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By T. E. Wilson

An exploration bore core sample of coal ought to be reduced from its original cylindrical form to a particle size distribution and particle composition that reflects, insofar as possible, a process stream of? raw? coal it represents. Often, coal cores are reduced with a laboratory crushing machine, the product of which may not match the raw coal size distribution or size fraction composition. This study employs drop-shatter impact breakage followed by dry batch tumbling in a steel cylinder rotated about its transverse axis in order to characterize the core material in terms of first-order and zeroth-order breakage rate constants. These are indices of the propensity of the coal to degrade during excavation and handling. Initial drop-shatter and dry tumbling tests were done with synthetic cores, to reduce material variables and . conserve difficult-to-obtain coal cores.? Cores of three different coal beds --Illinois No.6, Upper Freeport, and Pocahontas No. 5 -were subjected to drop-shatter and dry batch tumbling tests to determine breakage response. Comparison of coal preparation plant feed with a crushed bore core and a bore core prepared by drop-shatter and tumbling (all from the same Illinois No.6 coal mining property) indicated that the size distribution and size fraction composition of the drop-shattered/tumbled core more closely resembled the plant feed than the crushed core.

Jan 1, 1998

By Jin Zhao, Weijie Wei, Jinwang Zhang, Xiaohang Wan, Shengli Yang

Reasonable mining-retention ratio (ratio of room width to pillar width) is vital to recovery rate and stope stability in underground mining of solid potassium salt deposits. Based on the engineering background of a solid underground potassium salt mine in Khammouan Province, characteristics of the plastic zone of the pillar, and the variation of recovery rate and stope stability under different mining-retention ratio conditions are discussed. The results show that compared with current room width (8 m) and pillar width (10 m), the optimization method of improvement of stope stability. The research results are helpful to recover as much solid potash resources as possible under the premise of ensuring the stability of stope.

Jun 25, 2024

By Gordon T. Austin

Garnet is the general name for a family of complex silicate minerals having similar physical properties and crystallizing in the isometric (cubic) system. All garnets have the same general chemical formula but vary greatly in chemical composition. The name garnet is derived from the Latin word granatus, meaning like a grain, which refers to the mode of occurrence wherein crystals resemble grains or seeds embedded in the matrix. GEOLOGY Mineralogy Chemical Properties: The general formula for garnet is A3B2(SiO4)3, whereas A can be calcium, magnesium, ferrous iron, or manganese, and B can be aluminum. ferric iron, or chromium, or rarely titanium. The formulas and names of common garnet species are: [ ] Almandite and almandite-pyrope solid solution garnets are the best abrasive types, but andradite, grossularite, and pyrope also are used. All species of garnet have been used as gemstones. The structure of garnet consists essentially of isolated SiO, tetrahedra connected by oxygen-cation-oxygen bonds through the distinct A and B group cation sites. Within this structure magnesium, ferrous iron, and manganese easily interchange and substitute for each other in the A cation position, and calcium does so less readily. Additionally, aluminum, femc iron, and chromium substitute for each other to a limited extent in the B cation position. This ability to substitute or exchange ions without changing the crystal structure is called isomorphism, and garnet is one of the finest examples of a isomorphous series. Because of this isomorphism there is complete solid solution between certain garnet species but not between others. Fig. 1 illustrates these solid solution relationships. Some rare species of garnet are known that illustrate the wide range of cation substitution that the garnet crystal structure can accommodate. They include: [ ] These rare species are not of interest for industrial applications, but can be of interest to mineralogists and the gem industry. Physical Properties: Garnet displays the greatest variety of color of any industrial mineral. Garnets have been found in all colors except blue. For example, grossularite can be colorless, white, gray, yellow, yellowish green, various shades of green, brown, pink, reddish, or black. Andradite garnet can be yellow- green, green, greenish brown, orangy yellow, brown, grayish black or black. Pyrope is commonly purplish red, pinkish red, orangy red, crimson, or dark red; and almandite is deep red, brownish red, brownish black or violet-red. Spessartite garnet can be red, reddish orange, orange, yellow-brown, reddish brown, or blackish brown. A few garnets exhibit a color-change phenomenon. They are one color when viewed in natural light and another color when viewed in incandescent light. Because of the great variation in color of garnet within each species and similarities in color between garnets of different species it is recommended that garnet identification not be based on color alone. The Mohs hardness of garnet varies from 6.5 to 9.0. Grossularite and uvarovite have a hardness of 6.5 to 7.5; andradite is 6.5 to 7.0; and pyrope, almandite, and spessartite are 7.0 to 7.5 in hardness. There are reports of almandite having a hardness of between 8.0 and 9.0. As with hardness, the specific gravity of garnet varies considerably. The specific gravity may be as low as 3.2 or as high as 4.3 depending on chemical composition. Garnet crystallizes in the isometric system with rhombic dodecahedra and trapezohedra the most common forms. Crystals also form in combinations of dodecahedra and trapezohedra or either of these in combination with hexoctahedra. Crystals can have cubic or octahedral faces, but these are rare. Under favorable conditions of formation garnet will crystalize in nearly perfect forms that rival study models. Garnet also forms as irregular blebs, grains, knots, or masses, with or without distinguishable crystal faces, and as coarse- or fine-grained granular masses that appear to be totally lacking in crystal form. The fracture of garnet also shows great variation. In some garnets, particularly those that are well crystallized and glassy in appearance, the fracture is subconchoidal to conchoidal. Other, more poorly crystallized garnets exhibit a fracture that can only be described as uneven. Garnet occasionally has an indistinct dodecahedral cleavage. Certain species of garnet from specific locations have a pronounced laminated structure consisting of planes of weakness along which parting takes place. This parting may resemble cleavage, but since it is mechanical and not related to crystal structure it is not true cleavage. The optical properties of garnet are sensitive to even small changes in chemical composition or strain in the crystal structure. For this reason each species does not have a single index of re- fraction (IR) but has a range of 1Rs. Uvarovite in its pure form should have an IR of 1.870, but in nature samples vary from 1.74

Jan 1, 1994

By L. A. Roe

The year 1867 marks the first year of commercial production of phosphate rock in the United States. South Carolina produced almost all of the domestic output of mineral phosphate until phosphate mining began in Florida in 1888. During the period 1868 to 1949 the total marketed production of domestic phosphate rock was about 186 million long tons of which 71.5 percent was produced in Florida, 18 percent in Tennessee and 7 percent in South Carolina (1). From 1949 through 1960, Florida phosphate rock production has ranged Prom 71 to 77 percent of the total domestic production. Since three-fourths of the domestic phosphate production is from the Florida field, and since most of the phosphate from the Tennessee and Western fields is not processed, but used directly as electric furnace burden, this paper will concern itself almost entirely with water requirements for mining and processing ore from Florida. Figure 1 summarizes phosphate rock production for Florida vs. total United States production over the period 1947-1960.

Jan 1, 1962

By C. N. Greene

I am sure it is obvious to all of you that a complete program of casualty and property insurance is as necessary for any tunneling contractor as it is for anyone else involved in trade in the United States today. Going beyond those general undefined terms, there are many areas that need specific attention, particularly for contractors, regardless of size. WORKERS' COMPENSATION Workers' Compensation is mandatory in all states and the District of Columbia. In most of the states, private insurance provides this coverage. In a few states, the state operates Workers' Compensation funds, some of which are competitive with the private sector and others are operated on a monopolistic basis. Under a monopolistic setup, you have no choice, you must buy coverage from the state. Self insurance of the Workers' Compensation risk is also an alternative in most jurisdictions. With a contractor operating only in the U.S., the coverage extensions are few in number. If your work brings you anywhere near navigable waterways or land extensions thereof, you should have both U. S. Longshoreman and Harborworkers' coverage, as well as Employer's Liability coverage for the master or members of the crew of a vessel.

Jan 1, 1983

By K. N. Han

Coal is becoming increasingly important as a major energy source in the face of the world's depleting energy mainly based on oil reserves. Coal is by far the most abundant fossil fuel both in the United States and abroad. Currently, because of increased mine mechanization, the fineness of preparation plant feed is increasing. Further, in the future as the grade of coal diminishes and the sulfur content increases, upgrading preparation of coal is very important. Because the density of coal is less than that of rock materials that occur as impurities, coal is separated from such waste largely by gravity-controlled processes for particle size between 5 inches and 28 mesh. If the size of coal particles is below 28 mesh, froth flotation is a good method for upgrading fine coal. Previously, numerous investigators have tried to upgrade coal values by froth flotation(1-16) and have achieved moderate success. However, the recovery and grade of coals in the concentrates are not always satisfactory, especially when the particle size is small. In general, when the size of coal is below 100 mesh, the above methods suffer from poor grade and low recovery. The reason for this is that as size decreases, the effects of gravity diminish, and other forces take effect.

Jan 1, 1985

By Henry H. Roos

NTRODUCTION In the mining industry, a "drill jumbo" is a drilling unit equipped with one or more rock drills and mounted on a mechanical conveyance. Jumbos range from single¬drill ring drills mounted on simple steel skids to sophisti¬cated multiple-drill units mounted on diesel engine powered carriers and equipped with automatic controls and sound-abatement cabs. Individual types of jumbos usually are designed for specific tasks such as fan drilling in sublevel caving operations. Some units, such as development jumbos, can be utilized for several functions in addition to their normal applications, e.g., for production drilling in room-and-pillar operations, stoping in cut-and-fill mining, etc. Mine operators can purchase individual components from manufacturers, assembling these components into a jumbo suitable for specific conditions. However, this requires that mine personnel have good engineering and mechanical abilities. Although manufacturers of jumbos maintain facilities for designing machines to meet con¬ditions created by new mining methods and unusual ap¬plications, the cost of the engineering and experimental work for new types of jumbos should be evaluated in terms of both costs and benefits; it may be advantageous to plan the mining operation so that existing and proven units can be utilized. GENERAL SELECTION CRITERIA Since the operating conditions vary in underground mines, the design of a jumbo must be selected to cope with the individual characteristics of the mine. The necessary considerations include access space into the working areas, grades expected to be encountered, radii of the curves, ambient temperatures, the characteristics of the rock, the acidity or alkalinity (pH rating) of the mine water, etc. Access to Mine Workings The mine workings must be accessible to the selected jumbo. Frequently, a jumbo must be disassembled at least partially to pass through the mine shafts. There¬fore, a bolted construction allowing disassembly into pieces of suitable size and weight is desirable in most applications. Type of Undercarriage Generally, a crawler-type undercarriage should not be used in trackless mines having acidic mine water. The acidic water causes an electrolytic action between the individual crawler parts and causes rapid corrosion and early failures. Propulsion A two-wheel drive on a pneumatic-tired jumbo is marginal for grades exceeding 12%. A four-wheel drive unit with good weight distribution is capable of operat¬ing on grades of up to 35%. At least 30% of the gross vehicle weight (GVW) should be carried on the steering axle; otherwise, the steering tires may not have sufficient traction on loose road surfaces and may "plow" instead of steer. To assure stable operation in mines with steep grades, the height of the center of gravity of the jumbo should be considered. It should not make the unit prone to rolling over on the steep grades that may be encoun¬tered. Turning Ability In confined working areas, a skid-steering or crawler unit has the best maneuverability. An articulated carrier is preferable when base-rotated parallel booms are being utilized. A rigid-frame jumbo with automotive steering is compact and economical, having lower maintenance requirements than the other two types. However, the turning radius of a rigid-frame unit is wider than either the skid-steering or articulated units, and this wider turning radius may be detrimental in mines with narrow drifts. JUMBO COMPONENTS Rail Undercarriages A mine with a rail-transportation system generally utilizes drill jumbos that are mounted on rail-type under¬carriages. With a light load and good weight distribu¬tion, this carrier may consist of a simple two-axle four-wheel platform onto which the boom-mounting brackets are attached. As the depth of the round and the penetration rates increase, the weight of the equip¬ment installed on the chassis also increases. The greatest problem with a heavy overhung load is balancing the carrier; a three-boom unit may require a substantial amount of counterweighting to maintain an acceptable 70% to 30% axle-load balance. Although lengthening the wheelbase helps balance the unit, a long wheelbase increases the turning radius, often creating problems on curves and sometimes requiring a swivel truck-type chassis. A good rule of thumb for a simple four-wheel undercarriage is to maintain a wheelbase length to track gage-width ratio that does not exceed 2.5 to 1.0. For a larger ratio, a swivel truck should be utilized. Swing-out outriggers or roof jacks help keep a jumbo in place during the drilling cycle. Usually, a rail-mounted jumbo is not self-propelled. Instead, it is maneuvered into place by a locomotive. Occasionally, several headings are being advanced in close proximity, and a self-propelled jumbo is con¬venient. In electrified mines, such a jumbo utilizes conventional battery-powered traction gear; in dieselized mines, hydrostatic drive components offer good flexi¬bility. The tractive power requirements of a typical rail jumbo may be calculated from the formula: HP = [(RR + GR) X Sl/[33,000 X Em X Eh]

Jan 1, 1982

By Richard Kojo Gabah

Western mining companies are entering an African critical minerals market where access is harder to secure, risk is being priced more sharply, and execution advantages are increasingly decisive. The continent holds significant reserves and production potential of cobalt, lithium, copper, graphite, manganese and rare earths critical to the energy transition, yet Chinese-aligned capital has built a structural edge in access and execution speed. Simply signing narrow offtake agreements to buy output is no longer sufficient. Western firms win when they convert quality orebodies into bankable projects by reducing aboveground risk faster than competitors through integrated infrastructure access, durable fiscal alignment, and credible local value creation. Western mining companies will break into Africa by pairing capital with partnership, building corridors enabling infrastructure and power, designing credible value addition pathways and operating in a way that is politically durable through transparency, community benefit and fiscal terms that share upside in commodity upcycles. This feature article offers a practical playbook for mining executives and investors. The core argument is straightforward. Winning in Africa requires competing on the full system around the mine. Corridors and power, processing pathways, contract durability, community benefit and regulatory execution are now decisive variables in project valuation and capital access.

Mar 1, 2026

By T. Lee

Ongoing economic success for mining companies is dramatically enhanced when they really know what they are harvesting, such that they can accurately forecast their head grades for any time period in excess of a month. This is an uncommon experience. It is a very common scenario for resource/reserve estimates to overstate the concentration (grade). Grade is a critical input of revenue, and hence, it is to cashflow projections. With the current direction being taken by the legal climate, it is no longer adequate for directors to accept the resource/reserve estimates of experts at face value. This is because resource/reserve estimates are the foundation of primary mineral economic decisions. Directors of mining assets need to undertake their own due diligence analysis of these estimates, in the best interest of themselves, and the company's shareholders. In the light of the industry's past achievements, this is quite a challenge. This paper suggests a set of new objective tools for directors to undertake an overview of the unique commodity concentration pattern and assess associated economic dynamics of each mineralization. These tools allow the examination of global graphical trends that can be helpful to directors and others in undertaking due diligence of resource/reserve statements. Ensure that it smells right.

Jan 1, 1995

By Koichi Nishimura

Japan's coal reserves are estimated at 8,583 million tons (according to the materials on X World Energy Conference,. 1976). Japan is a long island country in the shape of an elongated cashew nut whose top is pointing to the north and its lower tip is pointing to the west. And her major coal fields are located in the two extreme far parts of Hokkaido in the north and Kyushu in the south. On the other hand, Japan's major industrial center are located in the central part of the country far from either coal-producing areas. This fact places coal a great geographical disadvantage in comparison with petroleum whose refining bases are concentrated on the coastal regions virtually next to major industrial centers.

Jan 1, 1982

By T. O. Kuhl

The Royal-Mountain King Project is 7.2 kilometers (4.5 miles) northwest of Copperopolis, California. Reserves of 8,250,000 t (9,100,000 st) at 2.32 g/t (0.068 oz/st) gold will be processed at 2500 t/d (2750 st/d) from three pits. Production is scheduled to begin the first quarter of 1989. District geology consists of northwest trending sequences of Jurassic meta-sedimentary and meta-volcanic rocks. Three ore bodies are located along the Hodson fault which trends northwest and dips 40 degrees northeast. The Gold Knoll and North Pit ore bodies are hosted in carbonate and silica altered meta-volcanic rocks whereas the Skyrocket ore body is hosted in quartz stockwork zones in meta-sedimentary rocks. Gold is present as inclusions and micro-veinlets in pyrite.

Jan 1, 1989

By James E. Myers

This study is a survey of the current "state-of-the-art" of commercially-available sonar tools to monitor the true shape of man-made cavities within the Hutchinson Salt of south-central Kansas. The work entailed ferreting out the available information, most of which is proprietary in nature; then examining actual existing conditions and arriving at a reasonable scientific evaluation of the method. Our studies were confined to one LPG field and two brine well operations in south-central Kansas. No field testing of any devices was performed, only questioning user firms, and studying cores, logs, and sonar surveys graciously made available by the companies we have contacted. Since these data are still somewhat proprietary, the company participants have asked that their company names be omitted from this presentation.

Jan 1, 1973

By Tim Lundquist

Disa Technologies Inc. provides innovative, sustainable solutions for mineral processing and remediation through its patented High-Pressure Slurry Ablation (HPSA) technology. HPSA processes solid feed material in slurry form, propelled by high pressure pumps through opposing nozzles that generate impinging jets within a collision housing. This process induces particle-to-particle collisions in a high energy zone, creating intergranular fractures along grain boundaries. In our batch scale and continuous operating testing, we have found that controlling key processing variables such as nozzle velocity, slurry solids percentage, and the number of passes can allow for controlled size reduction and maximum mineral liberation. Since 2018, Disa Technologies has demonstrated the versatility of HPSA by testing it on diverse materials, including phosphate, copper, uranium, vanadium, zinc, rare earth elements, lithium, nickel, mineral sands, gold tailings, and more. The intent of this paper is to present an overview of our test results describing in detail impacts on size reduction, recovery, and grade with a focus on HPSA's adaptability across ore types. Looking forward, it explores the potential to process materials such as DR-grade iron, clay, PGMs, bauxite, and various tailings. Additionally, it examines planned advancements in HPSA technology, including optimized nozzle spacing, higher capacity models, improved tonnage-to-footprint ratios, enhanced maintenance features, and expanded nozzle configurations.

Jan 1, 2025

By Derrick Chambers, George Kevin Chapin, M. Shawn Boltz

Seismic monitoring is one of the few noninvasive technologies with the potential to provide sub-surface geomechanical information to operators of large open-pit mines. Although passive seismic data has been used to refine emerging failure geometries and provide advance indication of surface deformations in the literature, doing so reliably in an operational context is much more difficult. This is due in part to difficulties in estimating and interpreting source locations and parameters in complex, low-stress open-pit environments. Additionally, the high costs associated with implementing, operating, and maintaining deep borehole seismic networks, which are most commonly used to monitor large open pits, can be difficult to justify, especially if monitoring benefits are not readily apparent. In this study, we explore the use of a near-surface nodal seismic deployment, which is commonly used in oil and gas exploration, for monitoring open-pit mining-related seismicity on a short-term basis. A deployment of 18 geophones was conducted on the surface in and around the Bingham Canyon Mine, a large open-pit mine near Salt Lake City, Utah, USA, where we find the small seismic array can detect and locate a variety of mining-related seismic sources, even with an extremely simplified velocity model. We outline the process of creating an idealized velocity model, developing a local magnitude scale, and interpreting the observed seismicity. Of note, we analyze a sequence of mining-induced events associated with a known structure on the south pit wall. We conclude with discussion on how surface-based deployments may be used to augment, or in some cases supplant, borehole seismic networks at large open-pit mines depending on monitoring requirements and objectives.

Apr 26, 2022

By L. Martin, M. Raffaldi, M. Stepan, D. Benton

The Office of Mine Safety and Health Research, Spokane Mining Research Division, is continuing its high-energy, high-displacement testing of field-scale shotcrete panels. A test program was developed to determine the relationship between applied force, displacement and energy for both unreinforced and reinforced shotcrete panels. Reinforcement options consisted of synthetic macro-fibers, sprayed polyurea liners, chain-link mesh, welded-wire mesh and combinations of them. During testing, photogrammetry was used to measure the geometric changes of the panels, including volume changes and panel cracking. These measurements were correlated with the load and displacement data, allowing visual observation to be related to the applied force and displacement. The test results provide a comparison of the mechanical performance of the various panel types and can assist in interpreting the condition of installed surface support. Visual assessment of the loading cycle and strength capacity of shotcrete in underground excavations will improve mine safety by providing a means to better quantify the stability of installed shotcrete support.

Jan 1, 2016

By Howard M. Cotton

Early in 1977, Amoco Production Company and Houston Chemicals, a subsidiary of Pittsburg Plate Glass (PPG) Industries, started producing iodine commercially in northwestern Oklahoma. This is significant because it is the first plant in over 40 years to be built in the United States with iodine as its sole commercial product. With the exception of a limited amount of iodine produced by Dow Chemical in Michigan, the United States is dependent upon imports from Chile and Japan for its iodine needs. The two million pounds of iodine produced annually from the Woodward plant will supply over one-third of the United States' requirements. Routine analysis of subsurface brines by the Formation Water Lab at the Amoco Production Company Research Center in Tulsa, Oklahoma, revealed unusually high concentrations of certain potentially economic minerals. Investigations determined that, of the minerals in question, iodine appeared to offer the best potential. The brines in question are located in the Morrow sands (basal Pennsylvanian) at a depth of 7,175 to 7.400 feet, in an area where Amoco has been active in a gas play for the past 20 years. The regional iodine concentration ranges from 10 to 700 ppm and averages around 300 ppm with the project area. The project is located 8 miles north and slightly east of the town of Woodward, where the well-developed, porous, and permeable sands of the Woodward trench contain large volumes of brine.

Jan 1, 1978

By K. H. McDaniel, L. Griswold

The Waste Isolation Pilot Plant (WIPP) is adding a third fan to supplement its two existing main fans. The third fan will operate in parallel with the two existing fans. An engineering analysis conducted in 1995 identified the need for improved system availability and efficiency. The WIPP, located near Carlsbad, NM, is a US Department of Energy (DOE), Carlsbad Area Office, facility that is designed to permanently dispose of US defense-generated transuranic waste in a deep, bedded salt deposit. Engineers at the WIPP performed a feasibility analysis for modifying, supplementing or replacing its two main mine fans. Since the centrifugal fans were installed in 1988, multiple operational and performance concerns have been identified. A comprehensive engineering study was conducted (McDaniel et al., 1997) to identify and quantify operational concerns, evaluate possible alternatives and recommend an optimum solution. The study indicated that adding a third single-duty centrifugal fan similar to the two existing fans and equipping that fan with Inlet Van Controls (IVCs) was the best choice. This alternative provided the most desirable combination of operational readiness and improving system performance. The fan installation project accommodates several operational and scheduling con¬straints. WIPP was scheduled to receive waste in May 1998. This milestone is proceeded by an operational readiness review. Fan installation could not be allowed to compromise the WIPP 's ability to declare facility readiness. Therefore, operational disruptions during the system tie-in had to be minimized. All engineering for the project has been com¬pleted, and physical modifications were begun in July 1997. The project was completed in 1998.

Jan 1, 2000

By Samuel S. Adams

The Permian Salado Formation of west Texas and southeastern New Mexico is composed of halite and subordinate amounts of anhydrite, clay and potassium and magnesium-bearing evaporite minerals. Aspects of the geochemistry of the Salado Formation have been investigated through studies of the stratigraphy, mineral assemblages, textures and minor element content of the salts. These studies provide information on the origin of the evaporites when combined with data on equilibria in saturated salt solutions. The principal potash ore zone in the district is composed essentially of halite (NaC1) and sylvite (KC1). Data on the color, bromide content, and proportions of halite and sylvite suggest that this simple assemblage is the product of a series of replacements rather than primary precipitation. The bromide content of the salts also indicates that the brine which precipitated the Salado Formation was derived from the dissolution of older evaporites rather than the simple evaporation of sea water.

Jan 1, 1966

By D. Scott Scovira, Thomas Gustavsson

Exiting WW2, the potential of nitrates and hydrogen peroxide for application as industrial explosives both became known. The technology stream advanced the development and uptake of nitrate-based explosives to the point that they are the current global standard for blasting. Recently environmental issues are influencing the strategic agenda of extractive industries. The mid-2010s saw renewed interest in hydrogen peroxide explosives to eliminate NOx fume. Carbon reduction initiatives in the 2020s provided additional impetus to investigate hydrogen peroxide-based explosives. Hypex Bio is at the forefront of developing and delivering bulk gas sensitized Hydrogen Peroxide Emulsion (HPE) for blasting. HPE consists of hydrogen peroxide along with smaller amounts of fuel and emulsifier. The consistency of HPE is similar to industry- standard nitrate-based emulsions. It is compatible with existing priming and initiation systems. HPE does not contain nitrates and thereby does not produce post blast nitrous oxide fumes nor discharge of nitrates or ammonia to mine water. Importantly, HPE contributes to reduction in total carbon emissions as compared to nitrate-based explosives.

Feb 1, 2025

By Z. Jin, D. DePaoli, P. Zhang

"Phosphogypsum is a byproduct created during the production of industrial wet-process phosphoric acid. This study focused on recovering rare earth elements (REEs) from a Florida phosphogypsum sample and investigated the effects of removing detrimental impurities such as phosphorus pentoxide (P2O5 ), uranium (U) and fluorine (F) during the leaching process. Experimental results indicated that REE leaching efficiency increased rapidly, reached a maximum and then began to decrease with sulfuric acid concentrations ranging from 0 to 10 percent and temperatures ranging from 20 to 70 °C. At a sulfuric acid concentration of 5 percent and leaching temperature of 50 °C, REE leaching efficiency obtained a maximum value of approximately 43 percent. Increasing the leaching time or liquid/solid ratio increased the leaching efficiency. The leaching efficiencies of P2O5, U and F consistently increased with sulfuric acid concentration, temperature, leaching time and liquid/solid ratio within the testing ranges. A fine-grain gypsum concentrate, sized smaller than 40 µm, was separated from leached phosphogypsum through elutriation, in which the P2O5, U and F content levels were reduced by 99, 70 and 83 percent, respectively, from their content levels in fresh phosphogypsum. IntroductionPhosphogypsum is a byproduct generated during the industrial wet process of phosphoric acid production, in which sulfuric acid is used to digest phosphate rock. Gypsum (CaSO4·2H2O), the main component of phosphogypsum, usually accounts for 65 to 95 percent of phosphogypsum by weight.There are small quantities of impurities in phosphogypsum, such as phosphates (H3PO4, Ca(H2PO4)2·H2O, CaHPO4·2H2O and Ca3(PO4)2), fluorides (NaF, Na2SiF6, Na3AlF6, Na3FeF6 and CaF), sulfates, trace metals and radioactive elements (Rutherford, Dudas and Arocena, 1996). Global phosphogypsum generation is estimated at 200 Mt/a (Parreira, Kobayashi and Silvestre, 2003; Yang et al., 2009), but only about 15 percent is recycled as building materials, agricultural fertilizers or soil stabilization amendments (Tayibi Choura and Lopez, 2009)."

Jan 1, 2017