Search Documents

By S. Owada

A national project of ?Establishing ?Green-Hydrogen (G-H)? Society in Honjo-Waseda Area? is now being developed by Waseda University together with four other universities and ten companies. The project involves three tasks of technological development of, (1)?G-H? production, (2)?G-H? refining, transportation and storage, and (3)?G-H? utilization. This paper focuses the first task of ?G-H? production from aluminium dross. We developed the physical treatment process by combining selective grinding with vibrating rod mill and electrostatic separation, in order to produce two kinds of materials, one is metal aluminium concentrate to recover it and the other is raw material to produce ?G-H? and aluminium hydroxide which can be generated by the treatment with sodium hydroxide aqueous solution. Here, we described the concentration mechanism of metal aluminium in the selective grinding and electrostatic separation and proposed a separation flowchart for optimizing the ?G-H? system in Honjo-Waseda area.

Jan 1, 2014

By P. K. Sen, Mrinal K. Ghose

Tailing slurry is usually abrasive and possesses high viscosity. This paper examines the existing iron ore beneficiation process and focuses on some of the key environmental issues related to the disposal of tailings. It identifies that almost 32% of the iron ore extracted ends up as tailings and they are usually disposed in slurry form in tailing ponds. By the year 2000, 27 Mt of iron ore tailings were generated in India, which has become one of the biggest waste handling problems to the industry. Characteristics of the tailings vary widely. So the physical nature of tailings cannot be considered separately in isolation without considering the mill effluent from the beneficiation plant. In the present investigation, studies were carried out in three iron ore mines in India to evaluate the characteristics of tailings from the beneficiation plant. The tailing samples were collected from different locations during a time period of one year and analyzed. The results will be discussed and the characteristics of the tailings have been evaluated. The disposal system of tailings at the three mines was evaluated. The research on the settling characteristics of tailings indicates that the area provided in the existing tailing ponds in India is much more than that of the experimental results. This paper concludes that sedimentation tests are essential to design appropriate tailings pond with respect to size. In the proposed scheme it is suggested that an additional unit process, i.e. sedimentation tank be added to the process before the disposal of tailings to the tailing pond.

Jan 1, 2003

By John Starkey

"The development of the Minnovex SAG Power Index (SPI) Test in Canada has created a new and accurate way to measure ore hardness in a SAG environment. Coupled with the standard Bond Ball Mill Work Index Test it is now possible to determine from these two relatively inexpensive laboratory tests, the amount of energy required to grind an ore from the primary crushed size to the desired liberation size. By testing multiple samples to discover where the hard and soft ore zones are located, the representative hardness distribution for the ore body can be determined and grinding equipment selected that is capable to meet production targets for all mining areas of the deposit.In the last century, it was deemed prudent to select up to 50-tonne samples of ore for Semi Autogenous Grinding (SAG) pilot plant tests and a second 5-tonne sample for metallurgical pilot plant work. The methods outlined in this paper show how the 50-tonne sample is no longer required for SAG design because it is better to measure the representative hardness distribution of the ore body than the hardness of a “chosen” representative sample. This is demonstrated to be true by the fact that the lower horizons of an ore zone cannot initially be accessed to recover 150mm pieces, and the bulk samples taken, rarely represent the desired design hardness of the ore. Median hardness will not yield a good result in most cases and a clear understanding of the location and extent of the hardest zones is imperative to achieve a truly successful grinding circuit design.This paper discusses two plants (Kubaka and Agnico Eagle) that have been designed using SPI and Bond with no pilot plant test backup. Both have been very successful in that they can grind design tonnage on the hardest ores in the mine. This guarantees that the mine’s profitability is protected in any mining sequence. It also allows the extra power to be converted to higher throughput on softer ores if additional cash flow is needed. The advantages from the owner’s point of view are dramatic. This procedure will be attractive as well when considering the costs for test work, and the samples for testing. Existing diamond drill core is normally used and this allows the inclusion of data from the deepest regions of the mine. In addition, it is also clear that the decision to use a crusher can now be made at the design stage of a project based on measured parameters and the estimated capital costs of alternative designs."

Jan 1, 2003

By S. M. Viduka

This paper presents a numerical investigation of solid separation in jigging device, which is a gravity separation method widely used in ore processing. Separation is recognized as being heavily dependent on fluid motion in the jig. This study explores the effects of the inlet time dependent velocity profile on jigging performance. Modelling of the liquid-solid system is performed through a combination of computational fluid dynamics (CFD) to simulate liquid flow and discrete element method (DEM) to resolve particle motion. The initial packing conditions consist of a binary-density particle system of 1130 particles each 1 cm in diameter. A variety of jigging profiles are implemented in jigging. The saw tooth pulsation profile is selected with three variations in both amplitude and frequency. The performance of each profile variant is compared in terms of solid flow patterns, separation kinetics, energy, and mean particle position. These quantitative comparisons demonstrate significant differences in the segregation rate, energy, and solid phenomena, helping find an alternative optimum operating setting for the system.

Sep 1, 2012

By Mike Hollitt

The first decade of the 21st century was one of fundamentally changed dynamics for the minerals industry. Following intense globalization commencing in the late 20th century production is now concentrated into large businesses that can compete across geography in diverse commodities. Asian industrialization and urbanization is now the main driver of growth in demand for energy and materials. Demand for the output of these industries has risen sharply, reversing decade long trends to reduced real commodity prices. Supply responded with expansions of existing mining and processing operations, and large investment in new resource development. Development of new, lower grade or more remote resources was stimulated. Resource development by global entities in frontier environments reinforced the importance of effective forms of social contract, and of stronger environmental performance. The worst economic shock in decades provoked no significant pause despite large impacts on corporate ownership. State owned enterprises commenced unprecedented foreign direct investment in minerals and energy resources. A thrust towards resource nationalism re-emerged as governments sought to ensure that the export of state owned resources contributes more strongly to government revenue, reducing the burden of trade in scarce resources on other trade-exposed sectors. The unprecedented combination of forces at work has made future predictions difficult, with day-by-day volatility in anticipated corporate fortunes, and investment plans. The challenge for process innovation (and for exploration) has been to keep up, maintaining a lid on costs as lower grade and more challenging ore bodies are brought on quickly in a context of competition for land use, community expectations and continued care for natural and living environments. While new projects have provided the necessary platforms for implementation of innovative approaches, there is evidence that a gap may have emerged between the pace of growth and the pace of innovation. The history of a century of process innovation in the context of growth of output, declining resource grades and commodity prices is presented. The necessary conditions for accelerated process innovation are considered, and future needs and approaches are discussed. Keywords: process innovation, resource development

Sep 1, 2012

By S. M. Bradshaw, V. Rocher, L Kabondo, B. Combrink, C. A. Snyders

Media losses are a significant contributor to the operational cost in a dense media separation (DMS) circuit. Of these losses, up to 80 wt% can occur on the drain and rinse vibrating screens. Although these screens are an integral part of any DMS circuit, surprisingly little work can be found in open literature regarding the effect of aperture configuration on the drain rates (draining water and medium). To establish the effect of slot aperture size, experiments were conducted on a 0.6 x 1.2 m vibrating screen with polyurethane (PU) panels at slurry densities between 1.6 – 2.8 kg/L, and volumetric flow rates of 19 – 25 m3/h for both ferrosilicon and magnetite. Results showed that an increase in the volumetric flow rate led to an increase in drainage rate, moisture content and medium carryover. Once an optimum volumetric flow rate was exceeded, a further increase in flow rate resulted in a decrease in drainage rate with a sharp increase in moisture and medium bypass to the oversize stream. An increase in ferrosilicon slurry density led to a decrease in drainage rate with an increase in moisture and medium bypass with each of these rates increasing as the slurry density increased. For magnetite, a gradual decrease in drainage rate was observed with increase in slurry density and volumetric flowrate beyond the screen optimum point. It was found that an increase in aperture size from 0.63 x 8.8 mm to 0.8 x 8.8 mm to 1.0 x 13 mm resulted in an increase in ferrosilicon drainage rate of between 1.3 - 1.8 m3/m2/h depending on the flow rate and slurry density with a reduction in moisture and medium carryover of between 1.0 – 1.2 % and 14.1 – 20.2 kg/t/m respectively. For magnetite, the drainage rate increased between 1.0 - 1.4 m3/m2/h as the slot width increased from 0.63 x 8.8 mm to 0.8 x 8.8 mm while an increase in slot length from 0.63 x 8.8 to 0.63 x 12 mm only resulted in an increase in drainage rate of 0.1 - 0.5 m3/m2/h.

Jan 1, 2018

By Francesco Vegliò, Luigi Toro, Francesca Pagnanelli

Different hydro-metallurgical processes have been studied in order to recover manganese(II) from oxidised minerals such as MnO2. An innovative acid reductive leaching carried out in mild experimental conditions was here considered using agricultural and industrial wastes containing carbohydrates as reducing agents. The leaching process was investigated from a kinetic and equilibrium point of view in order to optimise the experimental conditions, develop a kinetic model and obtain high purity concentrated MnSO4 solutions. To study the leaching kinetic a Shrinking Core Model (SCM) was modified by a variable activation energy term to take into account both the variable reagent concentrations and the reaction rate change with respect to the manganese dioxide conversion. The influence of the particle size in the kinetic model is discussed with the support of SEM analysis before and after leaching. Manganese extraction yield was maximised (170-190 g/L) using appropriate carbohydrates and acid excesses, while impurity concentrations were kept low (Fe<10ppm and Ca<300ppm) pre-treating the ores, using hydro-alcoholic leaching medium and different combinations of down-stream processes. In particular precipitation, solvent extraction and adsorption onto active carbon were tested to eliminate Fe and Ca from MnSO4 solutions.

Jan 1, 2003

By Emile Scheepers, Chris Aldrich, Jacques J. Eksteen

The pneumatic injection of CaC2 powder into molten iron has become a very reliable and effective way to carry out desulphurisation. The key variables that influence the kinetics of this process are the condition and composition of the top slag, the oxygen activity in the hot metal and the injection conditions. Notable injection parameters include carrier gas flowrate, reagent flowrate, lance depth and initial sulphur concentration. A one-dimensional, steady-state model for momentum, heat- and mass transfer in rising gasliquid- powder plumes was developed for conditions relevant to the CaC2 refining process at Saldanha Steel?, South Africa. Combined with a model that predicts the contribution of the topslag to the process, the overall rate of desulphurisation as a function of time was determined, thereby quantitatively demonstrating the influence of the above-mentioned injection parameters on the kinetics of the desulphurisation process.

Jan 1, 2003

By Long Han, Jianyuan Liu, Ping Ying

"Particle-bed compressive stressing is the main work mechanism of comminution by high pressure grinding rolls(HPGR). An experimental study on comminution and mineral liberation of two copper sulfide ores was carried out using a piston-die compressive stressing rig to simulate the situation of comminution with HPGR as the final-grinding device. The tests carried out include compressive comminution tests on particle-bed with narrow-size feed, and the locked-cycle comminution test on particle-bed with broad-size feed, which was then compared to a corresponding locked-cycle test of ball-mill grinding. The narrow-size feed is made up of particles in the size range 2.36~3.35 mm, whereas the broad-size feed of particles in the size range 0~3.35 mm. The liberation analysis for copper-mineral in the comminution products was accomplished using BPMA system – an automatic mineral liberation analyzer developed by BGRIMM. The influences of the stressing intensity and the method of comminution on the copper mineral liberation are discussed in terms of product size distribution, copper-metal deportation among size fractions, distribution of copper mineral among particle-size and particle-grade classes, degree of mineral liberation in size class as well as degree of mineral liberation overall.INTRODUCTION Traditionally, comminution process commonly applied in mineral processing is a flowsheet consisting of crushing of crude ore with conventional crushers, followed by grinding of the crushed ore in tumbling mills. In last decades, the energy-efficient HPGR (high-pressure grinding rolls) has found its application in mineral processing, mostly as tertiary or quaternary crusher to generate a fine-crushed product either as feed to subsequent grinding or as feed to a pre-beneficiation process before further grinding. Compared with the process of conventional crushing followed by grinding in ball mill, this mode of HPGR-application can achieve energy saving to some extent by reducing particle size of the feed to ball milling, and by reducing amount of the feed to ball milling if a significant portion of tailings in relatively coarse particle-size range can be discarded at the pre-beneficiation stage. In recent years, the approaches of letting HPGR take more comminution work from ball mill by applying it in semi-finish grinding mode or even finish grinding mode have been discussed (Burchardt, 2014). Although HPGR finish-grinding has been successfully applied in the cement industry for grinding of cement clinker and raw materials, this mode of HPGR application has yet rarely been implemented in mineral processing, despite the advantage of more energy-saving and other potential benefits such as preferential breakage, internal damage of particles and enhanced mineral liberation which may lead to a better downstream processing performance. The reasons for the retardation of the progress of this kind of HPGR-application in the mineral industry lies not only in that a finish-grinding with HPGR has to be operated in dry condition whereas most of ore-beneficiation processes like flotation are operated in wet condition, but also in that there are large variety of ore materials with various complexity of processing technology, which need to be addressed on a case-by-case basis with a lot of test work, in order to evaluate the potential advantages or disadvantages of this application."

Jan 1, 2018

By F. Karakas

In this investigation, one of the most energy consuming stage of the cement manufacturing process, grinding stage, was studied. The aim of the study is to reduce the energy consumption. Optimum operating parameters were determined. Experimental studies were performed at three differ-ent stages. Grinding of limestone, clay and marl which are the main components of the cement, to approximately below 90 microns, was the first stage of the cement grinding. At this stage, effect of feed size and ball charge were investigated. At the second stage, the Bond work index of clinker and additives (slag, trass, limestone and gypsum) was found separately. After forming composite cement with clinker and additives, the Bond work index of this mixture was also determined, thus the results of separate grinding and grinding of mixture were compared. The Bond work index of mixture was found as 13.59 kWh/t, while the arithmetic mean of the Bond work index values of components was 14.90 kWh/t. Finally, clinker and additives (slag, trass, limestone and gypsum) were ground under the same conditions. At this stage, laboratory type of ball mill was used in order to understand grinding characteristics of the cement components. As a result of the experiments, it was found that energy consumption for the grinding will be lowered if the mills with 38 % ~ 40 % ball charge are used in the cement grinding. Moreover, grinding with mixture of clinker and additives gave better results than separate grinding of these components in terms of energy consumption.

Jan 1, 2014

By U. Dmitrakova, G. Sedelnikova, D. Kim, E. Savari

"The paper presents the results of research on the development of gold and silver extraction technology from refractory gold sulphide flotation concentrate of one deposits of Nord-East of Russia. The concentrate is due to the complex mineral composition. Gold and silver are finely disseminated in sulphide minerals (arsenopyrite and pyrite partially oxidized by 7-11%). These are characterized by high content of silver 219 g/t and sulphide sulfur 32%, the presence of poorly soluble silver minerals (silver sulfosalts, fahlore, finely dispersed hypergenic acanthite in iron hydroxides and jarosite, etc.), and impurity minerals capable of interacting with cyanide (pyrrhotite, marcasite, nonferrous sulphides) and causing higher than normal cyanide consumption. Pretreatment of refractory sulphide concentrate by biooxidation using a mixed association of mesophilic and moderately thermophilic bacteria at a temperature of 36-40 °C for 120 hours oxidized arsenopyrite by 97.5%, pyrite by 93.5%, unlocked refractory gold, and generally oxidized the minerals absorbing cyanide and oxygen before cyanidation. Further oxidation of these minerals-absorbents was facilitated by the aeration in calcareous medium of the solid biooxidation residues of the concentrate. Sorption cyanidation of the solid biooxidation residues with addition of lead (II) of recovered 91.2% of gold and 82.9% silver from biooxidation residue, compared with 80.1% and 46.6%, respectively, for sorption cyanidation without the preceding biooxidation step. Biooxidation of the concentrate prior to cyanidation improves the recovery of precious metals, especially silver, and significantly reduces cyanide consumption from 18.7 kg/t to 3-5 kg/t of concentrate. INTRODUCTION Biooxidation of gold sulphide concentrates using acidophilic microorganisms has been successfully applied worldwide (van Aswegen et al., 2007; Gericke et al., 2009; Sovmen et al., 2007; Sovmen et al., 2009). At least 15 full-scale plants for tank biooxidation of sulphide concentrates are presently in operation, and the construction of new ones is planned (Bulaev et al, 2015)."

Jan 1, 2018

By B. A. Kutlin, S. A. Ropeyko, N. A. Yurlova

"The aim of NPO RIVS research and practice activities is to minimize impact of the mineral processing plants (MPP) on environment by using new concentration methods, high-technology equipment, implementation of engineering solutions directed to reduce emission of polluting substances (PS) into atmosphere, application of low-waste technologies, decrease of water withdrawal from a surface water or groundwater source for process needs. In our studies environmental safety of mineral flotation is provided through technologies using highly selective chemicals, that leads not only to reducing reagent consumption, and production of saleable products of high content of extracted minerals, but also to reducing pollutant emissions, decreasing supply of surfactants (SAA) in natural geosystems, primarily, in ground and surface waters. Decrease of water withdrawal from a surface water or groundwater sources for process needs can be achieved by using closed circuits and waste water treatment for further use in process operations, recycled water conditioning to obtain optimum quality parameters for process operations of concentration. Concentration in water (wet processing), tailings dewatering and semidry and dry (filtration cake) stockpiling in tailing ponds, efficient dust-collecting systems contribute to pollutant emission reduction. Use of mineral wastes – concentration tailings as a source of valued components, facilitates efficient use of natural resources and reduces wastes and its impact on natural ecosystems due to smaller areas of damaged lands during waste products disposal. Process and engineering solutions of NPO RIVS that allow diminishing impact of MPP on natural environment (NE) have been implemented in mining and processing complexes of Russia, Kazakhstan, Ukraine, Kirghizia and Mongolia. Compliance with environmental safety requirements contributes to enhancement of mineral processing and sustainable mineral development.INTRODUCTION Mining and processing complexes have a significant impact on environment as a result of extraction and recovery of mineral resources, landscape changes, waste disposal and, as a consequence, pollution of soils, surface and underground water sources. Therefore, the aim of the operation of the mineral processing enterprises in its research and practical activities is to reduce impact on environment due to new beneficiation technologies, high-technology equipment, implementation of engineering solutions directed to reduce emissions of polluting substances (PS) into atmosphere, use of low-waste technologies, decrease of water withdrawal from a surface water or groundwater source for process needs. Compliance with the requirements of environmental safety encourages advancement of mineral processing technologies and sustainable mineral development. Concentration in water, tailings dewatering and semidry and dry (filtration cake) stockpiling in tailing ponds, efficient dust-collecting systems contribute to pollutant emission reduction. Use of mineral wastes – concentration tailings as a source of valued components, facilitates efficient use of natural resources and minimizes waste formation and its impact on natural ecosystems due to reduction of damaged land areas during waste disposal."

Jan 1, 2018

By S. P. Nagaeva, A. V. Kuptcova, O. Yu. Poperechnikova

"The present paper contains study results of gold morphology and grain size distribution in flotation concentrates produced from original ore samples from deposits of different genesis. Pre-concentration methods were used with selective dissolution of rock minerals and mineral heavy medium separation to obtain statistically valid data on gold grain size and morphology in concentration products. Special attention is given to study of flash flotation concentrates that is mainly used for coarse gold, underextracted in gravity circuit. Analysis of geometrical optics has allowed to establish that during flash flotation gold grains more than 150 µm can be extracted from 10 to 35%, and in some cases single gold grains above 300 µm. INTRODUCTION Distinctive features of gold that have a significant impact, and in some cases, decisive influence on its recovery into saleable products are mineral shape, grain size and morphology of metal particles, paragenetic associations of gold. Peculiar feature of coarse gold is its easy extraction during grinding from associated mineral components like quartz, sulphide and other and almost complete recovery into gravity concentrates (Lodeischikov V.V., 1997). Morphology of native gold is so diverse that different gold grains are better extracted using different methods of concentration. Compacted and rounded particles are easily processed using gravity concentration but low cyanidable and hard to process using flotation. On the contrary, lamellar, flake, dendrite and capillary aggregates of high specific surface are easily cyanidable and under definite conditions it has strong floatability (Lodeischikov V.V., 1997). Flotation of gold-containing sulphide minerals and free gold takes place simultaneously during flotation concentration. In case of low-sulphide ores, native gold takes the basic load, having the high density (15.6 to 18.3 g/cm3, for pure gold – 19.3 g/cm3) it has limited size and morphology for successful flotation. It is known that flake gold and fine-grained gold up to 0.1 mm are easily extracted (Lodeischikov V.V., 1997). Authors of the present paper performed a study of gold granulometry and morphology in flotation concentrates produced from gold-containing ores from two deposits of different types: gold-copper oxidized hematite ores and low-sulphide gold-quartz ores. Ores are different by both host rock composition, mineralogical and petrographic features, gold grade in mineral assemblage and morphology and size of precious metal. Common for both ore types is low-sulphide content and presence of free gold."

Jan 1, 2018

By Fangming Liu

The key problems of current flowsheets and equipments are analyzed. A new steel slag&apos;s crushing flowsheet whose key equipments are the improved inertia cone crusher and inertia vibrating jaw crusher is proposed. An advanced two stage open-circuit crushing method is adopted in the flowsheet, with 90% of particle size crushing under 6mm. Using inertia vibrating technology and selective crushing principle the crushers can realize steel slag separating fully into steel and slag and with flexible transmission mechanism the crusher can be protected when iron lump is passing. The flowsheets can enhance the recovery of metal greatly, and expand the application range of tail slag and added value.

Sep 1, 2012

By S. Z. Shafaei

An experimental investigation has been carried out using a laboratory scale Denver flotation cell. For evaluation of cokeable coal of Alborze Sharghi coal washing plant, the full factorial method was used to statistically design and analyse the experiments. The 2 factorial interaction model were developed for combustible recovery and ash content as response and diesel dosage, conditioning time, feed percent solids and rotor speed as factors. Model validation and residual analysis were con-ducted and results indicated that the fitness, predictability power and residual distributions of models were good. The effect of parameters and interactions were examined and it has been demonstrated that rotor speed, solid percent and interaction between diesel dosage and solid percent were more important terms of all responses. A product with approximately 78% combustible recovery and 10% ash content was obtained at 4000gr/ton diesel fuel oil (high level), 30 sec conditioning time (low level), feed percent solids of 15% (low level) and 800 rpm rotor speed in appropriate condition.

Jan 1, 2014

By T. B. M. Himawan

In this study, effect of thiosulphate and oxidation using oxygen were studied in arseno copper ore flotation. Single mineral study of chalcopyrite and tennantite in regard to the aforementioned techniques was also studied. Zeta potential, XPS, contact angle and floatability of single minerals were conducted for each treatment to understand the mechanism. It was revealed that the separation is best conducted in alkaline condition at where there will be interaction between thiosulphate and the mineral surface as well as the formation of hydroxide species in the oxidation using oxygen. From zeta potential of both thiosulphate and oxidation conditioning, it can be found that the reactivity of tennantite is much higher rather than chalcopyrite resulting higher rate of depression on both techniques as shown from contact angle and floatability of each mineral after treatment. XPS spectra confirmed qualitatively and quantitatively the existence of species responsible for the depression of each conditioning techniques. As for the copper ore flotation test, it is the oxidation using oxygen provides best performance after 60 minutes of oxidation. Keywords: tennantite, chalcopyrite, arseno copper ore A, thiosulphate, oxidation using oxygen

Sep 1, 2012

By Robin J. Batterham

The Bologna Process started in 1999 with a declaration signed by ministers from most European countries. As of 2012, the Bologna Process now has 47 participating countries (EHEA 2012). Overall, the Bologna process has demonstrably changed higher education in many countries to allow for considerably more flexibility in course offerings. Keywords: bologna model, education

Sep 1, 2012

By B. Tora

Coal mining activity is inextricably connected to waste production. These include coal slurries deposited in environment. Current knowledge in the field of mining and especially mineral processing allows extracting valuable fuel from deposit coal slurries. The article discusses of previous works devoted to coal slurries inventory in Jankowice Mine in Poland (Upper Silesia) and quality assessment of coal slurries. 12 samples of coal slurries deposited in waste pond of Jankowice Mine was taken for the investigation. Total amount of wastes deposited is more than 100 thousands tones. Keywords: re-flotation, coal wastes, waste storage, industrial verification

Sep 1, 2012

By Ata Akcil, Z. B. Karshigina, Ye. G. Bochevskaya, E. A. Sargelova, Z. S. Abisheva

Phosphorus slag is one of the most large-tonnage of yellow phosphorus production waste, which for decades stored in the slag disposal, by polluting the environment and creating environmental problems in the regions. Phosphorus slags from the processing of Karatau phosphorites are a very promising source of raw materials not only for silicon compounds but also rare earth metals (REM). Among the REM, yttrium, neodymium, europium and lutetium predominate, which are relevant to high-tech industries. The report presents technological scheme of complex processing of slags of phosphoric production with obtaining of REM concentrate and precipitated silicon dioxide ("white soot"). The regime parameters of the main operations of the technology are determined: I stage- leaching of slag with nitric acid solution; extraction of the REM-containing solution with tributyl phosphate and stripping of the REM with water; settling of solution of salts of oxalic acid, calcining the precipitate to obtain a concentrate S REM oxides and II stage of leaching silicon cake to obtain "white soot". Recovery of S REM from slags of phosphoric production on various redistribution has made, %: leaching – 95.0; extraction - 90.2; extraction on the average ~ 93.2; the production of a concentrate of REM oxide is 93.9. A concentrate containing 17.3 % of REM oxides was obtained. According to X-ray analysis it contains the following phases: calcium oxide, portlandite2, gadolinium oxide and yttrium, gadolinium oxide, gadolinium oxide and cerium, neodymium oxide, neodymium oxide and cerium. Thus, the concentrate can serve as a raw material for the production of individual rare-earth metals like gadolinium, cerium, yttrium and neodymium. After performing the II stage of leaching siliceous cake with nitric acid the samples of "white soot" were obtained. Its chemical composition corresponds to the state standard and has a specific surface area equal to 180 - 200 m2/g. The technology has been tested in a large-scale laboratory scale and will solve the problem of complex processing of phosphorus raw materials and import substitution in Kazakhstan. The end-to-end recovery of S REM oxides and silicon into concentrate and product from their initial content in slags is ~ 75.0 and 98.0 %, respectively.

Jan 1, 2018

By Gabriela Pino, Maurício Torem, Diego Veneu

Because of its simplicity, economy and biocompatibility, research regarding the use of microorganism for decontaminating heavy metals produced by many industries is an area of growing interest. Also, there is a stringent need for the control of toxic metals produced during various production processes and released into the aqueous environment in order to avoid damage relevant to soil or groundwater contamination. Among the available treatment technologies, sorptive flotation has been considered as a promising alternative for the wastewater treatment. In the present study Streptomyces lunalinharesii strain was applied as bioreagent for the removal of copper, cadmium and zinc. The removal of those metal ions depends mainly on the respective pH value, influencing the aquatic speciation during the process, as well as the zeta potential of the system and biomass concentration. Langmuir and Freundlich isotherms have been depicted. Dispersed air flotation was applied as the subsequent separation method for harvesting the suspended metal laden microorganisms, following the biosorption of copper, zinc and cadmium. The investigated parameters (in batch mode, laboratory scale) were in this case the saturator pressure, the coagulant concentration and the recycled flow. Applying the optimum defined conditions, over 60% removal of metal ions have been achieved in one stage and simultaneously, quantitative separation of the used (metal-loaded) biomass has been obtained.

Jan 1, 2014