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By R. R. Sayers

The increasing use of hydrogen fluoride (annual consumption now exceeds 500,000 pounds (1)4/) directly and its occurrence as a byproduct of the utilization of fluorine compounds in the mineral industries, especially in metallurgical processes and in the refining of petroleum products, has aroused interest in its toxicity, and a brief review of the literature, with special reference to the hazard of poisoning in the mineral industries, seems to be opportune. Recently, residents in the vicinity of aluminum plants have been complaining of injury to livestock and vegetation as well as to their own health from the gases discharged into the air during operation of the plants, hydrofluoric acid gas apparently being the offender. The comparatively recent utilization of hydrofluoric acid in the alkylation process for the production of high-octane gasoline has raised the question of the hazard of poisoning in the petroleum Industry. In addition, the use of fluorine-containing refrigerants has extended the potential al exposure outside of industry (2).

Jan 1, 1945

By Lowell B. Moon

Regardless of how a mineral deposit in first discovered or by whom, any mining enterprise based upon it must pass through a preliminary stage of exploration. The common understanding of ?exploration? among mining engineers is well-expressed by Jackson and Knaebel:3/ Exploration work ranges from that performed by the individual prospector employing only the simplest tool, and equipment to elaborate campaigns involving the expenditure of largo stuns of money end the use of churn- car diamond-drilling equipment, large test-pitting crews, or sometimes a regular mining organization. In any event, the object is to determine as accurately as possible, with the funds available, the size, shape, and other characteristics of the ore bodies and their average value or grade.

Jan 1, 1945

By H. Foster Bain

The war has brought about many changes in the Western States, and some have deep pr sent or potent al economic significance. The West has been feeling severe growing pains for a number of years. Especially since the beginning of preparation for national defense and through the period of

Jan 1, 1945

By Ernest W. Johnson

Diamond, drilling of some blast holes in stoning operations is practised in at least two iron mines in the Lake Superior district - the Soudan mine of the Oliver Iron Mining Co., on the Vermilion range at Soudan, Minn., and the Anvil-Palms mine, operated by Pickands, Bather & Co., on the Gogebic range at Bessemer, Mich. Diamond drilling, at the Soudan nine has partly replaced percussion drilling because of the extreme hardness of the ore and of the lean formation. According to Wolff,4/ the jasper or lean formation in this mine is the hardest rock regularly drilled in any commercial operation.

Jan 1, 1945

By Oliver Bowles

In 1943 the Bureau of Mines began a review of trends in consumption and prices of the more important nonmetallic minerals. The first report covering building materials4/ appeared in December of that year. The present paper, which deals with chemical raw materials and fertilizers, is the second of the series. The 34 years from 1910 to 1943, for which statistics are presented herein, comprise periods of uneventful peace, unparalleled prosperity, industrial depression almost to the point of stagnation, and two wars of world proportions.

Jan 1, 1945

By A. C. Fieldner

The past full year of war has increased greatly the demand for virtually all kinds of fuel, and the Bureau of Mines research and service facilities have been extended to meet these unprecedented requirements. Liquid fuels, such as aviation and motor gasolines, are fundamental to modern warfare. Bituminous coal and anthracite are needed, not only to servo the expanded industrial program for which coal normally is used but also to replace natural gas, wherever possible, and fuel oil in the Eastern States, New England, and the Pacific Northwest. Railroad transportation with energy derived from coal is replacing much of the motor-vehicle transportation that has been stopped or curtailed to conserve rubber. Pulverized coal hoe been sound to be a satisfactory and cheaper substitute for fuel oil in metallurgical heating furnaces. Celloidal fuel - a mixture of coal dust and oil - may offer a partial substitution for curtain coal-burning equipment. Several industrial experiments have been made with this type of fuel. The expansion of the steel industry in connection with the war program has required a corresponding increase in the production of metallurgical coke and its associated byproducts - light oil, tar, ammonium sulfate, and surplus gas. If the war is of long duration and new reserves of petroleum are not discovered, wartime trends from fuel oil to coal probably will not be reversed.

Jan 1, 1945

Geophysical Abstracts 1 - 86 wore issued in mimeographed form by the Bureau of Mines; Abstracts 87 - 111 were published in bulletins of the Geological Survey; Abstracts 112 - 119 were issued in mimeographed form by the Bureau of Mines as Information it ion Circulars 7256, 7257, 7267, 7273, 7285, 7292, 7303, and 7310. 1. GRAVITATIONAL METHODS 7786. Barton, D. C.3/ Case Histories and Quantitative Calculations in Gravimotric Prospecting. Am. Inst. Min. and Meat. Eng., New York, Tech. Pub. 1760, 1944, 49 pp.

Jan 1, 1945

By D. Harrington

The greatly extended use of the underground trolley-locomotive system for hauling coal without doubt was one of the most important factors in the rapid progress of coal mining and the increased production of coal in American coal mines during the period 1910-20. Much of the superior efficiency of production of our underground coal and metal lines should also be credited to the trolley locomotive system. The trend to mechanization of mines during the past 15 years, mere particularly the past 5 years, with higher production per man employed and greatly accelerated advancement of working places, has required increased use of trolley locomotives, necessitating larger equipment, higher speeds, and more 'frequent turn over of pit cars. This is re¬flected in increased size of locomotives and the use of larger mine ears (some with a capacity up to or over 10 tons); moreover, heavier rails and larger-size trolley wires have boon or ought to have boon installed. Trolley-locomotive haulage has proved to be rapid; economical, efficient, and productive; nevertheless; in spite of these advantages, so-many hazardous features and, unsafe conditions are involved and the price paid in life and property is so high as to justify the statement that the system should be scrapped if it cannot be operated under reasonably safe conditions. Since bare trolloy wires were introduced into underground mines, they have boon responsible for the death of hundreds of diners, property damage totaling millions of dollars, an indeterminate loss of tonnage through the abandonment of mines or parts of mines, and loss of time after disasters caused by fires or explosions originated by the trolley haulage system.

Jan 1, 1945

By D. Harrington

Although the explosion-fatality record for the fiscal year 1944 showed considerable improvement over those of the preceding 4 years, it is still fur from creditable, and the coal-mining industry and agencies interested in the prevention of coal-mine accidents should not be satisfied until accidents from explosions and fires are eliminated. In view of present knowledge of the methods of preventing explosions and fires, such disasters are inexcusable and discredit the mining industry. Despite this knowledge, far too many coal¬mine operators and employees continue to follow procedures that have resulted in disasters in the past. Included in the appendix to this circular are a number of safety measures designed to prevent coal-mine explosions and fires and metal-mine fires. Their adoption is essential if explosions and fires are to be prevented, as certainly they should be. An epidemic of disastrous mine fires of electrical origin during the past 2 years emphasizes the need for better methods of protection of underground electrical circuits. At present, committees of mining-electrical engineers, electrical-equipment manufacturers' representatives, and others are cooperating with the Bureau of Mines seeking means to solve this problem.

Jan 1, 1945

The revised inspection standards or recommendations herein have been prepared for use in Federal inspection of bituminous-coal and lignite mines. They succeed a compilation of similar standards published as Bureau of Mines Information Circular 7268 in December 1943 and employed as a guide in Federal inspections since that time. Important alterations and additions have been made because of changes in mining, practice and temporary shortages of some safety equipment; moreover, several previous standards have been found not generally applicable and have accordingly been deleted. Mining methods and equipment continue to change, and new hazards and new safeguards are introduced. Consequently, these standards are subject to revision from time to time. Questions from the coal-mining industry regarding these standards and suggestions as to changes and additions thereto will be welcomed and considered carefully when the next revision is made. Many constructive criticisms from the mining industry have been considered in preparing this edition.

Jan 1, 1945

By Henry P. Wheeler

As recently as 1915, helium was available only in very small quantities at a cost equivalent to $2,500 per cubic foot. It was a laboratory curiocity, and its properties were of interest to a limited number of scientists (11).3/ During the past 30 years, however, helium has grown from a plaything of scientists to a factor of importance in the prosecution of the recent war. Navy blimps filled with nonflammable helium proved to be more than a match for German submarines operating in the Atlantic. American bombers were able to fly unheard-of distances to drop bombs on Tokyo, Nagoya, Yokahama, and other Japanese cities because they had been made lighter with magnesium, arc-welded in a helium atmosphere. The Army utilized helium-filled radio-sonde balloons to obtain vital information concerning weather conditions affecting D-day invasions and other military maneuvers.

Jan 1, 1946

By Charles L. Harness

The barite industry has made notable progress since the days when barite was used only as an adulterant in white-lead paints and the only method of mining it was with pick and shovel. The following chronological record may serve to show how this heavy white mineral has grown in importance in the national exonomy and at the same time to indicate development of methods for obtaining it. 1845. - Barite first, mined in Fauquier County, Va., for use as an adulterant in white-lead paints. 1850 (approx.). - French settlers 60 miles southwest of St Louis, Mo., discovered barite; called it "'tiff;' meaning white. It was mined and shipped to St. Louis for use in paint.

Jan 1, 1946

By W. S. Landers

Analysis of the size consist of broken coal has been extended in recent years beyond the mere representation of the relative quantities of the various sizes present in a given lot of the material. Fundamental characteristics of the coal related to the process of breakage fix the distribution of sizes, and it has been found by Rosin and Rammler4/ that a relatively simple law-governs this property. Benhett5/ has described a graphical method of expressing the relationship, and by its use considerable simplification in the expression of size distribution is possible.

Jan 1, 1946

By Harold M. Smith

Among the more important raw materials now utilized for the commercial production of synthetic organic chemicals is natural 'gas. Natural gas has been used as a fuel and source of energy almost from its discovery, but its potentialities as a chemical raw material were not realized until recently. Research in the use of natural gas for Chemical synthesis received great impetus from the discovery by Brooks and Humphrey4/ in 1918 of alcohols in the diluted ?acid oil? obtained by sulfuric acid treatment of cracked petroleum distillates. Experimental data soon showed that hydrocarbons from natural gas could be converted to these same products. Laboratory methods for chlorination of natural-gas hydrocarbons, particularly of methane for the production of methyl chloride, methylene chloride, carbon tetrachloride, and chleroform were known before that time but were not developed commercially. Methods for obtaining alcohol by oxidation of hydrocarbons derived from natural gas also were known before 1918 but had not received commercial consideration. Since 1918, and particularly during the past 15 years, the work of chemists and chemical manufacturers throughout the world has resulted in an accumulation of data regarding the reactivity of natural-gas hydrocarbons, and related hydrocarbons found in refinery gases or made synthetically. These data have been used to develop methods for converting hydrocarbons into chemical products and thus form the basis for a large and growing industry.

Jan 1, 1947

By William W. Odell

In Europe and in certain other foreign countries studies have been made, extending over a period of years, relating to the winning of oil from oil shale. More work has been done in these countries than in the United States, for the reason that a supply of natural petroleum has not been so generally available there as here. Information has been obtained relating to present practices in these foreign lands in the development of a shale-oil industry. It is realized that in the past there has been very little inducement to invest capital in shale-oil enterprise in the United State's because the supply of petroleum has been plentiful; however, the time possibly is not far distant when the utilization of oil shale may be cons¬idered a desirable and financially sound venture, as it may be necessary before long to augment our supply of oil with that recovered by processing shale. The data presented herein portrays at least some of the thoughts of those engaged in obtaining oil from oil, shale in Europe, and they depict some of the results thus far obtained as well as certain plans for further efforts to win oil from shale; it is hoped that those who undertake the development of a shale-treating industry in this country will find useful information in this report.

Jan 1, 1946

By A. C. Fieldner

This is the tenth annual report of research and technologic work conducted by the Bureau of Mines on the occurrence, properties, mining, preparation, and uses of coal and coal products. These annual reviews are guide's to the current work-and publications of the Bureau but do not replace the more complete reports published under the authorship of the individual investigators on specific problems in Bureau of Mines bulletins, technical papers, reports of investigations, and information circulars and in the technical press. The Annual Report of the Director of the Bureau of Mines to the Secretary of the Interior for the Fiscal Year ended June 30, 1945, summarizes the year's work on coal as follows: Coal and Coal Products The United States maintained its No. 1 industrial position in supplying fuel for war and in preparing for peace through more complete mining, improved preparation and up-grading of coal for special uses, and better utilization of coal in industrial establishments and homes.

Jan 1, 1946

8186. Aquilina, C. Determinazioni relative di gravita eseguite nel 1939 (Relative Determinations of Gravity Made in 1939), Ric. Ingegn, Rome, vol. 10, 1942, pp, 6376. In 1939, the author made a survey of relative gravity in the Mediterranean-basin, 41° 35,5' to 41° 56.3' northern latitude and 0° 10,3' to 0° 28' longitude, referred to Mt. Mario. Ten stations were covered; 25 other stations had been occupied in the vicinity of Rome and in Albanian mountains during previous years. The new measurements revealed gravity anomalies ranging within the following limits: (1) With a free-air reduction, between + 29 and + 120 mgl., average + 60 mgl.; and (2) with a Bouguer reduction, between + 22 and + 87 mgl., average + 41.5 mgl. - V. S.

Jan 1, 1946

By Oliver Bowles

In 1940 the Bureau of Mines issued a report describing all the cement plants of Latin America, their design, capacity, and output, and the cement imports, exports, and requirements of the several countries. Since that time there has been such great activity in cement plant construction that a revision of the paper is highly desirable. The present compilation comprises the essential data in the previous report together with descriptions of all cement plants completed, under construction, or planned since that date and an overall picture of the supply and requirement situation of each country. Before World War I, Latin America was one of the world's largest export markets for cement. Its dependence on outside sources created no special problems of supply until the shortage of shipping and abnormally high prices of the First World War stimulated a movement toward greater self-sufficiency. Under this incentive many cement plants were constructed, and several countries were able by 1939 to manufacture enough cement for their modest needs. Substantial imports were still required for many important areas, and as the volume of demand was rapidly increasing the Latin American countries as a whole were far from self-sufficient in cement when tine Second. World War began. South and Central America depended to a large extent on European countries, chiefly Germany arid Belgium and to a smaller degree Scandinavia, United Kingdom, France, and Italy, to Supply their cement shortages. The cost of manufacture in these European countries was much lower than in the United States, and transportation expense had been kept at a particularly low level because of the two-way trade that had been developed. Ships destined for Latin American ports for coffee, tropical woods; fruits, and other native products could carry cargoes of cement on their westward voyages at very low cost In some instanced cement was taken in exchange for South American -products because cash was not available. Great Britain had withdrawn from this market to quite an extent because of low prices and because trade with its own Empire had been increasingly fostered. United States trade in cement with Latin America had been confined principally to white and other special varieties. In few places could ordinary portland cement made in the United States compete in price with the European products; although in general it was of better quality and cool d be delivered more promptly.

Jan 1, 1946

By Frank E. Cash, Max S. Petersen

"INTRODUCTION Explosives have been used in ever—increasing amounts since gunpowder was invented. For hundreds of years only low explosives of the deflagrating type were used, and they were fired by means of a flame or hot object. Ben¬jamin Franklin first ignited gunpowder from a distance in 1751 by means of an electrostatic spark. Further efforts to develop a satisfactory electrical method to ignite explosives from greater distances were overshadowed by the invention of safety fuse in 1831, as this offered a relatively simple and inexpensive means of firing explosives.The discovery and introduction of high explosives of the detonating type and the invention of the fulmitate of mercury blasting cap about the middle of the nineteenth century provided the needed impetus for inventors to develop means of firing the cap by electricity. The original high-tension igniter, following Benjamin Franklin's experiment in which the detonating compound was ignited by a spark, was discarded in favor of a low-tension igniter, in which the detonating compound was ignited by a heated wire. The past 2 decades have seen considerable improvement in the design and construction of electric detonators to make them safer and more efficient, yet in spite of the improvement it is estimated that less than 50 percent of the explosives used in industry today are ignited or detonated electrically. The trend, however, is toward the use of electric methods. In recent years numerous-mining companies have introduced electric blasting exclusively at their mines as a means of improving safety and efficiency."

Sep 1, 1946

By D. O. Kennedy

"INTRODUCTION During the recent war attention was directed to prevent the destruction of American industries by sabotage. By Executive order of Lay 19, 1942, the Bureau of Mines was required to conduct investigations and make recommendations that would prevent loss of production of essential war minerals. The Health and Safety Branch of the Bureau of Lines was able to extend its activities with minimum loss of time to include security surveys of the important mineral facilities in the United States.A Mineral Production Security Division was established in the Health and Safety Branch with funds appropriated for that purpose by Congress in April 1942. From July 1942 to July 1945 engineers of this division, under the direction of D. Harrington, Chief, Health and Safety Branch, and J. J. Forbes, Chief, Mineral Production and Security Division, conducted investigations of 1,560 metallic and nonmetallic mines and associated facilities in accordance with the requirements of the Executive order.PURPOSEAn analysis of losses in the production of minerals shows that failure or destruction of equipment either from deliberate or accidental causes produces essentially the same result. Maximum production is insured by the prevention of subversive activities, fires, and industrial accidents."

Sep 1, 1946