link of the flow sheet of DRI-Smelter-deS-BOF, despite similar EAF-smelters being used for various applications of Fe-Ti and Fe-Ni processes. The latest progress is that several pilot-scale and industrial-scale EAF-smelters with reducing capability are planned for construction within next several years and low-grade Australia iron ores are certainly to be employed as basic feedstocks for H2-based route of DRI-Smelter-deS-BOF.

Sep 18, 2023

By Pitkajarvi J

Waste rock dilution causes mill feed grade to be lower than mineral resource grade. In nickel mines relative grade decrease (dilution) may be tens of per cent because of irregular ore boundaries and weak wall rocks. Five per cent dilution costs millions of dollars annually in medium size underground mine. In Outokumpu Group selective bench and fill stoping, cable bolting/shotcrete-skin support and fast ore boundary definition (OMS-logg in-hole logging or sludge sampling) are the key tools in dilution control. Commitment of the whole organisation to keep dilution low is also needed. Dilution sources and effects are discussed with examples of the dilution control methods applied in Outokumpu mines.

Jan 1, 1996

By Reeves T. J, Hansen J. Y

Dense medium cyclone theory, supported by extensive experimental and plant-scale evidence, demonstrates that medium rheology (stability and viscosity) substantially affects cyclone performance in mineral applications.Two instruments have therefore been developed to allow medium stability and viscosity to be-monitored in the plant environment. The instruments are described, and examples are given of their application in full-scale plants.

Jan 1, 1989

By Kidd CH

The excavation of a coal mine or any other mine, tunnel, or quarry, below the water table establishes a void towards which ground- water will flow. Inflows into the mine, if significant, can cause not only problems such as flooding, and/or muddy floors, in the mine, but commonly also require disposal of poor quality groundwater. The flow of groundwater towards a mine is accompanied by a decline in groundwater levels, which may extend up to several kilo- metres around the mine. This may seriously effect vegetation, stream flow and existing users of groundwater. At the pit face groundwater gradients can also cause slope stability problems and where a water table is intersected, increase blasting costs.

Jan 1, 1983