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By W. J. Kroll

The production of beryllium metal and its alloys is one of the most difficult tasks in metallurgy. In this report we shall examine the progress made in this work- in the last 15 years; taking into account the outstanding publications, including; those of the patent literature, and the information obtained during our 20 years? experience with this metal. The difficulties experienced' in producing elementary beryllium derive from the physical nature as well as from the chemical behavior of the metal and its compounds. Its oxygen affinity is about the same as that of calcium and a little higher than that of magnesium. Its chlorine affinity is much lower than that of magnesium, about equal that, of manganese, and little higher than that of aluminum. The sulfur and nitrogen affinity is probably almost the same as that of calcium for these elements, and beryllium carbide is probably more stable than aluminum carbide, A14C3. The intermetallic affinity of beryllium may be given in descending order, as follows: Nickel - copper - iron. It forms eutectics with -aluminum and silicon as well as with silver. It does not alloy with magnesium and only partly with calcium. Its oxide melts at 2,570° C., but CaO and BaO form readily fusible eutectics with BeO(65).3/ No igneous solvents are known for BeO, which behaves id this regard like Mgo. The beryllium silicate is a strong compound, the aluminete much less so; however, CaO easily displaces Be in the heated mixtures. The Anhydrous chloride hydrolyzes, and it cannot be made from aqueous liquors. It sublimes at 488° C, and melts at 405° C., The fluoride, which, is very Soluble in water, hydrolyzes also, but a kind of oxyfluoride of the approximate formula 2 BeO?5 BeF2 can be made from solutions by dessication. The fluoride melts at 800° C, and boils above 1,100° C. It forms very stable double fluorides with alkalifluorides, which have very low melting points and are fairly soluble in water. They are more stable than the analogous fluosilicates and the sodium fluoaluminate cryolite.

Jan 1, 1945

By R. R. Sayers

The contemplated use of dichloro-difluorco methane in domestic and commercial refrigerating appliances and in air-conditioning equipment for public buildings and possibly homes, brims attention to the health hazards involved in a wide potential exposure of the public to vapors of another new product, and for the first time to vapors of an organic fluorino compound. The objective in the development of this new refrigerant, however, has been the mitigation of health and explosion hazards in automatic refrigeration, and accordingly these factors have been given primary attention. Early in the development, the Bureau of Mines as requested to make a laboratory study of the toxicity and potential hazard, and it was ca the oasis of the results is of this work and the results of a preliminary investigation made in another laboratory6 that the compound has been selected for commercial use. The investigation conducted by the Bureau of Mines is still in progress, enough information has been obtained to indicate the order of the toxicity and the magnitude of the health hazards involved in the use of dichloro-difluoro methane as a refrigerant. The following is a summarized report of the work completed to date:

Jan 1, 1930

By Robert H. Ridgway

This circular outlines salient facts regarding the sulphur industry of the United States and the world. It is founded chiefly upon published information available in the literature of the subject. The Bureau of Mines has in its files additional, more detailed data upon many of the topics presented very briefly here, and will endeavor to assist the mineral industries and the public by giving further information in response to individual inquiries. It will welcome comments, criticisms, and contributions of data that may assist in making later editions of this circular more accurate, or in developing more fully the bureau's mineral files pertaining to sulphur. Throughout this paper sulphur is used to designate crude sulphur or brimstone, not sulphur produced from pyrites or' smelter gases.

Jan 1, 1930

By Gerhard Braüner

The report gives a review of the methods of predicting mine subsidence; these methods are used particularly in European coalfields. The methods are subdivided into two groups, based on mathematical expressions either for the trough profile or for the influence of infinitesimal extraction elements. The fundamental relationships common to all methods described herein are the principles of superposition and of equivalent extraction areas. The involved parameters are derived from field observations. For calculating horizontal displacements, their relation to the slope of the subsidence profile is applied. The time-dependent development of the subsidence process is characterized by the empirical "time factor." Modifications for the case of inclined strata are considered. A brief review of experimental and theoretical model investigations is given.

Jan 1, 1973

By CDC CDC

In 2004, a total of 251 metal mining operations reported employment to the Mine Safety and Health Administration (MSHA). Metal mines were the smallest mining commodity sector, comprising 1.7% of all mining operations. • Gold mines

Sep 1, 2007

By G. E. McElroy

Tae purpose of this paper is to present types of charts adapted to aid in the graphic solution of fan-performance problems of selection and operation, and to urge the adoption of similar charts by the National Association of Fan Manufacturers as standard forms for presenting fan-performance data. As matters now stand, it is difficult for the average engineer to solve such problems because a laree number of variables are involved, and performance data are not presented in a manner that permits their direct application to many problems encountered in practice. The performance of any centrifugal machine is determined not only by the machine itself but also by the fluid-flow system on which it operates. Actual performance of centrifugal fans is therefore e matter of the type, size, and speed of fan, on the one hand, and of the relation of pressure to quantity of flow, as determined by the physical condition of the airway system, on the other.

Jan 1, 1936

By G. E. McElroy

[The purpose of this paper is to present type: of charts adapted to aid in the graphic solution of fan-performance problems of selection and operation, and to urge the adoption of similar charts by the National Association of Fan Manufactures as standard forms for presenting fan-performance data. As matters now stand, it is difficult for the average engineer to solve such problems because a large number of variables are involved, and performance data are not presented in a manner that permits their direct application to many problems encountered in practice. The performance of any centrifugal machine is determined not only by the machine itself but also by the fluid-flow system on which it operates. Actual performance of centrifugal fans is therefore a matter of the type, size, and speed of fan, on the one hand, anti of the relation of pressure to quantity of flow, as determined by the physical condition of the airway s: stem, on the other.]

Jan 1, 1936

By William W. Adams

A new record in accident prevention was made by the metal-mining a industry of the United States in 1938, as signalized by a lower fatality rate than in any previous year. The rate was less than half as high as in 1911, the earliest year for which figures are available. A good safety record was also established in the prevention of nonfatal injuries, as the injury rate was lower than in any other years except 1931 to 1935, a 5-year period notable for its unusually low injury rates. Employment was more limited in 1938 than in 1937, both in number of men employed and total number of man-hours worked. The number of workdays per man also was smaller than in 1937. Operating companies reported that 7,233 mines were active in 1938 or some part of the year and that the total number of men employed was 103,027. This figure represents the summation of the average number of men employed as reported by the companies, the average for each mine being that for the period during which the mine was active. The number of employees at all mines in 1938 was 15,402 less than in 1937. Reports covering all mines indicated a total of 188 million man-hours worked during the year, or 21 percent less than the nearly 240 million man-hours worked in 1937. In the performance of this work accidents occurred that resulted in the death of 156 employees and the injury of 1.2,722, each injured employee being disabled for more than the remainder of the clay on which he was hurt.. The fatality rate for 1938 was 0.83 per million man-hours worked, which was 9 percent more favorable than the rate of 0.91 for 1937. Nonfatal injuries occurred at the rate of 67.61 per million man-hours worked, an improvement of 10 percent compared with the injury rate of 75.37 for 1937.

Jan 1, 1941

1. ACKERMAN, C. L. The Binary System Manganese-Zinc. Ztschr. Metall., vol. 19, 1927, p. 200. 2. ADKENASY, P., AND KLONOWSKY, S. Über die Manganatschmelze. Ztschr. Elektrochem., vol. 16, 1910, p. 107. 3. AKTIEBOLAGET FERROLEGERINGAR (assignees). Method for the Manufacture of Manganese Alloys Poor in Carbon or Silicon or Else Manganese. British Patent 163262, Apr. 28, 1921; U. S. Patent 1480267, Jan. 8, 1924. 4. Method of Producing Manganese or Manganese Alloys Poor in Carbon or Silicon. British Patent 174923, Jan. 25, 1922.

Jan 1, 1934

By D. G. Foot

The Bureau of Mines investigated energy-efficient methods for recovering potash values from process and waste brines. Laboratory pan evaporation of four chloride brines produced crude salts containing predominantly sylvite, halite, and carnallite. Six sulfate-chloride brines produced crude salts containing primarily schoenite, kainite, leonite, sylvite, carnallite, and halite. Potash grades ranged from 7.2 to 22.2 pct K20, and recoveries from 84 to 99 pct. Sylvite flotation from chloride evaporites, with amine collector, recovered 90 to 97 pct of the potash in a concentrate containing 54.3 to 60.3 pct K20. Fatty acid flotation of the high-sulfate evaporite recovered 78 pct of the sulfate minerals in a 27.8-pct-K20 concentrate. Flotation of the chloride minerals with amine collector recovered 80 pct of the potash in a 59.7-pct-K20 concentrate. Solar evaporation of 10,000 gal of brine recovered 99 pct of the potash in a crude evaporite containing 24.5 pct schoenite and 20 pct sylvite. Continuous flotation in a 100-lb/h process research unit recovered over 95 pct of the potash in schoenite and sylvite concentrates containing 28.0 and 62.3 pct K20, respectively. An economic evaluation suggested a rate of return of 3 pct for a new facility and 9 pct if. the process is adapted to fit an existing plant.

Jan 1, 1984

By Richard D. Hagni

The character of phosphorous-bearing minerals in the Birmingham red Iron ores and iron-bearing minerals in the Eufaula bauxite deposits in Alabama has been Intensively studied by petrographic, ore microscopic, luminescent microscopic, scanning electron microscopic, electron microprobe, and x-ray diffraction techniques. A total of 15 types of phosphorous-bearing mineral grains have been recognized in Birmingham iron ores by their characteristic sizes, shapes, and distributions. Size measurements, modal analyses, and texture analyses have permitted an estimate of potential liberation of phosphorous from the iron ores by beneficiation to be 27% In areas of previous mining and 60% in areas of current iron reserves. Fine grinding, selective flocculation, and flotation may constitute the best beneficiation technique for future research. Hematite and goethite are the most important iron minerals in Eufaula ferruginous bauxites, but pyrite, marcasite, and siderite are Important iron minerals in some varieties of ferruginous bauxite, and lepidocrocite and ilmenite occur locally in minor quantities. Although simple screening will remove the coarsest iron-bearing grains, research on the utilization of high gradient magnetic separation to reduce the amounts of iron-bearing grains is recommended.

Jan 1, 1981

By David Schlain

"IntroductionThe purpose of this investigation was to study the characteristics of the high-acid electrolytic manganese cell with the idea of fitting it into one of the flow sheets being worked out by the Metallurgical Division of the Bureau of Mines for the recovery of manganese from low-grade domestic ores.In construction, the high-acid cell 3/ differs from the low-acid type in that the cathode and anode compartments are separated by a diaphragm of relatively low porosity, such as alundum. This is necessary because in the high-acid cell the two electrolytes are circulated separately. The anolyte is 15 to 30 percent H2SO4. The catholyte consists of a solution of ammonium sulfate and manganese sulfate with a OH of 4 to 3. The only mixing of electrolytes is that resulting from flow through the diaphragms. In the low-acid cell the two electrolytes are not circulated separately and do not differ so widely in hydrogen-ion concentration. Hence, the canvas diaphragm is sufficient.During operation of the cell, manganese is deposited on the cathode, and sulfuric acid is produced in the anode compartments. Various other reactions take place in the cell. There is considerable decomposition of water; hydrogen is evolved at the cathode, and oxygen is liberated at the anode. When lead anodes are used, some hydrated oxides of manganese are formed at the anodes. The quantity of oxides formed is not as great as it is in the low-acid cell, because fewer Mn++ reach the vicinity of the anodes."

Jul 1, 1942

By Michael R. Norland

Surface and subsurface stabilization of mining-related wastes through revegetation depends upon the physical, chemical, and biological condition of the waste following mining. Mining disturbances can significantly alter the soil physical, chemical, and biological characteristics of a site, reducing or eliminating mycorrhizal fungi from the soil. Mycorrhizae are economically and ecologically important because they can alleviate environmental stresses caused by lack of proper soil condition and because they are vital to stabilization of mining waste by increasing plant survival and biomass through increased nutrient and water uptake. This report discusses some of the ecological factors that may affect mycorrhizae-plant associations on mining-related wastes and provides general information on mycorrhizae inoculation technology.

Jan 1, 1993

By L. J. E. Hofer

"INTRODUCTION This paper is riot to be considered a complete survey of data on carbides; it is only an attempt to correlate the more reliable of the existing data of interest in connection with the Fischer-Tropsch synthesis, and its purpose is to guide future experiment and thought.A general review of the literature on the Fischer-Tropsch synthesis will be published in the near future as a chapter by H. H. Storch for a book entitled, ""The Chemical Utilization of Coal,"" edited by H. H. Lowry. This chapter covers the literature up to l9). It is planned to bring the review up to date in a comprehensive bulletin on Synthetic Liquid Fuel Processes to be completed during the next year. ACKNOWLEDGEMENTSThe author discussed the significance of the data with several members of the Physical Chemistry and Hydrogenation Section.THE PREPARATION OF CARBIDES OF IRON, COBALT, AND NICKELThe reaction of carbon monoxide with Fischer-Tropsch metals was first studied in a quanitaive way by Bahr and his coworkers. The contents of their first papers, 3/ 4/ 5/ which deal with the action of carbon monoxide on nickel, cobalt, and iron, will be described in the following paragraphs, together with the pertinent results of other investigators."

Jul 1, 1944

By Harlan A. Walker

This paper on the mines of El Potosi Mining Co. is one of a series being prepared by the United States Bureau of Mines on mining practices, methods, and costs in the various mining districts of North America. Grateful acknowledgment is made of the helpful suggestions and criticisms offered by the management, together with the assistance of the mining staff in preparing maps and drawings and of C. L. Thornburg, mine geologist, in preparing the section on geology.

Jan 1, 1934

By S. H. Ash

THIS REPORT covers the third in a series of five projects into which the Conowingo tunnel system has been divided for geographical and practical reasons. It outlines the work constituting Project No.3 that consists principally of the following: (a) To sink the No. 15 shaft and extend the Alden, Sugar Notch, Baltimore No.2, and Laflin shafts from their present depths to tunnel level; (b) to drive a tunnel off these shafts to connect with the western end of the tunnel in Project No.1 (Lackawanna) and to a point 1 mile south of the No. 15 shaft; (c) to construct an emergency pumping plant at the No. 15 shaft, complete with 3 centrifugal pumps of 200-cubic-foot-per-second (c. f. s.) capacity each, and a discharge-water shaft and a discharge tunnel for conducting the water from the pumping plant into the Susquehanna River; and (d) to construct a lateral tunnel 1 mile long off the main tunnel in the vicinity of the No. 15 shaft, to be known as the Wyoming lateral. The project, as outlined, is a self-contained drainage unit that will permit unwatering inundated mines and safeguarding active mines in the Wyoming Basin of the Northern field and also will handle the water in the Lackawanna Basin, thus permitting the temporary pumping plant provided in Project No.1 to be discontinued. The pumps installed in the temporary pumping plant provided in Project No.1 can then be moved to the emergency pumping plants recommended in Projects Nos. 2 and 3, to be installed as the third or standby unit.

Jan 1, 1955

By R. G. Warncke, D. Harrington

"INTRODUCTION The use of black blasting powder as an explosive in coal mines has long been recognized as hazardous and has been responsible for many of the worst disasters in American coal mines. One of the most pressing of the numerous problems confronting the Bureau of Mines, upon its creation in 1910 was to determine methods that would lessen the hazards created by the use of explosives in coal mines. The Bureau continued the study begun by the Technologic Branch of the Geological Survey as to the nature of explosives and made numerous tests to determine types of explosives suitable for blasting in coal mines. The Bureau has tested and approved hundreds of types of explosives and has disseminated information on methods and conditions for use underground to make them permissible as to safety. The Bureau of Mines has encouraged the use of permissible explosives for coal-mine blasting, and its experts both in the laboratory and in the field believe that the use of black blasting powder in any form (granular or pellet) is hazardous in any underground coal mine. Despite the information published at various times and innumerous ways and the general knowledge of the hazards that the use of black blasting powder in any form creates in the blasting of coal, the coal mines in the United States, during 1947 used approximately 34 million pounds of black blasting powder (granular or pellet), or approximately 11.8 percent of the total quantity of explosives used by the coal-mining industry.Many coal mines of the United States, for various and sundry reasons, probably will continue the use of black blasting powder, and this circular has been written for the benefit of such users, not that any suggested method or methods will make the use of this explosive safe, but it has been found that methods and conditions of use of black blasting powder can be improved so as to lessen, though not eliminate, the hazards created by its use."

Mar 1, 1949

By Maria I. De Rosa

The U.S. Bureau of Mines conducted a study to determine if correlations exist between the chlorine or nitrogen contents of materials and the hydrogen chloride (HCI) or hydrogen cyanide (HCN) concentrations evolved during the thermal decomposition of these materials. Hydrogen chloride, hydrogen cyanide, and carbon monoxide (CO) were found to be the primary toxic gases evolved during the combustion process. The experiments were carried out in a 20-L furnace with 1-g samples. The furnace temperature, rising from ambient, was set at 1,000 °C with an airflow of 10 L/min. The variables measured were the gas loads (milligrams per gram) of HCI, HCN, CO, and CO2 (carbon dioxide); CO and CO2 concentrations as a function of time were also measured. Other variables included the average concentrations of submicrometer smoke particles and particles' average diameter, mass of particulates, sample and furnace temperatures, and sample weight loss. The data indicate that there are significant correlations between the percentage of chlorine or nitrogen contained in the original samples and the HC1 or HCN concentrations evolved during the combustion of the materials. These correlations may be used to predict and evaluate a material's toxic hazard during combustion.

Jan 1, 2010

By Walter T. Lewieki

"INTRODUCTION Numerous deposits of iron ore are found in Cherokee, Bartow, Floyd, and Polk Counties in northwest Georgia. The deposits are generally small and irregular in shape. The ore is usually referred to as ""brown ore"" and is predominately limonite. The crude or ""bank ore"" has to be washed and concentrated before being shipped.The proximity of the deposits to the Birmingham furnaces and a favorable freight differential permit the operation of many deposits that otherwise would be uneconomical. The district produced 413,468 long tons of brown-ore concentrates, averaging 45.53 percent iron in 1943.The necessity of developing additional iron-ore reserves for the war energeucy to supplement the production of the Birmingham district, prompted the Bureau of Mines to initiate exploration of the more promising northwest Georgia deposits. Thirteen properties in the four counties were explored during the program (fig. 1).HISTORY AND PRODUCTIONSeveral furnaces were operated in the district until the early 1900's, ranging from charcoal furnaces to more modern plants with capacities up to 50 tons of pig iron. No furnaces have operated for about 40 years, the product being shipped to Alabama and Tennessee.Bartow County iron mining is declining, although formerly it was the principal producer of the district. Most of the known merchantable ore deposits have been exhausted. For the past 3 years the Mitchell-Hodge mine has annually produced about 225,000 long tons of concentrates containing 46 to 43 percent iron and at present is the only large producer in Bartow County."

Jan 1, 1946

By Joseph J. Wallace

1. From the standpoint of present production and recoverable reserves, there are two beds of major importance in Allegheny County -Pittsburgh and Upper Freeport -and one of lesser importance -Redstone. 2. Known measured and indicated reserves in all beds, based on a minimum thickness of 14 inches and 1,800 short tons per acre-foot of coal in place, are estimated at 832 million short tons as of January 1, 1953. Of this total, 768 million short tons is in beds 28 inches and more thick. Areas in some beds were omitted from the estimate because available data relative to the bed characteristics are too meager for making an estimate that conforms with the definitions of measured and indicated coal adopted for this study. Should future drilling or development prove reserves in these areas, such reserves should be added to the total estimated reserves.

Jan 1, 1953