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By C. M. Frost

The hydrodesulfurization characteristics of a Venezuelan topped crude oil and a Venezuelan reduced crude oil were determined at temperatures from 740° to 850° F, pressures from 800 to 1,600 psig, and space velocities from 1.0 to 2.0 Vo/Vc/hr. Kinetic calculations showed that under these conditions the desulfurization reaction was first order with respect to sulfur and had an average activation energy of 32.5 kcal/mo1. Catalyst life tests made at 750° F, with pressures of 800, 1,200, and 1,600 psig and space velocities of 1.0 and 1.25 Vo/Ve/hr, showed that the decrease in the relative activity of the catalyst was a logarithmic function of time or volume of oil processed and the amount of vanadium deposited on the catalyst. Comparative tests made with residual fuels prepared from a Wilmington, Calif., crude oil and a Wyoming asphaltic crude oil showed that catalyst life may be extended by processing fuel oil with a low metal content, but it may be shortened by the presence of large amounts of asphalt in the feed.

Jan 1, 1971

By M. L. Whisman

Several commercial processes for reclaiming used lubricating oil were duplicated on a laboratory bench scale. Laboratory tests were selected and in some instances modified to determine the physical properties of each oil produced. In addition, the hydrocarbon composition of some samples was determined using a liquid chromatographic technique, and compared with the composition of new oil in order to determine the severity of the re-refining technique. Selected samples of reprocessed oil were reformulated with an additive package for further estimates of quality as determined by wear, corrosion, foaming, and oxidation stability tests. Additionally, several samples of commercially re-refined oil and new oil were obtained and physical properties were determined for comparative studies.

Jan 1, 1974

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Jan 1, 2011

By M. L. Whisman

The Bureau of Mines developed a radiotracer method for detecting the contribution of selected components and additives to thermally induce deposits of turbine aircraft fuels. Fuels were examined before and after 52 weeks of storage at 130° F. Of particular concern was the influence of aromatic hydrocarbon fuel constituents on thermal-stability quality of jet fuels during storage. A microfuel coker test apparatus was used to thermally stress the test fuels and blends, and the resultant contribution to deposits of selected fuel components, labeled with carbon-14, was determined by radioactive-counting techniques. Ninety-one blends of five test fuels with carbon-14-labeled fuel additives or components were prepared, tested, stored for 52 weeks at 130° F, and reanalyzed for deposit-forming tendency. These additives included two anti-oxidants, a metal deactivator, and a corrosion inhibitor. Of the labeled hydrocarbon fuel systems studied, the greatest reaction was observed in blends containing methyl-and ethyl-substituted indenes. Other aromatic types also showed some contribution to the deposits. Three of the additives showed a marked tendency to degrade and react during storage and thermal stress. A cresol antioxidant, however, barely contributed to deposit formation. Oleic acid interacted with cadmium present in aircraft fuel systems and produced deleterious effects upon the thermal-stability quality of the fuel.

Jan 1, 1971

By P. W. Jeran, C. M. McCulloch, Maurice Deul

The natural vertical fracture sys tem in bituminous coalbeds is called cleat. Cleat orientation commonly controls the direction of mining with major development paralleling the face cleat. Previous researchers have categorized the origin of cleat as endogenetic, relating the origin of cleat to compaction and coalification, and exogenetic, relating the origin of cleat to tectonic forces. In the coalbeds studied for this report it was found that tectonic forces were the controlling factor of cleat formation. Face cleats were formed as extension fractures during structural deformation, and butt cleats, as release fractures during erosion and uplift. The face cleat of the Pittsburgh coalbed rotates from N 80° W in north- western West Virginia to N 57° W in southwestern Pennsylvania ; the face cleat maintains a perpendicular orientation to the shifting axial trend of local structures . Cleat orientation in other bituminous coalbeds in Virginia, Utah, Oklahoma, and Central Pennsylvania showed a similar relationship to local structure. Directional permeability of coal is directly related to cleat. Holes drilled perpendicular to the face cleat yield from 2.5 to 10 times the amount of gas released as compared with holes drilled perpendicular to the butt cleat.

Jan 1, 1974

By James P. Ulery, Stephen J. Kravits, William P. Diamond

This report presents results of a cooperative research project between the U.S. Bureau of Mines and Beth Energy Mines, Inc. Four coreholes (two before mining and two after mining) were drilled at a longwall mine operating in the Lower Kittanning Coalbed to obtain coal and rock samples from overlying strata to determine their gas content at various times in the mining cycle. The results of those tests indicate that 91 pct of the gas removed from the overlying strata came from coalbeds. Material balance calculations were made to compare the volume of gas produced both from gob gas vent holes drilled on the panel and gas removed by the mine's ventilation system with the volume of gas removed from strata directly overlying the panel to a height of 275 ft. This analysis indicates that only 40 pct of the total gas produced from the panel actually came from the strata directly overlying the panel. The remaining volume of gas production probably migrated to the Iongwall gob from overlying, and perhaps underlying, strata immediately adjacent to the panel and perhaps from greater distances downdip because of the establishment of a long-term pressure gradient in the study area.

Jan 1, 1992

By E. W. Dean

The Bureau of Mines is engaged in the work of obtaining data regarding the physical and chemical properties of typical crude oils from the various producing fields of the, United" States. Preliminary reports have been published that cover the eastern fields* and the' Rocky Mountain districts.** Since the appearance of these, reports: it has been suggested that certain additional data. I regarding the samples would be of practical value. It was believed that a knowledge of the viscosity of crude oil was desirable, particularly in connection with the design and operation of pipe lines. In accordance with this suggestion, the authors have made viscosity tests upon as many of the samples of the two series as wore still available for examination. Determinations were made at temperatures of 70° and 100°F., and in addition the oils were Subjected to the A. S. T M, pour-test*** to as certain the lowest temperatures at which they remain in a fluid condition.

Jan 1, 1921

By Doris M. Hyde

The impact of mining activities on the economy in both 1983 and 1984 was minimal. The most recent available data on the gross domestic product (GDP) indicated a level of $1.6 billion in 1983.2 The estimated value for the production of cement, aragonite, and salt was about $17 million in that year, down from the estimated $20 million in 1982. No data are available on the economic impact of the large petroleum refinery at Freeport on Grand Bahama Island, but it represents the major mineral-related activity. Cement production remained at only a fraction of the 800,000 tons per year of plant capacity. The offshore search for hydrocarbons continued in 1984, and some companies were about to enter the third year of seismic and geological surveying around Andros and Grand Bahamas Islands. Getty Oil (Bahamas) Co. Inc.; Breoco Ltd., a subsidiary of REO Development Corp. of Tulsa, Oklahoma; and Natomas Petroleum (Bahamas) Ltd. were the first companies to be awarded exploration licenses. These companies were committed to drilling at least one well before the end of the third exploration year. Other companies actively engaged in exploration included Exxon Corp., Atlantic Richfield Co. (ARCO), Chevron Oil Bahamas Ltd., and Esso Oil Bahamas Ltd. Geophysical Services Inc. (GSI) of Dallas, Texas, and Petroleum Services (Bahamas) Ltd. of Englewood, Colorado, ran another seismic survey line during 1984. This 1,533-mile line was in the Great Bahama Bank and Cay Sal Bank areas off the southeast Florida coast, and tied in with a 4,530-mile program GSI ran in 1981-82. These surveys were nonexclusive and publicly available through GSI.

Jan 1, 1986

By S. D. Maksimovic

The Bureau of Mines identified and evaluated major sources of quartz dust during overburden drilling at a surface coal mine, The relative contribution of each source to the total dust hazard was estimated, using personal gravimetric and instantaneous dust-sampling devices. No attempt was made to determine actual dust generation rates. The major sources of dust at the drill rig during dry drilling opera-tions were the collector dump, drill shroud leakage, and drill stem seal leakage, These sources contributed 90 pct of the respirable dust and 89 pet of the respirable quartz dust generated during drilling, The collector dump cycle (21.6 pct of total drilling time) accounted for 38 pct of the respirable dust and 41 pct of the respirable quartz dust, with peak dust concentrations reaching 68 mg/m3. Shroud and drill stem leakage contributed 28 and 24 pct of the respirable dust and 32 and 16 pct of the respirable quartz dust, respectively. A dragline and second drill rig contributed the remaining 10 pct of dust and 11 pct of quartz dust. Gravimetric dust samples collected inside the drill cab and outside, near the cab door, averaged 1.65 and 1.43 mg/m3, respectively, with 6 pct respirable quartz.

Jan 1, 1985

By J. Schlocker

The present emergency has greatly stimulated interest in the light metals - aluminum and magnesium - owing to their extensive use in airplane construction. The $63,000,000 plant being erected in the Las Vegas Valley by Basic Magnesium, Inc., under the auspices of the Defense Plant Corporation,

Jan 1, 1942

By John M. Dower, Ralph W. Plummer, Terrence J. Stobbe, Hyunwook Kim

"The relationship between exposure to coal mine dust and the development of various respiratory diseases is well recognized. The cause of these diseases however. Is still uncertain. To study this cause-effect relationship, It Is necessary to characterize the coal mine dust In terms of the quantity of dust present and mineral content of the dust. Dust samples were collected using a Portable Continuous Aerosol Monitor (PCAM) and 4-stage cassette Impactors at various locations in an upper Freeport seam coal mine In West Virginia. The samples were analyzed using an X-ray microdiffraction film technique and energy dispersive scanning electron microscopy. This paper presents the results of the first phase of this characterization work which Includes determining the size distribution of the dust and the mineral content of the size intervals.IntroductionDiseases associated with dusts in coal mine environments continue to afflict miners in today's modem mines. These diseases still persist because, as Olishifski points out an employee rarely experiences exposures to a single environmental stress but rather to an Intricate Interplay of multiple stresses.(1) In the case of coal mining the multiple stresses are varying sizes of dust particles originating from coal imbedded minerals. Immediate roof strata bottom strata. Incombustible rock and the coal itself. The site of this Intricate Interplay Is the miner's lungs and the resulting diseases are a function of the composite dust exposures.The proper study of coal mine dust toxicity requires that the dusts used replicate existing coal and mineral dust compositions in their relevant size fractions. The purpose of this project is to develop the size and mineral content data necessary to support this ongoing toxicological effort.Existing coal mining standards and regulations also address total and respirable dust exposures. These dust terms refer to both the quality and quantity of the dust segment in the mine atmosphere. Dust quality addresses its coal and mineral content. whereas dust quantity Is described by mass per unit volume (mg/m3) The comprehensive characterization of coal mine dust exposures will enable revision of these standards and regulations to address the specific minerals and size fractions found to be toxic to human lung tissue."

Mar 1, 1989

By Stephen D. Smith

This chapter summarizes data on crude nonfuel mineral production for the United States, its island possessions, and the Commonwealth of Puerto Rico. Also included are tables that show the principal nonfuel mineral commodities exported from and imported into the United States and that compare world and U.S. mineral production. The detailed data from which these tables were derived are contained in the individual commodity chapters of Volume I and in the State chapters of Volume II of this edition of the Minerals Yearbook. Although crude mineral production may be measured at any of several stages of extraction and processing. the stage of measurement used in this chapter is what is normally termed ?mine output." It usually refers to minerals or ores in the form in which they are first extracted from the ground, but customarily includes the output from auxiliary processing at or near the mines.

Jan 1, 1989

By Douglas C. Peters, Valois R. Shea-Albin, Dennis R. Dolinar

An accurate assessment of the vertical stress on a coal seam at depth is important for mine design. Vertical stress calculation techniques presently available either are not sufficiently accurate or cannot handle complex surface topography. Therefore, the U.S. Bureau of Mines developed a computerized method to calculate vertical stress exerted on surfaces at depth that includes the effect of topography. Two input data sets are required: a digital elevation model containing topographic elevations and a coal seam file defining coal seam elevations at depth. Boussinesq's equation then quantifies the vertical stress resulting from topography. The computerized method was tested on a coal seam overlain by a complex topography where a vertical stress map encompassing several square miles was produced. Results show that depth mitigates the affects of surface topography, while the coal seam topography has a direct effect on the vertical stress. In comparison to the computerized method, the direct stress method overestimates stress under hills and underestimates stress under valleys. The largest difference between the two methods occurs under the steepest topographic relief. A limitation of the computerized method is that stresses cannot be accurately determined near an outcrop.

Jan 1, 1992

By N. A. C. Smith

During the past, six, years, the Bureau of Mines has made and. published several hundred analyses of typical crude oils and 'has developed a system of interpreting the analyses and of classifying crudes. This system is presented here with. It is apparently equate for classifying crude oils into four main groups and has also been found very convenient in studying the geological relationships between crude oils, and the probable refinery yields of valuable products from them. Crude petroleum is morn to be a very complex substance. An analytical statement of its properties must, therefore, consist of two distinct parts, - first, the report of the results of the determinations made by the analyst in the laboratory, - second, the proper arrangement, classification and interpretation of these results so that the analysis, as a mole, will indicate the meaning- and the relative- importance of the essential characteristics of the oil.

Jan 1, 1927

By W. W. Adams

During the calendar year 1927 the United States Bureau f Mines conducted, for the third consecutive year, a safety contest among more than 250 mines and quarries. Aside from its underlying purpose to promote safety, the object of the contest was to learn which mine or quarry had completed the year's work with the smallest proportionate loss of time from accidents to its employees. Competing companies were grouped into five classes, namely, anthracite mines, bituminous teal mines, metal mines, nonmetallic mineral mines, and quarries and open-pit mines. To the winning company in each group was awarded the bronze trophy "Sentinels of Safety," the gift of The Explosives Engineer magazine. The winner in each group was the mine or quarry whose record showed the smallest loss of time from accidents in proportion to the total amount of time worked by 411 employees. This proportion is designated the "accident-severity"3 rate; it indicates the number of days of disability resulting from personal injuries per thousand man-hours of work performed by all employees. Each company's standing was determined by the Bureau of Mines from detailed records furnished by the contestants. Records of the leading companies were made known to a committee of seven men well known to the mining industry but not connected with the Bureau of Mines. This committee selected the winning companies in accordance with rules governing the Competition. According to the contest rules, the competition for the trophy was restricted to mines employing at least 50 men underground and to quarries and open-pit mines employing at least 25 men in the pit. As several plants fell below these figures during the year, their records could not be considered in connection with the award of the trophy. Figures covering these plants are, however, included in the attached tables.

Jan 1, 1928

By J. E. Zeilinger

This Bureau of Mines report describes the preparation characteristics of the significant coalbeds of Beaver and Lawrence Counties, Pa. Washability analyses were made on seven coalbed samples, none of which were of metallurgical quality as received. Five of the samples could be sufficiently upgraded to produce acceptable products, and the remaining two samples could not be upgraded to metallurgical quality because their sulfur contents could not be lowered to meet the standard. For steam or power generation, one sample was of low sulfur content as received, one sample could be upgraded to low sulfur content, and three samples could be upgraded to medium sulfur content. The original sulfur content of the remaining two samples can be appreciably reduced by removal of the sink 1.58 speci fic gravity material; however, these coals would be classified as medium sulfur coals both before and after removal of the sink material.

Jan 1, 1969

By Blair Burwell

This paper describing the method of mining a deposit of vanadium ore near Rifle, Colo., is one of a series of similar papers on metal-mining methods and costs being issued by the United States Bureau of Mines. This vanadium deposit probably is the largest yet found in North America. It is situated 12 miles northeast of Rifle, Colo. (see fig. 1), on the southern flank of tae White River plateau, and is at an altitude of 6,500 feet. Between 150 and 200 tons of ore are mined daily and trucked to the mill at Rifle. The product of the mill is fined vanadium oxide, which is shipped to the company's plaits at Columbiana, Ohio, and Niagara Falls, N. Y., for the electric manufacture of ferrovanadium. HISTORY The deposit was discovered about 1909 by men prospecting for carnotite. Its outcrop on the bola cliff of Rifle Canon had been known to stockmen for many years.

Jan 1, 1932

By Joseph E. Matta

The Bureau of Mines conducted tests using a tracer-gas technique to measure the effectiveness of the jet fan, which is often employed in mines to ventilate dead headings. Results of these tests show that jet fans can (1) ventilate dead headings beyond the maximum penetration distance indicated by smoke-tube detection of air movement, and (2) redistribute available fresh air through larger working areas. However, if the fresh air base is insufficient, the fan will merely recirculate the contaminated air and disperse it over a larger volume.

Jan 1, 1978

To reduce accidents associated with transporting, installing or maintaining mine conveyor belts by providing easy-to-use tools for use in specific tasks. Approach The Bureau of Mines, through a re-search contract, developed three devices for use on conveyor belt systems 1) for use in moving and positioning conveyor components. 2) to reduce spillage and clean-up around conveyors, and 3) to lessen the maintenance of the belt system. The Saucer Skid Moving conveyor components using runner nose 1-beam skids is a simple task when the direction of travel parallels the beams. However, when the unit is moved sideways or around corners for final positioning, the web of the beam scrapes the floor with a bulldozing effect. Many strain and sprain injuries hap-pen when mine workers drag the skids into position at this paint. To minimize such injuries, the Bureau of Mines developed a saucer skid five feet in diameter with rounded sides and a flat bottom. Its design incorporates eight reinforced ribs with holes so the component may be secured to the skid, and eight exterior eyelets to which towing chains may be attached. The skid can be easily moved in any direction because its rounded sides slide over the mine floor rather than drag across it.

Jan 1, 1984

By Donald J. Barnes

Gold was found in samples collected from Pleistocene and Holocene stream and terrace deposits. Approximately 15,000 cu yd (11,400 cu m) of small and discontinuous terrace and stream gravel deposits in the study area are composed of material derived from sedimentary and granitic rocks. The detritus is subangular to subrounded, and poorly sorted, ranging from boulder to sand size. Gold values in samples collected averaged 8.2 cents per cu yd (gold value of $500 per oz). Pan concentrates and rock chip samples collected from reported mineralized zones showed an absence of economic minerals. Stream placer deposits are uneconomic. No potential was observed for metallic or nonmetallic minerals in the La Panza study area. No potential exists for gas, oil, or coal resources.

Jan 1, 1981