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By J. K. S. Tee

Using a novel method, zinc has been selectively removed from galvanized steel scrap on a laboratory scale. The separation is based on thermodynamic principles: during chlorination in air-chlorine (10:l) mixtures at 800 OC, zinc forms a volatile product (zinc chloride) while iron does not chlorinate as its oxides are more stable than the respective chlorides. As much as 92 % of zinc is removed from the surface of steel within 10 minutes. This process overcomes tedious and costly preparatory stages associated with leaching - electrowinning methods.

Jan 1, 1999

By Jian Li, Tiejun Chun, Jian Pan, Deqing Zhu, Vinicius Mendes

"A study of the coal-based direct reduction behaviors of composite binder magnetite pellets was carried out in a simulating coal-based grate-rotary kiln process. It is shown that preheated pellets possess much better reducibility than fired oxide pellets: 40 min are required for preheated pellets to reach over 90% metallization degree compared to 100 min for fired oxide pellets. The compressive strength of preheated pellets decreases dramatically at the earlier stage of reduction, climbs quickly after reducing for 30min and achieves a high value at the end of reduction. However, the compressive strength of metallized pellets from reducing of fired pellets is much lower, more cracks and fractures being formed. In the preheated pellets, crystallite of metal iron is coarse. In the oxide pellet, a large number of interconnected crystals of metal iron are formed inside pellets, and pellet structure is very compact.IntroductionDirectly reduced iron is an excellent feed in electric arc furnace (EAF) steelmaking, and possesses low tramp element content and steady component. It is generally preferred in the production of high quality steel [1-3]. Nearly 64.44 million tons of DRI were produced in 2009 over the world, over 80% of which were produced by gas-based processes, the left by coal-based processes. However, the DRI capacity was only 600 thousand tons in China in 2009. The EAF steel production has exceeded 40 million tons annually, and most of EAF operate on hot metal as feed [4]."

Jan 1, 2011

By A. Kontopoulos

The Olympias Mine in Northern Greece is producing an extremely refractory gold-bearing arsenical pyrite concentrate, containing on the average 41 3 S, 40 3 Fe, 10-12 3 As, 25 ppm Au and 35 ppm Ag. During the process selection stage, more than a dozen alternative technologies? were considered and an in-depth analysis was prepared for the three most promising, ie roasting, pressure oxidation and biological oxidation. Detailed capital and operating cost estimates were prepared, based, where appropriate, on laboratory and pilot-plant tests. A number of criteria was used for process evaluation and selection, including capital and operating costs; environmental impact, gold' recovery, stage of development, etc. Based on the above evaluation, the Sherritt Pressure Oxidation Process was finally selected. A detailed description of the process selection stage, supported with laboratory and pilot-plant test results on many of the processes considered, will be? presented.

Jan 1, 1989

By Adam J. Gesing

Eddy current separators are increasingly used by the auto shredder operators to produce higher grade of nonferrous metal concentrate for recycling. While this increases the unit price of the concentrate, metal losses through inefficient metal recovery quickly offset the price differential. We show how to optimize the eddy current separation system at the shredder to maximize mate- rial throughput, nonferrous metal recovery and grade of the nonferrous metal concentrate.

Jan 1, 1998

By P. K. N. Raghavan

This paper identifies potential technologies for Carbon dioxide abatement from the mining and metal industry with special reference to the Aluminium industry. Mine reclamation could contribute to this effort to successfully reach the greenhouse gas (GHG) emissions reduction commitments for a nation. An overview of GHG production by the mining and metal industry together with a review of principles used to set the context in which specific options for GHG reduction are described. Options for GHG reduction in the mining and metal industry include reforestation, Addition of soil amendments or neutralizing agents, CO2 capture and storage, initiatives towards energy reduction, waste heat recovery and alternative energy use. An analysis and quantification of the potential GHG reduction of potential carbon sinks and sequestration options for the mining and metal industry are provided. Cost estimates for different options are provided. The paper also identifies sources that could fund research regarding GHG reduction options. The paper concludes with recommendations.

Jan 1, 2011

By U .. C. Rojas, J .. C. Gomez

"Fire Refined Copper (EI Teniente Three Stars) has been produced at Caletones Smelter of Codelco Chile since almost the beginning of its operations.Due to changing features of the copper market, together with the targets on technical efficiency and productivity, it has become more and more relevant for copper industry to reach both, good final product quality and a proper environmental control.At present, copper refining process at Caletones Smelter takes place in two cylindrical tilting furnaces, where solid fluxes are injected through horizontal tuyeres into the molten bath. (Fig. N2 1)Solid reagents are pneumatically conveyed and injected into the liquid copper bath attaining excellent solid - liquid contact, so the impurities removal efficiencies are found to be high. Same injection tuyeres are used to introduce both oxidising agent (normal air) and reducing agent (reformed gas) into the molten bath. Air or nitrogen is used as conveying gas for solid reagents, depending on the process stage.This pap~r gives a fundamental description of the process and industrial results related to the injection of blend of sodium and calcium carbonates to remove arsenic and antimony, silica and granulated reverberatory slag to remove lead and a mixture of calcium carbonate and mineral coal to reduce the selenium content of the fire refined copper."

Jan 1, 1996

By Ramana G. Reddy, Yuxiang Peng

The long-term corrosion behavior of Haynes 230 (H230) alloy in MgCl2–KCl eutectic salt was evaluated at 1273 K for 500 h in Ni crucible in argon gas. The results showed H230 alloy has good corrosion resistance. In addition, corrosion was noted to occur by depletion of Cr, which was deposited on the Ni crucible. Based on the calculation of Gibbs energy of Ni-Cr alloy and exchange current density of Cr in MgCl2–KCl, the Tafel model was constructed to investigate the corrosion potential and rate. The galvanic corrosion can be explained as the predicted results were in agreement with the experimental data.

Mar 1, 2017

By Brian P. Atkin

The NISOMI-81 opaque mineral searcil and identification system uses quantitative color values (Pe, dA, y) and VHN as its determinative para-meters. The system is designed to operate on a Radio-Shack TRS-80 micro-computer which is interfaced to a motorised diffraction grating mono-chromator (WILSCAN). Using an interfaced monochromator/photometer combination a typical identification including the measurement of the photometer data on both specimen and standard, calculation of color values and a computer search takes about 6 minutes. The data file contains 240 minerals at present but can easily be expanded as reliable new data become available.

Jan 1, 1982

By S. Viswanathan, Q. Han, A. S. Sabau

"In spite of recent advances in the mathematical modeling of fluid dynamics for materials processing applications, no significant advances have been made in the numerical discretization of these equations. In this work, the application of two-step projection methods for the numerical simulation of interdendritic flows is discussed. Unlike previous methods, the methods presented here are constructed for the exact equations which are characterized by variable density and volumetric fraction of the liquid. The drag terms, which describe the momentum loss due to the flow around and through the dendrite structures, are treated implicitly. Numerical examples for shrinkage-induced flow during solidification of an Al-4.5% Cu alloy bar is used to illustrate the effectiveness of the proposed algorithm.IntroductionLiquid contraction during solidification plays an important role in the formation of casting defects such as shrinkage voids, microporosity, and macrosegregation. Owing to their importance, the study of transport processes during solidification have received considerable attention during the past years [1, 2]. By the use of volume-averaging techniques, the mass and momentum equations for flow through a stationary dendritic structure were derived [3]. By using the volume-averaging techniques for multi-phase systems, two-phase transport equations for solidification problems were derived [4]."

Jan 1, 1999

By M. Hamamoto, S. Tanaka, K. Noda

"Tamano Smelter or Hibi Kyodo Smelting Co. Ltd. is operating with the Tamano Type Flash Smelting Furnace method which is a flash smelting furnace without slag cleaning furnace but which can discharge a slag equivalent to that from the slag cleaning furnace and with the development or coke combustion technology which is the basis of this world's only one type flash smelting furnace process, the smelter exhibits a low operation cost under high productivity operation. Utilizing this experience and improving it we have developed and put to practice an operation guide system using a general purpose computer in order to further establish s stable operation. In this paper these improvements are described. Background of System DevelopmentWith the recent rapid progress of general purpose computers and improvements in their performance an environment for the use or computer in process simulation at low cost and simple operation has been established. If an accurate operation simulation can be done with the Tamano Type Flash Smelting Furnace the merits would be very great and thus we started development of the system. The official name of this system is Computer guide system for Coke Combustion in the T-FSF and taking the initial letters we call it CCCT. We aim to achieve operation with stable mane grade, temperature and slag loss in the furnace by maintaining the most suitable combustion conditions of concentrate and coke in the flash furnace with the assistance of CCCT to the flash smelting furnace operators.Through several production expansion projects clone in the past by oxygen enrichment the copper concentrate treatment quantity and matte grade have increased step by step as shown in Figure I. Following this increase the difference between the operation calculation results al the initial stage of coke combustion and the actual behavior of furnace (matte grade. temperature in the furnace. etc.) gradually became bigger. Further operation procedures taken by different operators against the same phenomenon were sometimes different depending on each individual, which from time to time caused the operation to become unstable. Prior to the development of the system we checked out thoroughly the weak points of operation calculation procedures which were in practice until that time. The results were analyzed and study was carried out to establish a most suitahle operation calculation procedure and finally we reached this system"

Jan 1, 2000

By Juárez T. Julio Cesar, Mendez R. Eliecer, Reyes P. Martín, Flores G. Mizraim Uriel, Teja R. Aislinn Michelle, Hernández C. Leticia, Reyes D. Iván Alejandro

The present study shows the characterization of a zinc concentrate collected at Hidalgo, Mexico, in order to identify its mineralogical species and to propose a leaching methodology for silver recovery. The results obtained by X-Ray Diffraction (XRD) show Sphalerite (ZnS) as the mineralogical matrix and silver into the specie proustite (Ag3AsS3). The techniques of Scanning Electron Microscopy-Energy Dispersive Microanalysis (SEM-EDS) and Polarized Optical Microscopy (POM) identified the presence of sulfides of Fe, Cu, Pb and Zn, in addition to silicates and feldspar. The proposed dissolution method of Ag(I) was carried out with [S2O3 2−] = 0.5 M and [NaOH] = 0.1 M to regulate the medium at pH = 9 for 12 h at 298 K. Oxidation of the concentrate was favored by injection of O2 to a partial pressure of 1 atm. Monitoring of the reaction was carried out by reading the [Ag] and [As] by AAS.

Mar 1, 2017

By Rina Kim

There are many factors which affect the gold cyanidation mechanism— mineral composition, free cyanide and dissolved oxygen (DO) concentrations, heavy metal additions, etc. This study combines electrochemistry and surface analysis methods to examine the effectiveness of the above factors on gold cyanidation process. Three gold ore samples were used in this study. Sample 1 was a pyrite concentrate, contained mercury and silver. Sample 2 also contained sulfide minerals, including galena. Sample 3 contained pyrite with sphalerite and galena. In the case of samples 1 and 2, the presence of heavy metals enhanced gold cyanidation kinetics, though the addition of higher DO was not effective on improving the kinetics. Sample 3 showed an opposite behavior: the kinetics was not enhanced by galena, because of its relatively small amount, however, the use of higher DO made improvement in the gold leaching kinetics, likely caused by iron species generated by pyrite oxidation.

By Qingyun Huang, Wei Lv, Junyi Xiang, Xuewei Lv, Chenguang Bai

The kinetics of iron leaching from ilmenite in hydrochloric acid solutions were investigated. The effects of pre-oxidation roasting, leaching temperature, and holding time on iron extraction rate were determined. The results obtained show that the extraction of iron is significantly enhanced by pre-oxidation roasting and increasing leaching temperature from 75 to 108 °C. The results of the kinetic analysis of the leaching data indicate that the reaction is controlled by diffusion through the product layer. The apparent activation energy for the extraction of iron has been calculated to be 62.5 and 55.1 kJ/mol for untreated and oxidized ilmenite, respectively.

Mar 1, 2018

By L. J. Davies

Refractories usage in furnaces for the extraction of nickel from both sulphides and lateritic ores is reviewed. Recent changes in raw materials and basic brick qualities developed to meet the increasing demands of existing and new processes are outlined. Examples of used brick examinations to establish mechanisms of wear are given. The importance of physical and chemical properties are discussed. The use of simulative laboratory testing to aid in refractories development and selection is described.

Jan 1, 1988

By Ross R. Bhappu

Anticipating a major power cost increase in 1990, Cyprus Copper Company decided to modernize the Miami Smelter at a cost of $92.5 million. The modernization project included the addition of an Isasmelt vessel for use as the primary copper smelter and the modification of the existing electric furnace to a slaglmatte separating vessel. The project was completed in June of 1992 and is currently operating at close to its design capacity. This paper provides a summary of the decision making process, a description of the project, a summary of start-up problems and solutions and the current status of the smelter operation.

Jan 1, 1994

By Isabela Leao Amaral da Silva, Felipe Perisse Duarte Lopes, Alice Barreto Bevitori, Sergio Neves Monteiro

"Jute fibers have in the past decades being investigated as possible reinforcement of polymer composites. However, information is still needed on the fiber interaction with a polymeric matrix for a complete evaluation of the capacity of load transference inside the composite. The present work investigated the interaction of jute fibers with polyester matrix by means of the critical length assessment through pullout tests. Tensile tests of polyester sockets embedded with different fiber lengths allowed the critical length to be determined and then the interface shear stress to be calculated. A relatively low interfacial strength was found, which indicates a weak adhesion between the ramie fiber and the polyester matrix. The SEM analysis of pulled out fibers corroborates this result.Introduction Natural fiber, mainly those lignocellulosic extracted from plants, have, in the past few decades, attracted the attention not only of scientists but also of industrial technologists of our society interested in their engineering applications. As it is well known, uses of natural fiber in clothes carpets, baskets, ropes and low cost construction roofing has existed from the beginning of our civilization. Today environmental and energy saving issues are motivating research works on new uses of lignocellulosic fibers in polymer composites [1-6]. Moreover, industrial application of lignocellulosic fiber composites are already in technological sectors such the automobile industry, packing and civil construction [7-9].In addition to environmental, economical and social benefits, some lignocellulosic fibers present specific properties that are comparable to those of other synthetic fiber used for polymer composite reinforcement. For instance, the specific strength (GPa.cm3/g) of curaua (1.31), sisal (0.92) and ramie (0.93) fibers, from results obtained with very thin diameters [10] are relatively closer to that of glass fiber E (1.33). Therefore, in principle, it would be technically justified to replace glass fiber, which is more expensive, toxic and represents a problem to the environment [ll], by a strong lignocellulosic fiber. However, serious drawbacks such non-uniform dimensions and heterogeneous properties [6] as well as the tendency to form aggregates during processing and incompatibility with a hydrophobic polymer matrix, reduce the potential of lignocellulosic fiber to be used as composite reinforcement [1-6]. In particular, a low interfacial strength causes a weak adhesion between the hydrophilic fiber and the polymer matrix."

Jan 1, 2011

By Rajesh Kumar Mishra

About 500,000 troy ounces of Platinum Group Metals (PGM) will be available for recycling each year from spent automobile catalytic converters in North America alone. Platinum Group Metals? from spent catalyst can be extracted by Hydrometallurgical, Pyrometallurgical or Gas Phase volatilization processes. This paper is a review and comparative study of various processes investigated for PGM extraction. A number of processes described in this paper have already been commercialized. The technical and environmental aspects of the important processes are discussed.

Jan 1, 1989

By Vinicius Alves Gomes, Jean Igor Margem, Thallis Cordeiro, Frederico Muylaert Margem, Roberto Faria Jr., Sergio Neves Monteiro, Marina Rangel Margem

Natural fibers are attracting the interest of engineering sectors owing to specific advantages such as lightweight and lower cost as well as for their inherent condition of being renewable, biodegradable, recyclable and neutral with respect to CO2 emission. In particular, the fiber extracted from the malva plant stem is nowadays recognized as one of the strongest lignocellulosic fibers. However, the thermal properties of the malva fibers have yet not been fully investigated. The present work had as its objective to investigate, by photoacoustic spectroscopy and photothermal techniques the thermal properties of diffusivity, specific heat capacity and conductivity of a pressed malva fibers sample. The results revealed that these fibers showed a superior thermal insulation capacity.

Jan 1, 2015

By S. Chama, P. Chishimba, Tina Chanda Phiri, J. Machona, S. Parirenyatwa, G. Kaluba, Y. R. S. Hara, D. M. Musowoya

The investigation focuses on leaching of copper (2 wt%), cobalt (0.5 wt%) and iron (2.4 wt%) from complex tailings material from the Democratic Republic of Congo. The highest recovery of copper and cobalt into the leach solution were 78 and 10%, respectively, under direct leaching with sulphuric acid. Higher recoveries (90% for copper and 96% for cobalt) were attained when the material was pre-reduced with coal for 1.5 h in the temperature range of 700–950 °C. The increased recoveries were due to metallisation of all the copper and cobalt which is in the silicate matrix. The effects of pre-reduction temperature and sample to carbon weight ratios were analysed and found to be important in; (i) achieving high recoveries of copper and cobalt and (ii) decreasing the amount of iron in the leach solution. The samples were characterised by atomic absorption spectroscopy and scanning electron microscopy (SEM) techniques.

Mar 1, 2017

By Priscilla Aki Mori de Hanashiro, Viviane Tavares de Moraes, Denise Crocce Romano Espinosa, Hugo Hashimoto

"The LCDs are used in televisions, calculators, mobile phones, computers (laptops and tablets), video games and other electronic devices. The advancements in technology make obsolete these devices, causing excessive disposal of LCDs and therefore decreasing life span of landfills. In this context, the LCDs from LED LCD TVs arise as an additional source of waste electrical and electronic equipment (WEEE). Thus, it is essential to develop LCDs recycling methods, beginning with the LCD characterization followed by displays processing, aiming the materials separation and using some Ore Treatment Techniques, and finally, the recovery of indium using acid leaching. The analysis methods that will be used in this work are: Fourier Transform Infrared (FT-IR) and Inductively Coupled Plasma Optical Emission Spectrometry (ICP-OES).IntroductionLiquid Crystal Display (LCD) technology is applied in modem televisions, calculators, mobile phones, computers and a wide range of electronic devices. It has replaced Cathode Ray Tube (CRT) technology as the most advantageous display product, due to lower electrical power consumption, size and weight reduction, and no radiation emission [ 1]. The constant improving of LCD screen technology reflects on its growing contribution to the amount of waste electrical and electronic equipment (WEEE): an estimated 50 million tons of WEEE are produced every year [2]. Once the most common method of its disposal are landfills, the LCD technology therefore became an environment issue [3].LCD structure is composed by components made by different materials. In order to develop a LCD recycling methodology that gives the right destination to these materials, a previous characterization stage is required. This characterization includes a disassembly process and material identification analysis. One of the LCD components is the screen, which is composed by polymeric and glass layers. The liquid crystal glass was the starting material of this study. It contains indium in the form of indium tin oxide (ITO) film. This ITO film is deposited in the glass by a sputtering process and acts as the electrode material [4,5]. It has in its composition 90% ofln203 and 10% ofSn02 [6]."

Jan 1, 2014