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By T. Shungu, N. Vermaut

The various copper-cobalt ores mined by Gecamines, together with typical plant applications and results, are briefly described. Intensive laboratory investigations have been undertaken in recent years to improve the metallurgical performances of the various concentrators. As a result of these tests, it was shown that the flotation of the siliceous oxide ores could be improved by increasing the efficiency of the palm oil collector (energetic conditioning, chemical emulsifier, petroleum sulfonate addition) and by varying the froth depth in the cells. A new flowsheet incorporating these modifications and a regrinding stage has been approved for the rehabilitation of the Kolwezi concentrator. For what affects dolomitic oxide ores, hydroxamates were tested as secondary collectors and, based on successful laboratory results, plant trials were run but failed due to excessive frothing. In other plant tests, xanthates were replaced by a xanthate- fatty acid mixture; plant trials over more than one year proved successful for copper, but not for cobalt. Mercaptans were tested as secondary collectors for the sulfides flotation from sulfide or mixed oxide-sulfide ores; laboratory results proved successful but, to date, no plant test has been run.

Jan 1, 1987

By Wilfred M. Kenan

The relationship of various genetic classifications of graphite, their properties and general applications are reviewed. The classifications being amorphous, flake, high crystalline (vein) primary synthetic graphite and secondary graphite. The properties discussed are size, carbon, sulfur, ash content, general chemical analysis and degree of graphitization of each type. The major sources for natural and synthetic graphite powders are discussed in addition to factors which govern the cost as well as the supply. The economics of graphite are basically determined by the consumer and the end application. Graphite is a strategic mineral and is on the government stockpile list.

Jan 1, 1984

By Bernard J. Scheiner, R. J. Wesely, Cy E. Jordan, A. D. Zunkel, Gary M. Wilemon

The U.S. Bureau of Mines has investigated leaching of off-grade western United States phosphate deposits using sulfuric acid (H2SO4) in the presence of methanol. A combination of ore grinding followed by sulfuric acid in methanol leaching extracted over 80 pct of the phosphate. This leaching technique significantly limited the dissolution of iron, aluminum, and magnesium impurities and produced a phosphoric acid that was well within the desired limits for these impurities. The dissolution rate of phosphate rock in the sulfuric acid methanol system was significantly slower than the conventional aqueous sulfuric acid dissolution. Initially dissolution of the phosphate particle was controlled by the amount of surface area available to the sulfuric acid reactant. After about an hour of leaching, phosphate dissolution was slowed almost to a stop, limited by the rate of ion diffusion through the calcium sulfate barrier layer surrounding the unreacted phosphate particle. Consequently, the ore was ground below 38-pm to increase the particle surface area available and improve the overall dissolution kinetics and extraction. In addition, the sulfuric acid was slowly metered into the reactor to prevent any excess heat from the mixing of acid with the methanol from simulating the formation of methyl sulfates. The formation of methyl sulfate ultimately lowered the overall phosphate extraction by exhausting the supply of available sulfate ions for the dissolution reaction. Subsequent evaporation of the methanol from the product acid decomposed the methyl sulfates leaving undesirable sulfate ions in the product acid. Slow acid addition to the reactor provided high phosphate extraction and limited the amount of sulfate in the final product acid.

Jan 1, 1993

By R. C. Fox

The geophysical aspect of reconnaissance marks the beginning of extensive computer applications supporting development of a mine. Although there are some storage and retrieval applications in geology, and some statistical analysis in geochemistry, large-scale compilation, reduction, and interpretation of mineral resource data are initiated in reconnaissance geophysics. The reasons for this fact are quite simple. Geophysics is oriented toward quantitative evaluation of areas of interest, and methods of data collection are automated to the extent that large amounts of analog and digital information are recorded. The large volume of data must be interpreted in a reasonable time. Furthermore, some modeling problems involving complex numerical solutions could not be attempted without the computer. Therefore, the computer is essential to the success of an exploration project using geophysics. For example, aeromagnetics is a common technique for reconnaissance examination of areas associated with sulfide systems and porphyry deposits. An area covering 161 X 161 km (100 X 100 miles) may be flown with a 1.6-km (1-mile) line spacing yielding 10,000 line miles (16,093 km) of data. If only 10 measurements are recorded per mile, 100,000 data points, including location and magnetic field intensity, must be reduced and stored for quantitative interpretation. Computer applications often represent a significant investment in manpower and hardware. It is desirable, therefore, to initiate an engineering approach to the application of computers to geophysics. By this it is meant that computer programs and systems should be formulated, developed, and implemented in a disciplined manner such that their usage is dependent only on the application and not on the individual doing the programming. In other words, computer application, development, and usage should evolve beyond the personal gadget phase to an important applied technology. Geophysics has evolved over the past two decades in a course parallel to computer hardware development. During the sixties, the computer became large enough and fast enough that complex models required by geophysics could be solved. Automation also relieved the geophysicist from routine manual calculations. During the seventies, computing power in¬creased and applications expanded from two-dimensional problems to three-dimensional modeling. Moving into the eighties, as computer hardware costs will significantly decrease, the major expense of computing will be the manpower required to develop, implement, and use an application; therefore, improved programming techniques and applications software engineering methods will be used to optimize and preserve this investment. This chapter presents a general overview of computer methods in geophysical reconnaissance; it is divided into two parts: geophysical methodology and software engineering.

Jan 1, 1979

By Robert M. Belesky, H. R. Hardy

A methodology to detect the presence and monitor the stability of shallow cavities is presented in this paper. The approach incorporates surface-wave seismic and acoustic emission/microseismic (AEIMS) techniques. Application of tomography to the seismic data is made to enhance the ability to locate cavities. Zonal and hit-sequence location techniques are introduced into AE/MS monitoring schemes. These source location techniques simplify the analytical procedure yet still provide sufficient information regarding the region of AE/MS activity. The concept of unique velocity data for conventional, least-squares, source location routines is discussed. A hypothetical case utilizing the algorithm is presented. The method described has been successful based on preliminary studies. Areas of current and future research are identified.

Jan 1, 1986

By U. E. Paakkinen

Progress in computer control of flotation circuits has developed parallel with advances in reliability of on-stream X-ray analysis (Cooper, 1976). Attainment of acceptable results with X-ray fluorescence analysis over the past ten years has led to application of computer control in more than 30 concentrators. Gains in applying flotation control also have given incentive to improving measurement and control devices for other essential functions in control systems. At the same time, advancing technology has made available computer systems having characteristics practical and economical for the physical environments of concentrators and ore processing plants. Benefits from flotation control have centered on increased efficiency in mineral separations, derived by stabilizing circuit operation subject to changing ore characteristics. The gains have been most evident in processing complex ores for multiple concentrate products. In many cases, particularly when coupled with grinding control, the economic results from on-line control have been substantial compared to investments in monitoring and control equipment.

Jan 1, 1979

By Pasi Latva-Pukkila

Underground rock drilling has gone through intense development during the last 25 years. Mechanization and hydraulics have greatly increased the efficiency of drilling and improved the environment of the drill operator. As the total economy has become more and more important, the development has resulted in greater overall economy in drilling. The latest evolution step is computerization of drilling equipment. Computerization has been applied to tunnelling jumbos, long- hole drilling rigs and bolting rigs. With today's technology computerization is the natural way to increase capacity and productivity of the drilling process. However, it is still impractical to implement total "robotic" drilling. In computerized drilling the operator's role continues to be vital in controlling the drilling process and in analyzing the effect of individual parameters on the whole excavation process. Today this is called "CAD" - Computer Aided Drilling.

Jan 1, 1989

By George Bárdossy

Most of the bauxite deposits in Europe belong to the karst type. They are located mainly ill Southern Europe along the Mediterranean Sea and in the Ural Mountains. Lateritic bauxite deposits occur on the Russian Platform, in Poland, Northern Ireland and in Turkey. Tikhvin-type deposits arc found on the Russian Platform. Bauxite formation in Europe started in the Middle Devonian. The main bauxite forming period was the Upper Cretaceous. Very few bauxites are younger than Eocene. Most deposits are covered by overburden of up to 1000 m. Prospecting is carried out by drilling. Several geophysical methods are used to detect the hidden deposits. Geostatistical methods were introduced in several countries for evaluation of the reserves and the geometry of the deposits. Data on bauxite production are given for 1982 and since the beginning of mining in Europe.

Jan 1, 1984

By Shosei Serata

In the past, salt cavities for storage of liquid and gaseous fuels have been developed and operated using practical experience as a guide rather than rock mechanics principles and practices. Although many salt cavities are still operating satisfactorily. some of them are beginning to show various problems associated with long-term deterioration of the cavities. This paper describes a major breakthrough in the rock mechanics design of solution cavities which is the development and application of the REM computer simulation system. From the computer simulation analysis, the long-term deterioration process of cavities can be related to the basic parameters of rock mechanics design and the storage operations. The computer simulation system is also used for optimizing cavity design and operational specifications. This optimization technique is explained by its application to the three basic storage systems: 1) open dry storage system for liquids and solids 2) open wet storage system for liquids 3) pressurized storage system for gases, liquids and solids The effectiveness of the optimization technique is illustrated with some field examples by showing the direct interaction between the computer simulation system and field data of a test well including tectonic stress conditions, material property coefficients and geological anomalies.

Jan 1, 1974

By John R. Thalimer

For the past four years the U.S. Bureau of Mines has investigated the early detection of insulation failure in squirrel cage induction motors. Data modeling techniques based on values calculated from a motor's voltage and current phasors were used to produce a pair of polynomial equations that calculate a motor's insulation leakage current and power. This paper describes a prototype system using these models that monitors six motors on a continuous miner for insulation leakage in order to anticipate insulation failure. The system consists of a motor-data system for each motor on the machine, a control computer located some ' distance from the miner, and a serial bus to interconnect these items. Each motor-data system consists of an analog interface to the motor's voltages and currents, a single-board computer that reads digitized data and calculates voltage and current phasors, and a bus node that interfaces the single-board computer with the serial bus. The control computer can request and receive phasor data from any motor-data system on the bus. Using models developed at the Bureau, the control computer calculates and displays two deterioration values for each motor, one for leakage current and the other for leakage power. These values are then stored into a database from which the user can display them over time.

Jan 1, 1992

By D. W. Park

Underground room-and-pillar mining operations in the Warrior Coal Field in Alabama frequently suffer instability due to soft floor and thinly-laminated immediate roof. The investigation covered by this paper concerns a mine that was experiencing ground-control problems with weak floor conditions. Four hundred ft above the presently producing seam, another seam has been mined out. Several roof falls occurred locally, and as much as two ft of floor heaves have been experienced. The paper presents the results of comprehensive analysis conducted on floor heave, roof sagging, and the influence of the mined-out seam using instrumentation and numerical analysis.

Jan 1, 1991

By Roland C. Walker

Traditional headed rebar has existed in the mining industry as a ground support product for many years. The head of a rebar bolt is most commonly produced by hot upset die forging. Upset die forging produces a rugged, simple head that performs well. Certain elements of the head must comply with regulatory standards, such as ASTM F432-95, which offers a standard test procedure to ensure quality of the product. The head style produced by all major manufacturers has been optimized to reduce manufacturing costs, provide greater miner safety and provide an excellent performing product. Observations were made in some mines of heads failing under in-situ loading. These observations could not be replicated according to the ASTM testing method. This paper highlights the problem and how a solution was developed. The development includes pictures of in-situ failures from the underground operations, laboratory replication tests indicating how this loading occurs, and then the use of this calibrated test method to validate the new design created.

Jan 1, 2009

By Wayne Stange

Due to the availability of user-friendly microcomputer based packages, the use of simulation is increasing.. Users have however encountered problems inherent to the structure of sequential-modular simulators. These are the difficulties associated with estimating parameters for arbitrary' models and the solution of design and optimization problems. The implementation of an optimization routine in the simulator MicroSim has facilitated the solution of such problems. The literature indicates that more efficient numerical techniques for solving optimization problems than those presently used in MicroSim are available. These techniques, together with user-interfaces which allow such problems to be specified easily by users, will result in the development of simulators much more powerful than existing ones.

Jan 1, 1989

By M. H. Basiri

Crude oil, as a central commercial commodity, is tied to major economic activities in all nations. Also its price fluctuation plays a significant role in global political and economic situation, as a change in the price invariably affects the cost of other goods and services. Therefore reliable forecasts of the price of oil are interest for a wide range of applications. Several approaches have been proposed over the past few years. These may divide into three categories; artificial intelligent, statistical techniques and hybrid methods. The neuro-fuzzy is one of the sub divisions of hybrid method, containing neural network and fuzzy techniques. In this paper a novel forecasting model based on adaptive neuro-fuzzy inference (ANFIS) is proposed to predict monthly crude oil price. To be able to train and test the model, the statistical data from 1990 to 2010, was obtained from West Texas Intermediate oil prices. The results are compared with a multi criteria regression analysis, it is demonstrated that the neuro-fuzzy lead an accurate and more promising forecast.

Jan 1, 2012

By E. M. Frizzell

Decisions affecting ground control design require detailed knowledge of roof rock geology. This is especially true when weak roof materials and anomalies create hazardous conditions and. if not properly supported, result in roof falls. The U.S. Bureau of Mines has developed a system to evaluate geological conditions by using a roof drill that will provide an estimate of the compressive strength of the roof rock in real time. Through the use of sensors and a microcomputer on the roof drill critical drilling parameters can be interpreted and analyzed almost instantaneously, making it possible to inform an operator of hazardous roof conditions such as voids and changes in strata during the drilling process. Geotechnical data can be downloaded to a portable semiconductor memory device, which is brought to the surface so that data can be directly accessed with a personal computer for further analysis. Results from field tests are presented.

Jan 1, 1992

By Randall E. Brown

Irrigation simulates a climate change so that crops can be grown that otherwise would not thrive. The abundant sunshine and warm weather of many arid regions induces a rate of growth in excess of that in cooler, moister regions. Hence, the arid part of eastern Washington, traversed by the Columbia River, is admirably suited to irrigation. The Pasco Basin lies in south-central Washington at the south end of the Columbia Basin Irrigation Project of the U.S. Bureau of Reclamation. The Basin, because it lies in the rain shadow of the Cascade Mountains, receives only 6 to 10 inches of precipitation a year with somewhat greater amounts, commonly as snow, on the higher hills. Recent extremes included 3 inches of precipitation from August 1967 to August 1968, and 12 inches in the succeeding "12 months. Most of the precipitation falls during winter. If it were to fall in summer or were evenly distributed throughout the year, evaporation rates probably would produce a true desert.

Jan 1, 1971

By S. Henley

There is much in common between the requirements of open-pit mining and quarrying operations. Both involve the extraction of large volumes of material from surface excavations. The principal differences are of degree: open-pit mining of materials such as coal or gold generally involves the extraction of only small volumes of 'mineral' and large volumes of waste-they are operations with very high stripping ratios, and are made viable only because of the high unit value of the extracted mineral. In quarrying operations, the unit value of the mineral - sand, aggregate, limestone, or clay - is much lower, but stripping ration Are also lower. Thus the same techniques of geological modelling, reserve estimation, and pit planning are applicable, as is shown in two examples from the British quarrying industry. In each case, a primary requirement is the definition of production volume or tonnage. Sometimes, this need may be addressed simply by the use of a survey data processing package. However, in other cases, such as the two examples addressed in this paper, of sand and clay quarries, detailed assessment of the variation of mineral grades is a vital part of the exercise, and simple volumetric modelling cannot in itself be sufficient. In these cases, a block model approach using simple logical and numerical post-processing is also required to obtain required parameters for commercial classification of the products to be extracted. Pit designs themselves may be optimised by use of algorithms such as Lerchs-Grossmann, but the value of mineral produced can be dependent on factors other than its grade in any one part of a single pit, and the 'optimised' pit itself must be considered only a good sub-optimal. Given the right degree of healthy skepticism, and a software package with sufficient flexibility to be adapted readily to the rather different requirements of the quarrying industry, there is no reason why the quarrying industry should not benefit from the many years of investment in mining software technology.

Jan 1, 1989

By Jed H. (Original by) Mosgrove

Good mine ventilation starts at the drawing board. A coal mine will either be adequately ventilated or not, depending upon how good a job was done in the planning. Poor planning will not only result in inadequate ventilation, but may also lead to low productivity. A mine foreman cannot achieve high productivity while trying to maintain 4.2 ma/s (9000 cfm) of air at his last open crosscut.

Jan 1, 1981

By John Ralston, Rossen Sedev, Nicola Richards, Quinn Anthony, Geoffrey Reynolds

Derivatised 2,4-diketopyrimidine groups have been anchored to planar gold surfaces as self¬-assembled monolayers (SAMs) for chemical and photochemical studies. Three derivatives, 5-methyluracil (thymine), 5-trifluoromethyluracil and 5-nitrouracil, were chosen for the specific moiety present at position C-5, which can exert strong or weak inductive effects on the adjacent aromatic ring. The measured acidity constants decrease from 5-methyluracil to 5-nitrouracil as the inductive properties of the group at C-5 position increase. When grafted to the surface the acidity constants increase, albeit still adhering to the expected inductive trend. The functionality also exerts an influence on the surface wetting properties. Surface wettabilities indicate that the orientation of the pyrimidine groups at the surface occurs so that the C-5 position has a direct effect upon the surface chemistry. Upon dimerisation the surface contact angles increase signifi¬cantly. At pH 11 the contact angle changes reflect that the dimer has a higher pKa than the monomer. The monomer surface is deprotonated at this pH while the dimer surface is partially deprotonated, leading to changes in contact angle of up to 22 degrees. Large changes in contact angle were observed for 5-nitrouracil which were independent of surface charge and were appar¬ently due to conformational changes alone. Electrowetting of three fluoropolymer surfaces by electrolyte solutions was studied with the sessile drop method. The electrowetting curve (contact angle/potential) is analogous to the elec¬trocapillary curve (surface tension/potential) and may be described by a combination of the Young and Lippmann equations. We demonstrate that for some specific surfaces a systematic deviation occurs at positive potentials. This departure is attributed to double layer effects, namely the adsorption of hydroxide and halide anions. pH, ionic strength and polymer composi¬tion can all influence electrowetting behaviour.

Jan 1, 2003

By N. Santa, V. Salinas

"Printed circuit boards are potentially recyclable materials. Developing suitable methodologies for proper disposal and better utilization, brings major environmental and economic benefits. A methodology for copper recovery using heat treatment before conventional leaching is carried out. A comparison between conventional methodology and the one that includes incineration treatment is presented. It concludes about results and differences in terms of the percentage of copper leached over time. INTRODUCTION The rapid proliferation of electronic devices in the past two decades, has forced researchers to find a solution for one of the most toxic and hazardous materials, the printed circuit boards (Ghosh et al, 2015). For this, countless techniques have been developed, the methodologies includes hydrometallurgy, pirometallurgy, electrometallurgy or a combination between all of them. The amount of precious and base metals in its composition are very attractive and usable to implement methodologies that allow maximum recovery and recycling. This subject has been extensively studied and researched in order to provide solutions to the great problems generated by incorrect final disposal of this waste. Over 150 articles have been widely published in the last 15 years, covering large areas such as characterization of discarded printed circuit boards, health risks associated with processing and different routes of recycling have been analyzed to provide an overview understanding this issue (Ghosh et al, 2015). (Oh et al, 2003) performed a selective leaching of valuable metals from waste printed circuit boards by size reduction, magnetic and electrostatic separation, also leaching with sulfuric acid and hydrogen peroxide, achieving 95 \% of copper extraction. (Chaverra Arias, 2014) proposed a similar methodology to extract copper from electrical and electronic waste, performing similar processes and applying metallic copper electrowining as well as copper oxychloride precipitation. (Silvas et al, 2015) used hydrometallurgical processes for recycling printed circuit boards applying physical processing and copper extraction by selective leaching. (Kumar et al. 2014) conducted a leaching of metals from waste printed circuit boards using sulfuric and nitric acids. Also there have been proposed various methods for recovery of different metals including applying multiple metallurgical techniques that involve both living organisms and high temperature processes such as pyrometallurgical. The printed circuit boards are a very important source of copper, according to several authors mentioned above, the amount of copper on a printed circuit board can reach about 20 \%, because copper is responsible of establishing a conductive layer that will enable the connection between electrical and electronic components. This document proposes a methodology for recycling printed circuit boards and extract copper by selective leaching. The process that is carried out consist in a preliminary characterization and mechanical separation which will condition the material for further hydrometallurgical treatment that includes leaching in nitric acid media 3M."

Jan 1, 2017