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By I. A. Cameron, F. Ham, R. Sriram

"Planned increases in electric furnace productivity and higher matte temperatures needed for the Sudbury Smelter's S02 Abatement Plan, require an improved matte tap hole. Since startup in 1978, the matte tap holes have been incrementally improved by the addition of copper cooling blocks around the refractory tap blocks. These improvements provided a tap block life of about 100 taps per campaign.In July 1993, a prototype matte taphole was installed in Number 2 Electric Furnace to develop the technology to increase tap hole service life. The design was based on a heat transfer model of the tapping process to determine candidate refractory materials and cooler arrangements. The prototype tap hole features increased copper cooling, high conductivity refractories and extensive instrumentation. Eight trial campaigns are reviewed outlining the performance of silicon carbide and graphite refractories and typical heat loads during tapping.IntroductionFalconbridge Limited operates two 36 MYA, 6 electrode submerged arc electric furnaces in Falconbridge, Ontario. The furnaces, commissioned in 1978, smelt a partially roasted nickel-copper calcine, to produce matte for converting and slag for discard. Additional details of the smelter are available in the literature(1-4).Each furnace was equipped with two matte tap holes located in the furnace end wall. Early in the campaign, matte tap holes were identified as a weak area in the furnace which could be improved. From 1981 to 1987, incremental improvements were made to the design by the addition of water cooled copper blocks. In 1993, a prototype matte tap hole was designed and installed in Number 2 electric furnace to develop the technology to increase tap hole service life. Improved service life is required to meet planned increases in electric fWl1ace productivity and the higher matte temperature needed for the smelter's S02 Abatement Plan.This paper reviews matte tap hole development since 1978; outlines the prototype matte tap hole design, refractory selection and installation; and details the performance of the prototype tap hole during the first eight campaigns."

Jan 1, 1995

By N. Djilali

Many of the transport phenomena encountered in proton exchange membrane fuel cells occur intrinsically at the microscale level. Physically representative models that fully account for the salient physico-chemical and transport processes in PEM fuel cells are necessary to achieve truly predictive models that can be used with confidence to: (i) gain a better understanding of in-situ processes and couplings, (ii) explore new concepts, and (iii) support design and optimization. The development of more general, rationally based macroscale models requires use of knowledge on the microscale level to provide guidance, and to determine the required parameters and coefficients (model "constants"). In this paper we present a new membrane transport model, the binary friction membrane model (BFM2), recently developed to account for coupled protonic and water transport in polymer membranes. This general model is based on rational and physical consideration, removes several of the limitations of the empirical models used to date, and is formulated for all purfluoro-sulfonic acid membranes. The use of the BFM2 in a fuel cell model is illustrated highlighting significant performance predictions compared to existing empirical model. The second part of the paper addresses the fundamentals of two-phase transport in hydrophobic gad diffusion media. Computational and experimental visualizations resolving the microscale dynamics of water transport between the fibres of a GDL are presented, revealing transport mechanisms that are, contrary to assumptions used to date, dominated by fingering and channeling.

Jan 1, 2005

By W. Gan

The interactions between bitumen and quartz sands in aqueous solutions were studied with the objective of recovering residual bitumen from Athabasca oil sands froth treatment tailings. It was observed that the presence of various multivalent metal cation (Fe3-, Fe2+, Mg2+,Ca2+, etc.) increased the mutual coagulation between quartz particles and oil or bitumen droplets within certain pH ranges. While the increased coagulation was detrimental to the recovery of the bitumen since it lowered the degree of bitumen liberation from sands, this effect could be reduced or eliminated by the addition of organic chemicals such as citric acid, oxalic acid and EDTA. Among these organic chemicals, citric acid was found particularly effective even at very low concentration.

Jan 1, 2006

By S. I. Vobnout, J. Wm. White, J. P. Olson

"Mine management now recognizes the value of computer-based truck-shovel dispatching in open pit mines. The key tangible benefits are substantial productivity increases with a given fleet of equipment or, alternately, significant reductions in equipment required to meet production quotas. In this paper, the authors review the literature, report on efficient, optimal algorithms for haul truck dispatching in real-time, and briefly discuss methods used by various mines to evaluate productivity improvements over manual methods. Actual results obtained at thirteen mining operations around the world are also presented.IntroductionModular Mining Systems manufactures, installs, and supports its computer-based DISPATCH system at mines worldwide. DISPATCH is a large scale, computer-based mine management system which controls the dispatching of all haul trucks in any open pit mine (Fig. 1). When increased production is important, DISPATCH gets the needed production increase with fewer new or recommissioned trucks. DISPATCH also helps operations meet its blending objectives while minimizing rehandle and maintaining production. Furthermore, DISPATCH includes a powerful, eventdriven simulation subsystem. With the simulator mine management can pose ""what if' situations and see the predicted effect on production"

Jan 1, 1993

By M. G. Rylatt, G. M. Popplewell

"Production from Canada's first diamond mine is planned for the last quarter of 1998. The climatic conditions and the variation in kimberlite types to be treated have lead to the development of a compact and flexible processing plant.High kimberlite moisture contents and winter temperatures below -40°C have dictated a process flowsheet with limited in-circuit storage to reduce materials handling difficulties. The latest developments in High Pressure Grinding Roll technology will be used to liberate the valuable diamond, reduce diamond breakage, and increase fines production to reduce the amount of material for down stream processing in the Heavy Medium Separation section.A varying heavy mineral concentrate yield has lead to the development of a final Recovery section that will incorporate Attrition Milling and Wet High Intensity Magnetic Separation for concentrate reduction. The latest developments in diamond X-ray sorting will be used to produce a final diamond concentrate for mechanical sizing, weighing and packing.Fine tailings thickening will utilise Deep Bed Compression type thickeners. This relatively new technology can produce;i) high underflow densities at low flocculant dosage rates, andii) clear overflowswith a smaller thickening area than conventional high-rate thickeners."

Jan 1, 1998

By G. Begin

"The expansion undertaken at Selbaie in 1985 necessitated an adaptation and expansion of the equipment maintenance system. This paper relates briefly the stages of transformation of the maintenance administrative structures, work methods and tools. The maintenance in a mechanized mine requires an expenditure level in the order of 20% of the total operating cost of the enterprise. Thus, the maintenance organization was modified to apply more computerized planning and follow-up, and the role of preventative maintenance was further advanced.IntroductionAs far as maintenance is concerned at Selbaie, the scenario described herein is a resume of the current situation. Although positive results have been obtained, this outline is in no way a detailed account of a fail-proof maintenance system.Once zone A-I was put into production, the expansion the mine experienced in 1985 had a direct impact on the equipment maintenance system. As centralized as it was in the beginning, the system is now partially decentralized.The over-all changes to the maintenance department demonstrate the flexibility required by organizations in new situations. In spite of the exceptional results obtained before the expansion, it became evident that both the maintenance and production sectors would have to be combined. In doing so, a more appropriate coordination of maintenance work could be obtained and the maintenance staff would obtain a more detailed knowledge of the equipment in each sector. In addition, by keeping the general and specialized departments centralized, it was possible to offset the negative effect s of a decentralized system, namely too much manpower."

Jan 1, 1990

By C. Díaz, A. D. Dalvi, C. E. O'Neill

Roast-reduction smelting (RRS) of nickel concentrate, combined with flash smelting of copper concentrate, was one of the process options that Inco considered as a means of meeting its 1994 sulphur dioxide abatement target at its Copper Cliff operations. RRS involves deep roasting the nickel concentrate in fluid bed roasters. The roaster off-gas is treated in a sulphuric acid plant, and the low sulphur calcine is reduction smelted with coke in an electric furnace to yield a sulphur- deficient matte. The latter material is converted to Bessemer matte in Peirce-Smith converters, with minimal evolution of sulphur dioxide, and the converter slag is reverted to the electric furnace. Excellent nickel and cobalt recoveries (Ire obtained. This paper discusses the development of RRS, including extensive commercial scale testing at Inco's Thompson Smelter, and its key operating parameters.

Jan 1, 1994

By John Drobe, Robert M. Cann

"Abstract - The Minas de Oro Cu-Au skarn and replacement deposits are located in the highlands of central Honduras, 90 km north-northwest of the capital of Tegucigalpa.The deposits formed in Cretaceous volcano-sedimentary rocks following the emplacement of an early Paleocene granodiorite to dacite intrusive complex. Three types of skarn (Type IA, IB, and IC) and a low-temperature replacement mineralization (Type II) are recognized. Type IA skarn consists of massive brown-green andradite and lesser magnetite and pyroxene. Type IB skarn has magnetite + hematite as the main constituent and garnet <50%. Type IC skarn comprises >50% pyrrhotite + chalcopyrite with interstitial garnet or pyroxene. Au and Cu occur in potentially economic concentrations in all skarn types while other metals such as Ag, Pb, Zn, and Mo are locally present in significant quantities. The highly variable distribution and nature of the skarn deposits is controlled by: (1) intrusive activity, (2) composition of host rocks, (3) faulting and fracturing, and (4) attitude of host carbonates.Type II Au-Cu-As mineralization occurs in calcareous sandstone and conglomerate 2 km distal from skarns and comprises clots of Cu sulfides hosted within a zone of brecciation and quartz flooding. Garnet and/or magnetite skarn is not present and the mineralizing event appears to have been a low-temperature replacement type.The similarity of coeval Au-Cu-Fe skarns in central Guerrero, southern Mexico to Minas de Oro skarns, and the similar local stratigraphy is consistent with the generally accepted theory that the Chortis block originated from southern Mexico and during the Tertiary moved southeast to its present position."

Jan 1, 2000

By R. Sage, N. Rillette, M. D. Everell, G. Herget

"CANMET has been operating as a Government Technology Centre for two years. Many of CANMET&apos;s programs involve long-term research and require special expertise, often available at Canadian universities. CANMET&apos;s involvement with universities ranges from research grants and contracts to exchanges of scientists and joint use of research facililies. Examples of CANMET - university cooperation in mining are presented. IntroductionIn the last two years or so CANMET has undergone a significant metamorphosis, resulting in greater emphasis on applied research to enhance Canada&apos;s industrial capability. CANMET&apos;s new mandate is reflected in the types of projects undertaken and their categorization, (Fig . I). Emphasis is being placed on two project categories: strategic R&D, to enable CANMET to serve the changing technological needs of the industry; and incrernental R&D, to serve the more immediate industry needs through modifications to existing technologies and knowledge. The balance of CANMET&apos;s e ffor t is devoted to providing Mandated and Specialized Services, and to Exploratory Research.CANMET interaction with universities can involve one of several available vehicles : contracts, research grants, exchanges of scientists , student employment and nomination of professors on CANMET&apos;s advisory council. Instances of key university technical support to CANMET mining projects are highlighted."

Jan 1, 1990

By J. Dufour

Although the recovery of nitric and hydrofluoric acids from stainless steel pickle liquors has been solved by several methods, such as solvent extraction, acid retardation, evaporation or pyrohydrolysis, metals (mainly iron, chromium and nickel) are usually obtained as a waste or by-product that has to be disposed. Alternatively, the treatment requires a high liquor flow to be economical, as is the case for pyrohydrolysis. A new process has been developed for metals recovery, that produces metal oxides with a low fluoride content. This new technique is based on a selective precipitation mechanism, which produces nickel hydroxide with a purity of 90%, separate from a mixture of iron and chromium oxides and hydroxides suitable for recycling. The reaction mechanism is based on the precipitation of fluoride compounds of iron and chromium, K2FeF5 and CrF3. For this purpose, free fluoride must be added as potassium fluoride. Also, solid fluoride compounds are hydrolysed, releasing free fluoride. A part of the fluoride is recycled to the selective precipitation operation and the remainder is fed to the acid recovery stage. Nickel does not react in this operation; it remains in solution giving a high separation yield.

Jan 1, 2006

By A. Plugatyr, C. P. Baxter

"Bessemer matte iron content is a critical process parameter that needs to be closely monitored and controlled in order to achieve optimal Ni/Cu smelter returns. Current process control practices during Ni/Cu converting often rely on visual observations and typically involve matte sampling to confirm that target composition was reached. A high-level techno-economic analysis study was carried out to evaluate potential direct benefits of advanced process control during the final stages of Ni/Cu matte converting. The results indicate that the magnitude of direct benefits will largely depend on matte iron control practices already implemented as well as matte iron set point. Preliminary assessment suggests that under the assumptions used in this study, implementation of advanced process control can potentially result in additional revenues ranging from several hundreds of thousands to tens of millions of US dollars per year per converter producing about 200 tonnes of Bessemer matte per day based on Ni, Cu, and Co metal recoveries alone.INTRODUCTION Real-time measurement of molten metal elemental composition, arguably, remains one of the key unresolved issues impeding full automation and real-time optimization of pyrometallurgical operations in different industrial areas, including non-ferrous metals and ferro-alloys. In particular, current process control practices during Ni/Cu matte converting often rely on visual observations and typically involve matte sampling in order to confirm target matte composition. In addition to being time consuming, this approach relies heavily on operator experience and diligence, and, therefore, requires continuous performance and quality control efforts. For instance, the need to improve quality of the Bessemer matte (BM) at the Copper Cliff smelter has prompted an impressive staff engagement and training campaign that was carried out by Vale’s team in the late 2000’s (Zanini, Wong, & Cooke, 2012). This training exercise was executed to address the compounded effect of several operational challenges, namely demand for higher throughputs, changes in the feed concentrate composition, increased feed variability, loss of process knowledge and expertise due to retirement, as well as lack of a comprehensive approach to improving the overall performance of the flowsheet rather than meeting production targets for intermediate products. Although the campaign was very successful and has resulted in significant improvements in the Bessemer matte quality, it has also highlighted the need to move away from “the-art-of-converting” and develop analytical tools that would enable real-time process monitoring."

Jan 1, 2018

By Mihaita Matei

An adaptive approach to control the deformation in tube hydroforming process is presented. This requires: the use of an existing non-linear FE software (ABAQUS) that incorporates a user material model (VUMAT), the development and implementation of an adaptive control strategy to coordinate the internal pressure and the axial load so as to prevent fracture and wrinkling failures (knowledge-base controller) and the application of the developed adaptive simulation approach for finding the optimal loading path required to hydroform a defect-free part with as uniform thickness distribution as possible (user&apos;s load subroutine (VDLOAD). In order to validate the approach, the case of conical hydroforming and the case of bending followed by hydroforming component is discussed.

Jan 1, 2011

"Cambior currently has nearly 80 exploration properties, acting as operator on about 60 of these. The company&apos;s exploration budget has increased to over $11,100,000 for 1990. On-going efforts recently yielded a new gold discovery on the Douay- Vezza property, a joint venture project with Inco and Vior. Cambior continues to seek out new opportunities, recently acquiring an option agreement on the Sleeping Giant project in Quebec and four new exploration agreements in the United States, through its Reno office. Other nearly-concluded joint venture agreements have also given the company entries into Indonesia and Guyana.SummaryWhen it acquired SOQUEM&apos;s assets on August I, 1986, Cambior also acquired interests in 45 exploration projects. The subsequent mergers with Aiguebelle Resources and Sullivan Mines in 1987 brought the total number of exploration projects to 83, most of which are concentrated in northwestern Quebec. Cambior&apos;s strategy emphasizes gold exploration, and exploration activities were, therefore, initially limited to the Val d&apos;Or and Rouyn-Noranda mining camps, where Cambior has a large portfolio of properties. Approximately $25.8 million has been spent on surface exploration in this area since the formation of the company, resulting in the discovery of the Mouska deposit and four sub-economic zones on the Porcupine, Forbex, Bloc Sud and Flavrian project s. In 1988, Cambior became involved in projects in the United States to which the company expects to allocate about 38070 of its 1989 exploration budget."

Jan 1, 1990

By Z. Trojanová

The deformation behaviour of ternary magnesium alloys AJ (Mg-Al-Sr) and AX (Mg-Al-Ca) were investigated in tension as well as compression tests. The samples were deformed at temperatures between 20 and 300 °C and at an initial strain rate of the order 10-4 s 1. The flow stress decreases with increasing temperature. The macroscopic work hardening rate decreases with increasing flow stress and temperature. The stress and temperature dependence of the work hardening rate is a result of the hardening and softening processes. Stress relaxation experiments were performed in order to reveal features of the thermally activated dislocation motion. Internal and effective stress components of the applied stress were estimated. A decrease in the internal stress was observed at elevated temperatures, which indicates recovery process (-es). A more detailed analysis of the estimated values of the activation volume and activation energy helped to interpret the thermally activated processes during plastic deformation. It is concluded that the deformation behaviour of the alloys depends on the activity of non-basal slip that is strongly influenced by temperature.

Jan 1, 2007

By J. A. Eisele, D. L. Pool

"The Bureau of Mines has developed a particle agglomeration technique to improve the flow of leaching solution through heaps of low-grade gold-silver ores which contain clays. Benchscale experiments and industrial practice have shown that the percolation rate of cyanide leaching solution is greatly enhanced by mixing the ore with Portland cement as a binder, moistening the mixture, mechanically tumbling to form agglomerates, and aging before heap building and leaching. A slight modification ofthe technique allows its application to precious-metal-bearing tailings, which cannot normally be treated by heap leaching because they are too fine. IntroductionMany low-grade gold and silver deposits and tailing materials from former mining operations in the western United States are potential sources for precious metals. These sources are too low grade or too small to support the capital cost of a conventional cyanidation plant but have stimulated the development of lowcost procedures, such as extraction of the precious metals by heap leaching with cyanide. The Bureau of Mines has investigated methods to improve the recovery ofgold and silver by heap leaching these low-grade materials.For heap leaching to be successful, the crushed and stacked ore must have good permeability so that uniform distribution of the cyanide leaching solution through the heaps can be achieved. Some of the most difficult gold and silver ores to treat by heap leaching are those containing excessive amounts of clays, or fines generated during crushing. Excessive amounts of slimes, generally minus 50-micrometre or 270-mesh Tyler sieve size particles, in the heap feed will slow the percolation of the leaching solution, cause channelling, or produce dormant or unleached areas within the heap, resulting in long leaching periods and low extractions. In extreme cases, the clays or slimes can seal the heap and cause the leaching solution to run off the sides of the heap rather than through it."

Jan 1, 1987

By W. Evans, C. E. Ells

Nuclear power reactors using zirconium alloy pressure tubes generate electricity in several countries. Such reactors are particularly important in Ontario, where CANDUs* generate about 30% of the total electricity produced in the Province. Starting with the commitment of NPD-2 in 1956, the pressure tubes of the first five CANDU reactors were made of coldworked Zircaloy-Z, an alloy of Zr and Sn. This alloy was developed by the US Navy, but the decision to use it in a cold-worked condition was based on AECL work. In 1958, the USSR published information on a new alloy, Zr-2.5 wt% Nb. The Nb promotes stabilization of the (3-phase in the material, thus presenting opportunities of exploiting metallurgically strong pressure tubes analogous to the heat-treatable cx-{3 titanium alloys. After construction of two reactors using Zr-2.5 wt% Nb in a quenched and aged condition, an extensive development program on cold-worked Zr-2.5 wt% Nb pressure tubes resulted in them becoming the reference tubes for all CANDU reactors committed since 1966. Anticipating the future needs of the domestic and export markets, AECL have pressure tubes of Zr-3.3 wt% Sn-0.8 wt% Nb-0.8 wt% Mo (Excel) in an advanced state of development. These tubes will be used in an annealed condition; our projections show that they will have improved dimensional stability over the lifetime of the reactors. These improvements result from experimental programs leading to an understanding of the relationship between microstructures and fabrication variables and effects of the environment during service in nuclear reactors.

Jan 1, 1981

By Bradford P. Simser

The theoretical capacity of various ground support components can be misleading, especially in bursting ground where the failure mode is often in the retainment system. Wire mesh screen seams often peel open rather than breaking the wire strands, fractured rock often un-ravels around the bolts rather than breaking the bars. If a weak link(s) in the system fails prematurely, then the potential capacity of the system may never be fully realized. Underground observations are used to show how some support systems behave in the field. Various combinations of wire mesh screen with friction bolts, rebar, modified conebolts, cablebolts, shotcrete and mechanical rockbolts are considered. A short case history is used to contrast the performance of ?just-intime? development in a high stress faulted area versus a tunnel subjected to multiple stress changes in a similar environment. The latter proved to be a serious ground support problem when the well developed fracture zone around the opening was subjected to dynamic loading from a large seismic event causing a severe rockburst. In such cases an improved mining strategy may be more relevant than higher capacity support systems.

Feb 1, 2008

By J. G. Cullain

In conjunction with the over-all goals of energy conservation at Inco Metals Company, a program of improvement in compressed air utilization was established. Air flows were monitored and compared to calculated requirements to establish efficiency by area. With the cooperation of area management, measures were implemented to reduce nonproductive usage. At the operation, annual savings in power consumption alone were 80,000 dollars. The program is being extended to other mine areas within the Division.

Jan 1, 1979

By P. I. Laforest, M. S. Moats

"Antimony in smelted copper anodes has been shown to cause problems in electrorefining including brittleness of starter sheets. In order to improve deposit properties, a study was conducted examining the effect of anode chemistry on cathode ductility and electrolyte chemistry. Two industrial anodes with different molar ratios of As/(Sb+Bi) were used in laboratory electrorefining experiments with commercial electrolyte, and the addition of commercial glue and Avitone. The ductility of 21-hr copper deposits was evaluated by a 180° bend test. X-ray diffraction (XRD) and metallography were performed on unbent specimens to characterize the deposit structure. Increasing the anode As/(Sb+Bi) molar ratio from 0.54 to 3.8 resulted in an increase, on average, from four to eight bends to failure in cathode material produced. Significantly lower concentration of antimony (V) in the electrolyte was detected when operating with the higher molar ratio anode. The presence of (111) and (200) planes was noted in cathode material produced from the higher molar ratio anode suggesting that mixed growth character could be responsible for the observed increase in bend test results. The ductility of the starter sheet materials was improved by a higher anode molar ratio.INTRODUCTIONThe presence of antimony in copper electrorefining electrolyte has been reported to cause problems in cathode production (Hiskey, 2012; Peng, Zheng & Chen, 2012; Wang, Chen, Zhou-Lan & Lian-Sheng, 2006; Wang, Chen, Zhou-Lan, Wang, Xiao & Zhang, 2010; Wang, Chen, Zhou-Lan, Wang, Xiao & Tang, 2011; Wesstrom, 2014). To better understand the impact of antimony, laboratory scale electrorefining experiments were conducted using industrial inputs (anodes, cathodes and electrolyte). The influences of anode chemistry on the valences of antimony and arsenic in the electrolyte were monitored and correlated to physical cathode characteristics, such as a bend test to failure and crystallographic orientation.Commercially, starter sheets are produced by electrorefining impure cast copper anodes onto titanium blanks. The starter sheets are then hung in an electrorefining or electrowinning cell using loops of bent starter sheet material. These loops, in the absence of sufficient ductility, fail resulting in cathodes falling into the electrolysis cells. It is thought that the reduction in ductility can be related to anode composition; in particular, the molar ratio of arsenic to antimony plus bismuth As/(Sb+Bi). It has been stated that maintaining this ratio above 2:1 results in numerous improvements to electrorefining operations (Baltazar, Claessens & Thiriar, 1987; Kamath, Mitra, Radhakrishnan & Shetty, 2003; Krusmark, Young & Faro, 1995; Noguchi, Itoh & Nakamura, 1995; Wenzl, 2008)."

Jan 1, 2016

By X. W. Yi, Z. J. Li, G. W. Ma

In this paper, the compressive strength and failure patterns of reinforced cemented paste backfill (CPB) were studied aiming to promote the stability of backfilled stopes. The concept of ductile backfill was proposed and a series of unconfined compression tests were carried out on both non-reinforced and reinforced cemented paste specimens. Portland cement (3% to 5% by weight of tailings) and five different types of ductile materials (0 to 0.5% by weight of solids) were employed in this experiment for the specimen preparation. The test results showed that inclusion of ductile materials enhanced the unconfined compressive strength (UCS), reduced the post peak stress loss and transformed the failure behaviour of specimens from classical brittleness to ductility. The strength of CPB reinforced with different proportions of polypropylene fibres was compared. The stress-strain curves illustrated that both cement and fibres contributed to the increase of UCS, but higher strain values at the peak stress were achieved by fibre reinforcement. CT sliced images acquired from X-ray computed tomography (CT-scan) demonstrated that the reinforced specimen developed irregular crevices at the edge of cross sections and gained the capacity of bearing large displacements owing to the mobilised tensile strength of fibres. It leads to the potential of avoiding unexpected falling blocks of CPB when adjacent mining occurs. This finding highlights a strategy to improve the self-supporting capacity of the fill mass with less cement usage and reduce the ore dilution rates when excavating to adjacent stopes.

Jan 1, 2015