Search Documents

By Wm. W. Odell

This report comprises a brief outline of the experimental cracking of natural gas in a water-gas generator at Louisville, Kentucky, and a discussion of the results obtained. The work was done under a cooperative agreement by the U. S. Bureau of Mines with the Louisville Gas & Electric Co. The re-forming or partial cracking of natural gas is not a new process, but one which has been employed in the manufacture of city gas for a number of years. However, the apparatus used heretofore was not a water-gas generator containing a bed of ignited fuel, but instead it was a plurality of connected chambers containing spaced and arranged checker bricks, with means for heating the bricks and for admitting the natural gas. The procedure previously followed was quite different from that used during the tests at Louisville; likewise the results obtained were different. It is not uncommon for companies distributing natural gas to provide gas-generating equipment for producing manufactured gas which is used, mixed with natural gas, during periods of peak demand. Because this equipment is idle much of the time, in some instances being in use only for a few days a year, some of the gas companies have considered using it, during off-peak periods, in the manufacture of some gaseous products and for carbon black which might he produced and marketed with profit. There is one plant of this kind at Louisville. Kentucky. Its maintenance in condition ready to be operated is necessary because of the limited supply of natural gas and because of the variation in demand. The engineers of the Louisville Gas & Electric Co. considered in particular the possibility of cracking natural gas in a water-gas generator by injecting the gas into the incandescent fuel bed, thereby producing a gas comprised largely of hydrogen (H2) and carbon black, an appreciable amount of which is entrained in the gas as it leaves the generator, Because power and gas are available at low prices, Louisville was believed to be a satisfactory location for a plant which could use hydrogen. It was evident that this method of treating natural gas might directly benefit the gas company by: 1. Lowering, the cost of manufactured gas.

Jan 1, 1930

By T. A. Henrie, E. K. Kleespies

Electrolytic studies were conducted to determine the transfer rates of the alloying constituents from molten titanium anodes to solid titanium cathodes in molten salt systems . The metals , nickel , tin , copper , bismuth , and manganese , were selected on the basis of thermodynamic data and the melting point of the alloy system . The transfer of nickel , tin , and bismuth was very low . The content of these elements in the cathode was in the range of less than 0.01 to 0.001 percent . The copper transfer was 0.6 to 0.8 weight - percent in electrolytes containing titanium chlorides and 0.12 weight - percent in titanium fluoride salt systems . The manganese transferred at rates comparable to that of titanium . Highpurity titanium and titanium- manganese alloys of uniform composition were produced by electrorefining molten titanium alloys in chloride electrolytes . Comparisons are made between the calculated and the actual quantities of metal transfer .

Jan 1, 1964

By Wm. W. Odell

For a number of years there has been a very appreciable annual,, increase in the production and recovery of natural gas and natural-gas gasoline2 in the United States the latter product being used largely for blending with gasoline from petroleum in the production of motor fuel. On account of the increased amount of oil cracking in the production of gasoline and the accompanying increased percentage of low-boiling constituents in the resulting product, the specifications for the natural gasoline suitable for blending have been altered, that is, the amounts of propane and butane which it can contain have been limited. The result has been that large quantities of the latter materials are wasted because there has been no ready market for thorn in large quantities. Because of this wasteage and because it is probable that large quantities of there and similar materials will be produced in the near future us a result of the more general use of oil cracking processes, a study was made by the Bureau of Mines, under a cooperative agreement with the assistance of the Phillips Petroleum Company, of the suitability of these materials alone or in mixtures for use as gas enricher in the carburetion of water gas for city distribution. This investigation included: (a) A study of the properties of the low boiling members of the paraffin series including pentane with particular reference to their utilization as gases.

Jan 1, 1927

By D. E. Hirsch, J. W. Davis, Norman G. Foster, F. G. Schwartz

This investigation was undertaken to identify nitrogen , oxygen , and sulfur compounds (polar components ) found in catalytically cracked distillate fuel . It is significant that these compounds concentrate in the sediments and gum that form when the fuel is stored . The polar components were divided in three portions by elution from a chromatographic column filled with alumina . After the hydrocarbons were washed through the column with pentane , a benzene eluted extract was removed followed by an ether eluted extract and then an alcohol desorbed fraction . These extracts were individually distilled in a molecular still and the fractions were analyzed by gas chromatography , mass spectrometry , infrared spectrometry , and elemental and functional analyses . Naphthalene and its homologs , phenanthrene and its homologs , and other compounds such as methyl indene , C₂ quinolines , phenyl indan , and the benzothiophenes , appear in the benzene extracts . Quinolines are the major components of the lower boiling fraction of the ether extract , although carbazoles , acridans , and indoles are present in some concentration . Elemental and functional group analyses of the alcohol fraction indicated 10 percent of the distillate portion was nonhydrocarbon , and in this portion the average molecule contained more than one nonhydrocarbon element . Compounds of such complexity are not well known , and standards for positive identification are limited .

Jan 1, 1963

By Tobias W. Goodman, George N. Aul, Joseph Cervik

The Bureau of Mines conducted research to degasify a virgin block of coal in the Beckley Coalbed using long horizontal holes drilled in an array from the bottom of a ventilation air shaft. Eight horizontal holes and an in situ pressure hole were drilled in a radial pattern to depths ranging from 418 to 910 ft (127 to 277 m) and 205 ft (62 m), respectively. The investigation showed the shaft was in a basin saturated with water, which resulted in low gas flows from holes. The in situ pressure at 200 ft (61 m) into the coalbed was 79 psig (544.6 KN/m2). The aver- age gas and water flows for the eight holes were 94,100 ft3/day (2,665 m3/day) and 13 gal/min (49.3 l/min) . After 514 days of degasification, 18.7 million ft3 (0.53 million m3) of gas had been drained. Methane face emissions, which were measured as a section advanced toward the shaft, were reduced about 77 pct, emphasizing the value of drainage by this technique. All holes were grouted before the area around the shaft was mined.

Jan 1, 1982

By Anatol Wojtowicz

This research program was conducted to determine if respirable coal dust emanating from a continuous mining machine can be suppressed more effectively by a high expansion foam than by the water sprays conventionally used. A high expansion foam system was developed and tested on a continuous mining machine under actual operating conditions. The utility of the system was demonstrated. Test results tend to show that foam application is more effective than water sprays in suppressing respirable coal dust. However, because of the extreme variability of the test conditions, scatter in the sampling data, and other factors, not enough data was obtained to form a firm conclusion that foam is more efficient than a water spray in suppressing respirable coal dust. Sufficient statistical data was obtained, however, to indicate that foam is more efficient than water in suppressing total float coal dust.

Jan 1, 1974

By George T. Faust, S. R. B. Cooke

"The Southern Experiment Station of the Bureau of Mines, United States Department of the Interior, in cooperation with the University of Alabama, is investigating the preparation of pulverized coal for fuel. In this study the relative amount of surface in various products and samples had to be assessed. Because of the familiarity with screens and because of the simplicity of using the inverse ratio of the opening for ascertaining the amount of relative surface in the respective sizes, screens down to and including 270-mesh were used. This choice was made in full cognizance of the irregularity of screens, but it seemed that if the same screens were used throughout all the tests the relative values would be satisfactory.In dealing with the subsieve sizes, pneumatic elutriation was used to make several fractions to extend the sizing analysis into the range of hypothetical screens. This kind of a sizing analysis was thought necessary because it is familiar to all operators, and, furthermore, it is amenable to several ways of plotting curves that bring out the characteristics of various coals and various methods of grinding.The method of obtaining the data from which to set up the hypothetical screen scale is the subject of this paper. It consists in determining the average projected area of the particles in the respective elutriated products. By extending the ""area method"" to sieve sizes, a factor is found that may be applied to the subsieve sizes, and thus the scale is projected in a regular manner. This method avoids contentions about specific surface and steers clear of ""average diameter"" except as material sized on screens may be said to have an average diameter."

Aug 1, 1939

From time to time the Bureau of Mines has interpreted and applied certain provisions of the Federal Coal Mine Safety Act and Federal Mine Safety Codes, primarily for the guidance of Federal Coal Mine Inspectors. Although interpretations of the Act have appeared in the Federal Register, the Code interpretations and practical applications have not been published. In response to many requests from representatives of the coal-mining industry, the Bureau is publishing this information to promote better understanding of those provisions that may be misinterpreted or misapplied. INTERPRETATIONS AND APPLICATIONS Two Federal Mine Safety Codes are discussed in this report, namely the Federal Mine Safety Code for Bituminous-Coal and Lignite Mines of the United States, Part 1, and the Federal Mine Safety Code, Anthracite Mines of the United States, Part 1. In this circular the word Codes refers to both directives; Code* refers to the code for bituminous-coal and lignite mines; Code? refers to the one for anthracite mines. Act* refers only to bituminous-coal and lignite mines.

Jan 1, 1963

By Raja V. Ramani, Robert L. Frantz

"In response to the U.S. Bureau of Mines (USBM) Request for Proposal (RFP) for "" the establishment of a Generic Mineral Technology Center (GTC) in Respirable Dust,"" the Mining and Mineral Resources Research Institutes (MRIs) at The Pennsylvania State University (PSU) and West Virginia University (WVU) in association with participating MRIs at Massachusetts Institute of Technology (MIT), and the University of Minnesota (UMN) have prepared the comprehensive research program described herein. Michigan Technological University (MTU) joined the Center as an affiliate after its inception. This program was developed with recognition of the stated objective of the Federal Mine Safety and Health laws which is to "". . . permit each miner the opportunity to work underground during the period of his entire adult working life without incurring any disability from pneumoconiosis or any other occupation-related disease . . . .""Exposure to respirable contaminants in mine atmospheres has long posed a serious hazard to miners. The control of these hazards, some of which can have sudden and catastrophic consequences and some others, slow and long enduring, has been a major concern for labor, management and the government. This concern has manifested itself in four mechanisms of control -- (1) regulatory control through minimum standard setting by the passage of mine health and safety laws, (2) engineering control through design and operation of mines according to the best recommended practices, (3) interaction of dust and lung control through periodic physical examinations, wearing personal protection devices, etc., and (4) legal and social control through workman's compensation laws for occupation related health deterioration."

Aug 31, 1989

By Jacqueline A. McClaskey

The U.S. Bureau of Mines (USBM) Information and Analysis Directorate collects worldwide data on virtually every commercially important non fuel mineral commodity. These data form the base for tracking and assessing the health of the minerals sector of the U. S. economy. The USBM's data collection activity was instituted by the 47th Congress in an appropriations act of August 7, 1882 (22 Stat. 329), which placed the collection of mineral statistics on an annual basis. The most recent authority for the USBM survey activity is the National Materials and Minerals Policy, Research and Development Act of 1980 (Public Law 96-479, 96th Congress). This act strengthens protection for proprietary data provided to the U.S. Department of the Interior by persons or firms engaged in any phase of mineral or mineral-material production or consumption.

Jan 1, 1992

By A. Gene Collins

The Bureau of Mines conducted a research study of the geochemistry of the Smackover Formation to determine what geochemical relationships are useful in exploration for and production of oil and gas. Samples of oil, gas, brine, and rock were collected and analyzed. The oilfied brines were analyzed by methods recommended by the American Petroleum Institute and by tentative methods of the American Society for Testing and Materials. The crude oils were analyzed by Bureau of Mines methods; the gas, by Bureau of Mines methods; and the rocks, by wet-chemical, atomic absorption, and neutron activation methods. The results were correlated and interpreted, and several geochemical relationships useful in exploration and production were found. These include the type and class of brine, organic constituents in the brine, redox potential, in situ temperature and pressure of brine, degree of sulfate and carbonate saturation of brine, and halide concentrations in the brine.

Jan 1, 1974

By M. B. Cooke

An analytical method for the determination of the gum-forming material in gasoline has been developed by the Bureau of Mines, during a study nor in progress to determine the best rays for elimination of such constituents from gasoline. This method is similar in principle to that previously described by Smith end Cooke,2 which involved evaporation of e sample of gasoline in a small glass dish. The evaporation was started on an actively boiling steam bath and completed in an air oven at 105°C. In the improved method described below, the stem bath has been replaced by a steam heated oven in which an inert atmosphere is maintained. Air is excluded from the oven, consequently the precision of the determination is increased. Furthermore, evaporating dishes different from those previously described may be used.

Jan 1, 1925

By Robert F. Chaiken

More than 500 fires are now burning in abandoned coal waste banks and coal deposits in the United States. Once established, such fires can burn for decades, and extinguishing them by conventional methods such as surface sealing to exclude air, excavation to remove fuel, or flushing to cool the fire zone is usually difficult and always expensive. Burnout Control, a technique developed by the Bureau of Mines for the control of abandoned coal fires, involves the accelerated combustion of coal in place with total management of the heat and fumes produced. A burning waste bank or mine is placed under negative pressure relative to the atmosphere, and heat and combustion products are drawn from the combustion zone through an exhaust ventilation system. Heat produced appears as sensible heat in the exhaust, at temperatures as high as 1,000° C (1,832° F), and could be recovered for the production of steam, hot water, process heat, or electricity. The Bureau's first field demonstration of Burnout Control was at Calamity Hollow in Allegheny County, PA (near Pittsburgh). Calamity Hollow was the site of an underground mine in the. 1900's and was surface mined in the 1940's. In the winter of 1961~62, a fire of undetermined origin was discovered in the exposed coal. In 1963, the Bureau constructed a trench barrier around the fire and a surface seal over the affected area. The fire was isolated but, not completely extinguished. In 1979, when the Bureau began work on the Calamity Hollow Mine Fire Project to demonstrate controlled burnout, the fire was still smoldering on the hot side of the trench barrier. The project, which was begun in December 1979 and ended in July 1982, consisted of the design, construction, operation, and subsequent dismantling of a Burnout Control ventilation system. This report, although considered part 2, is actually the last of a five-part series that describes the Calamity Hollow Mine Fire Project. It was written last because it involved the analysis of a substantial body of data describing in detail the results of a continuous 4-month burnout operation. The first report, part 1, describes the design and construction of the field installation. Part 3 describes the instrumentation used to control and monitor the progress of the burnout operation. Parts 4 and 5 deal with the closeout phase of the field demonstration. Part 4 describes the procedure used to quench the fire, and part 5 describes the final excavation and backfilling of the heated zones. The reports in this series document the Calamity Hollow controlled burnout demonstration, which showed that (1) controlled in situ combustion is a feasible method for controlling underground fires in abandoned mines, (2) the resultant thermal exhaust output is suffIcient for energy utilization, and (3) water injection-fume exhaustion is a potentially effective method for cooling large underground fire zones. Further investigations of both Burnout Control and the water injection-fume exhaustion quenching procedure are planned.

Jan 1, 1989

By Ronald H. Church

The Bureau of Mines tested & ground penetrating radar (GPR) system in the central Florida phosphate district. to determine the feasibility of utilizing GPR technology for subsurface cavity detection. The test area is located in karst topography where sinkhole development is prevalent. State regulations require subsurface drilling of damsites to identify underground anomalies; however, this method is not totally accurate in locating subsurface cavities that could lead to sinkhole development. An electromagnetic method of identifying anoma-lous subsurface conditions could reduce or eliminate the possibility of dam failure due to sinkhole development. The Bureau devised a GPR system that successfully penetrated over 50 ft of overburden and gave recognizable radar return signals characteristic of a rock-cavity interface.

Jan 1, 1986

By D. Harrington

"In at least three out of every four working faces in metal mines there is no attempt made to cause air circulation other than by use of compressed air, and in at least nine cases out of ten the compressed air is released merely by opening, or partly opening, the valve and allowing the compressed air to escape through open air hose used to convey the compressed air to the drilling machines. Usually no blowers are in use during periods of drilling, as the exhaust from the drill provides cool, comparatively fresh air for the driller; however, in some instances, the compressed-air line is provided with a tea connection, which permits taking air for the drill from one side of the tee, and air for ventilation through a separate hose used as a blower, simultaneously with drilling.Table 1 contains temperature and humidity data as to compressed-air blowers from open end of air hose at 36 working places in eleven metal mines of four States, embracing the mining of gold, silver, copper, lead and zinc ores, and at horizons ranging from 500 feet below the surface to as low as 4900 feet.It is noticed that the ordinary air surrounding the worker at the face gives an average wet bulb temperature of 81.7° F. for the 36 working faces, with 84.7° F. dry bulb and 87.2 per cent relative humidity. The average wet bulb tem¬perature of 36 readings at these working faces of compressed air at the end of the,hose as the air issues from the hose was 67.4° F., or 14.3 degrees lower than the average wet bulb readings of the air of the working places; however, the average dry bulb temperature of the 36 readings of compressed air as it issued from the end of the hose was 79.7° F., or only 5 degrees less than that of the general air (84.7°); the relative humidity was 51.1 per cent as against 87.2 per cent for the surrounding air. Readings were taken in five raises, seven crosscuts, ten drifts and 14 stopes.It will be noted that the velocity or movement of the general atmosphere at each of the entire 36 working faces, was found to be practically imperceptible; this might readily be inferred since compressed air is rarely used on blowers if there is adequate circulation of the general air of the place. Where rook temperatures could be obtained readily, they are shown; it is noticeable that the dry bulb temperature of the air of the working place varies little from the rock temperature, and that the dry bulb temperature of the compressed air as it issues from end of air hose varies only a few degrees from the temperature of the surrounding rock; in some instances the dry bulb temperature of the compressed air as it issued from the end of the air hose was higher than the rock temperature or the dry bulb temperature of the surrounding air."

May 1, 1921

By Irving Hartmann, John Nagy

"The pressures produced by dust explosions are frequently so great and are developed so rapidly that widespread destruction of manufacturing equipment and buildings results. Experimental data on maximum pressures and rates of pressure rise produced in a closed vessel by numerous metal powders and by dusts used in the plastics industry were published in two previous Bureau of Mines papers.4/5/One means for reducing structural damage is provision in the enclosing walls and/or roof of rapidly opening explosion-relieving devices or relief vents through which the pressure of an incipient dust explosion can be quickly dissipated. The vents can be simply unrestricted or free openings: hinged or pivoted sash which swing outward at a predetermined internal pressure; fixed sash, with light wall anchorages; scored glass panes; light wall panels; monitors or skylights; poppet-type vent closures; paper, metal foil, or other diaphragms that burst at low pressures; pull-out diaphragms, or other similar arrangements.The use of pressure-relief vents is recommended in the dust-explosion codes of the rational Fire Protection Association,6/ and recently a special committee on explosion venting has been organized. However, technical data on which the design and distribution of relief vents can be based are meager. An experimental study on venting grain-dust and cornstarch explosions was made by the Bureau of Chemistry and Soils, United States Department of Agriculture.7/ Tests on cork fines, cinnamon, starch, barley dust, and a phenolic plastic were made in a laboratory-scale (0.1-cubic-foot) apparatus by the engineering department of the Factory Insurance Association.8/ A study on the venting of explosions of acetone-air mixtures was made by the Bureau of Mines.9/The object of the present investigation is to extend the limited knowledge on the effectiveness of pressure-relief vents of different types, shapes, and sizes. The aim is to determine the venting requirements in equipment and structures of various dimensions and shapes for dusts of widely different explosive properties. On the basis of such accumulated information, together with theoretical considerations, it is hoped that ultimately it will be possible to recommend correct venting for most operations in which a dust-explosion hazard exists."

May 1, 1946

By Valois R. Shea-Albin

An accurate assessment of the vertical stress on a coal seam at depth is important for mine design. Vertical stress calculation techniques presently available either are not sufficiently accurate or cannot handle complex surface topography. Therefore, the U.S. Bureau of Mines developed a computerized method to calculate vertical stress exerted on surfaces at depth that includes the effect of topography. Two input data sets are required: a digital elevation model containing topographic elevations and a coal seam file defining coal seam elevations at depth. Boussinesq's equation then quantifies the vertical stress resulting from topography. The computerized method was tested on a coal seam overlain by a complex topography where a vertical stress map encompassing several square miles was produced. Results show that depth mitigates the affects of surface topography, while the coal seam topography has a direct effect on the vertical stress. In comparison to the computerized method, the direct stress method overestimates stress under hills and underestimates stress under valleys. The largest difference between the two methods occurs under the steepest topographic relief. A limitation of the computerized method is that stresses cannot be accurately determined near an outcrop.

Jan 1, 2010

By L. A. Schutz

Personnel of the Bureau of Mines have conducted investigations in the principal asbestos mines and mills in the United States, to determine the concentration of airborne asbestos fibers in the workplace, and to establish the exposure of workers to such fibers. 'The surveys were conducted using the sampling and evaluation method recommended by the National Institute for Occupational Safety and Health. The method consists of collecting the air-borne sample on filters and, after appropriate sample preparation, counting the fibers utilizing phase contrast microscopy. The results of the investigation show that fiber concentrations are low in the asbestos mines but high in the asbestos mills, ranging well above 5 fibers/ml of air based on a count of fibers greater than 5 urn in length.

Jan 1, 1973

By C. P. Hood

"The amount of ash in anthracite coal interests every buyer, and occasionally produces caustic comment, but there is a lack of authentic figures that will take the subject out of the realm of opinion and agitated fancy and. give a true picture of the quality of coal actually delivered. What per cent ash is to be expected when the coal is good, and when have we a right to make serious complaint?During the past summer the Bureau of Mines took 127 samples of 1000 pounds each, representing nearly 30,000 tons of anthracite is dealers' yards in seventeen cities in the State of Massachusetts. There were three objects in view, to discover the average and the variation in amount of ash in anthracite in some easily described area; to demonstrate standard sampling methods, and to learn something about the feasibility of itinerant coal sampling. Massachusetts was selected because its principal cities could be visited in a single season. There also appeared need for demonstration of standard sampling of coal, since a coal quality law had been passed in the State, to be administered by those unfamiliar with coal sampling."

Feb 1, 1924

By E. J. Lintner

This paper is one of a series being prepared by the United States Bureau of Mines describing clay mining, crushing and grinding methods, and costs at various clay-mining operations throughout the United States. These papers are designed to disseminate technical information regarding methods used. The cost tabulations represent local operating expenditures only and not total production costs. Although the publication of total production costs might not be advisable in some instances, yet a knowledge of operating costs is essential to the technical discussion and study of the methods employed. The attention of the reader is specifically called to-this distinction between total and operating costs in order that no misunderstanding of the cost tabulations shall ensue. The following report deals specifically with the methods employed by the Dennison Sewer Pipe Co., Dennison, Tuscarawas County, Ohio.

Jan 1, 1936